AU2003278171B2 - Method for producing a continuous steam generator and continuous steam generator - Google Patents
Method for producing a continuous steam generator and continuous steam generator Download PDFInfo
- Publication number
- AU2003278171B2 AU2003278171B2 AU2003278171A AU2003278171A AU2003278171B2 AU 2003278171 B2 AU2003278171 B2 AU 2003278171B2 AU 2003278171 A AU2003278171 A AU 2003278171A AU 2003278171 A AU2003278171 A AU 2003278171A AU 2003278171 B2 AU2003278171 B2 AU 2003278171B2
- Authority
- AU
- Australia
- Prior art keywords
- steam generator
- continuous steam
- material category
- adapters
- fins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B37/00—Component parts or details of steam boilers
- F22B37/02—Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
- F22B37/10—Water tubes; Accessories therefor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B37/00—Component parts or details of steam boilers
- F22B37/02—Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
- F22B37/04—Component parts or details of steam boilers applicable to more than one kind or type of steam boiler and characterised by material, e.g. use of special steel alloy
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B37/00—Component parts or details of steam boilers
- F22B37/02—Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
- F22B37/10—Water tubes; Accessories therefor
- F22B37/101—Tubes having fins or ribs
- F22B37/102—Walls built-up from finned tubes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P80/00—Climate change mitigation technologies for sector-wide applications
- Y02P80/10—Efficient use of energy, e.g. using compressed air or pressurized fluid as energy carrier
- Y02P80/15—On-site combined power, heat or cool generation or distribution, e.g. combined heat and power [CHP] supply
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Butt Welding And Welding Of Specific Article (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Heat Treatment Of Articles (AREA)
- Arc Welding In General (AREA)
- Control Of Steam Boilers And Waste-Gas Boilers (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Description
2002P02955WOAU PCT/EP2003/012250 Description Method for producing a continuous steam generator and a continuous steam generator The invention relates to a method for producing a continuous steam generator, having an enclosing wall formed from steam generator pipes welded together in a gas-tight fashion, said wall being prefabricated in modules in the workshop, said modules being welded together during final assembly. It also relates to a continuous steam generator that is particularly suitable for production by such a method.
In a continuous steam generator a number of steam generator pipes, which together form the gas-tight enclosing wall of the combustion chamber, are heated to evaporate a fluid medium in the steam generator pipes completely in one passage. The fluid medium generally water is fed after evaporation to the superheater pipes connected after the steam generator pipes and superheated there. The steam generator pipes of the continuous steam generator can thereby be arranged vertically or in a spiral fashion and therefore at an angle.
In contrast to a natural circulation steam generator, a continuous steam generator is not subject to pressure limitation so that it can be designed for live steam pressures well above the critical pressure of water (Pkrit 221 bar), where it is impossible to differentiate between the water and steam phases and phase separation is therefore not possible. A high live steam pressure favors a high level of thermal efficiency and therefore lower CO 2 emissions from a fossil-fuel power plant.
2002P02955WOAU PCT/EP2003/012250 2 The enclosing walls of large combustion chambers for example for continuous steam generators with a design output of more than 100 MWel cannot be manufactured whole in the workshop for transport reasons. In such instances final assembly is required at the actual site of deployment, during which process the parts or even modules provided to form the enclosing wall of the combustion chamber are welded together directly on site. To facilitate production, a modular structure can be provided, with which the enclosing wall is prefabricated in modules, which have to be welded together during final assembly. Such a structure however significantly restricts the selection of materials that can be used, as when using materials that are subject to comparatively high thermal and mechanical loading, a subsequent heat treatment may be essential when welding.
Subsequent heat treatment of the weld seams involves a significant technical outlay and can therefore generally only be undertaken in the workshop and not on site during final assembly. Therefore when producing enclosing walls for large combustion chambers of continuous steam generators until now only materials that did not require subsequent heat treatment of the weld seams were used.
However to increase the efficiency and therefore reduce the CO 2 emissions of a fossil-fuel power plant, it is desirable to design continuous steam generators for particularly high live steam pressures and temperatures. The production of such continuous steam generators requires materials which withstand loading due to high heat flow densities at high steam temperatures and therefore high material temperatures. However these are the materials that require subsequent heat treatment of the weld seams.
00 O A possible alternative to these materials would be nickel-based materials, which N, despite their ability to withstand a high thermal load do not require subsequent heat treatment of the weld seams, the use of which would however significantly complicate CI) production and render it more expensive.
