AU2011273331B2 - Suspension smelting furnace and a concentrate burner - Google Patents

Suspension smelting furnace and a concentrate burner Download PDF

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Publication number
AU2011273331B2
AU2011273331B2 AU2011273331A AU2011273331A AU2011273331B2 AU 2011273331 B2 AU2011273331 B2 AU 2011273331B2 AU 2011273331 A AU2011273331 A AU 2011273331A AU 2011273331 A AU2011273331 A AU 2011273331A AU 2011273331 B2 AU2011273331 B2 AU 2011273331B2
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Australia
Prior art keywords
reaction gas
fine solids
channel
cooling block
gas channel
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AU2011273331A
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AU2011273331A1 (en
Inventor
Tapio Ahokainen
Peter Bjorklund
Mikael Jafs
Kaarle Peltoniemi
Lauri P. Pesonen
Kari Pienimaki
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Metso Metals Oy
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Metso Metals Oy
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Assigned to Metso Outotec Finland Oy reassignment Metso Outotec Finland Oy Request to Amend Deed and Register Assignors: OUTOTEC OYJ
Assigned to METSO METALS OY reassignment METSO METALS OY Request to Amend Deed and Register Assignors: Metso Outotec Finland Oy
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00Obtaining copper
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00Shaft or like vertical or substantially vertical furnaces
    • F27B1/02Shaft or like vertical or substantially vertical furnaces with two or more shafts or chambers, e.g. multi-storey
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00Obtaining copper
    • C22B15/0026Pyrometallurgy
    • C22B15/0028Smelting or converting
    • C22B15/0047Smelting or converting flash smelting or converting
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B19/00Combinations of furnaces of kinds not covered by a single preceding main group
    • F27B19/04Combinations of furnaces of kinds not covered by a single preceding main group arranged for associated working
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/0025Charging or loading melting furnaces with material in the solid state
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/18Charging particulate material using a fluid carrier
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D9/00Cooling of furnaces or of charges therein
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00Subject matter not provided for in other groups of this subclass

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Furnace Details (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Furnace Charging Or Discharging (AREA)

Abstract

The invention relates to a suspension smelting furnace comprising a reaction shaft (1), an uptake shaft (2), and a lower furnace (3), as well as a concentrate burner (4) for feeding reaction gas and fine solids into the reaction shaft (1) of the suspension smelting furnace. The concentrate burner (4) comprises a fine solids discharge channel (5) that is radially limited by the wall (6) of the solids discharge channel, a fine solids dispersion device (7) in the fine solids discharge channel (5), an annular reaction gas channel (8) that surrounds the fine solids discharge channel (5) and is radially limited by the wall (9) of the annular reaction gas channel (8), and a cooling block (10) that surrounds the annular reaction gas channel (8). The cooling block (10) is a component that is manufactured by a continuous casting method. The cooling block (10) is attached to the arch (11) of the reaction shaft (1) and the wall (9) of the annular reaction gas channel (8), so that the discharge orifice (12) of the annular reaction gas channel (8) is formed between a structure (13), which is jointly formed by the cooling block (10) and the wall (9) of the annular reaction gas channel (8), and the wall (6) of the solids discharge channel. The invention also relates to a concentrate burner (4) for feeding reaction gas and fine solids into the reaction shaft (1) of a suspension smelting furnace.

