AU2001257517A1 - Scorch inhibiting compositions for polyurethane foams - Google Patents

Scorch inhibiting compositions for polyurethane foams

Info

Publication number
AU2001257517A1
AU2001257517A1 AU2001257517A AU5751701A AU2001257517A1 AU 2001257517 A1 AU2001257517 A1 AU 2001257517A1 AU 2001257517 A AU2001257517 A AU 2001257517A AU 5751701 A AU5751701 A AU 5751701A AU 2001257517 A1 AU2001257517 A1 AU 2001257517A1
Authority
AU
Australia
Prior art keywords
carboxylic acids
compositions
heat
scorch
polyurethane foams
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001257517A
Inventor
Sandy G. Belue
Mark E. Ragsdale
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Milliken and Co
Original Assignee
Milliken and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/586,392 external-priority patent/US6541532B1/en
Application filed by Milliken and Co filed Critical Milliken and Co
Publication of AU2001257517A1 publication Critical patent/AU2001257517A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0023—Use of organic additives containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

New, useful and surprisingly effective antiscorch compositions for utilization within polyurethane foam production methods which utilize very popular tertiary amine catalysts are provided. Such compositions require the presence of nominal yet effective amounts of organic cyclic ester materials. The ring systems of such materials appear to open during exposure to heat (during the curing process) and release carboxylic acids into the curing formulation. The tertiary amines become quenched by the carboxylic acids and thus do not exhibit heat destabilization. The resultant foams exhibit extremely low, if no, areas of excessive heating (i.e., scorch) and thus are substantially uniformly colored throughout. The processes and resultant foams are also contemplated within this invention.
AU2001257517A 2000-06-02 2001-05-03 Scorch inhibiting compositions for polyurethane foams Abandoned AU2001257517A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US09586392 2000-06-02
US09/586,392 US6541532B1 (en) 2000-06-02 2000-06-02 Scorch inhibiting compositions for polyurethane foams
US09/795,066 US6525108B2 (en) 2000-06-02 2001-02-26 Scorch inhibiting compositions for polyurethane foams
US09795066 2001-02-26
PCT/US2001/014328 WO2001094455A1 (en) 2000-06-02 2001-05-03 Scorch inhibiting compositions for polyurethane foams

Publications (1)

Publication Number Publication Date
AU2001257517A1 true AU2001257517A1 (en) 2001-12-17

Family

ID=27079695

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2001257517A Abandoned AU2001257517A1 (en) 2000-06-02 2001-05-03 Scorch inhibiting compositions for polyurethane foams

Country Status (8)

Country Link
US (1) US6525108B2 (en)
EP (1) EP1290072B1 (en)
JP (1) JP3806086B2 (en)
CN (1) CN100336851C (en)
AT (1) ATE336542T1 (en)
AU (1) AU2001257517A1 (en)
DE (1) DE60122321T2 (en)
WO (1) WO2001094455A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5938899B2 (en) * 2011-12-27 2016-06-22 川崎化成工業株式会社 Ester composition for polyurethane foam production raw material and method for producing polyurethane foam
JP5513684B2 (en) * 2012-04-26 2014-06-04 モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 Polyurethane foam composition and method for producing flexible polyurethane foam
US9481775B2 (en) * 2014-04-28 2016-11-01 Vanderbilt Chemicals, Llc Polyurethane scorch inhibitor
BR112019006636A2 (en) * 2016-09-30 2019-07-02 Vanderbilt Chemicals Llc low emission pre-vulcanization inhibitor for polyurethane foam

