AU2010251212A1 - Method of protecting a flexible riser and an apparatus therefor - Google Patents
Method of protecting a flexible riser and an apparatus therefor Download PDFInfo
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- AU2010251212A1 AU2010251212A1 AU2010251212A AU2010251212A AU2010251212A1 AU 2010251212 A1 AU2010251212 A1 AU 2010251212A1 AU 2010251212 A AU2010251212 A AU 2010251212A AU 2010251212 A AU2010251212 A AU 2010251212A AU 2010251212 A1 AU2010251212 A1 AU 2010251212A1
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- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000012530 fluid Substances 0.000 claims abstract description 254
- 238000007667 floating Methods 0.000 claims abstract description 104
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 90
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 49
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 49
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 47
- 239000003345 natural gas Substances 0.000 claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 32
- 238000004891 communication Methods 0.000 claims description 20
- 238000012546 transfer Methods 0.000 claims description 18
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 16
- 239000001569 carbon dioxide Substances 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 11
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 238000005452 bending Methods 0.000 claims description 4
- 239000003351 stiffener Substances 0.000 claims description 2
- 238000005755 formation reaction Methods 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 238000001816 cooling Methods 0.000 description 20
- 230000033001 locomotion Effects 0.000 description 16
- 239000003507 refrigerant Substances 0.000 description 15
- 239000003112 inhibitor Substances 0.000 description 14
- 239000007789 gas Substances 0.000 description 8
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- 238000007906 compression Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 5
- 230000004044 response Effects 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- 239000003949 liquefied natural gas Substances 0.000 description 4
- 239000013535 sea water Substances 0.000 description 4
- 230000009919 sequestration Effects 0.000 description 4
- 230000001133 acceleration Effects 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
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- 239000002253 acid Substances 0.000 description 2
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- 238000005553 drilling Methods 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
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Classifications
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/01—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells specially adapted for obtaining from underwater installations
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B17/00—Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
- E21B17/01—Risers
- E21B17/015—Non-vertical risers, e.g. articulated or catenary-type
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B19/00—Handling rods, casings, tubes or the like outside the borehole, e.g. in the derrick; Apparatus for feeding the rods or cables
- E21B19/002—Handling rods, casings, tubes or the like outside the borehole, e.g. in the derrick; Apparatus for feeding the rods or cables specially adapted for underwater drilling
- E21B19/004—Handling rods, casings, tubes or the like outside the borehole, e.g. in the derrick; Apparatus for feeding the rods or cables specially adapted for underwater drilling supporting a riser from a drilling or production platform
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B7/00—Special methods or apparatus for drilling
- E21B7/12—Underwater drilling
Landscapes
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Mechanical Engineering (AREA)
- Earth Drilling (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Pipeline Systems (AREA)
Abstract
The present invention provides a method of protecting one or more flexible risers which can carry a riser fluid, for instance a hydrocarbon production fluid such as natural gas, to or from a floating structure and an apparatus therefor, said method comprising at least the steps of: (a) providing a floating structure (100), one or more flexible risers (10), each of said flexible risers carrying a riser fluid and having a first end (20) connected to the floating structure (100) and a second end (30) on the sea bed (500) and in fluid connection with one or more riser fluid reservoirs (250); (b) closing the fluid connection between the one or more flexible risers (10) and the one or more riser fluid reservoirs (250); (c) replacing at least a portion of the riser fluid in one or more of the flexible risers (10) with a protection fluid, wherein the density of said protection fluid is greater than the density of said riser fluid.
Description
WO 2010/133564 PCT/EP2010/056768 METHOD OF PROTECTING A FLEXIBLE RISER AND AN APPARATUS THEREFOR The present invention provides a method of protecting one or more flexible risers which can carry a riser fluid, for instance a hydrocarbon production fluid such as natural gas, to or from a floating structure and an 5 apparatus therefor. In particular, the method disclosed herein seeks to protect the flexible risers from buckling caused by the heave and/or the pitch of the floating structure in response to wave motion in severe weather conditions. 10 The Floating Liquefaction of Natural Gas (FLNG) concept combines the natural gas treatment, liquefaction process, storage tanks, loading systems and other infrastructure into a single floating structure. Such a structure is advantageous because it provides an off 15 shore alternative to on-shore liquefaction plants. A FLNG vessel can be moored close to or at a gas field, in waters deep enough to allow off-loading of the LNG product onto a carrier vessel. It also represents a movable asset, which can be relocated to a new site when 20 the gas field is nearing the end of its productive life, or when required by economic, environmental or political conditions. The floating structure can be in fluid communication with the producing well heads of the reservoir. The 25 floating structure can be connected to one or more flexible risers. The flexible risers can be secured to the sea bed by a riser base manifold. A subsea flowline can connect the riser base manifold directly to the well heads or optionally via a well manifold.