Object of the Invention It is the object of the present invention to substantially overcome or ameliorate 00 one or more of the disadvantages of the prior art.
Summary of the Invention I The present invention provides a method for producing a continuous steam generator, having an enclosing wall formed from steam generator pipes welded together in a gas-tight fashion, a number of pipe segments made from a material of a first material category and provided to form the steam generator pipes being combined into a number of modules, each module being provided respectively with an adapter made from a material of a second material category at a number of connection points provided for connection to a further module.
The invention is thereby based on the consideration that technical outlay and cost can be kept low when producing the continuous steam generator, in that the continuous steam generator is designed for the consequent processing of conventional materials rather than expensive nickel-based materials which are difficult to process. The continuous steam generator to be produced should thereby be designed in a suitable fashion for loading due to high live steam pressures and temperatures. Primary consideration is given to the fact that the essential components of the steam generator pipes A121(1813535 I):MI.W 2002P02955WOAU PCT/EP2003/012250 4 forming the enclosing wall are made from a material that is suitable for this purpose.
To keep production costs low still, the continuous steam generator should thereby be prefabricated to a particularly large extent in the workshop, so that in particular any subsequent heat treatment required for weld seams can take place in relatively simple conditions and with recourse to the plurality of resources available there. The prefabricated modules can therefore be formed from pipe segments of a material suitable for high live steam pressures and temperatures.
To allow final assembly of the modules, which have been prefabricated in a suitable fashion, in respect of these criteria, thereby consequently avoiding the need for subsequent treatment, the modules should be provided with corresponding adapters, which allow welding during final assembly without subsequent heat treatment of the weld seams.
To this end, in contrast to the pipe segments, the adapters are made from a material with correspondingly different characteristics.
Advantageous embodiments of the invention are set out in the subclaims.
The materials for the pipe segments on the one hand and the adapters or adapter units formed therefrom on the other hand are preferably selected specifically in respect of the criterion whether subsequent heat treatment of the weld seams is required. A particularly suitable criterion for assessing whether a material requires subsequent heat treatment of the weld seams is the so-called Vickers hardness (DIN 50 133).
2002P02955WOAU PCT/EP2003/012250 The parts of the combustion chamber walls of the continuous steam generator subject to a high level of loading due to high heat flow densities are therefore expediently made from a material of a first material category, the Vickers hardness of which is higher than the Vickers hardness of the parts of the combustion chamber walls subject to a lower level of loading.
The latter are expediently made from a material of the second material category, the Vickers hardness HV10 of the materials of the second material category thereby preferably being less than around 350 to 400.
Adjacent steam generator pipes connected parallel to the flow of a fluid medium are advantageously connected together via fins, in particular to ensure a high specific heat input into the steam generator pipes. These fins are advantageously made from a material of the second material category. As has been proven, as the fins are components of the continuous steam generator through which there is no flow, they are not subject to excessive loading due to the lack of internal pressure, with the result that the material specifications relating to them are by comparison not so stringent. These less stringent material specifications are also met by materials of the second material category. Such fins also allow the individual modules to be connected without any problem in a horizontal direction during final assembly when the pipes of the continuous steam generator are vertical. To this end halfwidth fins are preferably welded onto the modules at the points provided for connection to other modules in the workshop and are used for connection purposes during final assembly.
00 O The individual modules are expediently connected in a vertical direction via adapter units comprising a number of adapters and if necessary additional bend couplings.
o An adapter made from a material of the second material category for example is thereby N, welded in the workshop to a pipe segment made from a material of the first material category and the weld seam is subsequently heat-treated. During final assembly two pipe segments produced in this fashion are for example connected directly or by means of a bend coupling, which is also made from the material of the second material category. The 00 weld seams applied during final assembly do not have to undergo subsequent heat Streatment, because the material used does not require this.
The present invention also provides a continuous steam generator with an enclosing wall formed from steam generator pipes welded together in a gas-tight fashion and connected in parallel to allow the passage of a fluid medium, wherein at least some of the steam generator pipes are each formed from a number of pipe segments connected one behind the other on the fluid medium side and made from a material of a first material is category and with pipe segments of a steam generator pipe arranged one after the other in the direction of flow being connected together via an adapter unit made from a material of a second material category.
The adapter unit thereby advantageously comprises a number of adapters and in some instances a bend coupling and is arranged such that a weld seam applied to connect an adapter to a further component is outside a wall surface provided by the pipe segments.