Description

WO 20121001238 PCT/F120111050614 1 Suspension smelting furnace and a concentrate burner Background of the invention The invention relates to a suspension smelting furnace according to the preamble of claim 1 comprising a reaction shaft, an uptake shaft, and a lower furnace, 5 as well as a concentrate burner for feeding reaction gas and fine-grained solids into the reaction shaft of the suspension smelting furnace. The invention also relates to a concentrate burner according to the preamble of Claim 7 for feeding reaction gas and fine-grained solids into the reaction shaft of a suspension smelting furnace. 10 Publication WO 98/14741 discloses a method for adjusting the flow velocity of reaction gas and the dispersion air of powdery solids, when feeding reaction gas and fine-grained solids into the reaction shaft of a suspension smelting furnace for creating a controlled and adjustable suspension. Reaction gas is fed into the furnace around a fine-grained solids flow, the solids being distributed with an orientation 15 toward the reaction gas by means of dispersion air. The flow velocity and discharge direction of the reaction gas to the reaction shaft are smoothly adjusted by means of a specially shaped adjusting member which moves vertically in the reaction gas channel and by means of a specially shaped cooling block, which surrounds the reaction gas channel and which is located on the arch of the reaction shaft. The velocity of reaction 20 gas is adjusted to a suitable level, irrespective of the gas quantity, in the discharge orifice located on the lower edge of the reaction shaft arch, from where the gas is discharged into the reaction shaft, forming a suspension with the powdery material therein, and the amount of the dispersion air which is used to disperse the material is adjusted according to the supply of the powdery material. The publication also 25 discloses a multi-adjustable burner. One problem with this known solution is the high price of the cooling block. It is usually manufactured from copper by sand casting. Sand casting, as a method, often leads to problems in quality, and a large amount of copper is consumed in making the cooling block. 30 Short description of the invention The object of the invention is to solve the problems which are mentioned above. The object of the invention is achieved by a suspension smelting furnace, according to the independent claim 1.
WO 2012/001238 PCT/F12011/050614 2 The suspension smelting furnace comprises a reaction shaft, an uptake shaft, and a lower furnace, as well as a concentrate burner for feeding reaction gas and fine solids into the reaction shaft of the suspension smelting furnace. The concentrate burner of the suspension smelting furnace comprises a fine solids discharge channel 5 that is radially limited by the wall of the fine solids discharge channel, a fine solids dispersion device in the fine solids discharge channel, and an annular reaction gas channel that surrounds the fine solids discharge channel and that is radially limited by the wall of the annular reaction gas channel. The concentrate burner of the suspension smelting furnace further comprises a cooling block that surrounds the annular reaction 10 gas channel. In the suspension smelting furnace according to the invention, the cooling block is a component that is manufactured using a continuous casting method and that is attached to the arch of the reaction shaft and to the wall of the annular reaction gas channel, so that the discharge orifice of the annular reaction gas channel is formed 15 between a structure, which is jointly formed by the cooling block and the wall of the annular reaction gas channel, and the wall of the fine solids discharge channel. The invention also relates to a concentrate burner, according to the independent claim 7. The concentrate burner comprises a fine solids discharge channel that is 20 radially limited by the wall of the fine solids discharge channel, a fine solids dispersion device in the fine solids discharge channel, and an annular reaction gas channel that surrounds the fine solid matter discharge channel and that is radially limited by the wall of the annular reaction gas channel. The concentrate burner further comprises a cooling block that surrounds the annular reaction gas channel. 25 The cooling block in the concentrate burner according to the invention, is a component that is manufactured using a continuous casting method and that is attached with respect to the wall of the annular reaction gas channel, so that the discharge orifice of the reaction gas channel is formed between the structure, which is jointly formed by the cooling block and the wall of the annular reaction gas channel, 30 and the wall of the fine solids discharge channel. Preferred embodiments of the invention are disclosed in the dependent claims. An advantage of the continuously-cast cooling block, when compared for example, with the solution of the publication WO 98/14741, is that a great deal less raw material, such as copper, is consumed in the manufacture and that the 35 manufacturing process is also considerably easier. The continuously-cast cooling block provides improved protection against corrosions, which cause leaks, than a sand-cast cooling block.
WO 2012/001238 PCT/F12011/050614 3 The simple structure of the cooling block makes it considerably easier to install accessories and measuring devices that measure the process close to the concentrate burner. In a preferred embodiment, openings are formed in the cooling block for the feed-through of an outgrowth removal arrangement, such as the feed 5 through of outgrowth removal arrangement pistons. In one solution according to the invention, the cooling block comprises drilled channels with the purpose of circulating cooling fluid in the cooling block. List of figures In the following, some preferred embodiments of the invention are described 10 in detail with reference to the appended figures, wherein Fig. 1 shows the suspension smelting furnace; Fig. 2 shows a vertical section of one preferred embodiment of the concentrate burner in a state, where the concentrate burner is installed in the reaction shaft of a suspension smelting furnace; and 15 Fig. 3 shows a cooling block from above. Detailed description of the invention The invention relates to the suspension smelting furnace and the concentrate burner. First, the suspension smelting furnace and some of its preferred embodiments 20 and variations are described in more detail. Fig. 1 shows a suspension smelting furnace which comprises a reaction shaft 1, an uptake shaft 2, and a lower furnace 3, as well as a concentrate burner 4 for feeding reaction gas (not shown in the figures) and fine solids (not shown) into the reaction shaft 1. The operation of such a suspension smelting furnace is described in 25 the Finnish patent F122694, for example. The concentrate burner 4 comprises a fine solids discharge channel 5, which is radially, that is outwardly limited by the wall 6 of the fine solids discharge channel 5. The concentrate burner 4 comprises a fine solids dispersion device 7 in the fine solids discharge channel 5. 30 The concentrate burner 4 comprises an annular reaction gas channel 8, which surrounds the fine solids discharge channel 5 and which is radially limited by the wall 9 of the annular reaction gas channel 8. The concentrate burner 4 comprises a cooling block 10 that surrounds the 35 annular reaction gas channel 8.
