AU1438401A - High efficiency liquid oxygen storage and delivery system - Google Patents

High efficiency liquid oxygen storage and delivery system Download PDF

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Publication number
AU1438401A
AU1438401A AU14384/01A AU1438401A AU1438401A AU 1438401 A AU1438401 A AU 1438401A AU 14384/01 A AU14384/01 A AU 14384/01A AU 1438401 A AU1438401 A AU 1438401A AU 1438401 A AU1438401 A AU 1438401A
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Australia
Prior art keywords
lox
container
oxygen gas
portable
primary reservoir
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Granted
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AU14384/01A
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AU784005B2 (en
Inventor
Richard Davis
Mark R. Frye
Lee S. Toma
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Chart Industries Luxemburg SARL
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Chart Industries Luxemburg SARL
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Assigned to CHART BIOMEDICAL DISTRIBUTION LLC reassignment CHART BIOMEDICAL DISTRIBUTION LLC Alteration of Name(s) in Register under S187 Assignors: MALLINCKRODT, INC.
Assigned to CHART INDUSTRIES LUXEMBOURG S.A.R.L. reassignment CHART INDUSTRIES LUXEMBOURG S.A.R.L. Alteration of Name(s) in Register under S187 Assignors: CHART BIOMEDICAL DISTRIBUTION LLC
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C6/00Methods and apparatus for filling vessels not under pressure with liquefied or solidified gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C7/00Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass
    • F17C7/02Discharging liquefied gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C7/00Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass
    • F17C7/02Discharging liquefied gases
    • F17C7/04Discharging liquefied gases with change of state, e.g. vaporisation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05Size
    • F17C2201/058Size portable (<30 l)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/01Pure fluids
    • F17C2221/011Oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/04Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by other properties of handled fluid before transfer
    • F17C2223/042Localisation of the removal point
    • F17C2223/046Localisation of the removal point in the liquid
    • F17C2223/047Localisation of the removal point in the liquid with a dip tube
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/04Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by other properties of handled fluid after transfer
    • F17C2225/042Localisation of the filling point
    • F17C2225/046Localisation of the filling point in the liquid
    • F17C2225/047Localisation of the filling point in the liquid with a dip tube

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • External Artificial Organs (AREA)

Abstract

A high-efficiency liquid oxygen (LOX) storage/delivery system (100) utilizes a portable LOX/delivery apparatus (160) with a portable LOX container (319). A portable-unit LOX transfer connector (304) is connected to the portable LOX container (319) and is connectable to a main source of LOX in a primary reservoir LOX container (226). A portable-unit oxygen gas transfer connector (384) is provided for transferring oxygen gas from the portable LOX container (319) to an oxygen gas delivery device (90) for delivering oxygen gas to a patient. An inter-unit oxygen gas transfer connector (190) also is provided for connecting the portable apparatus (160) to a stationary source of oxygen gas in the primary reservoir container (226), for transferring oxygen gas to the portable apparatus (160). A portable-unit primary relief (315) valve is connected to the portable LOX container (319) for venting oxygen gas out of the portable LOX container (319) when pressure in the portable LOX container (319) reaches a predetermined level. When the inter-unit oxygen gas transfer connector (190) of the portable container (319) is connected to the stationary source of oxygen in the primary reservoir container (226), oxygen gas can be transferred to the oxygen gas delivery device (90) for delivery to the patient from the portable LOX container (319) while oxygen gas is transferred to the portable container (319) from the stationary source of gas in the primary reservoir LOX container (226).

Description

WO 01/33135 PCT/USOO/29374 HIGH EFFICIENCY LIQUID OXYGEN STORAGE AND DELIVERY SYSTEM CROSS-REFERENCE TO RELATED APPLICATION The present application claims priority from U.S. Provisional patent application Serial 5 No. 60/162,131, filed October 29, 1999. The disclosure of the above-referenced provisional patent application is incorporated herein by reference in its entirety. BACKGROUND OF THE INVENTION 1. Field of the Invention 10 The present invention relates generally to a liquid oxygen storage and delivery system. 2. Description of the Background Art Therapeutic oxygen is the delivery of relatively pure oxygen to a patient in order to ease pulmonary/respiratory problems. When a patient suffers from breathing problems, inhalation of oxygen may ensure that the patient is getting an adequate level of oxygen into his or her 15 bloodstream. Therapeutic oxygen may be warranted in cases where a patient suffers from a loss of lung capacity for some reason. Some medical conditions that may make oxygen necessary are chronic obstructive pulmonary disease (COPD) including asthma, emphysema, etc., as well as cystic fibrosis, lung cancer, lung injuries, and cardiovascular diseases, for example. 20 Related art practice has been to provide portable oxygen in two ways. In a first approach, compressed oxygen gas is provided in a pressure bottle, and the gas is output through a pressure regulator through a hose to the nostrils of the patient. The bottle is often wheeled so that the patient may be mobile. This is a fairly simple and portable arrangement. The drawback of compressed, gaseous oxygen is that a full charge of a bottle that is 25 portable does not last a desirable amount of time. In order to get around this limitation, in a second approach a related art liquid oxygen (LOX) apparatus has been used wherein LOX is stored in a container and the gaseous oxygen formed from the LOX is inhaled by the patient. The related art LOX apparatus enjoys a longer usable charge than the compressed gas 30 apparatus for any given size and weight, but has its own drawbacks. Related art LOX systems typically include a stationary storage container located in a patient's home and a portable unit that the patient uses outside the home. The stationary storage container must be periodically refilled with LOX by a distributor. 1 WO 01/33135 PCT/USOO/29374 A significant percentage of the cost of having a LOX system is in the cost of frequent recharging trips by the LOX distributor. A distributor may have to make weekly recharge trips to a patient's home, or even more frequently, to recharge the patient's LOX system. There thus is a need in the art to cut deliveries or cut costs in other ways. 5 The main drawback of the related art is that considerable waste occurs. One source of waste is that prior art devices provide continuous flow. Also, in the related art, the portable unit may be filled with LOX and used for normal activities and movement. When the patient is done using the related art portable unit, remaining LOX left within the related art portable unit is vented, wasting any remaining oxygen. Because the LOX continues to convert to gaseous 10 oxygen when not being withdrawn, venting is provided for in both the stationary and portable related art units. When the pressure in the related art stationary unit increases beyond a certain point (such as when the related art portable unit is being used), the related art stationary unit must be vented. There remains a need in the art, therefore, for an improved LOX storage and delivery 15 system, with less gas consumption and requiring fewer deliveries of LOX to the patients home. SUMMARY OF THE INVENTION A high-efficiency liquid oxygen (LOX) storage/delivery system is provided according to a first aspect of the invention. The high-efficiency liquid oxygen (LOX) storage/delivery system 20 may include a primary reservoir LOX storage/delivery apparatus comprising a primary reservoir LOX container and a portable LOX/delivery apparatus including a portable LOX container. The primary reservoir LOX apparatus includes a main LOX transfer connector connected to the primary reservoir LOX container for inputting LOX into the primary reservoir LOX container and for outputting LOX from the primary reservoir LOX container to the portable LOX 25 container, and a main-unit oxygen gas transfer connector for transferring oxygen gas from the primary reservoir LOX container. A primary reservoir indicator device may be connected to the primary reservoir LOX container for indicating the LOX contents of the primary reservoir LOX container. A main-unit primary relief valve is connected to the primary reservoir LOX container for venting oxygen gas out of the primary reservoir LOX container when pressure of oxygen gas 30 in the primary reservoir LOX container reaches a predetermined level for the primary reservoir container. The portable LOX apparatus includes a portable-unit LOX transfer connector connected to the portable LOX container and connectable to the main LOX transfer connector for transferring LOX to the portable container from the primary reservoir container, a portable-unit 2 WO 01/33135 PCT/USOO/29374 oxygen gas transfer connector for transferring oxygen gas from the portable LOX container to an oxygen gas delivery device for delivering oxygen gas to a patient, an inter-unit oxygen gas transfer connector for connecting the portable apparatus to the main-unit oxygen gas transfer connector for transferring oxygen gas from the primary reservoir container to the portable 5 apparatus, and a portable-unit primary relief valve connected to the portable LOX container for venting oxygen gas out of the portable LOX container when pressure in the portable LOX container reaches a predetermined level for the portable container. When the inter-unit oxygen gas transfer connector of the portable container is connected to the main-unit oxygen transfer connector of the primary reservoir container, oxygen gas can be transferred from the portable 10 container to the oxygen gas delivery device while oxygen gas is transferred to the portable container from the primary reservoir LOX container. A method for utilizing a high-efficiency liquid oxygen (LOX) storage/delivery system is provided according to a second aspect of the invention. One method comprises connecting the inter-unit oxygen gas transfer connector of a portable container to the main-unit oxygen transfer 15 connector of a primary reservoir container, and withdrawing oxygen gas from the portable container through the portable-unit oxygen gas transfer connector while oxygen gas is transferred to the portable apparatus and to the patient from the primary reservoir container through the main-unit oxygen transfer connector. 20 BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 schematically shows one embodiment of a high efficiency LOX system of the present invention, and illustrates how the primary reservoir and portable LOX storage/deliver apparatus may be interconnected; FIG. 2 schematically shows detail of one embodiment of the primary reservoir LOX 25 storage/delivery apparatus; FIG. 3 schematically shows detail of one embodiment of the portable LOX storage/delivery apparatus. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 30 FIG. 1 shows one embodiment of a high efficiency LOX system 100 of the present invention. The LOX system 100 includes a primary reservoir LOX storage/delivery apparatus (primary reservoir apparatus) 120 and a portable LOX storage/delivery apparatus (portable apparatus) 160. An umbilical conduit 110 may extend between an inter-unit oxygen gas transfer 3 WO 01/33135 PCT/USOO/29374 connector 190 of the portable apparatus 160 and a main-unit oxygen gas transfer connector 213 of the primary reservoir apparatus 120, and may be used to transfer gaseous oxygen therebetween. An oxygen delivery device 90, such as a mask or nasal tubes or cannulas may be attached to either apparatus in order to deliver gaseous oxygen to a patient. Alternatively, the 5 inter-unit oxygen gas transfer connector 190 may be directly connected to the main-unit oxygen gas transfer connector 213. Because LOX transforms from a liquid to a gas as heat is added, related art LOX systems have typically relied on venting of excess gaseous pressure to maintain acceptable internal pressure levels. The result is a higher cost for the health care provider. Pressure control of the 10 portable apparatus 160 and the primary reservoir apparatus 120 is of great importance, as keeping pressures down yields a safe, light weight, economical system through the reduction or elimination of venting. The present invention achieves such economy by balancing use of the primary reservoir apparatus 120 and portable apparatus 160 so that internal pressures do not build up to a point where either apparatus must be excessively vented. The LOX system 100 15 therefore allows usage cycles that make possible efficient LOX use without excessive venting. The primary reservoir apparatus 120 can be of any usable size for storage and delivery of LOX over a desired time period. Suitable units in accordance with the present invention can hold from 20-60 or more liters of LOX. In accordance with one embodiment, a primary reservoir container holding about 36 liters (about 85 pounds) of LOX is provided. In a second 20 embodiment, a primary reservoir container holding about 43 liters (about 110 pounds) of LOX is provided. The primary reservoir apparatus 120 includes the main LOX storage and container. The LOX may be transferred from the primary reservoir apparatus 120 to the portable apparatus 160 as needed to charge the portable apparatus 160 for mobile use. The primary reservoir apparatus 25 120 is intended to hold a sufficiently large charge so that the primary reservoir apparatus 120 can recharge the portable apparatus 160 on a substantially daily basis for a substantially long period of time, e.g., up to about one month or more. This can reduce recharge costs by up to seventy five percent or more over the related art. The portable apparatus 160 preferably is about 3.5 pounds fully charged with LOX and 30 about 2.5 pounds empty, is much smaller and lighter than the primary reservoir apparatus 120, and may provide gaseous oxygen to the patient while being carried by the patient. In use, the primary reservoir apparatus 120 is charged with LOX. The patient may use gaseous oxygen from the primary reservoir apparatus 120 directly via the main-unit oxygen gas 4 WO 01/33135 PCT/USOO/29374 transfer connector 213, or may transfer LOX to the portable apparatus 160 wherein the patient may withdraw gaseous oxygen from the portable apparatus 160. The portable apparatus 160 allows the patient mobility outside the home, while the umbilical conduit 110, which may be up to 50-100 feet in length or longer, allows the patient to connect the portable apparatus to the main 5 reservoir container to conserve LOX. The inter-unit oxygen gas transfer connector 190 may be connected to the main-unit oxygen gas transfer connector 213 of the primary reservoir apparatus 120 to allow oxygen gas withdrawal alternatively from either the portable apparatus 160 or the primary reservoir apparatus 120, or simultaneously from both. 10 FIG. 2 shows detail of one embodiment of the primary reservoir apparatus 120. The primary reservoir apparatus 120 includes a primary reservoir container assembly 205, a main LOX transfer connector 209, a main-unit oxygen gas transfer connector 213, and a main-unit primary relief valve 257. In the embodiment shown, a primary indicator device 274 also is included. 15 The primary reservoir container assembly 205 includes an outer container 223, an inner primary reservoir LOX container 226 spaced apart from the outer container 223, insulation 229 located between the outer container 223 and the inner container 226, a molecular sieve 231, and a vacuum plug 235. The space between the outer container 223 and the inner container 226 is preferably evacuated to at least a partial vacuum in order to minimize heat transfer to the LOX 20 inside the inner container 226. The primary reservoir LOX container assembly 205 also includes an outlet port 238, through which passes a neck conduit 242. The neck conduit 242 extends a short distance into the inner container 226, and is employed for gaseous oxygen withdrawal from the primary reservoir LOX container 226. Inside the neck conduit 242 is a fill conduit 244, preferably concentric with 25 the neck conduit 242. The fill conduit 244 may be used to fill the primary reservoir LOX container 226 with LOX. Inside the fill conduit 244 is a liquid withdrawal conduit 247, preferably concentric with the fill conduit 244. The liquid withdrawal conduit 247 may be used to withdraw LOX from the primary reservoir LOX container 226. Above the outlet port 238 of the primary reservoir LOX container 205 the neck conduit 30 242 splits into two independent conduits. A main-unit vent valve conduit 250 leads to a main unit vent valve 251 which is openable for filling inner container 226 with LOX through the main LOX transfer connector 209. When filling inner container 226 with LOX, main unit vent valve 251 is opened until liquid exits valve 251, indicating that container 226 is filled with LOX. 5 WO 01/33135 PCT/US00/29374 Relief/economizer conduit 255 leads to a main-unit primary relief valve 257 and an economizer valve 261. The main-unit primary relief valve 257 is provided for relieving excess internal gas pressure from the primary reservoir LOX container 226 if the internal gas pressure exceeds a predetermined limit, e.g., 55 psi. Conduit 255 also leads to a main-unit secondary 5 relief valve 258, which can be set at the same or a higher level (e.g., 10-20% higher) than the main-unit primary relief valve, and is a back-up thereto in case of failure thereof. Conduit 255 further leads to an economizer valve 261, the purpose of which will be explained below. Above the neck conduit 242 extends the fill conduit 244, which extends upward to the 10 main-unit LOX transfer connector 209. Between the top of the neck conduit 242 and the main unit LOX transfer connector 209 is a tee 263, where the liquid withdrawal conduit 247 exits the fill conduit 244. After exiting the fill conduit 244, the liquid withdrawal conduit 247 encounters a second tee 264 that joins the liquid withdrawal conduit 247 with an economizer conduit 266 in advance of a warming coil 269. The economizer conduit 266 connects the economizer valve 261 15 with warming coil 269. Gaseous oxygen passes through economizer valve 261 when the economizer valve is open. In order to conserve LOX, the economizer valve 261 can be set at any suitable level below the primary and secondary relief valve settings, so that gaseous oxygen will pass through the economizer valve 261 into the warming coil 269 before such gaseous oxygen is vented through the main-unit primary relief valve 257 or the main-unit secondary relief valve 20 258. One suitable setting for the economizer valve 261 is 22 psi. The liquid withdrawal conduit 247 supplies LOX to the warming coil 269, while the economizer conduit 266 supplies gaseous oxygen withdrawn by way of the relief/economizer conduit 255. In the warming coil 269 the withdrawn LOX and gaseous oxygen is warmed by exposure to room temperature, speeding the liquid-to-gas transformation. It should be noted that the inside diameter of the warming coil 269 25 may be greater than the inside diameter of the liquid withdrawal conduit 247, allowing the LOX to expand as it warms up and transforms from a liquid phase to a gaseous phase. However, the inside diameter of the liquid withdrawal conduit 247 preferably is sized so that when the economizer valve 261 is open, gas flow through line 266 is favored to warming coil 269 over liquid withdrawal through conduit 247. In the embodiment shown, the warming coil 269 is 30 connected to a pressure regulator 271 which can maintain a desired operating pressure at a main unit oxygen gas transfer connector 213. In the embodiment shown, the primary reservoir LOX container 205 includes a primary indicator device 274 that indicates a LOX level in the primary reservoir LOX container 226. The 6 WO 01/33135 PCT/USOO/29374 primary indicator device 274 is connected to a bottom portion of the primary reservoir LOX container 226 via a high pressure sensing conduit 279. The primary indicator device 274 may be interconnected to a pressure gauge 217. The pressure gauge 217 gives a visual readout of an internal gas pressure for the primary reservoir LOX container 226, and may be, for example, a 5 mechanical pressure gauge. The pressure gauge 217 is connected to conduit 255 via a low pressure sensing conduit 277. In use, LOX may be added to or withdrawn from the primary reservoir LOX container 226 through the main-unit LOX transfer connector 209 and the fill conduit 244. The main-unit oxygen gas transfer connector 213 may be used to withdraw gaseous oxygen for use. The 10 gaseous oxygen is provided to the main-unit oxygen gas transfer connector 213 from the economizer valve 261 and/or by conversion of LOX to gas through the liquid withdrawal conduit 247, both through the warming coil 269. FIG. 3 shows detail of one embodiment of the portable apparatus 160. The portable apparatus 160 includes a portable LOX container 302, a portable-unit LOX transfer connector 15 304, a portable-unit oxygen gas transfer connector 384, an inter-unit oxygen gas transfer connector 190, and a portable-unit primary relief valve 315. The portable container assembly 302 includes an outer container 318, an inner portable LOX container 319 spaced apart from the outer container 318, a fill conduit 322, a liquid withdrawal conduit 326, a vacuum plug 328, and a multi-lumen annular conduit 331. The space 20 between the outer container 318 and the inner container 319 is preferably evacuated to at least a partial vacuum in order to minimize heat transfer to the LOX inside the inner container 319. LOX may be introduced into the portable LOX container 319 through the portable-unit LOX transfer connector 304 and the fill conduit 322. The portable-unit LOX transfer connector 304 may be connected to the main-unit LOX transfer connector 209 of the primary reservoir 25 apparatus 120, whereby the portable apparatus 160 may be filled with LOX from the primary reservoir apparatus 120. LOX may be withdrawn via the liquid withdrawal conduit 326, and gaseous oxygen may be withdrawn via the neck conduit 331. A manifold 336 is connected to the neck conduit 331, and splits the neck conduit 331 into 30 a gaseous oxygen withdrawal conduit 339 and a vent conduit 341. The vent conduit 341 may include a vent valve 344. The vent valve 344 may be opened during filling of the portable LOX container 302. When LOX emerges from the vent conduit 341, it is a visual indication that the portable LOX container 319 is full. 7 WO 01/33135 PCT/USOO/29374 In the embodiment shown, the liquid withdrawal conduit 326 passes through the manifold 336 and is connected to a liquid withdrawal warming coil 349 in which the LOX can transform to the gaseous phase. The liquid withdrawal warming coil 349 warms the LOX by exposure to room temperature, speeding the liquid-to-gas transformation. It should be noted that the inside 5 diameter of the liquid withdrawal warming coil 349 may be greater than the inside diameter of the liquid withdrawal conduit 326, allowing the LOX to expand as it warms up and transforms from a liquid phase to a gaseous phase. The gaseous oxygen withdrawal conduit 339 connects with a gas withdrawal warming coil 352. The gas withdrawal warming coil 352 warms the gaseous oxygen before delivery to an 10 oxygen user. Connected to the gas withdrawal warming coil 352 is a portable-unit primary relief valve 315. The portable-unit primary relief valve 315 is capable of opening and relieving a gaseous oxygen pressure in the portable LOX container 319 if the internal gas pressure exceeds a predetermined level, e.g., 27 psi. 15 An economizer valve 356 connects the gas withdrawal warming coil 352 with conduit 380 containing gaseous oxygen from liquid withdrawal warming coil 349. The portable-unit economizer valve 356 can be set at any suitable level below the portable-unit primary relief valve 315, such as 22 psi, and allows gaseous oxygen from coil 352 to pass into line 380 when the pressure of the gaseous oxygen in the portable LOX container 319 exceeds the predetermined 20 threshold level, e.g., 22 psi. In preferred embodiments, the inside diameter of the liquid withdrawal conduit 326 is sized so that when the portable-unit economizer valve 356 is open, gas flow through line 339 is favored over liquid flow through conduit 326. This permits gaseous oxygen from the gaseous head-space in portable container 319 to pass to the patient without the need to waste through the portable-unit primary relief valve 315. The portable-unit economizer 25 valve 356 thus balances gaseous and liquid oxygen withdrawal from the portable LOX container 319, and outputs a resulting gaseous oxygen to a conduit 309. A portable-unit secondary relief valve 382 is provided as a back-up unit to the portable-unit primary relief valve 315, and can be set at the same or a higher level than the portable-unit primary relief valve, and is a back-up thereto in case of failure thereof. 30 Although the function of the economizer valves of the present invention has been described above with reference to preferred embodiments, other configurations, utilizing operating systems of any suitable pressure, will fall within the scope of the present invention. For example, with systems operating at 20 psig, an economizer valve may be set at any suitable 8 WO 01/33135 PCT/USOO/29374 setting such as between 19.5 psig and 22 psig. Alternatively, for systems having operating pressures at about 50 psig, economizer valves having settings, for example, between 48 psig and 55 psig can be utilized. Corresponding primary relief setting for a 20 psig system can, for example, be between 21 psig and 24 psig. Corresponding primary relief settings for a 50 psig 5 system can, for example, be between about 50 psig and 58 psig. However, these configurations are merely exemplary, and other configurations can be utilized in accordance with the present invention. The gaseous oxygen from the conduit 309 may be delivered to a demand flow control device 360, which also may receive gaseous oxygen from the primary reservoir apparatus 120 via 10 the inter-unit oxygen gas transfer connector 190. A check valve 363 may be included between the conduit 309 and the inter-unit oxygen gas transfer connector 190 to prevent backflow of gaseous oxygen from the portable apparatus 160 to the primary reservoir apparatus 120. The demand flow control device 360 is for adjustment of gas flow through a portable-unit oxygen gas transfer connector 384a to an oxygen delivery device 90 for delivery of gaseous 15 oxygen to a patient. Gaseous oxygen is provided to the patient through the portable-unit oxygen gas transfer connector 384a, either from the portable unit, or from the main reservoir unit through connector 190. In preferred embodiments, the demand flow control device 360 can be connected to a gas 20 conserving device 390. A known conserving device is disclosed in U.S. Patent No. 5,360,000. In the embodiment shown, a gas transfer connector system 384a and 384b is utilized, so that when the patient exhales, flow to the oxygen delivery device 90 is stopped, and gas accumulates in the conserving device 390. When the patient inhales, a puff (bolus) of oxygen gas is delivered to the patient from conserving device 390, thereby further preventing waste of 25 gaseous oxygen, followed by an even flow of gaseous oxygen, which then is stopped again when the patient exhales. Use of a conserving device 390 with the portable apparatus of the present invention connected to the primary reservoir apparatus 120 through connector 190 results in tremendous savings and LOX conservation. 30 A method of utilizing the high-efficiency LOX storage/delivery system 100 of the present invention is disclosed. The method uses an umbilical conduit 110 to economize oxygen use by a patient and balance use of the primary reservoir apparatus 120 and portable apparatus 160 so that excess oxygen venting is avoided. 9 WO 01/33135 PCT/US00/29374 The main-unit oxygen gas transfer connector 213 is connected to the inter-unit oxygen gas transfer connector 190, e.g., by umbilical conduit 110. The connection allows gaseous oxygen to flow from the primary reservoir apparatus 120 to the portable apparatus 160. The gaseous oxygen from either the primary reservoir LOX storage delivery apparatus 120 or the 5 portable apparatus 160 may be provided to the patient, depending on which has the higher gas pressure. The umbilical conduit 110 may be a flexible conduit (such as a hose, for example) to give the portable apparatus 160 mobility while yet being connected to the primary reservoir apparatus 120. In this hookup, the oxygen deliver device 90 is connected to the demand flow control 10 device 360 in order to provide gaseous oxygen to the patient. The method may utilize a filling/using cycle of the portable apparatus 160. The method of filling/using of the present invention avoids or reduces unnecessary venting of either the portable apparatus 160 or the primary reservoir apparatus 120. Gaseous oxygen is withdrawn from the primary reservoir 120 for a withdrawal time 15 period, which preferably is at least 5 hours per day, more preferably about 10 hours per day or more. The withdrawal of gaseous oxygen from the primary reservoir apparatus 120 may be through oxygen delivery device 90 either connected directly to connector 213, or connected to connector 384 of the portable apparatus with connector 190 of the portable apparatus connected to the main reservoir apparatus. This gaseous withdrawal time period hook-up to the primary 20 reservoir apparatus 120 permits withdrawal of gaseous oxygen from the primary reservoir LOX container without internal pressure in the primary reservoir LOX container reaching excess levels requiring venting. This conserving measure, in conjunction with economizer valve 261 (and economizer valve 356 if the portable unit is hooked-up), enables oxygen withdrawal without wasteful venting. 25 After the above-discussed withdrawal time period, the portable apparatus 160 may be filled with LOX from the primary reservoir apparatus 120 and disconnected, for example, if the patient wishes to go outside the home. In preferred embodiments, the portable LOX container holds about 1 pound of LOX, which, when utilized with the portable LOX/delivery apparatus of the present invention, can last 30 approximately 10 hours at a typical patient use/withdrawal rate of about 2 liters per minute. During withdrawal of gaseous oxygen from the primary reservoir LOX apparatus, oxygen gas pressure in the primary reservoir LOX apparatus is reduced to a level at which the economizer valve is set (e.g., 22 psi) such that after the portable container is filled with LOX and 10 WO 01/33135 PCT/USOO/29374 disconnected from the primary reservoir LOX apparatus, pressure may increase within the primary reservoir container for a gas pressurizing period within a range of 5-15 hours per day, e.g., about 10 hours per day, to a pressure of, for example, about 50 psi without LOX or oxygen gas being withdrawn from the primary reservoir container and without oxygen gas being vented 5 from the primary reservoir container during the gas pressurizing period. When the patient returns home prior to complete withdrawal of oxygen gas from the portable LOX container, the inter-unit oxygen gas transfer connector of the portable LOX container is connected to the main-unit oxygen transfer connector of the primary reservoir LOX container, and oxygen gas may be withdrawn from the portable LOX container or the primary 10 reservoir LOX container while oxygen gas may be transferred to the portable LOX apparatus from the primary reservoir LOX container through the main-unit oxygen transfer connector, depending on the pressure differential between the containers. In accordance with one embodiment, during the withdrawal period, the inter-unit oxygen gas transfer connector of the portable LOX container is connected to the main-unit oxygen 15 transfer connector of the primary reservoir LOX container, and oxygen gas is transferred from the portable container to the oxygen gas delivery device alternately or concurrently with oxygen gas being transferred to the oxygen gas delivery device through the portable LOX apparatus from the primary reservoir LOX container, thereby lowering gas pressure in the primary reservoir LOX container. 20 The present invention can provide significant savings as compared to related art systems. For example, at a patient use rate of 2 liters per minute, related art systems utilize about 10 pounds LOX per day. The present invention can provide the same 2 liters per minute utilizing about 2 pounds LOX per day, a savings of up to about 8 pounds LOX per day. While the invention has been described in detail above, and shown in the drawings, the 25 invention is not intended to be limited to the specific embodiments as described and shown. 11

Claims (20)

1. A high-efficiency liquid oxygen (LOX) storage/delivery system, comprising: a portable LOX/delivery apparatus comprising a portable LOX container, and including a portable-unit LOX transfer connector connected to the portable LOX container and connectable 5 to a main source of LOX in a primary reservoir LOX container for transferring LOX to said portable container; a portable-unit oxygen gas transfer connector for transferring oxygen gas from said portable LOX container to an oxygen gas delivery device for delivering oxygen gas to a patient; an inter-unit oxygen gas transfer connector for connecting the portable apparatus to a stationary source of oxygen gas in said primary reservoir container for transferring oxygen gas to 10 said portable container; wherein, when the inter-unit oxygen gas transfer connector of the portable container is connected to said stationary source of oxygen in said primary reservoir container, oxygen gas can be transferred to the oxygen gas delivery device for delivery to the patient from the stationary source of gas in the primary reservoir LOX container through the inter-unit oxygen gas transfer 15 connector.
2. The system of claim 1, wherein the inter-unit oxygen gas transfer connector is configured such that, when the inter-unit oxygen gas transfer connector of the portable container is connected to said stationary source of oxygen in said primary reservoir container, oxygen gas 20 can be transferred to the oxygen gas delivery device for delivery to the patient from the portable LOX container and gaseous oxygen is permitted to be transferred to the oxygen gas delivery device from the stationary source of gas in the primary reservoir LOX container.
3. The system of claim 2, further comprising: 25 a primary reservoir LOX storage/delivery apparatus comprising said primary reservoir LOX container; the primary reservoir LOX apparatus including a main LOX transfer connector connected to the primary reservoir LOX container for inputting LOX into said primary reservoir LOX container and connectable to the portable-unit LOX transfer connector for outputting LOX from 30 said primary reservoir LOX container to said portable LOX container; a main-unit oxygen gas transfer connector for transferring oxygen gas from said primary reservoir LOX container, the main-unit oxygen gas transfer connector being connectable to said inter-unit oxygen gas transfer connector, for said transfer of said oxygen gas from said stationary 12 WO 01/33135 PCT/USOO/29374 source of oxygen to said portable apparatus wherein said gaseous oxygen is permitted to be transferred to the oxygen gas delivery device from said stationary source of oxygen.
4. The system of claim 3, further comprising: 5 a portable-unit primary relief valve connected to the portable LOX container for venting oxygen gas out of said portable LOX container when pressure in said portable LOX container reaches a predetermined level for said portable LOX container; and a main-unit primary relief valve connected to the primary reservoir LOX container for venting oxygen gas out of said primary reservoir LOX container when pressure of oxygen gas in 10 said primary reservoir LOX container reaches a predetermined level.
5. The system of claim 3, further comprising a primary indicator device connected to the primary reservoir LOX container for indicating the LOX contents of the primary reservoir LOX container. 15
6. The system of claim 3, wherein said system is adapted for functioning within an operating cycle in which oxygen gas is withdrawn from the primary reservoir container for a withdrawal period of at least about 5 hours per day, then said portable LOX apparatus is filled with LOX from said primary reservoir LOX apparatus, whereby oxygen gas pressure in said 20 primary reservoir LOX apparatus is reduced to a level such that pressure may increase within said primary reservoir container for a gas pressurizing period of about 5-15 hours per day without LOX or oxygen gas being withdrawn from said primary reservoir container and without oxygen gas being vented from said primary reservoir container during said gas pressurizing period. 25
7. The system of claim 6, wherein said system is adapted for functioning within an operating cycle in which, during said withdrawal period, the inter-unit oxygen gas transfer connector of said portable LOX apparatus is connected to said main-unit oxygen transfer connector of said primary reservoir container so that oxygen gas can be transferred from the portable container to the oxygen gas delivery device while oxygen gas is transferred to the 30 portable apparatus from the primary reservoir container through the first oxygen transfer connector. 13 WO 01/33135 PCT/USOO/29374
8. The system of claim 5, wherein said system is adapted for functioning within an operating cycle in which said withdrawal period is at least about 10 hours per day.
9. The system of claim 3, wherein said oxygen gas delivery device is connectable to said 5 main-unit oxygen gas transfer connector for transferring oxygen gas from said primary reservoir LOX container for delivery to said patient.
10. The system of claim 9, wherein a flexible gas conduit is connectable between the main-unit oxygen gas transfer connector to said oxygen gas delivery device. 10
11. The system of claim 3, wherein a flexible gas conduit is capable of connecting the main-unit oxygen gas transfer connector to the inter-unit oxygen gas transfer connector for transferring oxygen gas from said primary reservoir container to said portable apparatus. 15
12. The system of claim 3, wherein said oxygen gas delivery device is connected to a gas conserving device, so that when said patient exhales, oxygen gas accumulates in said conserving device, and when said patient inhales, oxygen gas is delivered to said patient from said conserving device. 20
13. The system of claim 3, wherein said primary reservoir LOX apparatus further includes a pressure indicator device for indicating an internal gaseous oxygen pressure within said primary reservoir LOX container.
14. A method for utilizing a high-efficiency liquid oxygen (LOX) storage/delivery 25 system as in claim 3, said method comprising connecting said inter-unit oxygen gas transfer connector of said portable container to said main-unit oxygen transfer connector of said primary reservoir container, and withdrawing oxygen gas from said portable container through said portable-unit oxygen gas transfer connector while oxygen gas is transferred to the portable container from the primary reservoir container through the main-unit oxygen transfer connector. 30
15. The method of claim 14, further comprising the steps of withdrawing oxygen gas from the primary reservoir container for a withdrawal period of at least about 5 hours per day, then filling said portable LOX apparatus with LOX from said primary reservoir LOX apparatus 14 WO 01/33135 PCT/USOO/29374 through said portable-unit LOX transfer connector connected to said main-unit LOX transfer connector, disconnecting said portable LOX apparatus from said primary reservoir LOX apparatus, and withdrawing oxygen gas from said portable LOX apparatus, whereby during said withdrawal period, oxygen gas pressure in said primary reservoir LOX apparatus is reduced to a 5 level such that thereafter, pressure may increase within said primary reservoir container for a gas pressurizing period of about 5-15 hours per day without LOX or oxygen gas being withdrawn from said primary reservoir container and without oxygen gas being vented from said primary reservoir container during said gas pressurizing period. 10
16. The method of claim 14, wherein prior to complete withdrawal of oxygen gas from said portable LOX container while said portable LOX container is partially filled with LOX, the inter-unit oxygen gas transfer connector of said portable LOX container is connected to said main-unit oxygen transfer connector of said primary reservoir LOX container, and oxygen gas is withdrawn from the portable LOX container while oxygen gas is transferred to the portable LOX 15 apparatus from the primary reservoir LOX container through the main-unit oxygen transfer connector.
17. The method of claim 17, wherein during said withdrawal period, said inter-unit oxygen gas transfer connector of said portable LOX container is connected to said main-unit 20 oxygen transfer connector of said primary reservoir LOX container, and oxygen gas is transferred from the portable container to the oxygen gas delivery device while oxygen gas is transferred to the portable LOX apparatus from the primary reservoir LOX container through the main-unit oxygen transfer connector. 25
18. The method of claim 17, wherein during said withdrawal period, the inter-unit oxygen gas transfer connector is connected to the main-unit oxygen gas transfer connector by a flexible gas conduit.
19. The method of claim 14, wherein during said withdrawal period, the main-unit 30 oxygen gas transfer connector is connected to said oxygen gas delivery device by a flexible gas conduit. 15 WO 01/33135 PCT/USOO/29374
20. The method of claim 14, wherein said oxygen gas delivery device is connected to a gas conserving device, so that when said patient exhales, oxygen gas accumulates in said conserving device, and when said patient inhales, oxygen gas is delivered to said patient from said conserving device. 5 16
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US16213199P 1999-10-29 1999-10-29
US60/162131 1999-10-29
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US7721733B2 (en) 2005-07-29 2010-05-25 Ric Investments, Llc Portable liquid oxygen delivery system
US9186476B2 (en) 2007-01-31 2015-11-17 Ric Investments, Llc System and method for oxygen therapy
FR2916145A1 (en) 2007-05-14 2008-11-21 Air Liquide DOMESTIC AND AMBULATORY OXYGEN SUPPLY DEVICE
JP4918420B2 (en) * 2007-06-29 2012-04-18 三菱重工業株式会社 Cryogenic fluid storage and delivery device
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US4211086A (en) * 1977-10-11 1980-07-08 Beatrice Foods Company Cryogenic breathing system
US5417073A (en) * 1993-07-16 1995-05-23 Superconductor Technologies Inc. Cryogenic cooling system
US5979440A (en) * 1997-06-16 1999-11-09 Sequal Technologies, Inc. Methods and apparatus to generate liquid ambulatory oxygen from an oxygen concentrator

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AU784005B2 (en) 2006-01-12
ATE450750T1 (en) 2009-12-15

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