AU2002244517B2

AU2002244517B2 - Improved flotation

Info

Publication number: AU2002244517B2
Application number: AU2002244517A
Authority: AU
Inventors: John Patrick Andreatidis; Christofo Torrisi
Original assignee: BHP Billiton Innovation Pty Ltd
Current assignee: BHP Billiton Innovation Pty Ltd
Priority date: 2001-03-30
Filing date: 2002-03-28
Publication date: 2007-11-29
Anticipated expiration: 2022-03-28

Description

WO 02/078851 PCT/AU02/00400 IMPROVED FLOTATION The present invention is a method of recovering a valuable component from a feed slurry in a mineral processing plant for a mined material.

The present invention is concerned particularly, although by no means exclusively, with recovering a valuable component from a feed slurry in a flotation circuit of a mineral processing plant for a mined material that includes metal sulphides and/or metallic minerals.

The main valuable components in metal sulphides and metallic minerals from an economic viewpoint include silver, lead, copper, nickel, zinc, cobalt, molybdenun, tin and iron.

The present invention relates more particularly, although by no means exclusively, to recovering a valuable component, namely silver and lead, from a feed slurry in a flotation circuit of a mineral processing plant for a mined material, namely a silver-rich lead deposit.

The present invention was made during the course of a research program carried out at the Cannington mine of the applicant.

The Cannington mine, located in North Queensland, is a silver-rich lead and zinc deposit. The mineral processing plant at the mine produces a lead concentrate and a zinc concentrate. The concentrates contain silver, and the silver is separated from the concentrates in subsequent refining of the concentrates.

The feed to the mineral processing plant is a blend of a number of different lead and zinc bearing ores with varying silver, lead and zinc compositions. The lead and zinc in the ores are predominantly in the form of sulphides including galena (PbS) and sphalerite (ZnS).

WO 02/078851 PCT/AU02/00400 2 The ores contain 15-25 wt.% lead sulphides and 5-10 wt.% zinc sulphides. The ores also contain 30-50 wt.% iron/manganese silicates and 15-20 wt.% iron sulphides.

The applicant has found that significant amounts of silver and lead are lost in the tailings from the flotation circuit of the minerals processing plant.

The applicant has determined that one of the reasons for the loss is that the flotation stage is not able to float fines of less than 5 micron efficiently.

The applicant believes that poor flotation performance of fines is due to surface contamination of fines.

The applicant believes that one source of surface contamination is mineral oxidation species or metal hydroxide species from the plant feed on the fines.

In relation to the Cannington mine the applicant has found that poor flotation performance of fines can be significantly alleviated by a method that includes: splitting a fines stream from a bulk stream feed; adjusting the pH of the fines stream to be within a range that dissolves surface contaminants on the fines; and thereafter floating silver and lead from the pH adjusted fines stream.

The present invention is concerned with the above-described treatment of fines in a feed slurry.

WO 02/078851 PCT/AU02/00400 In more general terms, the applicant has realised that surface contamination due to mineral oxidation species or metal hydroxide species may not always be confined to fines and may be present on other particle size fractions in a feed slurry or on the whole particle size distribution in a feed slurry.

The present invention is also concerned with this more general treatment of a feed slurry.

According to one aspect of the present invention there is provided a method of recovering a valuable component from a feed slurry in a minerals processing plant for a mined material which includes the steps of: separating the feed slurry on the basis of particle size into at least two streams; adjusting the pH of at least one of the split streams to be within a range in which contaminants on the surface of particles in the split stream are soluble and thereby dissolving contaminants from the surface; and floating the valuable component from the pH adjusted split stream.

Preferably step includes adjusting the pH of a fines stream split from the feed slurry.

Preferably the mined material includes metal sulphides and/or metallic minerals.

It is preferred particularly that the mined material includes metal sulphides that have surface contaminants due to mineral oxidation species or metal WO 02/078851 PCT/AU02/00400 4 hydroxide species.

The valuable components may be any one or more of silver, lead, copper, nickel, zinc, cobalt, molybdenum, tin, and iron.

By way of example, the mined material is a silver-rich lead deposit that includes lead sulphides and the valuable component is silver and lead.