WO 2010/133564 PCT/EP2010/056768 -2 In such a configuration, a production hydrocarbon, such as natural gas, from a hydrocarbon reservoir, such as a gas field, can be passed along a sub sea pipeline from one or more well-heads, which can be in the same or 5 different hydrocarbon reservoirs, to the riser base manifold. The riser base manifold is the point at which the production and any injection pipelines are connected to the flexible risers which convey the production hydrocarbon to the floating structure. The flexible 10 risers are connected to the floating structure at a hangoff point. The hang-off point may be at a side of the floating structure, or situated within a moonpool in the floating structure, for example at the bottom of a turret. The floating structure can be moored to the sea 15 bed by a plurality of mooring lines which are anchored to the sea bed. The flexible risers are flexible pipes suspended between the floating structure and riser base manifold, and can be configured as free-hanging catenaries or 20 alternative configurations using buoyancy modules such as lazy wave and lazy S types. A detailed discussion of flexible risers can be found in the American Petroleum Institute's publication titled "Specification for unbonded pipe", API Specification 17J, Second edition, 25 effective date December 2002. A discussion of flexible riser operation can be found in the American Petroleum Institute's publication titled "Recommended Practice for Flexible Pipe", API Recommended Practice 17B, Third Edition, March 2000. 30 When the vertical motion of the hangoff point from the floating structure is severe, such as in heavy seas, compressive forces can arise in the flexible risers which can cause global buckling. The compressive forces are WO 2010/133564 PCT/EP2010/056768 -3 even more severe in those cases in which the hangoff point is distanced from the centre of motion of the floating structure because one or both of the heave and pitch of the structure is correspondingly amplified. 5 The paper titled "Guidelines for compression modelling in flexible risers for deepwater applications" by McCann et al, Offshore Technology Conference 5-8 May 2003, OTC 15168, identifies the problem of riser buckling associated with compressive loading due to severe heave 10 in Floating Production Storage and Offloading Vessels (FPSO), which can be moored in hostile environments. During downward heave and/or pitch, the riser is said to attempt to follow the applied motion of the structure. As the riser displaces through the water column, drag forces 15 act opposite to the direction of motion, retarding the motion of the riser. The motion of the floating vessel is therefore translated into a reduction in effective tension. When the riser enters compression, it relies upon cross sectional bending stiffness to limit 20 curvature. However, the cross sectional bending stiffness of the riser is small in comparison with the distances and forces involved. WO-2006/031335-Al is concerned with the prevention of hydrates in subsea equipment in a cold water production 25 environment of relatively small offshore developments. The disclosed system has at least one producing subsea well, a jumper for delivering produced fluids from the subsea well to a manifold, a production line for delivering produced fluids to a production gathering 30 facility, and an umbilical for delivering chemicals to the manifold. The umbilical terminates at the ocean floor. The umbilical may transmit chemical inhibitors to the ocean floor and then to equipment of the subsea WO 2010/133564 PCT/EP2010/056768 -4 processing system. The inhibitors are designed and provided in order to ensure that flow from the wells is not affected by the formation of solids in the flow stream such as hydrates, waxes and scale. The system of 5 WO-2006/031335-Al uses an umbilical, which renders the system relatively expensive. US-2003/008577-Al discloses a system, wherein pipes such as riser flowlines are provided with one or more additional channels for buoyancy control. The buoyancy of 10 the flowlines can be dynamically controlled by filling the additional channels with a buoyancy control material, to provide positive or negative buoyancy. The additional channels may be formed by pipes which are externally attached to the risers or by an additional annulus within 15 the risers, which will however increase the costs of the risers. WO-95/22678-Al discloses a riser assembly, comprising a pipe in a planar cyclically undulating configuration. Tension members extend in the longitudinal direction of 20 the riser assembly and are secured to the pipe at spaced intervals so that they absorb tension forces. US-5875848 discloses a system and a method for managing the weight of an underwater riser assembly. The system includes a blocking mechanism for selectively 25 blocking the bottom end of the riser assembly so that heavy drilling mud is retained within the riser assembly. Upper and lower flooding valves are located in the riser assembly above the blocking mechanism and are spaced apart. The valves can be opened so that an annulus in the 30 riser assembly is in fluid communication with surrounding water. Drilling fluid can be introduced to or removed from the annulus during deployment or disconnect conditions using the upper and lower flooding valves. The WO 2010/133564 PCT/EP2010/056768 -5 lower flooding valve is mounted immediately above the closing mechanism. The upper flooding valve is preferably arranged at approximately one-third of the distance between the ocean floor and the surface of the water. The 5 system of US-5875848 is therefore directed at filling the lower end of the annulus of the riser. The present invention seeks to address the problem of riser buckling during severe heave and/or pitch of the floating structure caused by extreme weather conditions. 10 In a first aspect, the present invention provides a method of protecting one or more flexible risers in a sub sea environment, comprising at least the steps of: (a) providing a floating structure, one or more flexible risers, each of said flexible risers carrying a riser 15 fluid and having a first end connected to the floating structure and a second end on the sea bed and in fluid connection with one or more riser fluid reservoirs; (b) closing the fluid connection between the one or more 20 flexible risers and the one or more riser fluid reservoirs; (c) replacing at least a portion of the riser fluid in one or more of the flexible risers with a protection fluid, wherein the density of said protection fluid 25 is greater than the density of said riser fluid. The forces experienced by the flexible riser in the water can most easily be understood by considering the movement of a free flexible riser. Downward motion of a flexible riser in water will occur under gravitational 30 acceleration. As the velocity increases, the restoring drag force increases until it matches the gravitational acceleration and the flexible riser reaches terminal velocity. At the terminal velocity, the acceleration of WO 2010/133564 PCT/EP2010/056768 -6 the flexible riser is balanced by the restoring drag force such that: V = 2.m.g Ter Cd p.Dag wherein m is mass of the flexible riser, including internal fluid, g is gravity, C is normal drag 5 coefficient, Drag, is the drag diameter, p is the water density and VTrm is the terminal velocity. When a flexible riser is constrained, such that it is attached at a first end to a floating structure on the surface of the water and at a second end on the sea bed, 10 vertical motion of the flexible riser can result from the heave and/or pitch of the floating structure in response to the water motion on the surface. Damage to flexible risers may occur when the terminal velocity of the flexible riser in the sea water is 15 exceeded by the velocity of the first end of the riser where it is connected to the floating structure. This point of connection is also called the hang-off point. When the downward velocity of the flexible riser at the hang-off point due to the heave and/or pitch of the 20 floating vessel (the "hang-off velocity") is greater than the terminal velocity of the flexible riser in the water, the riser will come under compression. Such compressive stresses can lead to buckling and permanent damage to the flexible riser. 25 Compressive stress in the flexible riser can also be viewed as negative riser tension. Interpreted mathematically, the possibility of buckling can occur when the ratio of the downward hang-off velocity of the riser to the terminal velocity of the riser in the water 30 exceeds 1. Compression modelling therefore allows the WO 2010/133564 PCT/EP2010/056768 -7 prediction of potential riser buckling for particular structure heave and/or pitch, riser type and the distance of the hang-off point from the centre of motion of the structure. 5 By filling at least a portion of a riser with a protection fluid, which has a higher density than the riser fluid, the apparent weight of the riser is increased. This leads to an increase in the terminal velocity of the riser in water. By increasing the 10 terminal velocity of the riser, higher hangoff velocities can be accommodated without riser buckling. This means that larger vertical heave and/or pitch can be tolerated by the flexible riser before compression and riser buckling may occur. The flexible risers carrying 15 protection fluid can therefore survive more severe weather conditions, and in particular increased wave heights, compared to those which have not been at least partly filled with protection fluid. In an embodiment, the floating structure comprises a 20 protection fluid storage tank, said protection fluid storage tank comprising an outlet for a protection fluid stream; and each of said flexible risers has a first end connected to said floating structure, said first end in direct fluid communication with a first end connection 25 for a riser fluid stream and an inlet for the protection fluid stream in fluid communication with the outlet of the protection fluid storage tank, said inlet being separate from said first end connection. In another embodiment, step (b) includes closing the 30 second end; and step (c) includes introducing the protection fluid stream into the one or more risers via the inlet to replace at least a portion of the riser fluid; and removing the replaced portion of the riser WO 2010/133564 PCT/EP2010/056768 -8 fluid via the first end connection for the riser fluid stream. The method of the present invention uses risers provided with a topside inlet for protection fluid. 5 Topside herein indicates the side of the riser attached to the floating structure. Said inlet is separate from the topside first end connection (inlet or outlet) for riser fluid. The inlet enables rapid filling of the main fluid channel of the riser with the protection fluid, 10 whereas at the same time the riser fluid can be removed via the first end connection. In a further aspect, the present invention provides an apparatus for protecting one or more flexible risers in a sub sea environment, said apparatus comprising at 15 least: - a floating structure comprising a protection fluid storage tank, said protection fluid storage tank comprising an outlet for a protection fluid stream; - one or more flexible risers, each of said flexible 20 risers having a first end connected to said floating structure, said first end in direct fluid communication with a first end connection for a riser fluid stream and an inlet for the protection fluid stream in fluid communication with the outlet of the protection fluid 25 storage tank, said inlet being separate from said first end connection, and each of said flexible risers having a second end on the sea bed, said second end having a second end connection for a riser fluid transfer stream in fluid communication with one or more riser fluid 30 reservoirs. The method and apparatus of the present invention provide a relatively inexpensive means to readily protect risers during adverse weather conditions. The invention WO 2010/133564 PCT/EP2010/056768 9 obviates an additional umbilical, pipe or annulus. The risers are provided with an inlet for the protection fluid stream to enable rapid replacement of the riser fluid with protection fluid from the topside of the 5 riser. Embodiments of the present invention will now be described by way of example only, and with reference to the accompanying non-limiting drawings in which: Figure 1 shows a first embodiment of a typical method 10 and apparatus scheme according to the invention. Figure 2 shows a second embodiment of a typical method and apparatus scheme according to the invention. For the purpose of this description, a single reference number will be assigned to a line as well as a 15 stream carried in that line. The same reference numbers refer to similar components, streams or lines. Figure 1 shows a cut-through section of a first method and apparatus 1 for the protection of one or more flexible risers 10, particularly during severe weather 20 conditions. The flexible risers convey a riser fluid between one or more riser fluid reservoirs 250 underneath the sea bed and a floating structure 100 on the sea surface. Thus, the risers can be sub sea risers. As used herein, the term "sub sea" is intended to encompass both 25 salt water and fresh water environments, and represents the region between the water surface and the bed of the body of water. Thus, the floating structure 100 can be a floating vessel, or an off-shore floating platform. A floating 30 vessel may be any movable or moored vessel, generally at least having a hull, and usually being in the form of a ship such as a 'tanker'.
WO 2010/133564 PCT/EP2010/056768 - 10 Such floating vessels can be of any dimensions, but are usually elongated. Whilst the dimensions of a floating vessel are not limited at sea, building and maintenance facilities for floating vessels may limit 5 such dimensions. Thus, in one embodiment of the present invention, the floating vessel or off-shore floating platform is less than 600m long such as 500m, and a beam of less than 100m, such as 80m, so as to be able to be accommodated in existing ship-building and maintenance 10 facilities. An off-shore floating platform may also be movable, but is generally more-permanently locatable than a floating vessel. The method and apparatus of the invention are for 15 instance advantageous for applications in deep water, such as water depths greater than 200 m, for instance 250 to 500 m, or greater than 1000 m. In one embodiment, the riser fluid is a hydrocarbon fluid such as natural gas, and the one or more riser 20 fluid reservoirs 250 are hydrocarbon fluid reservoirs such as natural gas reservoirs. In this embodiment, the hydrocarbon fluid would be conveyed from the hydrocarbon fluid reservoirs 250 under the sea bed 500 to the floating structure 100, where the hydrocarbon fluid can 25 be stored and preferably treated. When the hydrocarbon fluid is natural gas it is preferred that the floating structure 100 comprises natural gas treatment and/or liquefaction units such that the natural gas can be treated to remove unwanted impurities and cooled to 30 provide liquefied natural gas. This will be discussed in more detail in relation to Figure 2.
WO 2010/133564 PCT/EP2010/056768 - 11 In an alternative embodiment, the method and apparatus disclosed herein can be used for carbon dioxide sequestration. Many hydrocarbon reservoirs, such as natural gas 5 reservoirs may contain carbon dioxide, for instance in contents of 6-10%. This carbon dioxide could be separated in the floating structure from the hydrocarbon fluid, such as natural gas, removed from the reservoir, and then re-injected into the a riser fluid reservoir. 250. The 10 riser fluid reservoir can be any sealed subsurface geological formation such as a hydrocarbon reservoir, a depleted hydrocarbon reservoir, an aquifer or other sealed water containing layer. In this case, the riser fluid can comprise carbon dioxide, preferably as a dense 15 phase, such as supercritical carbon dioxide i.e. carbon dioxide having a pressure and temperature above the critical point. In contrast to the previous embodiment, the riser fluid comprising carbon dioxide would for instance be conveyed from a separation unit on the 20 floating structure 100 to the one or more depleted hydrocarbon reservoirs 250 under the sea bed 500, where the riser fluid comprising carbon dioxide can be stored. In a further alternative embodiment, also illustrating a carbon dioxide sequestration method, the 25 riser fluid comprising carbon dioxide passed to the riser fluid reservoir 250 can come from any source. For example, the carbon dioxide may be generated at a location different from the floating structure 100, such as an on-shore location, and transferred to the floating 30 structure 100 for sequestration underneath the sea bed. The riser fluid and riser fluid reservoir 250 may be as defined in the previous embodiment.
WO 2010/133564 PCT/EP2010/056768 - 12 For maximum benefit of the invention, it is preferred that the density of the riser fluid is less than 0.9 g/cm 3 , more preferably less than 0.7 g/cm 3 , still more preferably less than 0.5 g/cm 3 . 5 In the exemplary embodiment of Figure 1, the floating structure 100 is a floating vessel. The floating vessel is held in position by a plurality of mooring lines 610 which are connected to the floating vessel at a mooring point and maintain the mooring point of the floating 10 vessel in a fixed position. Figure 1 shows a trigonal arrangement of three bundles 620a, 620b, 620c of mooring lines, each bundle comprising four mooring lines 610a, b, c, d. The mooring lines 610 are fastened securely to sea bed 500, for instance using anchor piles. 15 The one or more flexible risers 10 may be provided as free-hanging catenaries or in alternative configurations using buoyancy modules such as lazy wave and lazy S types. Each flexible riser 10 has a first end 20 connected to the floating vessel 100. Figure 1 shows 20 eight flexible risers 10 a-h, arranged in first and second riser bundles of four, connected to the floating vessel 100 at first ends 20 a-h respectively. The flexible risers 10 a-h each have a second end 30 a-h on the sea bed 500. The second ends 30 a-h of the 25 flexible risers 10 a-h need not be in direct contact with the sea bed 500. It is preferred that the second ends 30 a-h of the flexible risers are adapted to be secured to the sea bed 500. In the embodiment shown in Figure 1, the second ends 30 of the flexible risers are connected to 30 two riser base manifolds 300. Second ends 30 a-d of the first riser bundle are connected to first riser base manifold 300a, while second ends 30 e-h of the second riser bundle are connected to second riser base manifold WO 2010/133564 PCT/EP2010/056768 - 13 300b. The riser base manifolds 300 are fastened securely to sea bed 500, for instance using fixed piles. In this way, the first and second ends 20, 30 of the flexible risers 10 are secured to the floating vessel 100 and sea 5 bed 500 respectively. The riser base manifolds 300 provide a fluid connection between the flexible risers 10 and one or more riser fluid transfer streams 210. The one or more riser fluid transfer streams convey the riser fluid between the 10 riser base manifolds 300 and the riser well heads 200. Figure 1 shows first riser base manifold 300a connected to four well heads 200 a-d via an optional well head manifold 220a. Four riser fluid transfer streams 210 a-d connect well heads 200 a-d to the well head manifold 15 220a. Two further riser fluid transfer streams 210 i, j connect the well head manifold 220a to the riser base manifold 300a. Similarly, second riser base manifold 300 is connected to four well heads 200 e-h via an optional well head manifold 220b. Four riser fluid transfer 20 streams 210 e-h connect well heads 200 e-h to the well head manifold 220b. Two further riser fluid transfer streams 210 1, m connect the well head manifold 220 b to the riser base manifold 300b. The well heads 200 are in fluid communication with the one or more riser fluid 25 reservoirs 250 which lie beneath the sea bed 500. In this way, riser fluid such as a hydrocarbon fluid can be conveyed from one or more hydrocarbon reservoirs 250 to the floating vessel 100. Similarly, a riser fluid comprising carbon dioxide can be conveyed from the 30 floating vessel 100 to the one or more riser fluid reservoirs for carbon sequestration. The mooring lines 610 are intended to maintain the mooring point of the floating vessel 100 in a fixed WO 2010/133564 PCT/EP2010/056768 - 14 position. However, the mooring lines 610, which may be steel chains, allow a degree of movement such that the mooring point of the floating vessel 100 can move in response to wave motion, such as the heave and/or pitch 5 of the floating vessel 100. Under severe weather conditions, the wave motion may become so significant that the one or more flexible risers are in danger of buckling. As previously discussed, riser buckling may occur when the terminal 10 velocity of the riser in the sea water is exceeded by the hang-off velocity of the first end 20 of the riser 10 where it is connected to the floating structure 100.. When the downward velocity of the riser at the hang-off point due to the heave and/or pitch of the floating 15 vessel 100 is greater than the terminal velocity of the flexible riser in the water, the riser will come under compression. Such compressive stresses can lead to buckling and permanent damage to the flexible riser. The method and apparatus disclosed herein seeks to 20 alleviate the problem of riser damage during severe weather conditions. In particular, at least a portion of the riser fluid, such as a hydrocarbon fluid or a carbon dioxide comprising fluid, in one or more of the flexible risers 10 is replaced with a protection fluid. The 25 density of the protection fluid is greater than the density of the riser fluid, such that the mass of the fluid in the riser 10 is increased for an equivalent fluid volume. Increasing the mass of the fluid in the riser increases the overall mass of the riser (i.e. the 30 mass of the riser plus fluid contents). Increasing the overall mass of the riser increases the terminal velocity of the riser in the water. This means that greater hang off velocities can be tolerated by the flexible riser WO 2010/133564 PCT/EP2010/056768 - 15 before the terminal velocity is exceeded. Greater hang off velocities correspond to higher heave and/or pitch at the hang-off point, such that more extreme sea conditions can be tolerated. 5 It is preferred that the density of the protection fluid is greater than 0.9 g/cm 3 , more preferably greater than 1.0 g/cm 3 , still more preferably greater than 1.1 g/cm 3 . The greater density of the protection fluid compared to the riser fluid, the greater the terminal 10 velocity increase of the flexible riser upon substitution of the riser fluid for the protection fluid. The greater the increase in the terminal velocity of the flexible riser, the greater the hang-off velocity which can be withstood without compressing the flexible riser. Thus, 15 it is preferred that the difference in density between the protection fluid and the riser fluid is at least 0.2 g/cm3, more preferably at least 0.4 g/cm 3 , even more preferably at least 0.6 g/cm 3 . Examples of suitable protection fluids are one or 20 more of the group comprising monoethylene glycol and hydrocarbon condensate. These fluids are particularly useful as protection fluids in the case where the riser fluid is a hydrocarbon fluid. The floating vessel 100 can comprise one or more hydrocarbon treatment units, such as 25 a separation unit, for instance a low pressure gas/liquid separator, to provide hydrocarbon condensate from a hydrocarbon riser fluid. The hydrocarbon fluid is preferably in stabilised form. Thus, a store of hydrocarbon condensate may be present in the floating 30 vessel, for instance in a condensate storage tank. In those cases where the hydrocarbon condensate has a density greater than the riser fluid, for example if the riser fluid is an unprocessed hydrocarbon stream, such as WO 2010/133564 PCT/EP2010/056768 - 16 a natural gas stream, the store of hydrocarbon condensate can comprise one source of protection fluid. In an alternative embodiment, in some cases where the riser fluid is hydrocarbon fluid, it may be necessary to 5 inject a hydrate inhibitor, such as monoethylene glycol (MEG), into the hydrocarbon fluid. For instance, the hydrate inhibitor can be injected to the hydrocarbon fluid at or before it emerges from the well heads 200 to prevent hydrate formation in the riser fluid transfer 10 streams 210 and the flexible risers 10. In this case, the floating vessel 100 could comprise a hydrate inhibitor storage tank, such as a MEG storage tank. The floating vessel 100 may also comprise a hydrate inhibitor regeneration unit, to separate the hydrate inhibitor from 15 the riser fluid. In those cases where the hydrate inhibitor has a density greater than the riser fluid, the store of hydrate inhibitor can comprise one source of protection fluid. In one embodiment, a MEG storage tank is provided 20 having a capacity such that 15-20% of the tank capacity of MEG can completely fill all of the flexible risers 10 with protection fluid. In such a case, it is preferred to maintain a minimum content of MEG in the tank of 15-20% to ensure that sufficient MEG is available to provide 25 maximum protection (i.e. completely fill) to each of the flexible risers 10. It is preferred that the one or more flexible risers 10 are filled with protection fluid from the first end connected to the floating structure 100. This allows the 30 protection fluid to be stored on the floating structure 100. Preferably, a portion of the riser fluid in each of the one or more flexible risers 10 is replaced with the WO 2010/133564 PCT/EP2010/056768 - 17 protection fluid. In this way, all of the flexible risers 10 may be protected from damage during adverse weather conditions. Still more preferably, the portion of the riser fluid replaced with the protection fluid is the 5 same in each riser. This is advantageous because the same mass is added to each riser. For identical risers, each riser will thus have the same terminal velocity in the sea water and therefore exhibit similar dynamic behaviour. 10 It is not advisable to replace different portions of the riser fluid with protection fluid in each flexible riser, because different risers will exhibit different dynamic behaviour, which can lead to collisions between adjacent flexible risers in response to movement of the 15 floating structure 100. It is particularly preferred to completely replace all of the riser fluid in the flexible riser with protection fluid. In the case where each riser was initially completely filled with riser fluid, this would 20 lead to completely filling each flexible riser with protection fluid. In doing so, a maximum gain for the overall riser mass using the method disclosed herein is achieved. This maximises the terminal velocity of the flexible riser in sea water. Consequently, the severity 25 of the weather conditions which can be withstood by the flexible risers is increased. In order to carry out the method disclosed herein, a decision must be taken to replace at least a portion of the riser fluid with protection fluid in one or more of 30 the flexible risers. Thus, the method may comprise the further step of: - monitoring the weather conditions in a zone around the floating structure 100 for one or more measured weather WO 2010/133564 PCT/EP2010/056768 - 18 variables and carrying out steps (b) and (c) when said one or more measured weather variables meet predetermined criterion or criteria. The zone around the floating structure 100 should be of a 5 size sufficient to allow the method disclosed herein to be carried out before the arrival of the adverse weather conditions at the floating structure 100. For instance, the zone may be 200 km around the floating structure 100, and more preferably 500 km around the floating structure 10 100 to allow sufficient time to replace the riser fluid with protection fluid. The adverse weather conditions are evaluated using one or more weather variables. The one or more weather variables include one or both of wind speed and wave 15 height. It is preferred that the predetermined criterion or criteria is indicative or predictive of a situation in which the hangoff velocity of the first end 20 of the flexible riser 10 approaches the terminal velocity of the 20 flexible riser 10 in operation i.e. when filled with riser fluid. The predetermined criterion can be selected from wind speeds in excess of 60 ms'. For instance, wind speeds in the range of 70-74 ms' are indicative of a 10000 year 25 cyclone. Alternatively the predetermined criterion can be selected from significant wave heights. For instance the predetermined criterion can be 16 m or greater significant wave height. The significant wave height is 30 for instance the wave height which is exceeded by 2/3 of the waves during a storm.
WO 2010/133564 PCT/EP2010/056768 - 19 Once the severe weather has passed, the flexible risers 10 can be returned to normal operation. Thus, the method may comprise the further steps of: (d) opening the fluid connection between the one or more 5 flexible risers 10 and the one or more riser fluid reservoirs 250; (e) passing the protection fluid from the one or more of the flexible risers 10 to the floating structure 100 as a spent protection fluid stream; and 10 (f) treating the spent protection fluid stream on the floating structure 100 to regenerate the protection fluid. Although it is possible to provide a dedicated unit for the treatment of the spent protection fluid on the 15 floating structure 100, it is preferred if the spent protection fluid can be processed by a unit already present for the treatment of the riser fluid. For instance, when the riser fluid is a hydrocarbon fluid which has been treated with a hydrate inhibitor, the 20 spent protection fluid, which will be rich in hydrate inhibitor such as MEG, but may also contain a small amount of hydrocarbon fluid not displaced from the flexible riser, can be sent to the hydrate inhibitor treatment unit for processing. This procedure may result 25 in a plug of hydrate inhibitor, such as MEG, requiring processing. If this plug of hydrate inhibitor exceeds the capacity of the inlet facilities, which can be designed to process the hydrate inhibited hydrocarbon fluid, the flow rate to the inlet facilities can be reduced until 30 all the spent protection fluid rich in hydrate inhibitor is processed. After the plug of spent protection fluid has been processed by the inlet facilities of the floating structure 100, normal production can be resumed.
WO 2010/133564 PCT/EP2010/056768 - 20 Figure 2 provides a further schematic for the method and apparatus disclosed herein, and in particular shows the connectivity of the first and second ends 20, 30 of the flexible risers 10 to the sea bed 500 and floating 5 structure 100. For the purposes of clarity, the numbers of mooring lines 610a, e and flexible risers 10a, 10e have been reduced to two each, although any number, such as 4-6 arranged in two or more separate bundles is envisaged. 10 The flexible risers 10a, 10e have first ends 20a, 20e connected to the floating structure 100, which is shown as vessel in Figure 2. The first ends 20 a, e of the flexible risers are secured to the floating vessel 100 at a turret 150. The turret 150 is connected to the sea bed 15 500 by the mooring lines 610a, 610b. The floating vessel 100 is provided with one or more bearings allowing the rotation of the vessel around the turret 150. In this way, the floating vessel may weather vane around the earth-fixed turret, such that the vessel 20 may be orientated to present the bow to the direction of the prevailing weather conditions, such as the incoming wave or wind. In a preferred embodiment, the turret 150 is provided towards an end of the floating vessel 100, to allow optimal rotation in response to the prevailing 25 weather conditions. This allows processing units 400, such as a natural gas treatment and liquefaction unit, which is discussed in greater detail below, to be placed behind the turret 150 along the deck of the floating vessel. 30 The turret 150 comprises one or more bending stiffeners 160a, b which route the flexible risers 10a, e through one or more I-tubes 170a, b to a hang-off deck WO 2010/133564 PCT/EP2010/056768 - 21 180. The hang-off deck 180 secures the first end 20 a, e of each of the flexible risers 10a, e. The first end 20 a, e of each of the flexible risers 10a, e is in fluid communication with a first end 5 connection 22a, 22e for the first riser fluid stream 40. The first ends 20 a, e can be in communication with the first end connections 22 a, e via a turret piping connection. Each first end connection 22a, 22e for the riser fluid stream 40 is connected to a riser emergency 10 shutdown valve 190a, e. An inlet 24a, 24e for the protection fluid stream 120, which is in fluid communication with the outlet 112 of a protection fluid storage tank 110, is also in fluid communication with the first end 20 a, e of each flexible riser 10 a, e. It is 15 apparent from Figure 2 that the inlets 24a, 24e for the protection fluid stream 120 are separate from the first end connections 22a, 22e for the first riser fluid stream 40. Rotating pipe connections in a swivel stack allow the riser fluid stream 40 and protection fluid stream 120 to 20 pass between the turret 150 and the rest of the floating structure 100. Thus a constant fluid connection is maintained even when the floating vessel is rotating around the turret 150. The protection fluid stream 120 can be passed to each 25 first inlet 22a, g and on to the first ends of the flexible risers 10a, e. By filling the flexible risers 10a, e from their first ends, the protection fluid can displace at least a portion of the riser fluid in one or more of the flexible risers. The displaced riser fluid, 30 which is less dense than the protection fluid, will be forced upwards as the flexible risers 10a, e fill with protection fluid such that the riser fluid can exit the risers at first ends 20 a, e, passing out of first end WO 2010/133564 PCT/EP2010/056768 - 22 connection 24a, e, which can be an outlet. The riser fluid can be passed to the processing units 400 as the riser fluid stream 40. The second end 30a, 30e of each flexible riser 10a, e 5 is on the sea bed 500. Each second end comprises a second end connection 32a, e which is in fluid communication with a riser fluid transfer stream 210a, b, g, h. The riser fluid transfer streams 210a, b, g, h are in fluid communication with one or more riser fluid reservoirs 10 250. In a preferred embodiment, the second end 30a, e of each flexible riser 10a, e is secured to the sea bed 500 by connection to a riser base manifold 300a, b. The riser base manifold 300a, b is rigidly fixed to the sea bed 500. 15 The riser base manifolds 300a, b comprise first manifold connections 302a, b, c, d to the riser fluid transfer streams 210a, b, g, h. Second manifold connections 304a, b are connected to the second end connections 32a, e of the flexible risers 10a, e. 20 In the embodiment of Figure 2, the riser fluid transfer streams 210 may be natural gas transfer streams. The one or more riser fluid reservoirs 250 can be natural gas reservoirs. The riser fluid stream 40 can be a natural gas stream. In this case, the natural gas 25 reservoirs 250 may be connected to the riser fluid transfer streams 210 via well heads 200a, b, g, h. Figure 2 shows a natural gas treatment and liquefaction unit 400 on the floating structure 100. This unit can be used for the pre-treating and cooling of the 30 riser fluid when this is natural gas. The arrangement discussed below is exemplary only and is not limited to the combination of the units described. Other, alternative line-ups will be known to the skilled person.
WO 2010/133564 PCT/EP2010/056768 - 23 Usually a natural gas stream 40 is comprised substantially of methane. Preferably the natural gas stream comprises at least 50 mol% methane, more preferably at least 80 mol% methane. 5 Depending on the source, natural gas may contain varying amounts of hydrocarbons heavier than methane such as in particular ethane, propane and the butanes, and possibly lesser amounts of pentanes and aromatic hydrocarbons. The composition varies depending upon the 10 type and location of the gas. Conventionally, the hydrocarbons heavier than methane are removed as far as efficiently possible from the natural gas stream prior to any significant cooling for several reasons, such as having different freezing or 15 liquefaction temperatures that may cause them to block parts of a methane liquefaction plant. The natural gas stream can first undergo acid gas removal by passing through an acid gas removal (AGR) unit or system, which may be a separate or dedicated unit, or 20 integrated with one or more other units or apparatus. The AGR system provides a process for the removal of carbon dioxide and hydrogen sulphide and/or COS in a manner known in the art, for example one or more of the methods described in WO 03/057348 Al. 25 The AGR system provides a treated natural gas stream. The treated natural gas stream can then pass into a first cooling stage which may comprise part of a cooling system and/or liquefaction system. The first cooling stage may comprise one or more heat exchangers in parallel and/or 30 series, and is able to reduce the temperature of the treated natural gas stream, preferably below 0 0C, and more preferably in the range -10 0C to -70 0C, and provide a cooled natural gas stream.
WO 2010/133564 PCT/EP2010/056768 - 24 The first cooling stage may have any configuration known in the art, and generally includes one or more refrigerant circuits passing one or more refrigerants to provide cold or cold energy to the treated hydrocarbon 5 stream. An example refrigerant circuit is a propane refrigerant circuit known in the art. A first refrigerant circuit can pass through the first cooling stage, from which the refrigerant stream, expanded after providing its cooling to treated 10 hydrocarbon stream, passes into a first stage compressor for recompression. The first stage compressor may comprise one or more compressors in series or parallel in a manner known in the art. Compression of the refrigerant usually increases the refrigerant temperature, such that 15 it is commonly cooled by one or more heat exchangers downstream of the first stage compressor. The downstream heat exchanger(s) may comprise one or more ambient water and/or air coolers known in the art. The cooled natural gas stream can pass through a 20 second cooling stage, again comprising one or more heat exchangers in parallel and/or series and designed to further cool and/or liquefy the cooled natural gas stream, to provide a further cooled natural gas stream, which is preferably a liquefied natural gas stream. The 25 further cooled natural gas stream can be passed into storage such as to one or more storage tanks, or be passed through a further pipeline or conduit to one or more storage tanks located elsewhere, such as on a land based facility or other floating vessel. The other 30 floating vessel may be an LNG carrier. As with the first cooling stage, the second cooling stage may involve one or more refrigerant circuits having a refrigerant adapted to provide the further cooling to WO 2010/133564 PCT/EP2010/056768 - 25 the cooled natural gas stream. An example refrigerant circuit is a mixed refrigerant, and the second cooling stage could reduce the temperature of the cooled natural gas stream to below -100 0C, preferably below -150 0C. 5 In the second cooling circuit, expanded refrigerant from the second cooling stage can pass through a second stage compressor (which may comprise one or more compressors in parallel and/or series), to provide a compressed stream which is usually then cooled by one or 10 more downstream heat exchangers, for example ambient water and/or air coolers. The refrigerant stream in the second refrigerant circuit can then pass through the first cooling stage in a manner known in the art, optionally with a first passage through the second 15 cooling stage for further cooling, prior to reaching a valve for expansion and reuse in the second cooling stage in a manner known in the art. One or more of the AGR system and the first and second cooling stages may include one or more generators 20 such as gas turbines, to drive one or more devices, units or separators therein, such as, by way of example only, the first and second compressors. The person skilled in the art will understand that the present invention can be carried out in many various 25 ways without departing from the scope of the appended claims.
Claims (14)
1. A method of protecting one or more flexible risers (10) in a sub sea environment, comprising at least the steps of: (a) providing a floating structure (100), one or more 5 flexible risers (10), each of said flexible risers carrying a riser fluid and having a first end (20) connected to the floating structure (100) and a second end (30) on the sea bed (500) and in fluid connection with one or more riser fluid reservoirs 10 (250); (b) closing the fluid connection between the one or more flexible risers (10) and the one or more riser fluid reservoirs (250); (c) replacing at least a portion of the riser fluid in 15 one or more of the flexible risers (10) with a protection fluid, wherein the density of said protection fluid is greater than the density of said riser fluid.
2. The method according to claim 1, wherein in step (c) 20 the protection fluid displaces at least a portion of the riser fluid in one or more of the flexible risers (10), such that the displaced riser fluid exits at a first end connection (22), which is an outlet in direct fluid communication with the first end (20) of the flexible 25 riser (10).
3. The method according to claim 1 or 2, wherein the floating structure (100) comprises a protection fluid storage tank (110), said protection fluid storage tank comprising an outlet (112) for a protection fluid stream 30 (120); and WO 2010/133564 - 27 - PCT/EP2010/056768 wherein each of said flexible risers has a first end (20) connected to said floating structure (100), said first end (20) in direct fluid communication with a first end connection (22) for a riser fluid stream (40) and an 5 inlet (24) for the protection fluid stream (120) in fluid communication with the outlet (112) of the protection fluid storage tank (110), said inlet (24) being separate from said first end connection (22).
4. The method of claim 3, wherein step (b) includes 10 closing the second end (30); and wherein step (c) includes introducing the protection fluid stream (120) into the one or more risers via the inlet (24) to replace at least a portion of the riser fluid; and 15 removing the replaced portion of the riser fluid via the first end connection (22) for the riser fluid stream (40).
5. The method according to any of the preceding claims, wherein said riser fluid comprises carbon dioxide and 20 said one or more riser fluid reservoirs (250) are sealed subsurface geological formations; said method further comprising, between steps (a) and (b), the step of: - passing the riser fluid comprising carbon dioxide from the floating structure (100) through at least the one 25 or more flexible risers (10) to the one or more sealed subsurface geological formations (250).
6. The method according to any of the preceding claims, wherein said riser fluid is a hydrocarbon production fluid and said one or more riser fluid reservoirs (250) 30 are hydrocarbon reservoirs; said method further comprising, between steps (a) and (b), the step of: - passing the hydrocarbon production fluid from the one or more hydrocarbon reservoirs (250) through at least WO 2010/133564 - 2 8 - PCT/EP2010/056768 the one or more flexible risers (10) to the floating structure (100).
7. The method according to any of the preceding claims wherein the protection fluid has a density of greater 5 than 0.9 g/cm 3 , preferably greater than 1.0 g/cm 3 , more preferably greater than 1.1 g/cm 3 .
8. The method according to claim 6 or claim 7 wherein the protection fluid is selected from one or more of the group comprising monoethylene glycol and hydrocarbon 10 condensate.
9. The method according to any of the preceding claims wherein in step (c) the one or more of the flexible risers (10) are filled with protection fluid from the first end (20) connected to the floating structure (100). 15
10. The method according to any one of the preceding claims, wherein the riser fluid is a hydrocarbon production fluid and the one or more riser fluid reservoirs (250) are hydrocarbon sub sea reservoirs, and further comprising the step of treating the hydrocarbon 20 production fluid on board the floating structure (100) to provide a liquefied hydrocarbon stream.
11. An apparatus (1) for protecting one or more flexible risers (10) in a sub sea environment, said apparatus comprising at least: 25 - a floating structure (100) comprising a protection fluid storage tank (110), said protection fluid storage tank comprising an outlet (112) for a protection fluid stream (120); - one or more flexible risers (10), each of said flexible 30 risers having a first end (20) connected to said floating structure (100), said first end (20) in direct fluid communication with a first end connection (22) for a riser fluid stream (40) and an inlet (24) for the WO 2010/133564 - 29 - PCT/EP2010/056768 protection fluid stream (120) in fluid communication with the outlet (112) of the protection fluid storage tank (110), said inlet (24) being separate from said first end connection (22), and each of said flexible 5 risers (10) having a second end (30) on the sea bed (500), said second end having a second end connection (32) for a riser fluid transfer stream (210) in fluid communication with one or more riser fluid reservoirs (250). 10
12. The apparatus according to claim 11 wherein the second end (30) of the flexible riser (10) is connected to a riser base manifold (300) which is rigidly fixed to the sea bed, said riser base manifold having a first manifold connection (302) for the riser fluid transfer 15 stream (210) and a second manifold connection (304) connected to the second end connection (32) of the flexible riser (10).
13. The apparatus according to claim 11 or claim 12 wherein the first end (20) of the flexible riser (10) is 20 connected to the floating structure (100) at a turret (150) comprising one or more bending stiffeners (160) to route the one or more flexible risers (10) through one or more I-tubes (170) to a riser hang-off deck (180) where the first end (20) of each of said flexible risers (10) 25 is secured, with the first end connection (22) for the riser fluid stream being connected to a riser emergency shutdown valve (190).
14. The apparatus according to any on of claims 11 to 13 in which the riser fluid transfer stream (210) is a 30 natural gas transfer stream, the one or more riser fluid reservoirs (250) are natural gas reservoirs, the riser fluid stream is a natural gas stream and the floating WO 2010/133564 - 3 0 - PCT/EP2010/056768 structure (100) further comprises one or both of a natural gas treatment unit and a liquefaction unit (400)
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EP09160763A EP2253796A1 (en) | 2009-05-20 | 2009-05-20 | Method of protecting a flexible riser and an apparatus therefor |
PCT/EP2010/056768 WO2010133564A2 (en) | 2009-05-20 | 2010-05-18 | Method of protecting a flexible riser and an apparatus therefor |
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GB2495287B (en) * | 2011-10-03 | 2015-03-11 | Marine Resources Exploration Internat Bv | A riser system for transporting a slurry from a position adjacent to the seabed to a position adjacent to the sea surface |
CN103453318B (en) * | 2013-09-04 | 2015-11-04 | 中国海洋石油总公司 | The storage of offshore platform lean glycol and delivery method |
WO2015108915A1 (en) * | 2014-01-15 | 2015-07-23 | Bright Energy Storage Technologies, Llp | Underwater energy storage using compressed fluid |
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US11827317B1 (en) * | 2022-05-04 | 2023-11-28 | Storeco2 Uk Limited | Carbon dioxide transport and sequestration marine vessel |
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US5553976A (en) * | 1994-02-18 | 1996-09-10 | Korsgaard; Jens | Fluid riser between seabed and floating vessel |
US5875848A (en) * | 1997-04-10 | 1999-03-02 | Reading & Bates Development Co. | Weight management system and method for marine drilling riser |
WO2002087869A2 (en) * | 2001-04-27 | 2002-11-07 | Fiberspar Corporation | Improved composite tubing |
CN100379485C (en) | 2002-01-14 | 2008-04-09 | 国际壳牌研究有限公司 | Process for removing carbon dioxide from gas mixtures |
US20060031335A1 (en) * | 2004-08-05 | 2006-02-09 | International Business Machines Corporation | Managing contained e-mail |
US7721807B2 (en) | 2004-09-13 | 2010-05-25 | Exxonmobil Upstream Research Company | Method for managing hydrates in subsea production line |
FR2888305B1 (en) * | 2005-07-11 | 2008-12-12 | Technip France Sa | METHOD AND INSTALLATION FOR CONNECTING A RIGID UNDERWATER DRIVE AND A FLEXIBLE SUBMARINE CONDUCT |
GB2454396B (en) * | 2006-09-21 | 2012-04-11 | Shell Int Research | Floating system connected to an underwater line structure |
CA2867387C (en) * | 2006-11-07 | 2016-01-05 | Charles R. Orbell | Method of drilling with a string sealed in a riser and injecting fluid into a return line |
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