AU2005100765B4 - Clinoptilolite Algae Control - Google Patents

Clinoptilolite Algae Control Download PDF

Info

Publication number
AU2005100765B4
AU2005100765B4 AU2005100765A AU2005100765A AU2005100765B4 AU 2005100765 B4 AU2005100765 B4 AU 2005100765B4 AU 2005100765 A AU2005100765 A AU 2005100765A AU 2005100765 A AU2005100765 A AU 2005100765A AU 2005100765 B4 AU2005100765 B4 AU 2005100765B4
Authority
AU
Australia
Prior art keywords
water
clinoptilolite
selected quantity
sock
grains
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2005100765A
Other versions
AU2005100765A4 (en
Inventor
John Walters
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ALGON SOUTH COAST
Original Assignee
ALGON SOUTH COAST
STRONG NEVILLE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ALGON SOUTH COAST, STRONG NEVILLE filed Critical ALGON SOUTH COAST
Priority to AU2005100765A priority Critical patent/AU2005100765B4/en
Publication of AU2005100765A4 publication Critical patent/AU2005100765A4/en
Application granted granted Critical
Publication of AU2005100765B4 publication Critical patent/AU2005100765B4/en
Priority to PCT/AU2006/001314 priority patent/WO2007030859A1/en
Priority to AU2006292010A priority patent/AU2006292010A1/en
Assigned to WALTERS, JOHN, ALGON SOUTH COAST reassignment WALTERS, JOHN Request for Assignment Assignors: ALGON SOUTH COAST, Strong, Neville, WALTERS, JOHN
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/165Natural alumino-silicates, e.g. zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2805Sorbents inside a permeable or porous casing, e.g. inside a container, bag or membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/14Base exchange silicates, e.g. zeolites
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/002Grey water, e.g. from clothes washers, showers or dishwashers
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/42Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools

Description

P:\WPDOCS\GXS\LNM\IOO6kspm\WALTERS JOHN24 Muc11 12660251 Iinnowlimodoc-05/04/06 -1- WATER PURIFIER Field of the Invention The present invention relates generally to purifying and cleaning water to improve its support of marine animals and cleanliness for human consumption. In particular applications, the invention is used to control the growth of impurities such as algae, and to remove other impurities such as excess chlorine and nitrates from water in swimming pools, fish tanks, ponds and dams.
Background to the Invention Algae are a common problem in bodies of water such as for example swimming pools, fish tanks, ponds and dams, as are other impurities such as nitrates, phosphates, ammonium ions and phosphate ions. They interfere with and pollute ecosystems and reduce the amount of marine and other life which may be supported by the body of water.
It is known to purify water with zeolite including those from the heulandite family, in particular clinoptilolite, which, when placed in water, all act as a filter for various impurities such as ammonium ions and nitrate ions, as well as other harmful impurities.
One patent application, publication WO 85/04390, describes beds of zeolite which are used for ion-exchange in sewage which flows over the beds. However, the zeolite quickly becomes exhausted and must be regenerated by the addition of regenerating solution to the beds, in the form of potassium salts. This is expensive and time consuming and also provides the opportunity for potassium salts to contaminate the environment.
After the zeolite becomes exhausted, a shovel or other labour intensive device is used to remove the zeolite so as to replace it with a fresh batch.
P:\WPDOCS\CXS\LNMOO6\spcc\WALTERS JOHN\24 Much12660231 _i ovalw.doc.05/04/06 -2- The present invention seeks to ameliorate one or more of the abovementioned disadvantages.
Summary of the Invention According to one aspect of the present invention there is provided a water purification apparatus including: a selected quantity of a zeolite powder or a selected quantity of zeolite grains; and a bag or container inside which the selected quantity of zeolite powder or grains is disposed, the bag or container including walls which are at least partially constructed from filter elements which retain the selected quantity of zeolite powder or grains within the bag or container while being adapted to allow water to pass therethrough when in use.
Preferably the zeolite powder or zeolite grains is selected from the family of heulandite or clinoptilolite so as to facilitate ion exchange between contaminated water within which the bag or container is disposed in use and the heulandite or clinoptilolite.
Preferably the bag or container is a sock or sack made from cotton or nylon or polyester, or a blend of two or more of those materials.
According to another aspect of the present invention there is provided a method of purifying water which comprises the steps of: providing a bag or container which includes walls which are at least partially constructed from filter elements; providing a selected quantity of zeolite and/or heulandite and/or clinoptilolite; placing the selected quantity of zeolite and/or heulandite and/or clinoptilolite in the bag or container; and placing the bag in a contaminated body of water.
Preferably the method includes directing contaminated water through the bag for greater efficiency of decontamination.
P:\WPDOCS\GXS\NM\2006'spec\WALTERS JOHN\24 Muh_12660251 _innovwim.doc.05i4/6 -3- Preferably the method includes sprinkling a supplementary selected quantity of zeolite and/or heulandite and/or clinoptilolite onto a surface of the body of water so as to provide a type of deflocculant, or to facilitate decontamination of water in the body of water.
Description of the Preferred Embodiments In order to enable a clearer understanding, the invention will hereinafter be described with reference to drawings and description of a preferred embodiment. In the drawings: Fig. 1 is a perspective view of a water-permeable sack filled with clinoptilolite according to a preferred embodiment of the present invention; and Fig. 2 is a perspective view of a water-permeable elongate sock filled with clinoptilolite according to a preferred embodiment of the present invention which is suitable for use in dams.
Referring to Fig. 1 there is shown a water purification apparatus generally indicated at 10 including a bag or container 12 which has opposed walls 14 and 16 and has stitching 18 which seals ends 15 and 17. The walls 14 and 16 are constructed from filter material in the form of a cotton/nylon blend sack 22. The filter material 20 is adapted to inhibit powder or grains from passing through the walls 14 and 16, but to allow water through the walls 14 and 16.
Zeolite and/or Heulandite and/or Clinoptilolite (not shown) is disposed within the sack 22 before the ends 15 and 17 are sealed. This material is inside the sack 22 so as to extract ions and other salts and impurities from a body of water into which the water purification apparatus 10 may be installed when in use.
P:\WPDOCS\GXS\LNMU06\pc WALTES JOKN\24 Mrch_ 12660251- 66-o60iw.doc-0504/06 -4- For increased efficiency when in use, the sack 22 should be placed in a flow of water in the contaminated body of water.
The sacks may be any suitable size or shape they are square in plan view as shown in Figure 1, or elongate as shown in Figure 2.
In operation, after some months, the zeolite loses its ability to remove ions and pollutants from the body of water, a condition known as "exhaustion". When the zeolite is exhausted, the sack may simply be picked up, removed from the body of water and replaced with another sack for continued purification. The water purification apparatus is placed in a flow of water, such as a filter outlet and the like, so as to gain exposure to all the water in a body.
Preferred embodiments of the invention are applied as a quilt on a floor of a body of water, a sausage of apparatus across a weir, or sacks may be piled up like sandbags to provide a barrier to flow, so that the flow must be filtered by the zeolite or clinoptilolite.
Preferred embodiments may be placed in spa baths, swimming pools, rainwater tanks, bird baths, grey water treatment plants, and the like.
The clinoptilolite sacks of preferred embodiments of the present invention provide great advantages over the prior art, wherein the powder is not free to move about the body of water and thus it will not become suspended in solution, clouding the water, nor will it clog filters, become lost in discharge pipes or become lodged in the swimming costumes of water users. The water in spa baths need not be drained after a spa bath, because the zeolite will keep filtering it. This is a great water-saving feature of the present invention.
Finally, when the sack becomes exhausted, it is simply picked up, removed and replaced with another one. This occurs once every three months or so, depending on the proportions used (see example below for tested proportions).
P:NWPDOCS\GXS\LNMN200ftpm'%WALTERS JOHN\24 Mdch_12660251_innovtin.dom-05/04/06
EXAMPLE
Test results have shown that the zeolite continues to filter ions from a body of water for three months, provided that efficient ratios are maintained. It has been demonstrated that one kilogram of clinoptilolite powder will treat a body of water 1500 litres for up to three months.
If the body of water includes extremely bad pollution, a method to accelerate the filtering of pollutants is by placing the sack in the water, ensuring the sack is located in a flow of water, as well as sprinkling or broadcasting a secondary amount of clinoptilolite across the surface of the water (the powder will eventually sink to the floor of the water body) so as to provide a kind of deflocculant.
Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", and variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
The reference to any prior art in this specification is not, and should not be taken as, an acknowledgment or any form of suggestion that that prior art forms part of the common general knowledge in Australia.
Finally, it is to be understood that the inventive concept in any of its aspects can be incorporated in many different constructions so that the generality of the preceding description is not to be superseded by the particularity of the attached drawings. Various alterations, modifications and/or additions may be incorporated into the various constructions and arrangements of parts without departing from the spirit or ambit of the invention.

Claims (1)

19-05-'06 16:29 FROM-DCC SYDNEY +61292621080 T-213 P009/010 F-207 P:\WPDOCS'GXESNM'29OOatlAWALTERSI JOH4M hIUli5tiHoaa&ln-at- l S-6- The claims defining the invention are as follows: 1. A water purification apparatus including: a selected quantity ofa clinoptilolite powder or a selected quantity of clinoptilolite grains; and a bag or container into which the \0 selected quantity of clinoptilolite powder or grains is disposed, the bag or container o being in the form of a sock which includes walls which allow water to pass through, _but retain the clinoptilolite powder and/or grains. 2. A water purification apparatus according to claim 1 wherein the sock is constructed from cotton or nylon or polyester, or a blend of two or more of those materials. 3. A method of purifying water which comprises the steps of: providing quantity of clinoptilolite; placing the selected quantity of clinoptilolite in the sock; and placing the sock in a contaminated body of water so that the clinoptilolite may be easily removed when it becomes exhausted. COMS ID No: SBMI-03646250 Received by IP Australia: Time 16:31 Date 2006-05-19 19-05-'06 16:30 FROM-DCC SYDNEY +61292621080 T-213 P010/010 F-207 tAWX)O5lXiUao'spKc\*At6A )OtHfl4 )mfctl&I25UMll~ 1idC df.-IDSr 0 7 0-7- ci 4. The method of purifying water according to claim 4 wherein the method includes the step of sprinkling a supplementary selected quantity clinoptilolite onto a surface of the body of water so as to provide a type ofdeflocculant, or to facilitate decontamination of the body of water. Va o 5. A water purification apparatus substantially as hereinbefore described with reference 0 -to the accompanying drawings. Dated this 19 th day of May, 2006 JOHN WALTERS AND NEVILLE JAMES STRONG by-their Patent Attorneys DAVIES COLLISON CAVE COMS ID No: SBMI-03646250 Received by IP Australia: Time 16:31 Date 2006-05-19
AU2005100765A 2005-09-18 2005-09-18 Clinoptilolite Algae Control Ceased AU2005100765B4 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU2005100765A AU2005100765B4 (en) 2005-09-18 2005-09-18 Clinoptilolite Algae Control
PCT/AU2006/001314 WO2007030859A1 (en) 2005-09-18 2006-09-07 Water treatment method and apparatus
AU2006292010A AU2006292010A1 (en) 2005-09-18 2006-09-07 Water treatment method and apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AU2005100765A AU2005100765B4 (en) 2005-09-18 2005-09-18 Clinoptilolite Algae Control

Publications (2)

Publication Number Publication Date
AU2005100765A4 AU2005100765A4 (en) 2005-10-13
AU2005100765B4 true AU2005100765B4 (en) 2006-06-08

Family

ID=35453279

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2005100765A Ceased AU2005100765B4 (en) 2005-09-18 2005-09-18 Clinoptilolite Algae Control

Country Status (2)

Country Link
AU (1) AU2005100765B4 (en)
WO (1) WO2007030859A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10240358B2 (en) * 2013-03-18 2019-03-26 R&R Regester Enterprises, Inc. Water treatment and purification system and methods thereof
US20220055922A1 (en) * 2020-08-18 2022-02-24 Norman Mendez System and method for pool sanitation

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1984003881A1 (en) * 1983-04-06 1984-10-11 Srs Water Research Corp Ab A method to purify water
WO1985004390A1 (en) * 1984-04-02 1985-10-10 Vizépito^"Ipari Tröszt Process and equipment for removal of suspended material, biogenetic nutrients and dissolved metal compounds from sewage contaminated with organic and/or inorganic substances

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2192808A (en) * 1986-02-19 1988-01-27 Dryden Aquaculture Ltd Filter
GB2245809B (en) * 1990-06-25 1994-03-16 Csir Method for transportation of live fish
JP3227570B2 (en) * 1997-11-17 2001-11-12 五十嵐 宏 Water purification bag
JPH11206267A (en) * 1998-01-27 1999-08-03 Kazuyasu Kubota Mixed filter medium for producing soft water

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1984003881A1 (en) * 1983-04-06 1984-10-11 Srs Water Research Corp Ab A method to purify water
WO1985004390A1 (en) * 1984-04-02 1985-10-10 Vizépito^"Ipari Tröszt Process and equipment for removal of suspended material, biogenetic nutrients and dissolved metal compounds from sewage contaminated with organic and/or inorganic substances

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Derwent Abstract no 2001-515285/57 *
Derwent Abstract no. 2002-016360/02 *
Web site http//mineral. galleries. Com/minerals/ silicate/clinopti/clinopti.htm *

Also Published As

Publication number Publication date
AU2005100765A4 (en) 2005-10-13
WO2007030859A1 (en) 2007-03-22

Similar Documents

Publication Publication Date Title
AT412275B (en) BIOLOGICAL WATER CLEANING
US5254252A (en) Ecological treatment system for flowing water
CN107215940A (en) Multistage arrangement uniform activation Zero-valent Iron goes the water treatment system and method for removing heavy metals
US8287729B2 (en) Field water purification system
US20120199525A1 (en) Filtration medium
JPH01310790A (en) Water treatment method, treatment agent and treatment apparatus
JPH0480757B2 (en)
EP0147795A1 (en) Process for waste water purification
CN102923892A (en) Mobile emergency water reinforcement treatment device
AU2005100765B4 (en) Clinoptilolite Algae Control
DE3120891C2 (en)
JPH04115008A (en) Sea water area purifying facility utilizing the range of tide
CN202912800U (en) Movable emergency reinforcing water-treatment device
DE10318708A1 (en) Swimming pool water filter has filter tank with bulk grain horizontal filter layers on a water permeable base under top layer of active carbon granules
US20110127216A1 (en) Method and device for biological treatment of water in swimming pools
CN109721212A (en) River sewage processing system
ES2232470T3 (en) METHOD AND DEVICE FOR WATER CLEANING.
Gerrard The ability of vetiver grass to act as a primary purifier of wastewater; an answer to low cost sanitation and freshwater pollution
AU2006292010A1 (en) Water treatment method and apparatus
HRP20030633A2 (en) A process and apparatus for submerged biodepuration of effluents disposed of in the sea
CN105668906A (en) Water purifier having digital display function and manufacturing method thereof
DE10313153B4 (en) Method and device for removing impurities from water
CN218810951U (en) Drinking water source treatment device
ES2251286B1 (en) CLEANING OF CONTINENTAL WATERS THROUGH CULTURES OF FILAMENT GREEN MACROALGAS THAT ABSORB AND RECYCLE NUTRIENTS AND / OR SET HEAVY METALS GENERATING VEGETABLE BIOMASS.
CN212246538U (en) Low-cost high-efficient domestic rural drinking water treater

Legal Events

Date Code Title Description
FGI Letters patent sealed or granted (innovation patent)
PC Assignment registered

Owner name: ALGON SOUTH COAST; WALTERS, JOHN

Free format text: FORMER OWNER WAS: ALGON SOUTH COAST; STRONG, NEVILLE; WALTERS, JOHN

MK22 Patent ceased section 143a(d), or expired - non payment of renewal fee or expiry