WO 2012/001238 PCT/F12011/050614 4 The operation of such a concentrate burner 4 is described in the publication WO 98/14741, for example. The cooling block 10 is a component that is manufactured using a continuous casting method. 5 The cooling block 10 is attached to the arch 11 of the reaction shaft 1 and to the wall 9 of the annular reaction gas channel 8, so that the discharge orifice 12 of the annular reaction gas channel 8 is formed between a structure 13, which is jointly formed by the cooling block 10 and the wall 9 of the annular reaction gas channel 8, and the wall 6 of the fine solids discharge channel 5. 10 The wall 6 of the fine solids discharge channel 5 preferably, but not necessarily, comprises a first curved portion 14 on the side of the annular reaction gas channel 8, which is adapted so as to work in cooperation with the second curved portion 15 of the structure 13 on the side of the annular reaction gas channel 8, which structure 13 is jointly formed by the cooling block 10 and the wall 9 of the annular 15 reaction gas channel 8, so that the flow cross-sectional area of the annular reaction gas channel 8 decreases in the flow direction of the reaction gas between the first curved portion 14 and the second curved portion 15. The wall 6 of the fine solids discharge channel and the structure 13 that is jointly formed by the cooling block 10 and the wall 9 of the reaction gas channel are 20 preferably, but not necessarily, vertically movable with respect to each other, so that the size of the flow cross-sectional area of the discharge orifice 12 of the annular reaction gas channel 8 changes. For example, it is possible to vertically move the wall 6 of the fine solids discharge channel, so that the size of the flow cross-sectional area of the discharge orifice 12 of the reaction gas channel changes. 25 The annular reaction gas channel 8 can be provided with adjustable or fixed swirl vanes (not shown in the figures). The cooling block 10 preferably, but not necessarily comprises channels 17, such as drilled channels for the purpose of circulating cooling fluid (not shown) in the cooling block 10. 30 The cooling block 10 is preferably, but not necessarily, provided with openings 16 for the feed-through of an outgrowth removal system (not shown). The cooling block 10 is preferably, but not necessarily, at least partly manufactured of copper or a copper alloy. The invention also relates to a concentrate burner 4 for feeding reaction gas 35 and fine solids into the reaction shaft 1 of the suspension smelting furnace. The concentrate burner 4 comprises a fine solids discharge channel 5, which is radially, that is outwardly limited by the wall 6 of the fine solids discharge channel 5.
WO 2012/001238 PCT/F12011/050614 5 The concentrate burner 4 comprises a fine solids dispersion device 7 in the fine solids discharge channel 5. The concentrate burner 4 comprises an annular reaction gas channel 8, which surrounds the fine solids discharge channel 5 and which is radially, that is outwardly, 5 limited by the wall 9 of the annular reaction gas channel 8. The concentrate burner 4 comprises a cooling block 10 that surrounds the annular reaction gas channel 8. The operation of such a concentrate burner 4 is described in the publication WO 98/14741, for example. 10 In the concentrate burner 4, the cooling block 10 is a component that is manufactured by the continuous casting method. The cooling block 10 is attached to the wall 9 of the annular reaction gas channel 8, so that the discharge orifice 12 of the annular reaction gas channel 8 is formed between the structure 13, which is jointly formed by the cooling block 10 and 15 the wall 9 of the annular reaction gas channel 8, and the wall 6 of the fine solids discharge channel 5. The wall 6 of the fine solids discharge channel 5 preferably, but not necessarily, comprises a first curved portion 14 on the side of the annular reaction gas channel 8, which is adapted so as to work in cooperation with the second curved 20 portion 15 of the structure 13 on the side of the annular reaction gas channel 8, which structure 13 is jointly formed by the cooling block 10 and the wall 9 of the annular reaction gas channel 8, so that the flow cross-sectional area of the annular reaction gas channel 8 decreases in the flow direction of the reaction gas between the first curved portion 14 and the second curved portion 15. 25 The wall 6 of the fine solids discharge channel 5 and the structure 13 that is jointly formed by the cooling block 10 and the wall 9 of the annular reaction gas channel 8 are preferably, but not necessarily, vertically movable with respect to each other, so that the size of the flow cross-sectional area of the annular reaction gas channel 8 discharge orifice 12 changes. For example, it is possible that the wall 6 of 30 the fine solids discharge channel 5 is vertically movable, so that the size of the flow cross-sectional area of the discharge orifice 12 of the annular reaction gas channel 8 changes. The annular reaction gas channel 8 can be provided with adjustable or fixed swirl vanes (not shown in the figures). 35 The cooling block 10 preferably, but not necessarily, comprises channels 17, such as drilled channels for the purpose of circulating cooling fluid (not shown) in the cooling block 10.
6 The cooling block 10 is preferably, but not necessarily, provided with openings 16 for the feed-through the outgrowth removal system (not shown). The cooling block 10 is preferably, but not necessarily, at least partly manufactured of copper or a copper alloy. 5 It is obvious to those skilled in the art that with the technology improving, the basic idea of the invention can be implemented in various ways. Thus, the invention and its embodiments are not limited to the examples described above but they may vary within the claims. It is to be understood that, if any prior art publication is referred to herein, 10 such reference does not constitute an admission that the publication forms a part of the common general knowledge in the art, in Australia or any other country. In the claims which follow and in the preceding description of the invention, except where the context requires otherwise due to express language or necessary implication, the word "comprise" or variations such as "comprises" or "comprising" 15 is used in an inclusive sense, i.e. to specify the presence of the stated features but not to preclude the presence or addition of further features in various embodiments of the invention. 5360517 1 (GHMatters) P92202.AU

Claims (14)

1. A suspension smelting furnace comprising a reaction shaft, an uptake shaft, and a lower furnace, as well as a concentrate burner for feeding of reaction gas and fine solids into the reaction shaft of the suspension smelting furnace, the concentrate 5 burner comprising a fine solids discharge channel that is radially limited by the wall of the fine solids discharge channel; a fine solids dispersion device in the fine solids discharge channel; an annular reaction gas channel that surrounds the fine solids discharge 10 channel and that is radially limited by the wall of the annular reaction gas channel; and a cooling block that surrounds the annular reaction gas channel, characterized in that the cooling block is a component that is manufactured using a continuous 15 casting method; and the cooling block is attached to the arch of the reaction shaft and to the wall of the annular reaction gas channel, so that the discharge orifice of the annular reaction gas channel is formed between a structure, which is jointly formed by the cooling block and the wall of the annular reaction gas channel, and the wall of the fine solids 20 discharge channel.
2. The suspension smelting furnace according to claim 1, characterized in that the wall of the fine solids discharge channel comprises a first curved portion on the side of the annular reaction gas channel, and 25 in that the first curved portion is adapted so as to co-operate with a second curved portion of the structure on the side of the reaction gas channel, which structure is jointly formed by the cooling block and the wall of the reaction gas channel, so that the flow cross-sectional area of the reaction gas channel decreases in the flow direction of the reaction gas between the first curved portion and the second curved 30 portion .
3. The suspension smelting furnace according to claim 1 or 2, characterized in that the fine solids discharge channel is vertically movable, so that the size of the flow cross-sectional area of the discharge orifice of the annular reaction gas channel 35 changes. 5360517 1 (GHMatters) P92202.AU 8
4. The suspension smelting furnace according to any one of claims 1 to 3, characterized in that the cooling block comprises channels for the purpose of circulating cooling fluid in the cooling block.
5 5. The suspension smelting furnace according to any one of claims 1 to 4, characterized in that the cooling block is provided with openings for the feed through of an outgrowth removal arrangement.
6. The suspension smelting furnace according to any one of claims 1 to 5, 10 characterized in that the cooling block is at least partly manufactured of copper or a copper alloy.
7. A concentrate burner for feeding reaction gas and fine solids into the reaction shaft of a suspension smelting furnace, comprising 15 a fine solids discharge channel that is radially limited by the wall of the fine solids discharge channel; a fine solids dispersion device in the fine solids discharge channel; an annular reaction gas channel that surrounds the fine solids discharge channel and that is radially limited by the wall of the annular reaction gas channel; 20 a cooling block that surrounds the annular reaction gas channel; characterized in that the cooling block is a component that is manufactured by a continuous casting method; and the cooling block is attached to the wall of the annular reaction gas channel, 25 so that the discharge orifice of the annular reaction gas channel is formed between a structure, which is jointly formed by the cooling block and the wall of the annular reaction gas channel, and the wall of the fine solids discharge channel.
8. The concentrate burner according to claim 7, characterized 30 in that the wall of the fine solids discharge channel comprises a first curved portion on the side of the annular reaction gas channel, and in that the first curved portion is adapted so as to co-operate with a second curved portion of the structure on the side of the reaction gas channel, which structure is jointly formed by the cooling block and the wall of the annular reaction gas 35 channel, so that the flow cross-sectional area of the annular reaction gas channel decreases in the flow direction of the reaction gas between the first curved portion and the second curved portion . 5360517 1 (GHMatters) P92202.AU 9
9. The concentrate burner according to claim 7 or 8, characterized in that the fine solids discharge channel is vertically movable, so that the size of the flow cross sectional area of the discharge orifice of the annular reaction gas channel changes. 5
10. The concentrate burner according to any one of claims 7 to 9, characterized in that the cooling block comprises channels for a cooling fluid.
11. The concentrate burner according to any one of claims 7 to 10, characterized in that the cooling block is provided with openings for the feed-through of an 10 outgrowth removal arrangement.
12. The concentrate burner according to any one of claims 7 to 11, characterized in that the cooling block is at least partly manufactured of copper or a copper alloy. 15
13. A suspension smelting furnace comprising a reaction shaft, an uptake shaft, and a lower furnace, as well as a concentrate burner for feeding of reaction gas and fine solids into the reaction shaft of the suspension smelting furnace, substantially as herein described with reference to the accompanying drawings. 20
14. A concentrate burner for feeding reaction gas and fine solids into the reaction shaft of a suspension smelting furnace, substantially as herein described with reference to the accompanying drawings. 5360517 1 (GHMatters) P92202.AU
AU2011273331A 2010-06-29 2011-06-28 Suspension smelting furnace and a concentrate burner Active AU2011273331B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI20105741A FI124223B (en) 2010-06-29 2010-06-29 SUSPENSION DEFROSTING OVEN AND CONCENTRATOR
FI20105741 2010-06-29
PCT/FI2011/050614 WO2012001238A1 (en) 2010-06-29 2011-06-28 Suspension smelting furnace and a concentrate burner

Publications (2)

Publication Number Publication Date
AU2011273331A1 AU2011273331A1 (en) 2013-01-17
AU2011273331B2 true AU2011273331B2 (en) 2014-06-26

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US (1) US9869515B2 (en)
EP (1) EP2588634B1 (en)
JP (1) JP2013540251A (en)
KR (2) KR20130020958A (en)
CN (2) CN202158756U (en)
AU (1) AU2011273331B2 (en)
BR (1) BR112013000057A2 (en)
CL (1) CL2012003730A1 (en)
EA (1) EA024190B1 (en)
ES (1) ES2751342T3 (en)
FI (1) FI124223B (en)
PL (1) PL2588634T3 (en)
RS (1) RS59521B1 (en)
WO (1) WO2012001238A1 (en)
ZA (1) ZA201300387B (en)

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EA038464B1 (en) * 2017-05-29 2021-08-31 Оутотек (Финлэнд) Ой Method and arrangement for controlling a burner of a suspension smelting furnace
CN111512108B (en) * 2018-01-12 2022-04-19 环太铜业株式会社 Raw material supply device, flash smelting furnace and operation method of flash smelting furnace

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EP2588634B1 (en) 2019-08-07
FI20105741A (en) 2011-12-30
AU2011273331A1 (en) 2013-01-17
ZA201300387B (en) 2013-09-25
KR20150104226A (en) 2015-09-14
US9869515B2 (en) 2018-01-16
WO2012001238A1 (en) 2012-01-05
KR101860618B1 (en) 2018-05-23
CN103038374A (en) 2013-04-10
KR20130020958A (en) 2013-03-04
ES2751342T3 (en) 2020-03-31
EA201291285A1 (en) 2013-09-30
JP2013540251A (en) 2013-10-31
CL2012003730A1 (en) 2013-04-12
BR112013000057A2 (en) 2016-05-10
PL2588634T3 (en) 2020-03-31
RS59521B1 (en) 2019-12-31
US20130099431A1 (en) 2013-04-25
CN103038374B (en) 2016-06-29
EP2588634A4 (en) 2017-04-05
FI20105741A0 (en) 2010-06-29
CN202158756U (en) 2012-03-07
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