AU1443197A - Biologically degradable esterquats as flotation aids - Google Patents
Biologically degradable esterquats as flotation aidsInfo
- Publication number
- AU1443197A AU1443197A AU14431/97A AU1443197A AU1443197A AU 1443197 A AU1443197 A AU 1443197A AU 14431/97 A AU14431/97 A AU 14431/97A AU 1443197 A AU1443197 A AU 1443197A AU 1443197 A AU1443197 A AU 1443197A
- Authority
- AU
- Australia
- Prior art keywords
- esterquats
- flotation
- acyl
- alkyl
- biologically degradable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005188 flotation Methods 0.000 title abstract 4
- 125000002252 acyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000012535 impurity Substances 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- -1 ester compounds Chemical class 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/0043—Organic compounds modified so as to contain a polyether group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
- B03D1/011—Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
- B03D1/025—Froth-flotation processes adapted for the flotation of fines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
Landscapes
- Detergent Compositions (AREA)
- Physical Water Treatments (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Paper (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing Of Solid Wastes (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The flotation process for removing mineral impurities, especially silicates, from ores comprises passing air through an aqueous suspension of the ground ore in the presence of a flotation aid and separating off the foam plus the impurities. The collector components used in the flotation aid comprise quaternised ester compounds (esterquats) of formula (I), (II) and/or (III), optionally with other anionic, cationic, amphoteric and/or non-ionic substances. In the formulae: R1CO, R5CO and R9CO = 6-24C acyl; R2, R3, R6 and R10 = H or 6-24C acyl; R4 = 1-4C alkyl or -(CH2CH2O)qH, where q = 1-12; R7, R8, R11, R12 and R13 = 1-4C alkyl; (m + n + p) or (m + n) = 0 or 1-12; and X = halide, alkylsulphate or alkylphosphate.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19602856 | 1996-01-26 | ||
DE19602856A DE19602856A1 (en) | 1996-01-26 | 1996-01-26 | Biodegradable ester quats as flotation aids |
PCT/EP1997/000186 WO1997026995A1 (en) | 1996-01-26 | 1997-01-17 | Biodegradable quaternary esters used as flotation aids |
Publications (2)
Publication Number | Publication Date |
---|---|
AU1443197A true AU1443197A (en) | 1997-08-20 |
AU708335B2 AU708335B2 (en) | 1999-08-05 |
Family
ID=7783797
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU14431/97A Ceased AU708335B2 (en) | 1996-01-26 | 1997-01-17 | Biologically degradable esterquats as flotation aids |
Country Status (10)
Country | Link |
---|---|
EP (2) | EP0876222B1 (en) |
KR (1) | KR19990067053A (en) |
AT (2) | ATE274377T1 (en) |
AU (1) | AU708335B2 (en) |
BR (1) | BR9707082A (en) |
DE (3) | DE19602856A1 (en) |
ES (2) | ES2174784T3 (en) |
MX (1) | MX9805334A (en) |
WO (1) | WO1997026995A1 (en) |
ZA (1) | ZA97573B (en) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000050003A1 (en) * | 1999-02-25 | 2000-08-31 | Chaperon Remy A | Hydrophobic, rheologically active agent, method for producing the same and use thereof |
SE514435C2 (en) | 1999-04-20 | 2001-02-26 | Akzo Nobel Nv | Quaternary ammonium compounds for foam flotation of silicates from iron ore |
WO2007122148A1 (en) * | 2006-04-21 | 2007-11-01 | Akzo Nobel N.V. | Reverse froth flotation of calcite ore |
EP1944088A1 (en) | 2007-01-12 | 2008-07-16 | Omya Development Ag | Process of purification of minerals based on calcium carbonate by flotation in the presence of quaternary imidazollum methosulfate |
EP1949963B2 (en) * | 2007-01-26 | 2014-04-02 | Cognis IP Management GmbH | Use of polymeric esterquats for the flotation of non-sulfidic minerals and ores |
EP1949964A1 (en) * | 2007-01-26 | 2008-07-30 | Cognis IP Management GmbH | Process for the flotation of non-sulfidic minerals and ores |
DE102008056338B4 (en) * | 2008-11-07 | 2012-02-16 | Clariant International Ltd. | Flotation reagent for siliceous minerals |