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1197314A (en) * 1967-05-01 1970-07-01 Nuodex Ltd Improvements relating to the production of Polyurethanes
US3886466A (en) 1973-05-24 1975-05-27 Rca Corp Bias circuitry for stacked transistor power amplifier stages
GB1453794A (en) * 1974-01-11 1976-10-27 Interox Chemicals Ltd Polyurethane foams
US4195148A (en) * 1978-07-12 1980-03-25 Uniroyal, Inc. Polyurethane spray composition containing lactone viscosity modifier
DE3425512A1 (en) * 1984-07-11 1986-01-16 Basf Ag, 6700 Ludwigshafen LIQUID DYE PREPARATIONS CONTAINING ORGANIC CARBONATES
JPS6131415A (en) * 1984-07-24 1986-02-13 Daicel Chem Ind Ltd Hydrophilic polyurethane foam
US4568702A (en) * 1985-04-15 1986-02-04 Atlantic Richfield Company Method for the preparation of semi-rigid polyurethane modified polyurea foam compositions
US4709002A (en) 1986-06-05 1987-11-24 Atlantic Richfield Company Method for the preparation of rigid non-cellular reaction injection molded thermoset polyisocyanurate compositions
US4757095A (en) * 1986-07-24 1988-07-12 Basf Corporation Utilization of lactones and lactams in the preparation of polyurethane-polyurea products
EP0276452A1 (en) 1986-12-24 1988-08-03 Cape Industries Viscosity reducing agents for aromatic polyester polyols and polyether polyols
US4731427A (en) 1987-04-01 1988-03-15 Arco Chemical Company Method for the preparation of rigid reaction injection molded thermoset polyurethane modified polyisocyanurate compositions
US4812523A (en) 1988-01-25 1989-03-14 The Glidden Company High solids coatings with reactive diluent
EP0350644A1 (en) 1988-06-28 1990-01-17 Miles Inc. Polyurea rin sytems having improved flow properties
US5028635A (en) 1988-06-28 1991-07-02 Mobay Corporation Polyurea-cyclic carbonate RIM systems having improved flow properties
US5149458A (en) 1988-06-28 1992-09-22 Miles Inc. Polyurea rim systems having improved flow properties and containing an organic cyclic carbonate
GB8822790D0 (en) 1988-09-28 1988-11-02 Ici Plc Novel polyisocyanate composition
US5703136A (en) * 1991-02-04 1997-12-30 Imperial Chemical Industries Plc Polymeric foams
US5116903A (en) 1991-04-05 1992-05-26 E. I. Du Pont De Nemours & Co. Pigment dispersant resin: reaction product of imidazoline and alkylene carbonate adduct and a half blocked diisocyanate
US5442034A (en) 1994-06-01 1995-08-15 Huntsman Corporation Spray polyurea elastomers containing organic carbonates to improve processing characteristics
ES2135927T5 (en) * 1995-11-01 2008-07-01 Basf Corporation A METHOD FOR ELABORATING INSULATING RIGID POLYURETHANE FOAMS.
US5864002A (en) * 1996-10-18 1999-01-26 Milliken Research Corporation Process for coloring polymer resins and products thereof
KR20010013092A (en) * 1997-05-29 2001-02-26 스윈넨 앤 마리 Rigid polyurethane foams
EP0900811A1 (en) * 1997-09-06 1999-03-10 Th. Goldschmidt AG Use of cyclic organic carbonates in the production of polyurethane foams
CA2302707A1 (en) * 1997-09-30 1999-04-08 Rosemarie A. Boccuzzi Stabilized polyether polyol and polyurethane foam obtained therefrom
US6294590B1 (en) * 2000-06-02 2001-09-25 Milliken & Company Reduction of color degradation of triphenylmethane polymeric colorants within polyurethane foams

Also Published As

Publication number Publication date
CN1432037A (en) 2003-07-23
JP3806086B2 (en) 2006-08-09
ATE336542T1 (en) 2006-09-15
US6525108B2 (en) 2003-02-25
EP1290072A1 (en) 2003-03-12
CN100336851C (en) 2007-09-12
WO2001094455A1 (en) 2001-12-13
DE60122321T2 (en) 2007-08-02
JP2003535941A (en) 2003-12-02
DE60122321D1 (en) 2006-09-28
US20020032247A1 (en) 2002-03-14
EP1290072B1 (en) 2006-08-16

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