AU2008200266A1

AU2008200266A1 - Refractory material for cement industry kilns and use thereof

Info

Publication number: AU2008200266A1
Application number: AU2008200266A
Authority: AU
Inventors: Pedro Fajardo Sola
Original assignee: Individual
Current assignee: Individual
Priority date: 2001-01-26
Filing date: 2008-01-18
Publication date: 2008-02-07

Description

P/00/01Il Regulation 3.2

AUSTRALIA

Pazte,rs~Aci 1990 ORI GINAL COMPLETE SPECIFICATION STANDARD PATENT Invention title- Refractory material for cement industry kilns and use thereof The following statement is a full description of this invention, including the best method of performing it known to us: 00 C REFRACTORY MATERIAL FOR CEMENT INDUSTRY KILNS AND USE

STHEREOF

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DESCRIPTION

Cl SThe invention protected by this Patent is a refractory material for cement Sindustry kilns and the use thereof.

00 This material can be used to line the inside of cement industry kilns or placed in particular areas of the kiln with a view to refractory capacity.

The cement industry is familiar with the use of refractory materials to line the interior of the kilns used to manufacture the said product in order to withstand the high working temperatures, which can reach around 1500 degrees Celsius in some areas, and the resulting physical and chemical reactions. However, the differing compositions of the refractory materials also lead to their having differing degrees of hardness and resistance to the deformation that is caused by the differences in kiln temperature in different parts of the same kiln, among other factors. This invention achieves a refractory material of greater hardness and resistance than the materials hitherto employed.

Various refractory materials are currently known and used but they all present drawbacks, both operative and functional, particularly as regards progressive deformation by high kiln temperatures, spalling and cracking.

Consequently, the use of the materials developed to date always presents certain limitations compared to the invention described herein, as a result of its technical and cost advantages. Already known refractory materials are the addition of glass-manufacture crucibles, lime, silica, chromium, magnetite, aluminium oxide and aluminous silica glass Norton, Refractarios, first 00 2 O Spanish edition published by Blume in 1972), as well as Japanese patents no.

C JP11230679 concerning variations in porosity of refractory bricks, no.

CJP11130485 as prefabricated panels or no. JP11201649 as glass textures; in n 00 relation to the arrangement of shapes of the materials the outstanding examples are European patent no. EP0911594 and the German patent DE19729582 IDconcerning prefabricated bricks. All of these are prior to the invention described IDherein but are generic and imprecise compared to the same, and are often Sdesigned for the steel industry; in all these inventions the resulting chemical 0 composition or form are either not applied to the peculiarities of the cement industry or are not detailed and not sufficiently established compared to that described herein.

These deficiencies are overcome by the chemical composition of this invention, a neo-silicate such as Andalucite (AI 1 1 Si0 4 a crystalline solid such as silicon carbide SIC and a hydroaluminosilicate pelitic rock such as clay.

This composition surpasses the above-mentioned limitations and increases the operational capacity and performance of the material, while its application presents certain features that significantly favour its use in cement industry kilns.

All the foregoing helps to achieve results as regards refractory quality, location within the kilns and resistance to alterations in shape wherever the invention is used (whether in geometrical configurations such as bricks or in formless configurations such as mortar) that already-known media do not provide.

00 3 The invention described herein combines certain chemical compounds Nfor their physical properties: Andalucite Al 11 SiO 4 for its low porosity, low thermal conductivity and refractory capacity, silicon carbide SiC for its 00 resistance to oxidation and abrasion, while also being highly refractory, and clay for its plasticity.

This three-part combination of solid crystalline compounds formed from 00 silicon can be made up of different proportions by weight of each of its 0 10 constituents in order to achieve a greater or lesser degree of thermal conductivity, according to the location and function of the refractory material in the different parts of the kiln.

In short, the result obtained by combining these components makes it possible to obtain a technical advantage with a product of greater hardness and greater resistance to the deformation caused by the heat inside cementproduction kilns and the physical and chemical reactions that occur within the said kilns. This leads to considerable cost advantages as the new invention reduces the number of kiln stoppage cycles for maintenance and replacing worn material in each work period. As well as these technical and cost improvements, it also results in a production process advantage for the most widely and frequently found kilns, those of the rotary type, as it achieves greater resistance and hardness in the materials arranged inside the kiln to assist the circulation of the cement clinker being processed such as retainers and areas with shapes or in the satellite coolers, with staggered :orms and elliptical inlets, respectively, and is consequently more efficient in maintaining their design and function.

For a better understanding of the above-mentioned general characteristics, drawings are attached hereto showing the following: Figure 1: Outline drawing of a rotary kiln with satellite coolers for the cement industry, in a configuration comprising a heat exchanger and a calcination area 2 safety area 3 transition area 4 sintering area outlet area coolers 7 kiln head 8 and flame burner 9).

Figure 2: Outline drawing of a rotary kiln with grate coolers for the cement industry, in a configuration comprising a heat exchanger 1 and a calcination area 2 safety area 3 transition area 4 sintering area 5 outlet area 6 coolers kiln head 8 and flame burner 9 The refractory material can be made up and placed as follows: As regards the chemical components, a percentage by weight of andalusite All 1 1 Si04 of 10-80%, a percentage by weight of silicon carbide SiC of 10-80% and a percentage by weight of clay of 10-15%.

The preferable average composition is in the following proportions: Andalusite( A I1 1 SiO4): Silicon carbide SiC): Clay: Percentage by weight 55 35 10 Given its cost advantages, kaolinite AI4 [(OH) 8 (Si0 4 4 can also be used instead of andalusite, in equal proportions.

00 0 c" As regards its location in the kilns, the areas where this refractory oo material is used are: the calcination area 2 the safety area 3 the transition area the kiln outlet 6 and the coolers (7

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Claims

2. Use of the refractory material as claimed under Claim 1, characterised by the use thereof to line the inside of cement industry kilns in the calcination areas 2 in the safety area 3 in the outlet area 6 and in the coolers 7).
3. Refractory material for cement industry kilns and its use for resistance to thermal, physical and chemical deformation, characterised by a chemical composition that combines a percentage by weight equal to or greater than of kaolinite AI4 [(OH) 8 (SiO 4 4 a percentage by weight equal to or greater than 10 of silicon carbide SiC and a percentage by weight equal to or greater than 5 of clay.