AU2002223897A1 - Synthesis of lithium transition metal sulphides - Google Patents

Synthesis of lithium transition metal sulphides

Info

Publication number
AU2002223897A1
AU2002223897A1 AU2002223897A AU2389702A AU2002223897A1 AU 2002223897 A1 AU2002223897 A1 AU 2002223897A1 AU 2002223897 A AU2002223897 A AU 2002223897A AU 2389702 A AU2389702 A AU 2389702A AU 2002223897 A1 AU2002223897 A1 AU 2002223897A1
Authority
AU
Australia
Prior art keywords
transition metal
lithium
lithium transition
synthesis
metal sulphides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2002223897A
Inventor
Peter George Bowles
Andrew Grahame Ritchie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinetiq Ltd
Original Assignee
Qinetiq Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinetiq Ltd filed Critical Qinetiq Ltd
Publication of AU2002223897A1 publication Critical patent/AU2002223897A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/007—Titanium sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00—Compounds of niobium
    • C01G33/006—Compounds containing, besides niobium, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00—Compounds of molybdenum
    • C01G39/006—Compounds containing, besides molybdenum, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00—Compounds of molybdenum
    • C01G39/06—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/12—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

A process for the production of a lithium transition metal sulphide such as lithium iron sulphide, the process comprising reacting a transition metal sulphide with lithium sulphide in a solvent comprising a molten salt or a mixture of molten salts. Lithium transition metal sulphides obtained using this process are useful in the production of electrodes, in particular for rechargeable lithium batteries.
AU2002223897A 2000-12-08 2001-11-27 Synthesis of lithium transition metal sulphides Abandoned AU2002223897A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0029958 2000-12-08
GBGB0029958.6A GB0029958D0 (en) 2000-12-08 2000-12-08 Synthesis of lithium transition metal sulphides
PCT/GB2001/005209 WO2002046102A1 (en) 2000-12-08 2001-11-27 Synthesis of lithium transition metal sulphides

Publications (1)

Publication Number Publication Date
AU2002223897A1 true AU2002223897A1 (en) 2002-06-18

Family

ID=9904702

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2002223897A Abandoned AU2002223897A1 (en) 2000-12-08 2001-11-27 Synthesis of lithium transition metal sulphides

Country Status (12)

Country Link
US (1) US7018603B2 (en)
EP (1) EP1341724B1 (en)
JP (1) JP4188685B2 (en)
KR (1) KR100755191B1 (en)
CN (1) CN1210826C (en)
AT (1) ATE272026T1 (en)
AU (1) AU2002223897A1 (en)
CA (1) CA2436600C (en)
DE (1) DE60104561T2 (en)
ES (1) ES2225655T3 (en)
GB (1) GB0029958D0 (en)
WO (1) WO2002046102A1 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4245581B2 (en) * 2001-03-29 2009-03-25 株式会社東芝 Negative electrode active material and non-aqueous electrolyte battery
KR100870902B1 (en) * 2007-07-27 2008-11-28 경상대학교산학협력단 A method for fabricating of lithium metal sulfide powder
GB2464455B (en) * 2008-10-14 2010-09-15 Iti Scotland Ltd Lithium-containing transition metal sulfide compounds
JP5271035B2 (en) * 2008-10-23 2013-08-21 日本化学工業株式会社 Method for producing lithium iron sulfide and method for producing lithium sulfide transition metal
WO2010084808A1 (en) * 2009-01-22 2010-07-29 独立行政法人産業技術総合研究所 Process for production of iron sulfide/lithium composite
JP5534000B2 (en) * 2010-02-18 2014-06-25 株式会社村田製作所 Electrode active material for all solid state secondary battery and all solid state secondary battery
US20130029227A1 (en) 2011-07-26 2013-01-31 Toyota Motor Engineering & Manufacturing North America, Inc. Polyanion active materials and method of forming the same
JP5742606B2 (en) * 2011-09-07 2015-07-01 株式会社村田製作所 Electrode active material, method for producing the same, and secondary battery
JP6059449B2 (en) * 2012-04-26 2017-01-11 古河機械金属株式会社 Method for producing positive electrode material for secondary battery, method for producing positive electrode for secondary battery, and method for producing secondary battery
CN105189358B (en) * 2013-03-18 2017-04-26 独立行政法人产业技术综合研究所 Lithium titanium sulfide, lithium niobium sulfide, and lithium titanium niobium sulfide
CN103367744A (en) * 2013-05-24 2013-10-23 深圳华粤宝电池有限公司 Preparation method and application of lithium-niobium sulfide
US10033040B2 (en) 2013-07-08 2018-07-24 The Board Of Trustees Of The Leland Standford Junior University Stable cycling of lithium sulfide cathodes through strong affinity with multifunctional binders
WO2015049986A1 (en) * 2013-10-04 2015-04-09 独立行政法人産業技術総合研究所 Amorphous (lithium) niobium sulfide or (lithium) titanium niobium sulfide
JP6577222B2 (en) * 2015-04-17 2019-09-18 トヨタ自動車株式会社 Method for producing sulfide solid electrolyte and sulfur-based material
TW201930199A (en) * 2017-12-25 2019-08-01 國立研究開發法人產業技術總合研究所 Halogen-containing composite body and method for producing same
CN108767234B (en) * 2018-06-05 2021-06-08 天津巴莫科技有限责任公司 Lithium-rich solid solution oxysulfide anode material and preparation method thereof
CN109052488B (en) * 2018-09-05 2020-12-29 中国工程物理研究院电子工程研究所 Cobalt disulfide material with high storage stability and preparation method and application thereof

Family Cites Families (13)

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FR2420852A1 (en) * 1978-03-24 1979-10-19 Comp Generale Electricite LITHIUM GENERATOR
FR2485267A2 (en) * 1978-03-24 1981-12-24 Comp Generale Electricite Positive active material mfr. - by reacting lithium sulphide and ferrous sulphide hot for one to three weeks
US4164069A (en) * 1978-04-28 1979-08-14 The United States Of America As Represented By The United States Department Of Energy Method of preparing a positive electrode for an electrochemical cell
US4172926A (en) * 1978-06-29 1979-10-30 The United States Of America As Represented By The United States Department Of Energy Electrochemical cell and method of assembly
US4401714A (en) * 1982-07-07 1983-08-30 The United States Of America As Represented By The United States Department Of Energy Corrosion resistant positive electrode for high-temperature, secondary electrochemical cell
DE3436698C1 (en) * 1984-10-06 1986-05-22 Degussa Ag, 6000 Frankfurt Process for the production of sodium polysulfides from the elements sodium and sulfur
US4676970A (en) * 1985-05-14 1987-06-30 Elkem Metals Company Method for producing metal sulfide and the product produced therefrom
US4761487A (en) * 1986-06-10 1988-08-02 The United States Of America As Represented By The United States Department Of Energy Method for improving voltage regulation of batteries, particularly Li/FeS2 thermal batteries
US4731307A (en) * 1986-06-10 1988-03-15 The United States Of America As Represented By The United States Department Of Energy Methods for achieving the equilibrium number of phases in mixtures suitable for use in battery electrodes, e.g., for lithiating FeS2
JPH11297358A (en) * 1998-04-14 1999-10-29 Matsushita Electric Ind Co Ltd Lithium secondary battery
JPH11297359A (en) * 1998-04-15 1999-10-29 Matsushita Electric Ind Co Ltd All solid lithium secondary battery
US6926997B2 (en) * 1998-11-02 2005-08-09 Sandia Corporation Energy storage and conversion devices using thermal sprayed electrodes
GB2351075A (en) * 1999-06-17 2000-12-20 Secr Defence Producing lithiated transition metal sulphides

Also Published As

Publication number Publication date
US20040018141A1 (en) 2004-01-29
JP4188685B2 (en) 2008-11-26
CN1210826C (en) 2005-07-13
US7018603B2 (en) 2006-03-28
CA2436600C (en) 2010-03-23
WO2002046102A1 (en) 2002-06-13
EP1341724B1 (en) 2004-07-28
ATE272026T1 (en) 2004-08-15
JP2004522674A (en) 2004-07-29
DE60104561T2 (en) 2005-08-04
CN1489553A (en) 2004-04-14
CA2436600A1 (en) 2002-06-13
ES2225655T3 (en) 2005-03-16
KR20040014436A (en) 2004-02-14
GB0029958D0 (en) 2001-01-24
KR100755191B1 (en) 2007-09-05
EP1341724A1 (en) 2003-09-10
DE60104561D1 (en) 2004-09-02

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