DE102009055379A1 (en) | 2009-12-29 | 2011-06-30 | Yara International Asa | Wastewater treatment agent for removing fat containing non-ionic surfactants, comprises additives that form solid suspension in the form of iron sulfide or insoluble hydroxide and/or prevents rotting of wastewater |
DE102010004893A1 (en) * | 2010-01-19 | 2011-07-21 | Clariant International Limited | Flotation reagent for magnetite- and / or hematite-containing iron ores |
CN102933310B (en) * | 2010-05-28 | 2014-04-16 | 阿克佐诺贝尔化学国际公司 | Use of quaternary ammonium compounds as collectors in froth flotation processes |
EP2679311A1 (en) * | 2012-06-30 | 2014-01-01 | Clariant S.A., Brazil | Foam prevention in the reverse flotation process for purifying calcium carbonate |
CN104646186A (en) * | 2015-01-30 | 2015-05-27 | 武汉理工大学 | Triester-based quaternary ammonium salt positive ion collecting agent and preparation method and application thereof |
EP3208315A1 (en) | 2016-02-16 | 2017-08-23 | Omya International AG | Process for manufacturing white pigment containing products |
FR3047675B1 (en) | 2016-02-16 | 2018-02-16 | Arkema France | USE OF ALKOXYLATED AMINES AS COLLECTING AGENTS FOR THE ENRICHMENT OF ORE |
FR3047674B1 (en) | 2016-02-16 | 2018-02-16 | Arkema France | USE OF ALKOXYLATED AMINES AS COLLECTING AGENTS FOR THE ENRICHMENT OF ORE |
EP3208314B1 (en) | 2016-02-16 | 2018-08-15 | Omya International AG | Process for manufacturing white pigment containing products |
EP3444036A1 (en) | 2017-08-16 | 2019-02-20 | Omya International AG | Indirect flotation process for manufacturing white pigment containing products |
FI3740319T3 (en) | 2018-01-16 | 2024-05-23 | Clariant Int Ltd | Esterquats for the flotation of non-sulfidic minerals and ores, and method |
WO2020245068A1 (en) * | 2019-06-06 | 2020-12-10 | Basf Se | Collectors for flotation process |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2177985A (en) * | 1938-03-09 | 1939-10-31 | Benjamin R Harris | Ore dressing |
SU1461514A1 (en) * | 1986-11-18 | 1989-02-28 | Институт минеральных ресурсов | Method of dressing ferrous-containing ores |
DE4224714A1 (en) * | 1992-07-27 | 1994-02-03 | Henkel Kgaa | Foaming detergent mixtures |
SE501623C2 (en) * | 1993-05-19 | 1995-04-03 | Berol Nobel Ab | Ways to flotate calcium carbonate ore and a flotation reagent therefor |
-
1996
- 1996-01-26 DE DE19602856A patent/DE19602856A1/en not_active Withdrawn
-
1997
- 1997-01-17 DE DE59706919T patent/DE59706919D1/en not_active Expired - Fee Related
- 1997-01-17 AT AT97901048T patent/ATE274377T1/en active
- 1997-01-17 AU AU14431/97A patent/AU708335B2/en not_active Ceased
- 1997-01-17 WO PCT/EP1997/000186 patent/WO1997026995A1/en not_active Application Discontinuation
- 1997-01-17 KR KR1019980702991A patent/KR19990067053A/en not_active Application Discontinuation
- 1997-01-17 BR BR9707082A patent/BR9707082A/en unknown
- 1997-01-17 EP EP19970901048 patent/EP0876222B1/en not_active Expired - Lifetime
- 1997-01-17 DE DE59711869T patent/DE59711869D1/en not_active Expired - Fee Related
- 1997-01-17 EP EP00107539A patent/EP1025908B1/en not_active Expired - Lifetime
- 1997-01-17 ES ES00107539T patent/ES2174784T3/en not_active Expired - Lifetime
- 1997-01-17 ES ES97901048T patent/ES2227665T3/en not_active Expired - Lifetime
- 1997-01-17 AT AT00107539T patent/ATE215404T1/en active
- 1997-01-23 ZA ZA97573A patent/ZA97573B/en unknown
-
1998
- 1998-06-30 MX MX9805334A patent/MX9805334A/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP1025908B1 (en) | 2002-04-03 |
ZA97573B (en) | 1997-07-28 |
EP0876222A1 (en) | 1998-11-11 |
DE19602856A1 (en) | 1997-07-31 |
AU708335B2 (en) | 1999-08-05 |
DE59711869D1 (en) | 2004-09-30 |
DE59706919D1 (en) | 2002-05-08 |
KR19990067053A (en) | 1999-08-16 |
ATE215404T1 (en) | 2002-04-15 |
EP1025908A1 (en) | 2000-08-09 |
WO1997026995A1 (en) | 1997-07-31 |
BR9707082A (en) | 1999-04-13 |
MX9805334A (en) | 1998-10-31 |
EP0876222B1 (en) | 2004-08-25 |
ES2174784T3 (en) | 2002-11-16 |
ATE274377T1 (en) | 2004-09-15 |
ES2227665T3 (en) | 2005-04-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |