ATE374226T1 - FLAME-RESISTANT POLYCARBONATE MOLDING COMPOUNDS - Google Patents
FLAME-RESISTANT POLYCARBONATE MOLDING COMPOUNDSInfo
- Publication number
- ATE374226T1 ATE374226T1 AT03766216T AT03766216T ATE374226T1 AT E374226 T1 ATE374226 T1 AT E374226T1 AT 03766216 T AT03766216 T AT 03766216T AT 03766216 T AT03766216 T AT 03766216T AT E374226 T1 ATE374226 T1 AT E374226T1
- Authority
- AT
- Austria
- Prior art keywords
- sup
- weight
- mol
- sub
- relation
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Silicon Polymers (AREA)
Abstract
A thermoplastic molding composition having good flame resistance, melt flowability, resistance to chemicals and creep is disclosed. The composition contains A) at least one member having weight average molecular weight (M<SUB>w</SUB>) of 25,000 to 35,000 g/mol, selected from the group consisting of aromatic polycarbonate and polyestercarbonate B) ABS graft polymer produced by the mass polymerization process and characterized in (i) having a butadiene content of 8 to 15% in relation to the weight of the graft polymer, (ii) having an acrylic acid derivative content of 15 to 30% in relation to the total weight of the acrylic derivative and styrene monomer, and (iii) containing styrene monomer-acrylic acid derivative copolymer having a weight average molecular weight of 5.10<SUP>4 </SUP>to 14.10<SUP>4 </SUP>g/mol. The composition may further contain one or more of halogen-free phosphorus compounds, fluorinated polyolefin, a polymer containing acrylate monomer and an inorganic material in particulate form.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10234420A DE10234420A1 (en) | 2002-07-29 | 2002-07-29 | Impact-modified polycarbonate blends |
DE2002154549 DE10254549A1 (en) | 2002-11-21 | 2002-11-21 | Composition containing aromatic polycarbonate or polyester carbonate or their mixtures useful in the production of housings etc., e.g. of information technology equipment, e.g. printers, copiers, monitors, and also mobile phones |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE374226T1 true ATE374226T1 (en) | 2007-10-15 |
Family
ID=31496735
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT03766216T ATE374226T1 (en) | 2002-07-29 | 2003-07-18 | FLAME-RESISTANT POLYCARBONATE MOLDING COMPOUNDS |
Country Status (13)
Country | Link |
---|---|
US (2) | US7220790B2 (en) |
EP (1) | EP1527138B1 (en) |
JP (1) | JP4272153B2 (en) |
KR (1) | KR100957883B1 (en) |
CN (1) | CN100408629C (en) |
AT (1) | ATE374226T1 (en) |
AU (1) | AU2003246717A1 (en) |
CA (1) | CA2494355C (en) |
DE (1) | DE50308282D1 (en) |
ES (1) | ES2290502T3 (en) |
MX (1) | MXPA05001111A (en) |
TW (1) | TWI317747B (en) |
WO (1) | WO2004013229A1 (en) |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10036057A1 (en) * | 2000-07-25 | 2002-02-07 | Bayer Ag | Fire-resistant polycarbonate composition for use, e.g. in domestic appliances, office machines or vehicle parts, contains a Bisphenol A-based oligo-phosphate with a low content of isopropenyl phenyl phosphate |
US7223804B2 (en) * | 2003-12-30 | 2007-05-29 | General Electric Company | Polycarbonate composition |
US20060004154A1 (en) * | 2004-07-02 | 2006-01-05 | Derudder James L | Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof |
US20090023871A9 (en) * | 2004-08-05 | 2009-01-22 | General Electric Company | Flame retardant thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof |
US7725721B2 (en) | 2004-11-18 | 2010-05-25 | Cisco Technology, Inc. | Method and system for transferring software and hardware feature licenses between devices |
JP5177940B2 (en) * | 2004-12-08 | 2013-04-10 | 出光興産株式会社 | Thermoplastic resin composition and molded body |
US20060142486A1 (en) * | 2004-12-23 | 2006-06-29 | Derudder James L | Thermoplastic polycarbonate compositions, articles made therefrom and method of manufacture |
WO2007001130A1 (en) * | 2005-06-29 | 2007-01-04 | Cheil Industries Inc. | Polycarbonate resin composition having good chemical resistance and flowability |
CN103333425B (en) * | 2005-10-12 | 2016-08-31 | 盛禧奥欧洲有限责任公司 | Polymerisation in bulk, the monovinylidene aromatic copolymer composition of modified rubber |
KR100838451B1 (en) * | 2005-12-30 | 2008-06-16 | 제일모직주식회사 | Flame retardant polycarbonate resin composition having good impact, high heat resistance |
US9127154B2 (en) * | 2006-10-13 | 2015-09-08 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
US8642700B2 (en) * | 2006-11-03 | 2014-02-04 | Bayer Materialscience Llc | Thermoplastic composition having low gloss and low temperature impact performance |
DE102006055479A1 (en) * | 2006-11-24 | 2008-05-29 | Bayer Materialscience Ag | Toughened filled polycarbonate compositions |
US7524898B2 (en) * | 2006-12-01 | 2009-04-28 | Bayer Materialscience Llc | Thermoplastic molding composition having improved toughness at low temperatures and surface appearance |
US8217101B2 (en) * | 2007-03-02 | 2012-07-10 | Bayer Materialscience Llc | Flame retardant thermoplastic molding composition |
US7977415B2 (en) * | 2007-11-30 | 2011-07-12 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
US7799848B2 (en) * | 2007-11-30 | 2010-09-21 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
DE102007061761A1 (en) * | 2007-12-20 | 2009-06-25 | Bayer Materialscience Ag | Flame-retardant toughened polycarbonate compositions |
US20090326111A1 (en) * | 2008-06-30 | 2009-12-31 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
DE102009014878A1 (en) * | 2009-03-25 | 2010-09-30 | Bayer Materialscience Ag | Flame-retardant toughened polycarbonate compositions |
CN101671470B (en) * | 2009-10-13 | 2011-03-16 | 青岛国恩科技发展有限公司 | Fire-retardant high-ductility composite material and manufacturing method thereof |
US20110130517A1 (en) * | 2009-12-01 | 2011-06-02 | Bayer Materialscience Llc | Hydrolytic stability of polycarbonate containing rubber modifier |
TWI521051B (en) * | 2010-03-11 | 2016-02-11 | 盛禧奧歐洲有限責任公司 | Impact modified ignition resistant carbonate polymer composition |
US8440762B2 (en) | 2011-01-14 | 2013-05-14 | Sabic Innovative Plastics Ip B.V. | Polymer compositions, method of manufacture, and articles formed therefrom |
US8404772B2 (en) | 2011-01-14 | 2013-03-26 | Sabic Innovative Plastics Ip B.V. | Polymer compositions, method of manufacture, and articles formed therefrom |
CN102746631B (en) * | 2011-04-20 | 2015-01-07 | 中国石油化工股份有限公司 | Low temperature impact resistant polycarbonate/ABS (acrylonitrile, butadiene and styrene) resin plastic alloy |
CN102746632B (en) * | 2011-04-20 | 2014-11-26 | 中国石油化工股份有限公司 | Polycarbonate/ABS (acrylonitrile, butadiene and styrene) resin plastic alloy |
TWI450930B (en) * | 2011-12-30 | 2014-09-01 | Chi Mei Corp | Carbonate-based polymer composition and products made from said carbonate-based polymer composition |
EP2657298A1 (en) * | 2012-04-27 | 2013-10-30 | Bayer MaterialScience AG | PC/ABS compounds with good thermal and chemical resistance |
US9023973B2 (en) | 2012-12-20 | 2015-05-05 | Sabic Global Technologies B.V. | Cross-linked polycarbonate resin with improved chemical and flame resistance |
EP2935399B1 (en) * | 2012-12-20 | 2018-08-22 | SABIC Global Technologies B.V. | Processes for enhancing flame retardance and chemical resistance of polymers |
EP2935398B1 (en) | 2012-12-20 | 2017-05-17 | SABIC Global Technologies B.V. | Blends containing photoactive additives |
CN103073864A (en) * | 2012-12-25 | 2013-05-01 | 江苏金发科技新材料有限公司 | High-impact low-smoke density halogen-free flame-retardant PC polycarbonate composition |
KR101922246B1 (en) * | 2013-02-06 | 2018-11-26 | 에스케이케미칼 주식회사 | Polymer resin composition having excellent impact resistance or heat resistance |
US9856406B2 (en) * | 2013-03-11 | 2018-01-02 | Covestro Llc | Flame retardant polycarbonate |
EP2970660A4 (en) * | 2013-03-12 | 2016-10-26 | Covestro Llc | Polycarbonate blend with law smoke generation |
WO2014152881A1 (en) | 2013-03-14 | 2014-09-25 | Sabic Innovative Plastics Ip B.V. | Photoactive additive with functionalized benzophenone |
US9587078B2 (en) | 2013-03-15 | 2017-03-07 | Sabic Global Technologies B.V. | Processes for enhancing flame retardance and chemical resistance of polymers |
EP2970655B1 (en) * | 2013-03-15 | 2021-10-27 | SHPP Global Technologies B.V. | Blends containing photoactive additive |
KR102049411B1 (en) * | 2013-06-11 | 2019-11-27 | 에스케이케미칼 주식회사 | Polymer resin composition with excellent chemical resistance |
KR102049410B1 (en) | 2013-06-11 | 2019-11-27 | 에스케이케미칼 주식회사 | Parts for vehicle, electrical/electronic instrument, home appliance, office machine, or household item |
KR101753821B1 (en) | 2013-12-18 | 2017-07-04 | 사빅 글로벌 테크놀러지스 비.브이. | Polyester/polycarbonate composition and article |
CN106687527B (en) | 2014-10-22 | 2018-03-30 | 沙特基础工业全球技术有限公司 | Polycarbonate/polyester composition and product prepared therefrom |
FR3033573B1 (en) * | 2015-03-10 | 2018-03-23 | Arkema France | THERMOPLASTIC COMPOSITION AND PRE-IMPREGNE, COMPOSITE MATERIAL BASED ON SAID PRE-IMPREGN AND USES OF SAID COMPOSITE MATERIAL |
CN104761860B (en) * | 2015-04-08 | 2016-03-23 | 台州市元嘉工业有限公司 | ABS resin material of a kind of nanocrystal composite oxide modified and preparation method thereof |
TWI692498B (en) * | 2015-04-21 | 2020-05-01 | 日商三菱瓦斯化學股份有限公司 | Fiber reinforced thermoplastic resin composition |
EP3500707A1 (en) * | 2016-08-19 | 2019-06-26 | Covestro LLC | Ultrathin polycarbonate panels for security isolation cells |
KR102018717B1 (en) | 2016-12-22 | 2019-09-05 | 롯데첨단소재(주) | Thermoplastic resin composition and article using the same |
KR102417442B1 (en) * | 2020-12-17 | 2022-07-07 | 주식회사 삼양사 | Polycarbonate resin composition with improved chemical resistance and molded article comprising the same |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
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DE3728924A1 (en) | 1987-08-29 | 1989-03-09 | Bayer Ag | FLAME-RESISTANT, THERMOPLASTIC MOLDING MATERIALS BASED ON POLYCARBONATE, POLYALKYLENE TEREPHTHALATE, GRAFT FCOPOLYMERISATE, FLUORINATED POLYOLEFIN AND PHOSPHORIC COMPOUND |
DE3853032T2 (en) | 1987-09-21 | 1995-09-14 | Mitsubishi Rayon Co | Polycarbonate resin composition. |
DE3819081A1 (en) | 1988-06-04 | 1989-12-07 | Bayer Ag | FLAME-RESISTANT, IMPACT TOOL POLYCARBONATE MOLDS |
US5204394A (en) | 1988-09-22 | 1993-04-20 | General Electric Company | Polymer mixture having aromatic polycarbonate, styrene I containing copolymer and/or graft polymer and a flame-retardant, articles formed therefrom |
JPH04345657A (en) | 1991-05-23 | 1992-12-01 | Mitsubishi Kasei Corp | Flame-retardant polycarbonate resin composition |
DE4235642A1 (en) * | 1992-10-22 | 1994-04-28 | Bayer Ag | Flame retardant molding compounds |
WO1994011429A1 (en) | 1992-11-18 | 1994-05-26 | The Dow Chemical Company | Ignition resistant polycarbonate blends |
JPH06239965A (en) | 1993-02-22 | 1994-08-30 | Mitsubishi Kasei Corp | Flame-retardant polycarbonate resin composition |
DE4328656A1 (en) | 1993-08-26 | 1995-03-02 | Bayer Ag | Flame retardant, stress crack resistant polycarbonate ABS molding compounds |
JPH0873692A (en) | 1994-09-08 | 1996-03-19 | Kanegafuchi Chem Ind Co Ltd | Flame-retardant resin composition |
JPH08319406A (en) * | 1995-05-26 | 1996-12-03 | Kanegafuchi Chem Ind Co Ltd | Flame-retardant resin composition |
TW360681B (en) * | 1995-06-07 | 1999-06-11 | Gen Electric | Phosphate flame retardant polymers |
TW386099B (en) | 1995-07-26 | 2000-04-01 | Gen Electric | Flame resistant compositions of polycarbonate and monovinylidene aromatic compounds |
DE19530200A1 (en) | 1995-08-17 | 1997-02-20 | Bayer Ag | Very fine inorganic powders as flame retardants in thermoplastic molding compounds |
SG69988A1 (en) * | 1995-11-01 | 2000-01-25 | Gen Electric | Flame retardant polycarbonate/graft blends exhibiting heat aging stability |
JP3396485B2 (en) | 1996-02-29 | 2003-04-14 | 鐘淵化学工業株式会社 | Flame retardant thermoplastic resin composition |
TW530078B (en) * | 1997-02-17 | 2003-05-01 | Asahi Chemical Ind | Flame retardant resin composition |
WO1999000456A1 (en) | 1997-06-27 | 1999-01-07 | Kaneka Corporation | Flame-retardant thermoplastic resin composition |
DE19734667A1 (en) * | 1997-08-11 | 1999-02-18 | Bayer Ag | Flame-retardant, reinforced polycarbonate ABS molding compounds |
DE19734661A1 (en) * | 1997-08-11 | 1999-02-18 | Bayer Ag | Flame retardant, stress crack resistant polycarbonate ABS molding compounds |
US6613820B2 (en) | 1997-08-29 | 2003-09-02 | General Electric Company | Polycarbonate resin composition |
SG72917A1 (en) * | 1998-01-28 | 2000-05-23 | Gen Electric | Flame retardant polycarbonate resin/abs graft copolymer blends |
JPH11302523A (en) | 1998-04-14 | 1999-11-02 | Qimei Ind Co Ltd | Thermoplastic resin composition for molding material |
TWI230726B (en) * | 1998-06-17 | 2005-04-11 | Bayer Ag | Thermoplastic molding compositions having improved plateability |
ES2268878T3 (en) | 1998-08-28 | 2007-03-16 | Teijin Chemicals, Ltd. | A COMPOSITION OF POLYCARBONATE RESIN AND MOLDED ARTICLE. |
DE19853105A1 (en) | 1998-11-18 | 2000-05-25 | Bayer Ag | Polycarbonate composition useful for production of molded articles contains graft polymer, phosphorous compound and fluorinated polyolefin |
JP4169437B2 (en) * | 1999-07-15 | 2008-10-22 | 帝人化成株式会社 | Aromatic polycarbonate resin composition |
JP2001031860A (en) | 1999-07-23 | 2001-02-06 | Teijin Chem Ltd | Flame-retardant thermoplastic resin composition and internal mechanism part of printing instrument composed of the composition |
JP4603653B2 (en) * | 2000-04-06 | 2010-12-22 | テクノポリマー株式会社 | Thermoplastic resin composition |
US6613824B2 (en) * | 2001-11-12 | 2003-09-02 | General Electric Company | Flame retardant resinous compositions and method |
-
2003
- 2003-07-18 EP EP03766216A patent/EP1527138B1/en not_active Expired - Lifetime
- 2003-07-18 CA CA2494355A patent/CA2494355C/en not_active Expired - Fee Related
- 2003-07-18 AT AT03766216T patent/ATE374226T1/en not_active IP Right Cessation
- 2003-07-18 KR KR1020057001627A patent/KR100957883B1/en active IP Right Grant
- 2003-07-18 JP JP2004525243A patent/JP4272153B2/en not_active Expired - Fee Related
- 2003-07-18 WO PCT/EP2003/007826 patent/WO2004013229A1/en active IP Right Grant
- 2003-07-18 AU AU2003246717A patent/AU2003246717A1/en not_active Abandoned
- 2003-07-18 MX MXPA05001111A patent/MXPA05001111A/en active IP Right Grant
- 2003-07-18 CN CNB038232669A patent/CN100408629C/en not_active Expired - Lifetime
- 2003-07-18 DE DE50308282T patent/DE50308282D1/en not_active Expired - Lifetime
- 2003-07-18 ES ES03766216T patent/ES2290502T3/en not_active Expired - Lifetime
- 2003-07-25 US US10/627,015 patent/US7220790B2/en not_active Expired - Lifetime
- 2003-07-25 US US10/627,163 patent/US7067567B2/en not_active Expired - Lifetime
- 2003-07-28 TW TW092120474A patent/TWI317747B/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1527138B1 (en) | 2007-09-26 |
KR100957883B1 (en) | 2010-05-13 |
US7067567B2 (en) | 2006-06-27 |
CN100408629C (en) | 2008-08-06 |
US20040059031A1 (en) | 2004-03-25 |
TWI317747B (en) | 2009-12-01 |
CA2494355A1 (en) | 2004-02-12 |
JP2005534757A (en) | 2005-11-17 |
US7220790B2 (en) | 2007-05-22 |
JP4272153B2 (en) | 2009-06-03 |
KR20050032099A (en) | 2005-04-06 |
TW200417567A (en) | 2004-09-16 |
ES2290502T3 (en) | 2008-02-16 |
AU2003246717A1 (en) | 2004-02-23 |
EP1527138A1 (en) | 2005-05-04 |
MXPA05001111A (en) | 2005-04-28 |
CN1685011A (en) | 2005-10-19 |
US20040132877A1 (en) | 2004-07-08 |
WO2004013229A1 (en) | 2004-02-12 |
CA2494355C (en) | 2011-03-22 |
DE50308282D1 (en) | 2007-11-08 |
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