AU2010294093A1 - Method and facility for producing oxygen through air distillation - Google Patents
Method and facility for producing oxygen through air distillation Download PDFInfo
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- AU2010294093A1 AU2010294093A1 AU2010294093A AU2010294093A AU2010294093A1 AU 2010294093 A1 AU2010294093 A1 AU 2010294093A1 AU 2010294093 A AU2010294093 A AU 2010294093A AU 2010294093 A AU2010294093 A AU 2010294093A AU 2010294093 A1 AU2010294093 A1 AU 2010294093A1
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04163—Hot end purification of the feed air
- F25J3/04169—Hot end purification of the feed air by adsorption of the impurities
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- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
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- F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
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- F25J2250/42—One fluid being nitrogen
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- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
In a method for producing oxygen through the distillation of air supplied by air at atmospheric pressure so as to produce a first and second compressed air flow, and through a first purification unit (5) and a second purification unit (7), the first and second compressed air flows being discharged from the compression means at a first and second pressure, the first and second pressures being different pressures of at least 0.5 bar: the first compressed air flow is sent from a first outlet of the compression means to the first purifying unit at the first pressure so as to produce a first purified air flow; the first purified air flow is sent from the first purifying unit to a column of the column system (15); the second purified air flow is sent, in an at least partially condensed form, from the second purifying unit to a column of the column system; an oxygen-rich liquid is bled off from the column system; said oxygen-rich liquid is vaporized through heat exchange with at least the second purified air flow; and said oxygen-rich liquid is provided as a material.
Description
WO 2011/030050 PCT/FR2010/051854 Method and facility for producing oxygen through air distillation The present invention relates to a method and to a 5 facility for producing oxygen by distilling air. The invention applies for example to the production of very large quantities of oxygen in which the oxygen pressure required is in a range comprised, for example, between 5 and 20 bar. The oxygen is produced in one or more 10 large-sized air distillation units in which it is advantageous for the liquid oxygen produced in the distillation unit(s) to be brought to these pressures using pumps and for the liquid oxygen to be vaporized by exchange of heat with a calorigenic fluid compressed 15 to a pressure sufficient to allow the oxygen to vaporize, this calorigenic fluid typically being pressure boosted air. The always tricky use of oxygen compressors is thus avoided. 20 It is common practice in such air separation units (ASUs) for air to be compressed at atmospheric. pressure in one or more main air compressor(s) installed in parallel. The air thus compressed is cooled by refrigeration means, typically in a range comprised for 25 example between 5 and 40 0 C. The air thus cooled is processed in one or more purification unit(s) in which impurities such as water, CO 2 and hydrocarbons are, for the most part, eliminated. 30 Some of this air thus purified is sent to a pressure booster where it undergoes an additional compression step, typically to beyond 10 bar, and for example constitutes a calorigenic fluid used to vaporize the product or products such as oxygen. 35 The production of large quantities of oxygen by ASUs entails purifying large quantities of air in the purification units and in order to do that minimizing WO 2011/030050 - 2 - PCT/FR2010/051854 the size of these purification units that are able to process a given volume of air. The use of purification units of the concentric bed 5 type makes it possible to reduce the size of these units, something that can also be obtained by increasing the pressure of the purified air in these units, or by lowering the temperature thereof. 10 US-A-5337570 describes a method in which two air flows are purified at different pressures, but one of these flows then has its pressure boosted to a higher pressure so as to be able to vaporize a pressurized liquid oxygen flow. 15 The present invention seeks to alleviate the defects of the prior art and may make it possible to reduce the cost of investments by avoiding the addition of any air pressure booster after the purification unit(s) and 20 instead to have equivalent compression prior to the step of purifying the air in the purification unit(s). The purification units will process two air flows at two different pressures, the first air flow at a first 25 pressure of between 5 and 9 bar or potentially of between 2 and 4 bar and the second air flow at a second pressure of between 11 and 50 bar or potentially of between 4.5 and 8 bar. 30 One subject of the invention is a method for producing oxygen by distilling air in an apparatus comprising at least one system of columns, at least one exchange line, at least one compression means driven by an electric motor and/or by a steam turbine and supplied 35 with air at atmospheric pressure to produce one first and one second pressurized air flow, one first purification unit, one second purification unit, the first and second pressurized air flows leaving the WO 2011/030050 - 3 - PCT/FR2010/051854 compression means at a first and a second pressure, the second pressure being higher than the first by at least 0.5 bar, possibly by at least 5 bar, potentially by at least 10 bar, even by at least 25 bar, and the second 5 pressure being the highest pressure of any air flow intended to be fed into the system of columns; in which method the first pressurized air flow is sent from a first outlet of the compression means to the first purification unit substantially at the first pressure 10 in order to produce a first air flow that is purified in terms of water and in terms of carbon dioxide, the second pressurized air flow is sent from a second outlet of the compression means to the second purification unit substantially at the second pressure 15 in order to produce a second air flow that is purified in terms of water and in terms of carbon dioxide, the purified first flow is cooled in the exchange line, possibly at the first pressure, the purified second flow is cooled in the exchange line, possibly at the 20 second pressure, the purified first air flow is sent from the first purification unit to one column of the system of columns, the purified second air flow from the second purification unit is sent to one column of the system of columns at least in partially condensed 25 form, an oxygen-rich liquid is tapped off from the system of columns, vaporized, possibly in the exchange line or in an auxiliary vaporizer by exchanging heat at least with the purified second flow at the second pressure and is delivered as product. 30 According to other subjects of the invention; - The difference in pressure between the two pressurized air flows is at most 4 bar or possibly at least 1 bar and at most 3 bar. 35 - The difference in pressure between the two pressurized air flows is at least 5 bar and at most 30 bar, or possibly at least 15 bar and at most 25 bar.
WO 2011/030050 - 4 - PCT/FR2010/051854 - At least some of the purified first air flow is sent into the same column of the system of columns as the purified second air flow. - No part of the second flow is sent into a reboiler 5 of the system of columns. - The second pressure is higher than the first by at least 5 bar. - The second pressure is high than the first by at least 10 bar. 10 - The second pressure is higher than the first by at most 25 bar. - The flow at the second pressure enters one column of the system of columns and is not used to heat a reboiler of the system of columns. 15 Another subject of the invention is a facility for producing oxygen by distilling air, comprising at least one system of columns, at least one exchange line, at least one compression means driven by a steam turbine 20 and/or by an electric motor, the compression means having a first and a second outlet, one first purification unit, one second purification unit, the compression means being designed to be supplied with air at atmospheric pressure and to produce, from the 25 first outlet, a first pressurized air flow at a first pressure and from the second outlet a second pressurized air flow at a second pressure, the second pressurized air flow being at a pressure that is higher, by at least 0.5 bar, possibly by at least 5 30 bar, potentially by at least 10 bar, even by at least 25 bar, than the pressure of the first pressurized air flow, a first pipe for connecting the first outlet to the first purification unit, a second pipe for connecting the second outlet to the second purification 35 unit, a third pipe for connecting the first purification unit to the exchange line, a fourth pipe for connecting the second purification unit to the exchange line, no means of boosting the air pressure WO 2011/030050 - 5 - PCT/FR2010/051854 being connected downstream of the second purification unit, a fifth pipe connecting the exchange line to one column of the system of columns, a sixth pipe for connecting the exchange line to one column of the 5 system of columns, a pipe for tapping of f an oxygen rich liquid from the system of columns and for sending to a vaporizer (25), possibly consisting of the exchange line, means for sending at least part of the purified second flow to the vaporizer where it 10 condenses and in which facility there is no means of compressing air between the first outlet and the first purification unit and there is no means of compressing air between the second outlet and the exchange line, or potentially the system of columns. 15 According to other aspects of the invention: - The compression means comprises a first compressor and a second compressor, means for supplying the first compressor and the second compressor with air at 20 atmospheric pressure, the first and second compressors possibly being driven by a common steam turbine. - Just one of the first and second air compressors comprises intermediate coolants (isothermal compression). 25 - Means for sending air from the outlet of that one of the two air compressors that does not have an intermediate coolant to a heat exchanger, and means for sending at least one fluid from the system of columns and/or water to the exchanger where it is heated up. 30 Another subject of the invention is a method of producing oxygen by distilling air in an apparatus comprising n systems of columns, where n 2, n exchange lines, at least one first compressor compressing 35 atmospheric air in order to produce an air flow at a first pressure, at least one second compressor compressing atmospheric air to produce an air flow at a second pressure, the first pressure lower by at least WO 2011/030050 - 6 - PCT/FR2010/051854 0.5 bar, possibly by at least 5 bar, potentially by at least 10 bar, or even by at least 25 bar, than the second pressure, and the second pressure being the highest pressure of any air pressure intended for 5 distillation, in which method air at the first pressure is sent from at least one first compressor to at least one first purification unit, air at the second pressure is sent from at least one second compressor to at least one second purification unit, air at the first pressure 10 is sent from the first purification unit to at least two systems of columns, air at the second pressure is sent from the second purification unit to at least two systems of columns, and oxygen is produced from at least one of the systems of columns. 15 Another subject of the invention is a facility for producing oxygen by distilling air in an apparatus comprising n systems of columns, where n 2, n exchange lines, at least one first compressor compressing 20 atmospheric air in order to produce an air flow at a first pressure, at least one second compressor compressing atmospheric air to produce an air flow at a second pressure, the first pressure lower by at least 0.5 bar, possibly by at least 5 bar, potentially by at 25 least 10 bar, or even by at least 25 bar, than the second pressure, at least one first purification unit, at least one second purification unit, means for sending air at the first pressure taken from the first compressor(s) to the first purification unit(s), means 30 for sending air at the second pressure taken from the second compressor(s) to the second purification unit(s), means for sending air to at least two systems of columns from the first purification unit(s) and means for sending air to the two systems of columns 35 from the second purification unit(s), in which facility there is no compression means between the first compressor(s) and the first purification unit(s) and there is no compression means between the second WO 2011/030050 - 7 - PCT/FR2010/051854 compressor(s) and the exchange lines, or potentially the systems of columns. For preference, there is no means of connecting the 5 outlet of (one of) the first compressor(s) to the outlet of (one of) the second compressor(s) and/or there is no means of connecting the outlet of (one of) the first purification unit(s) to the outlet of (one of) the second purification unit(s). 10 Thus, there is an independent circuit supplied by at least two compressors producing air at the first pressure and an independent circuit supplied by at least two compressors producing air at the second 15 pressure, each of the two circuits supplying at least two independent systems of columns. Some embodiments will now be described in relation to the attached drawings which depict air separation 20 facilities according to the invention. The facility depicted in figure 1 is intended to supply oxygen to one or more iron smelting-reduction unit(s) (Corex@/Finex@) or to one or more oxycombustion unit(s) 25 for example. In the first case, the pressure of the oxygen supplied is comprised in a range from 5 to 15 bar. In the second case, the pressure of the oxygen supplied is comprised in a range of 1 to 5 bar (preferably 1 to 2 bar abs). 30 The facility comprises one first compressor 1 and one second compressor 3, installed on the same site, means for supplying the first compressor and the second compressor with air at atmospheric pressure, the first 35 and the second compressor being driven by electric motors and respectively bringing the air to a first pressure comprised between 2.5 and 8 bar and to a second pressure comprised between 4 and 30 bar.
WO 2011/030050 - 8 - PCT/FR2010/051854 The two separate compressed air flows leaving the two air compressors are cooled for example using a final coolant, before being sent into a first and a second 5 purification unit 5 and 7, one of the air flows being substantially at the first pressure and the second substantially at the second pressure. The purified first air flow is sent into the main 10 exchange line 13 by means of the pipe 11 and the purified second air flows is sent into the main exchange line 13 by means of the pipe 9. Once it has been cooled in the exchanger 13, the first 15 air flow is introduced into the system of columns 15, the second air flow is introduced into the system of columns 15 in at least partially condensed form after having passed through an auxiliary vaporizer 25 using an oxygen-rich liquid tapped off from the system of 20 columns 15 by means of a pipe 17 and a pump 23. The first air flow introduced into the system of columns 15 is at least partially introduced into the same column as the second air flow introduced at least partially condensed into the system of columns 15 (for example 25 the high-pressure column of a double column comprising a high-pressure column and a low-pressure column). Figure 2 illustrates a first alternative form of this facility in which just one of the first and second air 30 compressors comprises intermediate coolants (isothermal compression) namely the compressor 1, means for sending air taken from the outlet of that one of the two air compressors that does not comprise an intermediate coolant to a heat exchanger 31, and means for sending 35 at least one fluid taken from the system of columns and/or water to the exchanger where it is heated up.