Adjacent steam generator pipes are expediently connected together in a gas-tight fashion via fins, the fins also being made from a material of the second material category.
A121(1813535 I):MLW 2002P02955WOAU PCT/EP2003/012250 7 The advantages achieved with-the invention are in particular that by using different materials in the enclosing wall of the combustion chamber, i.e. for the pipe segments on the one hand and for the adapters and the adapter units formed therefrom on the other hand, with characteristics, which are tailored to the respective thermal loading of the steam generator pipes, the production method for continuous steam generators for high steam pressures can be kept particularly simple. The use and combination of different types of material allows this in particular in that the steam generator pipes are prefabricated in the workshop from a material of the first material category, welded to form modules, subjected to subsequent heat treatment and provided with adapters made from a material of the second material category, which does not require subsequent heat treatment, at the points provided for connection to other modules during assembly. Suitable arrangement of these adapters outside the area exposed to high heat flow densities prevents the material being subjected to excessive loading. The weld seams resulting from welding the individual modules together during assembly do not require subsequent heat treatment, as only materials of the second material category have to be welded during final assembly.
An exemplary embodiment of the invention is described in more detail below with reference to a drawing, in which: FIG 1 shows a schematic illustration of a continuous steam generator with vertically arranged evaporator pipes, FIG 2 shows two pipe segments connected together by means of an adapter unit, FIG 3 shows two pipe segments connected together by means of an alternative embodiment of an adapter unit, 2002P02955WOAU PCT/EP2003/012250 8 FIG 4 shows two pipe segments connected together by means of a further alternative embodiment of an adapter unit and FIG 5 shows a cross-section through evaporator pipes conhected together via fins.
Identical parts are marked with the same reference characters in all the figures.
Figure 1 shows a schematic illustration of a continuous steam generator i, the vertical gas duct of which is surrounded by an enclosing wall 4 and forms a combustion chamber, with a bell-shaped base 6 at the lower end. The base 6 encloses an outlet opening 8 (not shown here) for ash.
In the area A of the gas duct a number of burners 10, of which only one is shown, are attached in the enclosing wall of the combustion chamber formed from vertically arranged steam generator pipes 12. The vertically arranged steam generator pipes 12 are welded together via fins 14 to the gas-tight enclosing wall 4.
During operation of the continuous steam generator 1 a body of flame 16 results in the combustion chamber during combustion of a fossil'fuel. This body of flame 16 exposes the area marked A of the continuous steam generator 1 to a very high heat flow density during its operation. The body of flame 16 has a temperature profile, which decreases in a vertical direction starting from the area of the burner. Below the area.
A is an area B that is remote from the flame and above the area A is a further area C also remote, from the flame, both of 2002P02955WOAU PCT/EP2003/012250 9 which are exposed to a comparatively low level of heat due to the resulting temperature profile.
The continuous steam generator 1 is designed to be suitable for operation at high live steam pressures and temperatures and therefore for a particularly high level of efficiency even with quite limited production outlay. To this end the steam generator pipes 12, in particular in the area of high heat flow densities and high material temperatures, are made from a material, which withstands loading due to high heat flow densities. To keep production outlay and cost low at the same time, the enclosing wall 4 of the combustion chamber is prefabricated in modules 17 in the workshop. During prefabrication of the modules 17 in the workshop specific use is made of the fact that a large number of resources are available there without further outlay, so that it is possible in particular to process materials that can be subjected to a high level of thermal loading despite the associated outlay in particular during the subsequent heat treatment of weld seams.
To produce the modules 17 therefore finished pipe segments 18 made from a material of a first material category, that can in particular be subjected to a high level of thermal loading, are welded together. The pipe segments 18 are thereby selected such that after final assembly a plurality of pipe segments 18 connected one behind the other on the fluid medium side respectively form a steam generator pipe 12.
To be able to avoid subsequent heat treatment during final assembly of the modules 17, said modules 17 are then provided still in the workshop at the connection points provided for connection to a further module 17 with an adapter 19 made from a material of a second material category. The material of 2002P02955WOAU PCT/EP2003/012250 the second material category is thereby selected such that it is suitable for welding without subsequent heat treatment.
During attachment to the respectively assigned pipe segment 18 also still in the workshop said weld seam is subjected to a subsequent heat treatment, in order to satisfy the requirements of the material forming the respective pipe segment 18. The materials of the second material category thereby have a lower Vickers hardness than the materials of the first material category.
During final assembly on site the individual modules 17 are finally welded together at horizontal joints 20 and vertical joints 21 respectively via the adapters 19, with only components made from a material of the second material category being connected together so that no subsequent heat treatment is required.
At the vertical joints 21 a connection is achieved via fins 14 and at the horizontal joints 20 via adapter units 22 formed from a plurality of adapters 19 welded together.
Figure 2 shows an exemplary embodiment of the transition area at a horizontal joint 20, which is particularly suitable for use in the area A in proximity to the flame. Two steam generator pipes 12, provided for use in the area A, in which the heat flow density is particularly high, are connected there via an adapter unit 22 in the direction of flow. The adapter unit 22 thereby comprises two adapters 19 and a bend coupling 23, each made from a material of the second material category. Two connectors 24 made from a material of the first material category are provided to connect the adapters 22 to the steam generator pipes 12.
2002P02955WOAU PCT/EP2003/012250 11 A weld seam 25 between a pipe segment 18 and a connector 24 is executed in the workshop, because it requires subsequent heat treatment due to the characteristics of the material of the pipe segments 18; the same applies to a weld seam 26 between a connector 24 and an adapter 19. A weld seam 27 between an adapter 19 and a bend coupling 23 on the other hand can be executed during final assembly, as it does not require subsequent heat treatment due to the material characteristics of the adapters 19 and the bend coupling 23.
The fins 14 are not subject to internal pressure from a fluid medium and can therefore be made from a material of the second material category, even if they are in the area A. A weld seam 28 between fins 14 can therefore be executed without any problem during final assembly.
Figure 3 shows an,alternative embodiment of the adapter unit 22, which is also used in the area A, comprising two adapters 19 made from a material of the second material category. The pipe segments 18 are thereby bent at the points provided for welding during final assembly such that they curve out from the surface formed by the pipe segments 18 combined to form a module 17. A separate connector 24 is therefore not required with this exemplary embodiment. A weld seam 26 between a pipe segment 18 and an adapter 19 is executed in the workshop, as it requires subsequent heat treatment, while a weld seam 27 between two adapters 19 can be executed during final assembly.
The fins 14 can also be welded together here without any problem at a weld seam 28 during final assembly, as the lack of internal pressure from a fluid medium means that they can be made from a material of the second material category, which does not require subsequent heat treatment.
2002P02955WOAU PCT/EP2003/012250 12 Figure 4 shows two pipe segments 18, which are connected together via an adapter unit 22, which can be attached in the areas B and C. The adapter unit 22 thereby comprises two adapters 19 made from a material of the second material category. The weld seams 26 between the pipe segments 18 and the adapters 19 are executed in the workshop, while the weld seam 27 can be executed during final assembly, as it is between two materials of the second material category, which do not require subsequent heat treatment. In this exemplary embodiment the adapter unit 22 is not configured for the adapters 19 to be welded together in a plane outside the wall surface provided by the pipe segments 18, as the heat input in the areas B and C that are remote from the flame is low and the arrangement of components made from a material of the second material category in the actual plane of the wall can therefore be permitted.
Figure 5 shows a cross-section through pipe segments 18 combined into a module 17, which are connected together via fins 14 and form the steam generator pipes 12. The steam generator pipes 12 are made from a material of the first material category, while in contrast the fins 14 are made from a material of the second material category. Weld seams 29 between a steam generator pipe 12 and a fin 14 are executed in the workshop, as they require subsequent heat treatment due to the material characteristics of the steam generator pipes 12.
In contrast weld seams 30, via which two modules 17 are connected together at vertical joints 21, can be executed during final assembly, as they do not require subsequent heat treatment. During final assembly two modules 17 are welded together at the vertical joints 21 via half-width fins 31.
Claims (6)
- 3. Method according to claim 1 or 2, wherein the pipe segments are combined into modules such that each module respectively forms a surface, out of which the respective adapters curve such that the adapters provided to connect two adjacent modules can be welded together in a plane that is offset in respect of the respective surface.
- 4. Method according to one of claims 1 to 3, wherein adjacent steam generator pipes are welded together in a gas-tight fashion via fins, with the fins being made from a material of the second material category. Continuous steam generator with an enclosing wall formed from steam generator pipes welded together in a gas-tight fashion and connected in parallel to allow the passage of a fluid medium, wherein at least some of the steam generator pipes are each formed from a number of pipe segments connected one behind the other on the fluid medium side and made from a material of a first material category and with pipe segments of a steam generator pipe arranged one after the other in the direction of flow being connected together via an adapter unit made from a material of a second material category.
- 6. Continuous steam generator according to claim 5, with the materials of the first material category having a higher Vickers hardness than the materials of the second material category.
- 7. Continuous steam generator according to claim 5 or 6, wherein a number of adapter units, each comprising a number of adapters made from a material of the second material category, are arranged such that a weld seam applied to connect two AH21(1813535 I)MLW 00 O adapters of the same adapter unit together is outside a wall surface provided by the pipe N segments.
- 8. Continuous steam generator according to any one of claims 5 to 7, the N combustion chamber wall of which comprises vertical piping.
- 9. Continuous steam generator according to any one of claims 5 to 8, with adjacent steam generator pipes being welded together in a gas-tight fashion via fins, the r- fins being made from a material of a second material category. 00 10. A method for producing a continuous steam generator substantially as Cl hereinbefore described with reference to any one of the embodiments as that embodiment is shown in the accompanying drawings. C 11. A continuous steam generator substantially as hereinbefore described with reference to any one of the embodiments as that embodiment is shown in the accompanying drawings. Dated 22 October 2008 Siemens Aktiengesellschaft Patent Attorneys for the Applicant/Nominated Person SPRUSON FERGUSON All21(1813535 I:MI.W
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02026797A EP1429073A1 (en) | 2002-12-02 | 2002-12-02 | Method of manufacturing a once-through steam generator and the once-through steam generator |
EP02026797.7 | 2002-12-02 | ||
PCT/EP2003/012250 WO2004051142A1 (en) | 2002-12-02 | 2003-11-03 | Method for producing a continuous steam generator and continuous steam generator |
Publications (2)
Publication Number | Publication Date |
---|---|
AU2003278171A1 AU2003278171A1 (en) | 2004-06-23 |
AU2003278171B2 true AU2003278171B2 (en) | 2008-11-20 |
Family
ID=32319548
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2003278171A Ceased AU2003278171B2 (en) | 2002-12-02 | 2003-11-03 | Method for producing a continuous steam generator and continuous steam generator |
Country Status (16)
Country | Link |
---|---|
EP (2) | EP1429073A1 (en) |
JP (2) | JP2006508321A (en) |
KR (2) | KR101260905B1 (en) |
CN (1) | CN100354564C (en) |
AR (1) | AR042147A1 (en) |
AU (1) | AU2003278171B2 (en) |
BR (1) | BR0316974A (en) |
CA (1) | CA2507821C (en) |
DK (1) | DK1570208T3 (en) |
ES (1) | ES2402100T3 (en) |
MX (1) | MXPA05005849A (en) |
NO (1) | NO20053238L (en) |
PL (1) | PL206759B1 (en) |
RU (1) | RU2317484C2 (en) |
TW (1) | TWI292808B (en) |
WO (1) | WO2004051142A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8096268B2 (en) | 2007-10-01 | 2012-01-17 | Riley Power Inc. | Municipal solid waste fuel steam generator with waterwall furnace platens |
EP2119880A1 (en) | 2008-02-15 | 2009-11-18 | Siemens Aktiengesellschaft | Method for starting a steam producer |
DE102008047784A1 (en) | 2008-07-02 | 2010-01-07 | Hitachi Power Europe Gmbh | Membrane wall of a large steam generator |
DE102008037085B3 (en) | 2008-08-08 | 2009-08-06 | Alstom Technology Ltd. | Pipe wall production process for steam generator comprises producing pipe wall register, heat-treating weld seams, connecting up register and joining planes |
CN102607008B (en) * | 2012-02-06 | 2013-10-23 | 上海锅炉厂有限公司 | Method for selecting materials on upper part of spiral section of supercritical tower-type boiler water cooled wall |
Family Cites Families (10)
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FR1314175A (en) * | 1962-01-23 | 1963-01-04 | Watertight or sufficiently watertight partitions for heat exchange chambers | |
DE1246761B (en) * | 1962-03-08 | 1967-08-10 | Babcock & Wilcox Dampfkessel W | Fin tube for pipe walls, especially of steam generators |
FR1332576A (en) * | 1962-04-17 | 1963-07-19 | Fives Lille Cail | Improvements in the production of tubular panels for boilers |
BE759112A (en) * | 1969-11-18 | 1971-04-30 | Babcock & Wilcox Co | TUBE SCREEN IMPROVEMENTS |
US4041907A (en) * | 1976-08-02 | 1977-08-16 | Combustion Engineering, Inc. | Spacer arrangement for steam generator |
JPH08334187A (en) * | 1995-06-07 | 1996-12-17 | Mitsubishi Heavy Ind Ltd | Repairing method for furnace wall pipe |
JP3926932B2 (en) | 1998-09-30 | 2007-06-06 | 株式会社東芝 | Assembly method for water heater |
US6321691B1 (en) * | 1999-01-14 | 2001-11-27 | The Babcock & Wilcox Company | Oxidation resistant low alloy attachments for boiler components |
JP2001324103A (en) * | 2000-05-15 | 2001-11-22 | Ishikawajima Harima Heavy Ind Co Ltd | Method for manufacturing furnace wall panel of boiler |
CN2466509Y (en) * | 2001-02-27 | 2001-12-19 | 天津宝成集团有限公司 | Vertical water-tube boiler with circular boiler body |
-
2002
- 2002-12-02 EP EP02026797A patent/EP1429073A1/en not_active Withdrawn
-
2003
- 2003-11-03 ES ES03769483T patent/ES2402100T3/en not_active Expired - Lifetime
- 2003-11-03 BR BR0316974-0A patent/BR0316974A/en not_active IP Right Cessation
- 2003-11-03 MX MXPA05005849A patent/MXPA05005849A/en active IP Right Grant
- 2003-11-03 CN CNB2003801078357A patent/CN100354564C/en not_active Expired - Fee Related
- 2003-11-03 DK DK03769483.3T patent/DK1570208T3/en active
- 2003-11-03 KR KR1020117020224A patent/KR101260905B1/en not_active IP Right Cessation
- 2003-11-03 EP EP03769483A patent/EP1570208B1/en not_active Expired - Lifetime
- 2003-11-03 JP JP2004556104A patent/JP2006508321A/en active Pending
- 2003-11-03 PL PL375591A patent/PL206759B1/en unknown
- 2003-11-03 AU AU2003278171A patent/AU2003278171B2/en not_active Ceased
- 2003-11-03 RU RU2005120741/06A patent/RU2317484C2/en not_active IP Right Cessation
- 2003-11-03 CA CA2507821A patent/CA2507821C/en not_active Expired - Fee Related
- 2003-11-03 KR KR1020057009993A patent/KR20050086899A/en not_active Application Discontinuation
- 2003-11-03 WO PCT/EP2003/012250 patent/WO2004051142A1/en active Application Filing
- 2003-11-28 AR ARP030104397A patent/AR042147A1/en unknown
- 2003-11-28 TW TW092133487A patent/TWI292808B/en not_active IP Right Cessation
-
2005
- 2005-07-01 NO NO20053238A patent/NO20053238L/en not_active Application Discontinuation
-
2008
- 2008-02-14 JP JP2008033272A patent/JP4901778B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See reference of WO 2004/051142 * |
Also Published As
Publication number | Publication date |
---|---|
PL206759B1 (en) | 2010-09-30 |
NO20053238D0 (en) | 2005-07-01 |
JP2006508321A (en) | 2006-03-09 |
BR0316974A (en) | 2005-10-25 |
MXPA05005849A (en) | 2005-08-26 |
RU2317484C2 (en) | 2008-02-20 |
JP4901778B2 (en) | 2012-03-21 |
EP1570208B1 (en) | 2012-12-26 |
CN1732357A (en) | 2006-02-08 |
EP1570208A1 (en) | 2005-09-07 |
KR20050086899A (en) | 2005-08-30 |
CA2507821A1 (en) | 2004-06-17 |
KR101260905B1 (en) | 2013-05-06 |
CA2507821C (en) | 2011-07-05 |
AU2003278171A1 (en) | 2004-06-23 |
EP1429073A1 (en) | 2004-06-16 |
TW200413671A (en) | 2004-08-01 |
NO20053238L (en) | 2005-07-01 |
RU2005120741A (en) | 2006-03-20 |
PL375591A1 (en) | 2005-11-28 |
DK1570208T3 (en) | 2013-03-11 |
ES2402100T3 (en) | 2013-04-29 |
WO2004051142A1 (en) | 2004-06-17 |
CN100354564C (en) | 2007-12-12 |
AR042147A1 (en) | 2005-06-08 |
JP2008134053A (en) | 2008-06-12 |
TWI292808B (en) | 2008-01-21 |
KR20110111322A (en) | 2011-10-10 |
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