AU2005309556A1

AU2005309556A1 - Vaccinium injection molding

Info

Publication number: AU2005309556A1
Application number: AU2005309556A
Authority: AU
Inventors: Glen Axelrod
Original assignee: TFH Publications Inc
Current assignee: TFH Publications Inc
Priority date: 2004-11-22
Filing date: 2005-11-22
Publication date: 2006-06-01
Also published as: WO2006058110A3; CN101111160A; EP1814806A2; WO2006058110A2; CA2588458A1; US20060110501A1

Description

WO 2006/058110 PCT/US2005/042525 VACCINIUM INJECTION MOLDING Cross Reference To Related Applications The present application claims the benefit of the filing date of U.S. Utility Application 5 Ser. No. 10/995,028 filed November 22, 2004, the teachings of which are incorporated herein by reference. Field of Invention The present invention relates to animal chews and animal chew additives. More 10 specifically, the present invention relates to the addition of vaccinium powder to animal chews either of the edible or non-edible type, depending upon the edible and/or plastic type carrier ingredients. Background 15 Most dogs and other animal pets enjoy chewing on various items, and many are especially attracted to animal bones and animal-derived chew toys. A variety of products have been manufactured to provide animal pets with objects to chew or gnaw. These products are intended to provide the pet with exercise for the teeth to maintain a healthy condition satisfying a need that arose when the natural pet food, raw meat, was replaced with 20 processed pet foods. Rawhide strips knotted on the ends to resemble bones, for example, provide abrasion for cleaning teeth by removing tartar and massaging the gums, which is not provided by the typical canine dog food. Numerous pet chews have been developed to address the various dental and nutritional concerns. Examples of these devices include but are not limited to the following 25 U.S. Patents. These patents are commonly owned by the assignee herein: U.S. Pat. No. 5,476,069 entitled "Molded Rawhide Chew Toy"; U.S. patent application Ser. No. 08/923,070 filed Sep. 3, 1997 entitled "Vegetable Based Dog Chew now U.S. Pat. No. 6,093,427; U.S. patent application Ser. No. 08/738,423 filed Oct. 25, 1997 entitled "Edible Dog Chew" now U.S. Pat. No. 5,827,565; U.S. patent application Ser. No. 08/784,834 filed 30 Jan. 17, 1997 entitled 'Carrot-Based Dog Chew" now U.S. Pat. No. 5,941,197; U.S. patent application Ser. No. 09/114,872 filed Jul. 14, 1998 entitled "Heat Modifiable Edible Dog Chew" now U.S. Pat. No. 6,180,161; U.S. patent application Ser. No. 09/138,804 filed Aug. 1 WO 2006/058110 PCT/US2005/042525 21, 1998 entitled "Improved Edible Dog Chew" now U.S. Pat No. 6,126,978; U.S. patent application Ser. No. 09/116,070 filed Jul. 15, 1998 entitled "Wheat & Casein Dow Chew With Modifiable Texture" now U.S. Pat. No. 6,110,521; U.S. patent application Ser. No. 09/116,555 filed Jul. 15, 1998 entitled "Heat Modifiable Peanut Dog Chew" now U.S. Pat. 5 No. 6,093,441; U.S. patent application Ser. No. 09/227,767 filed Jan. 8, 1999 entitled "Method of Molding Edible Starch" now U.S. Pat. No. 6,159,516; and U.S. Patent No. 6,200,616 entitled "Animal Chew". U.S. Patent No. 5,407,661 entitled "Pet Chew Product Having Oral Care Properties" discloses an edible pet chew product having a flexible cellular matrix in which is contained 10 cellulosic fibrous material such as corn cob fractions which are described as having a mechanical cleansing function when chewed by a pet. Other earlier examples of chew products are disclosed in U.S. Patent No. 3,871,334 to Axelrod (nylon substrate containing liquid flavor and odor components), U.S. Patent No. 4,771,733 to Axelrod (polyurethane toy containing aqueous-based flavor and odor 15 components), and U.S. Patent Nos. 4,557,219 and 4,513,014 to Edwards (use of flavorings in a molded polyurethane dog chew). European Patent 0 272 968 BI discloses a chewable product for dogs and other domestic animals wherein certain aqueous solutions of oral care agents, e.g., sodium fluoride (anti-caries agent), sodium benzoate (anticalculus agent) and bromochlorophene 20 (antimicrobial/antiplaque agent) are used to soak rawhide, beef tendon, or ligament. The solution treated product is then dried whereby the oral care agents are absorbed into the surface of the product. As is apparent from the above review of the prior art, a variety of efforts have been made to create animal pet chews and particularly dog chews that are nutritionally satisfying, 25 digestible, devoid of deleterious additives and/or of modifiable texture or hardness. An object of the present invention is to improve and expand upon the art of providing nutritional and dental supplementation in animal pet chew and particularly dog chews. Furthermore it is an object of the present invention to provide an additive that introduces both a flavoring and a colorant to starch media hereinbefore not seen in the art. 30 Furthermore, it is an object of the present invention to provide an additive that supplements nutritional pet chews with an antioxidant. 