By way of particular example, the mined material is a silver-rich lead and zinc deposit that includes lead sulphides and zinc sulphides and the valuable component is any one or more of silver, lead, and zinc.

Preferably the valuable component is silver.

Preferably the flotation step includes a lead flotation circuit.

In that event, the feed slurry for step may be a feed slurry to the lead flotation circuit or a tails slurry from the lead flotation circuit.

Preferably the feed slurry for step is a feed slurry to the lead flotation circuit.

Preferably the flotation step includes a lead flotation circuit and a zinc flotation circuit.

In a situation where the lead flotation circuit precedes the zinc flotation circuit, preferably the feed slurry for step is any one or more of: a feed slurry to the lead flotation circuit; WO 02/078851 PCT/AU02/00400 5 (ii) a tails slurry from the lead flotation circuit, i.e. a feed slurry to the zinc flotation circuit; and (iii) a tails slurry from the zinc flotation circuit.

Preferably in such a situation the feed slurry is a feed slurry to the lead flotation for step circuit.

The flotation step may include any other flotation circuits. By way of example, the flotation step may include a talc flotation circuit.

Preferably the pH range is 95 in pH adjustment step Preferably the pH range is More preferably the pH range is 3.5-4.5.

It is preferred particularly that the pH range be 4-4.5.

the fines Preferably the fines are 10 micron or less in stream produced in step More preferably the fines are 5 micron or less.

Preferably pH adjustment step includes adding an acid to the feed slurry to adjust the pH to be within the required range.

The acid may be any suitable acid. Preferably the acid is sulphuric acid.

WO 02/078851 PCT/AU02/00400 6 Preferably pH adjustment step includes providing contact time for the contaminants to dissolve.

Preferably the contact time period is at least minutes.

In a situation where the valuable component is silver, lead, and zinc, preferably step of floating the valuable component in the pH adjusted fines stream includes: floating lead and silver in the pH adjusted fines stream from step in a lead flotation circuit; and (ii) floating zinc and silver in a tails stream from the lead flotation circuit in a zinc flotation circuit.

A zinc depressant and a lead/silver collector may be added during and/or after pH adjustment step However, preferably the zinc depressant and the lead/silver collector are added to the pH adjusted fines after pH adjustment step More preferably the lead/silver collector is added just before and/or during step of floating the lead and silver in the pH adjusted fines stream in the flotation lead circuit.

According to another aspect of the present invention there is also provided a flotation stage of a mineral processing plant which includes the abovedescribed method of recovering a valuable component from a feed slurry of the flotation stage.

WO 02/078851 PCT/AU02/00400 7 Preferably the flotation stage includes floating the valuable component from the one or more than one other streams produced in step According to another aspect of the present invention there is provided a method of recovering a valuable component from a feed slurry in a minerals processing plant for a mined material which includes the steps of: adjusting the pH of the feed slurry to be within a range in which contaminants on the surface of particles in the feed slurry are soluble and thereby dissolving contaminants from the surface; and floating the valuable component from the pH adjusted feed slurry.

It is preferred particularly that the mined material includes metal sulphides that have surface contaminants due to mineral oxidation species or metal hydroxide species.

As noted above the present invention is based on a research program carried out by the applicant at the Cannington mine.

The current mineral processing plant at the Cannington mine includes the following stages.

WO 02/078851 PCT/AU02/00400 8 1. Comminution which produces a feed slurry.

2. Flotation specifically, the following flotation circuits, in order: talc flotation; lead flotation; and zinc flotation.

3. Leaching of fluorine bearing minerals, namely fluorite, from separate lead and zinc concentrates.

4. Dewatering froth from the lead and zinc circuits which produces separate lead and zinc concentrates.

Tails disposal.

The applicant has found by size analysis of flotation tailings of the current Cannington mineral processing plant that over 50% of the silver and lead losses to final tailings occur in the fines fraction of the tailings.

The applicant has also found from plant data that fine, i.e. smaller than 5 micron, particles of silver minerals and lead minerals are poorly captured by the lead flotation circuit of the existing flotation stage. The results of the analysis of plant data are shown in Figure 1.

Figure 1 is a plot of recovery versus particle size of each of silver, lead, zinc, magnesia, iron, and WO 02/078851 PCT/AU02/00400 9silica to the lead concentrate produced in the lead flotation circuit. Figure 1 is derived from plant data.

The figure shows that the recoveries of silver and lead in the fines fraction, i.e. 3-5 micron, of the plant feed to the lead concentrate is considerably lower than the recoveries of these metals in the next size fraction, i.e.

to 30 micron, of the plant feed to the lead concentrate.

By way of example, with reference to Figure 1, only 70 wt.% of the lead mineral particles and approximately 73 wt.% of the silver mineral particles in the 3 micron particles in the plant feed to the lead flotation circuit are recovered in the lead concentrate.

By comparison, approximately 100 wt.% of the lead particles and the silver particles in the 10 micron particles in the plant feed to the lead flotation circuit are recovered in the lead concentrate.

The poor flotation performance of fine mineral particles, as exemplified by Figure 1 for fine lead and silver particles, has been recognised for many years in the technical literature.

By way of example, an article by W.J. Trahar and L.J. Warren (1976) entitled "The Flotability of Very Fine Particles A Review" in the International Journal of Mineral Processing reports that the overall flotation performance of a wide range of minerals deteriorated with particle size. The article also reports that the precise effects of particle size on grade, recovery and flotation kinetics are complex. The article also reports that there is no evidence of a critical size below which particles become unfloatable, even down to 1 micron.

The findings of Trahar and Warren are supported by an article by C.J. Greet, S.R. Grano, and J Ralston (1994) entitled "The Effects of Conditioning on the WO 02/078851 PCT/AU02/00400 10 Flotation of Galena of Different Size Fractions", Fifth Mill Operators Conference. The article reports that at smaller particle sizes a constant specific flotation rate is approached.

After considering the above-mentioned plant data and information found in the above-mentioned technical documents (and other technical documents), the applicant investigated split flotation of fines and other size fractions of the plant feed using standard flotation practice as a possible solution to the poor flotation performance of fine lead and silver. The applicant found that there was a marginal improvement in the flotation performance of intermediate (20-38 micron) and coarse (+38 micron) size fractions when floated separately under the same flotation conditions used in flotation of the combined feed. The applicant also found that there was no improvement in flotation performance of the fines fraction micron) when the fines were floated separately. The applicant also found that higher recoveries of the fines could be achieved by using very high collector additions but that these high collector additions decreased selectivity between lead, zinc, silicates and iron markedly. In addition, the applicant found that the available retention time in the lead flotation circuit was insufficient to achieve high recoveries of fine lead and silver.

In the final analysis, the testwork did not support split flotation using standard flotation practice as a viable option for improving flotation performance of lead and silver fines.

The applicant carried out testwork to identify the mechanism that causes poor flotation performance of lead and silver particles in fines. The testwork investigated a range of possible mechanisms.

WO 02/078851 PCT/AU02/00400 11 The results of the testwork established that surface contamination of fines causes poor flotation performance of lead and silver particles in fines.

The applicant investigated a range of options for removing surface contamination. The options were based on assumptions as to the source of surface contamination of fines.

One option involved evaluating the effect of pH on fine particles. Testwork was carried out on plant feed having an average P80 of 8 micron. Figures 2 and 3 summarise the results of the testwork on the effect of pH.

Figure 2 is a plot of the effect of pH on infinite time recovery of fine lead and silver particles.

Figure 3 is a plot of the effect of pH on the rate constant for the fines.

Figures 2 and 3 show that lead and silver recoveries and rate constants improved significantly if the fines slurry was conditioned at a pH of 5 or less.

The testwork also showed that selectivity of fine lead and silver particles against iron and silica particles was also improved at the low pH of 5 or less.

The testwork confirmed that surface contamination is a major cause of the poor flotation performance of the lead and silver fines. However, the testwork and further testwork carried out by the applicant has not established conclusively the precise nature of the surface contamination. Possible sources of surface contamination include mineral oxidation species or metal hydroxide species from the plant feed on the fines.