WO 2011/030050 - 9 - PCT/FR2010/051854 The two compressed air flows leaving the two air compressors are sent into two purification units 5 and 7, one of them substantially at the first pressure and the second substantially at the second pressure. 5 The purified first air flow is sent into the main exchange line 13 by means of pipes 11 and the purified second air flow is sent into the main exchange line 13 by means of the pipe 9. 10 Once it has been cooled in the exchanger 13, the first air flow is introduced into the system of columns 15, the second air flow is introduced into the system of columns 15 in at least partially condensed form after 15 having passed through an auxiliary vaporizer 25 using an oxygen-rich liquid tapped off from the system of columns 15 by means of a pipe 17 and a pump 23. The first air flow introduced into the system of columns 15 is at least partially introduced into the same column 20 as the at least partially condensed second air flow 15. The oxygen-rich liquid tapped off from the system of columns 15 by means of the pipe 17 and which was vaporized in the auxiliary vaporizer 25 against the purified second air flow, is introduced into the heat 25 exchanger 31 and allows the cooling of the air compressed in the compressor 1 comprising no intermediate coolants. The facility depicted in figure 3 represents a second 30 variant, intended for supplying oxygen to an iron smelting-reduction unit (Corex@/Finex@) . The pressure of the oxygen supplied is comprised in a range from 5 to 15 bar (preferably from 8 to 12 bar abs). 35 The facility comprises a first compressor 1 and a second compressor 3, means for supplying the first compressor and the second compressor with air at atmospheric pressure, the first and second compressors WO 2011/030050 - 10 - PCT/FR2010/051854 being driven by a common steam turbine 39 and respectively bringing the air to a first pressure of between 4 and 7 bar and to a second pressure of between 10 and 30 bar. 5 The two compressed air flows leaving the two air compressors are sent into two purification units 5 and 7, one of them substantially at the first pressure and the second substantially at the second pressure. 10 A first portion of the purified first air flow is sent into the main exchange line 13 by means of the pipes 11 and the purified second air flow is sent into the main exchange line 13 by means of the pipe 9. 15 The second portion of the purified first air flow is sent into the compressor 33 of a booster turbine by means of the pipe 29, before being cooled in the main exchange line 13 and then expanded in the turbine 20 part 35 of the booster turbine. The air expanded in the turbine 35 is sent into the system of columns via the pipe 41. The purified second air flow, once cooled in the 25 exchange line, is introduced into the system of columns 15 by means of the pipe 43. As in the other cases, the first air flow introduced into the system of columns 15 is introduced at least 30 partially into the same column as the second air flow introduced at least partially condensed into the system of columns 15. Figure 4 illustrates a third alternative form derived 35 from figure 3 in which just one of the first and second air compressors (the compressor 3) comprises intermediate coolants (isothermal compression), comprising means for sending air from the outlet of WO 2011/030050 - 11 - PCT/FR2010/051854 that one of the two air compressors that does not have an intermediate coolant to a heat exchanger and means for sending water to the exchanger where it heats up. 5 Figure 5 describes a fourth variant of the facility described in figure 1, in which the two compressors are combined into one and the same machine 3, for example an axial-radial compressor. 10 Figure 6 describes an additional variant in which n facilities described in figure 1 are interconnected. This figure, for the sake of clarity, shows the case n=2: thus it shows two facilities as described in figure 1, interconnected by means of the pipes 45 and 15 47 on the one hand, and 49 and 51 on the other. Thus, the pipe 45 connects the outlet of the compressor 1 and that of the compressor 1', and the pipe 47 connects the outlet of the compressor 3 and that of the compressor 3'; the pipe 49 connects the outlet of the purification 20 means 7 with that of the purification means 7', and finally, the pipe 51 connects the outlet of the purification means 5 with that of the purification means 5'. 25 The first of the two interconnected facilities comprises a first and second compressor 1 and 3, the second facility comprises a first and a second compressor 1' and 3'. The first compressors 1 and 1' and the second compressors 3 and 3' are supplied with 30 air at atmospheric pressure, the first and second compressors being driven by electric motors and respectively bringing the air to a first pressure comprised between 2.5 and 8 bar and to a second pressure comprised between 4 and 30 bar. 35 The air flows pressurized by the compressors 1 and 1' on the one hand, and 3 and 3' on the other, are cooled for example using a final coolant before being sent WO 2011/030050 - 12 - PCT/FR2010/051854 into the first purification units 7 and 7' on the one hand, and into the second purification units 5 and 5' on the other, the air flows being substantially at the first pressure on the one hand in the case of the flows 5 taken from the compressors 1 and 1', and substantially at the second pressure on the other hand in the case of the flows taken from the compressors 3 and 3'. The facility comprises a pipe 45 connecting the first 10 air flows compressed by the first compressors 1 and 1', and a pipe 47 connecting the second air flows compressed by the second compressors 3 and 3'. The facility also comprises a pipe 49 connecting the first air flows purified by the purification means 7 and 7', 15 and a pipe 51 connecting the second air flows purified by the purification means 5 and 5'. The system of columns 15 in all the figures may comprise just one column, a conventional double column 20 or a triple column with a high-pressure column, an intermediate-pressure column and a low-pressure column, amongst others.
Claims (14)
1. A method for producing oxygen by distilling air in an apparatus comprising at least one system of 5 columns (15), at least one exchange line (13), at least one compression means driven by an electric motor and/or by a steam turbine and supplied with air at atmospheric pressure to produce one first and one second pressurized air flow, one first purification 10 unit (5), one second purification unit (7), the first and second pressurized air flows leaving the compression means at a first and a second pressure, the second pressure being higher than the first by at least 0.5 bar, possibly by at least 5 bar, potentially by at 15 least 10 bar, even by at least 25 bar, and the second pressure being the highest pressure of any air flow intended to be fed into the system of columns; in which method the first pressurized air flow is sent from a first outlet of the compression means to the first 20 purification unit (5) substantially at the first pressure in order to produce a first air flow that is purified in terms of water and in terms of carbon dioxide, the second pressurized air flow is sent from a second outlet of the compression means to the second 25 purification unit (7) substantially at the second pressure in order to produce a second air flow that is purified in terms of water and in terms of carbon dioxide, the purified first flow is cooled in the exchange line (13), possibly at the first pressure, the 30 purified second flow is cooled in the exchange line (13), possibly at the second pressure, the purified first air flow is sent from the first purification unit to one column of the system of columns (15), the purified second air flow from the 35 second purification unit is sent to one column of the system of columns (15) at least in partially condensed form, an oxygen-rich liquid is tapped off from the system of columns, vaporized, possibly in the exchange WO 2011/030050 - 14 - PCT/FR2010/051854 line or in an auxiliary vaporizer (25) by exchanging heat at least with the purified second flow at the second pressure and is delivered as product. 5
2. The method as claimed in claim 1, in which the difference in pressure between the two pressurized air flows is at most 4 bar or possibly at least 1 bar and at most 3 bar. 10
3. The method as claimed in claim 1, in which the difference in pressure between the two pressurized air flows is at least 5 bar and at most 30 bar, or possibly at least 15 bar and at most 25 bar. 15
4. The method as claimed in claim 1, 2 or 3, in which at least some of the purified first air flow is sent into the same column of the system of columns as the purified second air flow. 20
5. The method as claimed in claims 1 to 4, in which no part of the second flow is sent into a reboiler of the system of columns.
6. The method as claimed in one of the preceding 25 claims, in .which the second pressure is higher than the first by at least 5 bar.
7. The method as claimed in one of the preceding claims, in which the second pressure is high than the 30 first by at least 10 bar.
8. The method as claimed in one of the preceding claims, in which the second pressure is higher than the first by at most 25 bar. 35
9. A facility for producing oxygen by distilling air, comprising at least one system of columns (15), at least one exchange line (13), at least one compression WO 2011/030050 - 15 - PCT/FR2010/051854 means driven by a steam turbine and/or by an electric motor, the compression means having a first and a second outlet, one first purification unit (5), one second purification unit (7), the compression means 5 being designed to be supplied with air at atmospheric pressure and to produce, from the first outlet, a first pressurized air flow at a first pressure and from the second outlet a second pressurized air flow at a second pressure, the second pressurized air flow being at a 10 pressure that is higher, by at least 0.5 bar, possibly by at least 5 bar, potentially by at least 10 bar, even by at least 25 bar, than the pressure of the first pressurized air flow, a first pipe for connecting the first outlet to the first purification unit, a second 15 pipe for connecting the second outlet to the second purification unit, a third pipe (11) for connecting the first purification unit to the exchange line, a fourth pipe (9) for connecting the second purification unit to the exchange line, no means of boosting the air 20 pressure being connected downstream of the second purification unit, a fifth pipe connecting the exchange line to one column of the system of columns, a sixth pipe for connecting the exchange line to one column of the system of columns, a pipe (17) for tapping off an 25 oxygen-rich liquid from the system of columns and for sending to a vaporizer (25), possibly consisting of the exchange line, means for sending at least part of the purified second flow to the vaporizer where it condenses and in which facility there is no means of 30 compressing air between the first outlet and the first purification unit and there is no means of compressing air between the second outlet and the exchange line, or potentially the system of columns. 35
10. The facility as claimed in claim 9, in which the compression means comprises a first compressor (1) and a second compressor (3), means for supplying the first compressor and the second compressor with air at WO 2011/030050 - 16 - PCT/FR2010/051854 atmospheric pressure, the first and second compressors possibly being driven by a common steam turbine (39).
11. The facility as claimed in claim 9 or 10, in which 5 just one of the first and second air compressors comprises intermediate coolants (isothermal compression).
12. The facility as claimed in claim 11, comprising 10 means for sending air from the outlet of that one of the two air compressors that does not have an intermediate coolant to a heat exchanger (31), and means for sending at least one fluid from the system of columns and/or water to the exchanger where it is 15 heated up.
13. A method of producing oxygen by distilling air in an apparatus comprising n systems of columns, where n 2, n exchange lines (13, 13'), at least one first 20 compressor (1, 1') compressing atmospheric air in order to produce an air flow at a first pressure, at least one second compressor (3, 3') compressing atmospheric air to produce an air flow at a second pressure, the first pressure lower by at least 0.5 bar, possibly by 25 at least 5 bar, potentially by at least 10 bar, or even by at least 25 bar, than the second pressure, and the second pressure being the highest pressure of any air pressure intended for distillation, in which method air at the first pressure is sent from at least one first 30 compressor to at least one first purification unit (5, 5'), air at the second pressure is sent from at least one second compressor to at least one second purification unit (7, 7'), air at the first pressure is sent from the first purification unit to at least two 35 systems of columns (15, 15'), air at the second pressure is sent from the second purification unit to at least two systems of columns, and oxygen is produced from at least one of the systems of columns. WO 2011/030050 - 17 - PCT/FR2010/051854
14. A facility for producing oxygen by distilling air in an apparatus comprising n systems of columns, where n22, n exchange lines (13, 13'), at least one first compressor (1, 1') compressing atmospheric air in order 5 to produce an air flow at a first pressure, at least one second compressor (3, 3') compressing atmospheric air to produce an air flow at a second pressure, the first pressure lower by at least 0.5 bar, possibly by at least 5 bar, potentially by at least 10 bar, or even 10 by at least 25 bar, than the second pressure, at least one first purification unit (5, 5'), at least one second purification unit (7, 7'), means for sending air at the first pressure from the first compressor(s) to the first purification unit(s), means for sending air 15 at the second pressure from the second compressor(s) to the second purification unit(s), means for sending air to at least two systems of columns (15, 15' ) from the first purification unit(s) and means for sending air to the two systems of columns from the second purification 20 unit(s), in which facility there is no compression means between the first compressor(s) and the first purification unit(s) and there is no compression means between the second compressor(s) and the exchange lines, or potentially the systems of columns.
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PCT/FR2010/051854 WO2011030050A2 (en) | 2009-09-10 | 2010-09-07 | Method and facility for producing oxygen through air distillation |
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EP2551619A1 (en) * | 2011-07-26 | 2013-01-30 | Linde Aktiengesellschaft | Method and device for extracting pressurised oxygen and pressurised nitrogen by cryogenic decomposition of air |
EP2600089B1 (en) * | 2011-12-01 | 2014-09-03 | L'AIR LIQUIDE, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Method of operation of a cryogenic air separation unit |
MX2016001221A (en) * | 2013-08-02 | 2016-05-24 | Linde Ag | Method and device for producing compressed nitrogen. |
US9995530B2 (en) * | 2016-02-24 | 2018-06-12 | Charles Bliss | Method for the capture of carbon dioxide through cryogenically processing gaseous emissions from fossil-fuel power generation |
FR3093169B1 (en) | 2019-02-21 | 2021-01-22 | Air Liquide | Installation and process for separating gases from air using a parallelepiped shaped adsorber |
FR3093008B1 (en) | 2019-02-21 | 2021-01-22 | Air Liquide | Low pressure air gas separation plant and process |
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DE2903089A1 (en) * | 1979-01-26 | 1980-07-31 | Linde Ag | METHOD FOR OBTAINING OXYGEN FROM AIR |
JPS56115896A (en) * | 1980-02-19 | 1981-09-11 | Kawasaki Heavy Ind Ltd | Gas compressor plant equipped with power recovering means |
US4895583A (en) * | 1989-01-12 | 1990-01-23 | The Boc Group, Inc. | Apparatus and method for separating air |
FR2681415B1 (en) * | 1991-09-18 | 1999-01-29 | Air Liquide | PROCESS AND PLANT FOR THE PRODUCTION OF GAS OXYGEN UNDER HIGH PRESSURE BY AIR DISTILLATION. |
US5337570A (en) * | 1993-07-22 | 1994-08-16 | Praxair Technology, Inc. | Cryogenic rectification system for producing lower purity oxygen |
US5571309A (en) * | 1995-07-28 | 1996-11-05 | The Boc Group, Inc. | Adsorption process |
US5666823A (en) * | 1996-01-31 | 1997-09-16 | Air Products And Chemicals, Inc. | High pressure combustion turbine and air separation system integration |
US6141950A (en) * | 1997-12-23 | 2000-11-07 | Air Products And Chemicals, Inc. | Integrated air separation and combustion turbine process with steam generation by indirect heat exchange with nitrogen |
EP1197717A1 (en) * | 2000-10-12 | 2002-04-17 | Linde Aktiengesellschaft | Process and apparatus for air separation |
FR2819583B1 (en) * | 2001-01-12 | 2003-03-07 | Air Liquide | INTEGRATED AIR SEPARATION AND ENERGY GENERATION PROCESS AND INSTALLATION FOR CARRYING OUT SUCH A PROCESS |
US6536234B1 (en) * | 2002-02-05 | 2003-03-25 | Praxair Technology, Inc. | Three column cryogenic air separation system with dual pressure air feeds |
FR2961586B1 (en) * | 2010-06-18 | 2014-02-14 | Air Liquide | INSTALLATION AND METHOD FOR AIR SEPARATION BY CRYOGENIC DISTILLATION |
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US20120167622A1 (en) | 2012-07-05 |
CN102859303A (en) | 2013-01-02 |
IN2012DN00957A (en) | 2015-04-10 |
CA2771205A1 (en) | 2011-03-17 |
ZA201201601B (en) | 2014-06-25 |
FR2949846B1 (en) | 2012-02-10 |
WO2011030050A2 (en) | 2011-03-17 |
CN102859303B (en) | 2014-12-03 |
JP2013509558A (en) | 2013-03-14 |
AU2010294093B2 (en) | 2015-01-15 |
EP2475945A2 (en) | 2012-07-18 |
FR2949846A1 (en) | 2011-03-11 |
WO2011030050A3 (en) | 2014-01-09 |
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