2 WO 2006/058110 PCT/US2005/042525 Summary According to one aspect, the present invention provides an animal chew comprising a resin and a vaccinium additive, wherein the resin may be selected from the group consisting of starch, thermoplastic, casein, denatured and partially hydrolyzed collagen, wheat gluten, 5 rawhide, moldable proteins, and mixtures thereof. According to another aspect, the present invention provides a process for forming a molded animal chew comprising providing a resin and a vaccinium additive, wherein the resin is selected from the group consisting of starch, thermoplastic, casein, denatured and partially hydrolyzed collagen, wheat gluten, rawhide, moldable proteins and mixtures thereof; 10 combining the resin and vaccinium additive to form a mixture; introducing and mixing the mixture in a melt mixing apparatus and forming the mixture into a desired shape. Detailed Description The present invention relates to animal chews and animal chew additives. More 15 specifically, the present invention relates to the addition of vaccinium to animal chews of either edible or non-edible type, depending upon the edible and/or plastic type carrier ingredients. An embodiment of the present invention relates to an animal chew comprising a starch and a vaccinium additive. Preferably, the vaccinium additive is a blueberry powder. 20 More preferably, the blueberry additive is prepared from a blueberry concentrate disposed on a malto-dextrin carrier. Most preferably, the vaccinium supplements the animal chew with an antioxidant. In the context of the present invention the vaccinium may be present at levels of about 0.1-40% (wt.), and all incremental values therebetween. In addition to the nutritional benefit of the vaccinium herein, it is worth noting that the 25 vaccinium powder also supplies a unique appearance and color to the chew product, along the lines of an aqua-marine type color. It is also believed to provide an attractive flavor for the pet, thereby making the treats herein desirable to various pets. Preferably, the starch is composed of any carbohydrate of natural or vegetable origin composed mainly of amylase and/or amylopectin. More preferably, the starch may be 30 isolated from potato, rice, tapioca, corn, rye, oats or wheat. As alluded to above, the starch may be present at levels between 99% - 60 % (wt.), and at all incremental values therebetween. 3 WO 2006/058110 PCT/US2005/042525 In another embodiment of the present invention a thermoplastic (polyurethane, polyamide, ethylene copolymers), or a thermoplastic such as a polyesteramide may be mixed with the vaccinium. The amount of vaccinium may again be present at levels of between about 0.1-40% (wt.) and the thermoplastic present at levels of about 99% - 60% (wt.), and at 5 all incremental values therebetween. Most preferably, the thermoplastic is an aliphatic polyesteramide, a mixed aliphatic/aromatic polyesteramide, an aromatic polyesteramide, and a mixture thereof. In another embodiment of the present invention, a number of additives may be added to the vaccinium animal chew, of either the edible (starch) or plastic variety. Preferably, 10 these additives include attractants or humectants. More preferably, attractants such as chicken powder, liver powder, ham, turkey, beef or fish may be used. Also more preferable is the use of oat fiber, sorbitol, glycerol or propylene glycol as a humectant. In another embodiment, the present invention provides a process for forming a molded animal chew comprising combining starch (or thermoplastic) and a vaccinium 15 additive to form a mixture; introducing and mixing the mixture in a melt mixing apparatus such as an extruder or injection molding machine and forming the mixture. According, the mixture may be formed through extrusion and injection molding techniques into a desired shape. More preferably, the mixture may be formed by injection molding the mixture into a desired shape such as bone, a disk, a rod or a ring. 20 In the context of the melt processing herein, it is also preferable that the melt mixing is carried out under those conditions wherein any thermal degradation of the vaccinium is substantially minimized or avoided. In that context, moisture may be included in the mixture, at levels of between 1-40% (wt), and at all increments therebetween which moisture level is then selectively reduced during melt processing to a desired level. In that fashion, the 25 moisture serves to allow for melt processing at lower temperatures, thereby minimizing or avoiding thermal degradation of the vaccinium. In one particularly preferred process of manufacturing the animal chew toy herein, starch and water and vaccinium are first combined wherein the water content is in the range of 20-40% by weight with respect to that of said starch. The mixture is introduced into a 30 vented barrel extruder to form extruded beads, wherein the water content upon discharge is less than the water content of said mixture entering the extruder. 4 WO 2006/058110 PCT/US2005/042525 This is followed by introduction of the extruded beads to a heated injection molding machine containing a mold and injection molding and cooling to form the molded article wherein the water content of the molded article is at or below about 20% by weight, wherein the injection molding machine contains a hopper feed section, a barrel and an output nozzle, 5 including a plurality of heating zones in said barrel extending from said hopper section to said nozzle including a plurality of heating zones extending from the hopper section to said output section wherein the heating zones are set at the following temperature ranges: zone 1 is at or below about 70 0 F; zone 2 is at or below about 150 0 F, zone 3 is at or below about 300 0 F and zone 4 is at or below about 375 0 F and melt mixing and molding and cooling to 10 form said chew toy wherein the water content of said chew toy is between 5% and 20% with respect to the resin so that a portion of the vaccinium mixed therein is not thermally degraded by said molding. The foregoing description is provided to illustrate and explain the present invention. However, the description hereinabove should not be considered to limit the scope of the 15 invention set forth in the claims appended here to. 5

Claims

1. An animal chew comprising a resin and a vaccinium additive.

2. The animal chew of claim 1 wherein said resin is selected from the group consisting of starch, thermoplastic, casein, denatured and partially hydrolyzed collagen, wheat gluten, rawhide, proteins, and mixtures thereof.

3. The animal chew of claim 1 wherein said resin is present between about 60 99% by weight and said vaccinium additive is present between about 1-40% by weight.

4. The animal chew of claim 1 wherein said vaccinium additive comprises blueberry powder.

5. The animal chew of claim 4 wherein said vaccinium additive is prepared from a blueberry concentrate disposed on a malto-dextrin carrier.

6. The animal chew of claim 1 wherein said resin is a starch is composed of any carbohydrate of natural or vegetable origin composed of amylase and/or amylopectin.

7. The animal chew of claim 6 wherein said starch may be selected from a group consisting of potato, rice, tapioca, corn, rye, oats and wheat.

8. The animal chew of claim 1 wherein said resin is selected from the group consisting of polyurethane, polyamide, ethylene copolymers, polyesteramide and mixtures thereof.

9. The animal chew of claim 8 wherein said polyesteramide is selected from the group consisting of aliphatic polyesteramide, a mixed aliphatic/aromatic polyesteramide, an aromatic polyesteramide, and mixtures thereof.

10. The animal chew of claim 1 further comprising an attractant.

11. The animal chew of claim 10 wherein said attractant may be selected from the group consisting of chicken powder, liver powder, ham, turkey, beef or fish.

12. The animal chew of claim 1 further comprising a humectant.

13. The animal chew of claim 12 wherein said humectant may be selected from the group consisting of oat fiber, .sorbitol, glycerol, propylene glycol and mixtures thereof. 6 WO 2006/058110 PCT/US2005/042525

14. The animal chew of claim 1 wherein said animal chew is shaped like a bone, a rod, a disk or a ring.

15. An animal chew comprising a starch, water and a vaccinium additive, wherein the water content is between about 1-40 % (wt.) and said vaccinium additive is at about 0.1 - 40 % (wt).

16. A process for forming a molded animal chew comprising: providing a resin and a vaccinium additive; combining said resin and vaccinium additive to form a mixture; introducing and mixing said mixture in a melt mixing apparatus; and forming said mixture.

17. The process of claim 16 wherein said resin is selected from the group consisting of starch, thermoplastic, casein, denatured and partially hydrolyzed collagen, wheat gluten, rawhide, proteins and mixtures thereof.

18. The process for forming a molded animal chew of claim 16 wherein said resin is present between about 60-99% by weight and said vaccinium additive is present between about 0.1-40% by weight.

19. The process for forming a molded animal chew of claim 16 wherein said vaccinium additive is a blueberry powder.

20. The process for forming a molded animal chew of claim 19 wherein said vaccinium additive is prepared from a blueberry concentrate disposed on a malto-dextrin carrier.

21. The process for forming a molded animal chew of claim 17 wherein said starch is composed of any carbohydrate of natural or vegetable origin composed mainly of amylase and/or amylopectin.

22. The process for forming a molded animal chew of claim 21 wherein said starch may be selected from a group comprising potato, rice, tapioca, corn, rye, oats and wheat.

23. The process for forming a molded animal chew of claim 17 wherein said thermoplastic is selected from the group consisting of polyurethane, polyamide, ethylene copolymers, polyesteramide and mixtures thereof. 7 WO 2006/058110 PCT/US2005/042525

24. The process for forming a molded animal chew of claim 23 wherein said polyesteramide is selected from the group consisting of aliphatic polyesteramide, a mixed aliphatic/aromatic polyesteramide, an aromatic polyesteramide, and a mixture thereof.

25. The process for forming a molded animal chew of claim 16 further providing an attractant and combining said attractant to form said mixture.

26. The process for forming a molded animal chew of claim 25 wherein said attractant may be selected from the group comprising chicken powder, liver powder, ham, turkey, beef or fish.

27. The process for forming a molded animal chew of claim 16 further providing a humectant and combining said humectant to form said mixture.

28. The process for forming a molded animal chew of claim 25 wherein said humectant may be selected from the group consisting of oat fiber, sorbitol, glycerol, propylene glycol and mixtures thereof.

29. The process of forming a molded animal chew of claim 17 further providing water, present between about 1-40% (wt.) of the resin component, providing a resin component present between about 60-99% (wt)., wherein said resin is starch, and a vaccinium additive 0.1 to 40% (wt.).

30. The process for forming a molded animal chew of claim 16 further comprising injection molding said mixture.

31. The process for forming a molded animal chew of claim 16 further comprising injecting said mixture into a mold prior to forming said mixture.

32. The method of forming a molded animal chew toy of claim 16 wherein said heating zones are set at the following temperature ranges: zone 1 is at or below about 70'F; zone 2 is at or below about 150'F; zone 3 is at or below about 300 0 F and zone 4 is at or below about 375 0 F.

33. The process for forming a molded animal chew of claim 16 wherein said mixture is formed into a bone, a rod, a disk or a ring. 8