WO 02/078851 PCT/AU02/00400 12 On the basis of the above-described testwork the applicant developed a method of improving flotation performance of fine lead and silver that includes: splitting a fines stream from a plant bulk stream feed; adjusting the pH of the fines stream to be or less; and thereafter floating silver and lead from the adjusted pH fines stream.

Figure 4 is a flowsheet of a preferred embodiment of the method described in the preceding paragraph.

The flowsheet is designed to form part of the flotation stage at the Cannington mine.

With reference to Figure 4, the fines flotation method begins with the classification of talc prefloat tailings to separate the fines micron) from the coarser fractions.

The prefloat tailings are pumped via line 3 from the existing lead conditioning tank 5 to a primary fines cyclone (150mm) cluster 7 where a preliminary size split is made to reduce the flow requiring finer separation.

The overflow from the primary fines cyclone 7 is pumped via line 9 to a secondary fines cyclone cluster 11 where the fines fraction 5 micron) is separated into the overflow.

Underflow from the primary and secondary fines cyclones 7, 11 are combined, diluted to the required WO 02/078851 PCT/AU02/00400 13 solids concentration, and delivered by gravity via line 13 to the existing lead rougher flotation bank of the existing lead flotation circuit 43. The underflow is thereafter processed in accordance with standard Cannington practice in the lead flotation circuit 43.

The overflow from the secondary fines cyclone 11 is transferred to a lead conditioner tank 17.

In the lead conditioner tank 17 dilute sulphuric acid is added to the slurry to adjust the pH of the slurry to be 5 or less.

After a residence time of at least 5 minutes in conditioner tank 17, acidified i.e. pH adjusted) slurry overflows into conditioner tank 21 and collectors, frother and zinc depressants are added to the slurry.

The conditioned slurry overflows from the conditioner tank 21 and is transferred via line 23 to a lead flotation circuit.

With reference to Figure 4b, the lead flotation circuit includes a fines rougher bank 25 consisting of 2 of 100m 3 tank flotation cells.

The concentrate from the rougher bank 25 is pumped by a centrifugal froth pump (not shown) via a line 44 to a cleaner bank 27 consisting of 2 of 40 m 3 tank cells. Tailings from the rougher bank 25 are pumped via line 29 to combine with and thereby dilute the underflow from the primary and secondary fines cyclones 7,11.

The concentrate from the cleaner 27 is pumped via line 47 to a cleaner 31 which is a single 40 m 3 tank cell. The tailings from the cleaner 27 are pumped via line 45 to combine with conditioned slurry from the WO 02/078851 PCT/AU02/00400 14 conditioner tank 21 that is being transferred via line 23 into the rougher bank The concentrate from the cleaner 31 is pumped via line 49 to a cleaner 35, a single 40 m 3 tank cell which produces a final lead fines concentrate that is transferred via line 51 for mixing with coarse lead concentrate from the existing lead flotation circuit 43 prior to leaching and filtration.

The tailings from the cleaner 35 gravitate via line 37 to the cleaner 31 and the tailings from the cleaner 31 gravitate via line 39 to the cleaner 27.

The method is designed for flexibility in allowing variation in the operation of the rougher bank either as a rougher only or as a rougher and a scavenger. The design also allows for the number of cleaning stages to be varied, eg. by cutting out the cleaner 35 and sending the concentrate for the cleaner 31 directly to leaching.

The applicant has carried out pilot plant work on a method of improving flotation performance of fine lead and silver particles which is based on the abovedescribed flowsheet and also includes a zinc circuit for the tailings from the lead circuit. The pilot plant work confirmed that pH adjustment of fines enables significantly higher recoveries of lead mineral and silver minerals from a fine particulate stream.

Many modifications may be made to the preferred embodiment of the present invention described above without departing from the spirit and scope of the present invention.

Claims

2. The method defined in claim 1 wherein the mined material includes metal sulphides and/or metallic minerals.
3. The method defined in claim 1 or claim 2 wherein the mined material includes metal sulphides that have surface contaminants due to mineral oxidation species or metal hydroxides.
4. The method defined in any one of the preceding claims wherein the valuable component is any one or more of silver, lead, copper, nickel, zinc, cobalt, molybdenum, tin, and iron. The method defined in any one of the preceding claims wherein the mined material is a silver-rich lead deposit N \MclboumeCases\Paent\41000-4 1999\P41714 AUI ISpccis\P41714 AU I Specification 2007-10-I2 docl O/07 -16 0 that includes lead sulphides and the valuable component is (N silver and lead. O 0
6. The method defined in claim 5 wherein the valuable component is silver.
7. The method defined in claim 5 wherein the flotation step includes a lead flotation circuit.
8. The method defined in claim 7 wherein the feed slurry C-I for step is a feed slurry to the lead flotation circuit or a tails slurry from the lead flotation circuit.
9. The method defined in claim 5 wherein the mined mineral is a lead and zinc deposit that includes lead sulphides and zinc sulphides and the valuable component is silver, lead and zinc and the flotation step includes a lead flotation circuit and a zinc flotation circuit.
10. The method defined in claim 10 wherein the lead flotation circuit precedes the zinc flotation circuit, and the feed slurry for step is any one or more of: a feed slurry to the lead flotation circuit; (ii) a tails slurry from the lead flotation circuit, ie a feed slurry to the zinc flotation circuit; and (iii) a tails slurry from the zinc flotation circuit.
11. The method defined in claim 10 wherein the feed slurry for step is a feed slurry to the lead flotation circuit. N \Melboumc\Ces\Paten\41000.41999\P4714 AU l\Specis\P41 714AU I Spccification 2007-10-12 doc12110107 17 0 12. The method defined in any one of claims 5 to 11 (N wherein the flotation step includes a talc flotation O O circuit.
13. The method defined in any one of claims 5 to 12 wherein pH range is
14. The method defined in claim 13 wherein the pH range is (N Cq 15. The method defined in claim 13 wherein the pH range is 3.5-4.5.
16. The method defined in claim 13 wherein the pH range be 4-4.5.
17. The method defined in any one of the preceding claims wherein the fines are 10 micron or less in the fines stream produced in step
18. The method defined in claim 16 wherein the fines are micron or less.
19. The method defined in any one of the preceding claims wherein the pH adjustment step includes adding an acid to the feed slurry to adjust the pH to be within the required range. The method defined in any one of the preceding claims wherein the pH adjustment step includes providing contact time for the contaminants to dissolve.
21. The method defined in claim 20 wherein the contact time period is at least 5 minutes. N\Meboume\Cases\Paten\41000.41999\P41 714AU.I\Specis\P4171 IAU. I Spcciication 2007-10-I doc]2I10/0 7 18 0 22. The method defined in any one of the preceding claims c_ wherein the valuable component is silver, lead, and zinc, O O and flotation step includes: floating lead and silver in the pH adjusted fines stream from step from step in a lead flotation circuit; and (ii) floating zinc and silver in a tails stream from the lead flotation circuit in a zinc flotation i9 1circuit.
23. The method defined in claim 22 includes adding a zinc depressant and a lead/silver collector to the pH adjusted fines after pH adjustment step
24. The method defined in claim 23 includes adding the lead/silver collector just before and/or during step (c) of floating the lead and silver in the pH adjusted fines stream in the lead flotation circuit. A method of recovering a valuable component from a feed slurry in a minerals processing plant for a mined material which includes the steps of: adjusting the pH of the feed slurry to be within a range in which contaminants on the surface of particles in the feed slurry are soluble and thereby dissolving contaminants from the surface; and floating the valuable component from the pH adjusted feed slurry.
26. The method defined in claim 25 wherein the mined material includes metal sulphides and/or metallic minerals. N.\Melboumc\Caws\Pateni\4100041999\P41714 AU i\Spccis\P41714 AU.I Spccification 2007-10. 12,docl2I/07 19 0 27. The method defined in claim 25 or claim 26 wherein the mined material includes metal sulphides that have 0 O surface contaminants due to mineral oxidation species or h metal hydroxide species.
28. The method defined in any one of claims 25 to 27 wherein the valuable components is any one or more of silver, lead, copper, nickel, zinc, cobalt, molybdenum, I tin, and iron. N \Mclboumc\Cases\PatenI\4 I0-41999\P41714AU. I\Spccis\P4 1714 AU I Spccificaion 2007-10-1 2docl 210107