ATE55766T1 - HYDRATION PROCESSES OF NITRILE COMPOUNDS. - Google Patents

HYDRATION PROCESSES OF NITRILE COMPOUNDS.

Info

Publication number
ATE55766T1
ATE55766T1 AT85306670T AT85306670T ATE55766T1 AT E55766 T1 ATE55766 T1 AT E55766T1 AT 85306670 T AT85306670 T AT 85306670T AT 85306670 T AT85306670 T AT 85306670T AT E55766 T1 ATE55766 T1 AT E55766T1
Authority
AT
Austria
Prior art keywords
catalyst
nitrile compounds
iron
hydration processes
hydration
Prior art date
Application number
AT85306670T
Other languages
German (de)
Inventor
Shiro Asano
Jun Kitagawa
Original Assignee
Mitsui Toatsu Chemicals
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Toatsu Chemicals filed Critical Mitsui Toatsu Chemicals
Application granted granted Critical
Publication of ATE55766T1 publication Critical patent/ATE55766T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/06—Preparation of carboxylic acid amides from nitriles by transformation of cyano groups into carboxamide groups
    • C07C231/065—By hydration using metals or metallic ions as catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/22—Separation; Purification; Stabilisation; Use of additives
    • C07C231/24—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C233/09—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to carbon atoms of an acyclic unsaturated carbon skeleton
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Disclosed herein is a process for the hydration of a nitrile compound. Owing to the use of a Raney copper catalyst having an iron content of 0.7 wt. % or less based on the copper component in a suspended state, the process allows the catalyst to retain high activity and facilitates the separation of the catalyst and liquid reaction mixture by sedimentalion and/or filtration. In an example, a catalyst with 0.1 iron achieved 67% conversion of acrylonitrile to acrylamide, whereas a catalyst with 1.56% iron achieved only 40%.
AT85306670T 1984-09-20 1985-09-19 HYDRATION PROCESSES OF NITRILE COMPOUNDS. ATE55766T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP59195721A JPS6176447A (en) 1984-09-20 1984-09-20 Hydration of nitrile compound
EP85306670A EP0175581B1 (en) 1984-09-20 1985-09-19 Hydration process of nitrile compound

Publications (1)

Publication Number Publication Date
ATE55766T1 true ATE55766T1 (en) 1990-09-15

Family

ID=16345860

Family Applications (1)

Application Number Title Priority Date Filing Date
AT85306670T ATE55766T1 (en) 1984-09-20 1985-09-19 HYDRATION PROCESSES OF NITRILE COMPOUNDS.

Country Status (11)

Country Link
EP (1) EP0175581B1 (en)
JP (1) JPS6176447A (en)
KR (1) KR870001678B1 (en)
AT (1) ATE55766T1 (en)
AU (1) AU561379B2 (en)
BR (1) BR8504588A (en)
CA (1) CA1227488A (en)
DE (1) DE3579280D1 (en)
ES (1) ES8605751A1 (en)
SU (1) SU1575935A3 (en)
ZA (1) ZA856934B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0662527B2 (en) * 1985-03-27 1994-08-17 三井東圧化学株式会社 Method for producing (meth) acrylamide
DE3767365D1 (en) * 1986-05-21 1991-02-21 Allied Colloids Ltd CATALYSTS AND THEIR USE FOR HYDROLYSIS OF NITRILES.
CA2087557C (en) * 1992-07-31 2000-04-25 Matthew Raskin Method for removing catalyst
US20020038051A1 (en) 2000-02-18 2002-03-28 Degussa-Huls Ag Raney copper
EP1382389A1 (en) * 2000-02-18 2004-01-21 Degussa AG Raney copper catalyst for the dehydrogenation of alcohols
EP1382595A1 (en) 2000-02-18 2004-01-21 Degussa AG Fixed bed copper Raney catalyst for dehydrogenating alcohols
JP5732678B2 (en) 2010-08-02 2015-06-10 国立大学法人 岡山大学 Metal complex compound and method for producing amides using the metal complex compound

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3944609A (en) * 1973-06-01 1976-03-16 American Cyanamid Company Catalyst preparation method
AU471081B2 (en) * 1973-10-12 1976-04-08 Method of producing olefinic amides with a raney copper catalyst
JPS5233612B2 (en) * 1973-12-21 1977-08-30

Also Published As

Publication number Publication date
EP0175581A3 (en) 1987-05-20
ZA856934B (en) 1986-04-30
AU561379B2 (en) 1987-05-07
ES547124A0 (en) 1986-04-01
ES8605751A1 (en) 1986-04-01
KR860002457A (en) 1986-04-26
AU4730985A (en) 1986-03-27
JPS6176447A (en) 1986-04-18
KR870001678B1 (en) 1987-09-22
SU1575935A3 (en) 1990-06-30
EP0175581B1 (en) 1990-08-22
EP0175581A2 (en) 1986-03-26
BR8504588A (en) 1986-07-15
CA1227488A (en) 1987-09-29
DE3579280D1 (en) 1990-09-27

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Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee