ATE306572T1 - ZINC-NICKEL ELECTRO PLATING - Google Patents
ZINC-NICKEL ELECTRO PLATINGInfo
- Publication number
- ATE306572T1 ATE306572T1 AT00951046T AT00951046T ATE306572T1 AT E306572 T1 ATE306572 T1 AT E306572T1 AT 00951046 T AT00951046 T AT 00951046T AT 00951046 T AT00951046 T AT 00951046T AT E306572 T1 ATE306572 T1 AT E306572T1
- Authority
- AT
- Austria
- Prior art keywords
- bath
- anolyte
- zinc
- nickel
- anode
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
The present invention relates to an apparatus (12) for applying a zinc-nickel electroplate to a workpiece. The apparatus comprises a zinc-nickel electroplating bath (16) comprising an amine additive, such as poly(alkyleneimine), which is capable of being oxidized in the bath to cyanides. The bath has a pH more than about 14. A cathode workpiece (18) is positioned in the bath. An anode assembly (20) is also positioned in the bath. The anode assembly comprises an enclosure (22) defining an anolyte compartment (24), at least a portion of the enclosure being an ion exchange membrane (26). An anolyte (28) is positioned in the compartment. An insoluble metal anode (30) is immersed in the anolyte. The anolyte is a conductive salt or base solution and the anode is a metal or metal coating selected from the group consisting of nickel, cobalt, iron, chromium and alloys thereof.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2000/040208 WO2001096631A1 (en) | 2000-06-15 | 2000-06-15 | Zinc-nickel electroplating |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE306572T1 true ATE306572T1 (en) | 2005-10-15 |
Family
ID=21742124
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT00951046T ATE306572T1 (en) | 2000-06-15 | 2000-06-15 | ZINC-NICKEL ELECTRO PLATING |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1292724B2 (en) |
AT (1) | ATE306572T1 (en) |
DE (1) | DE60023190T3 (en) |
ES (1) | ES2250166T5 (en) |
WO (1) | WO2001096631A1 (en) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6755960B1 (en) | 2000-06-15 | 2004-06-29 | Taskem Inc. | Zinc-nickel electroplating |
US8377283B2 (en) | 2002-11-25 | 2013-02-19 | Coventya, Inc. | Zinc and zinc-alloy electroplating |
DE10261493A1 (en) | 2002-12-23 | 2004-07-08 | METAKEM Gesellschaft für Schichtchemie der Metalle mbH | Anode for electroplating |
US7368043B2 (en) * | 2003-04-10 | 2008-05-06 | Applied Intellectual Capital | Configurations and methods of electrochemical lead recovery from contaminated soil |
EP1639155B1 (en) * | 2003-06-03 | 2016-11-02 | Coventya, Inc. | Zinc and zinc-alloy electroplating |
FR2864553B1 (en) * | 2003-12-31 | 2006-09-01 | Coventya | INSTALLATION OF ZINC DEPOSITION OR ZINC ALLOYS |
US7442286B2 (en) * | 2004-02-26 | 2008-10-28 | Atotech Deutschland Gmbh | Articles with electroplated zinc-nickel ternary and higher alloys, electroplating baths, processes and systems for electroplating such alloys |
ES2324169T3 (en) | 2005-04-26 | 2009-07-31 | Atotech Deutschland Gmbh | ALCALINE GALVANIC BATHROOM WITH A FILTRATION MEMBRANE. |
DE102007060200A1 (en) * | 2007-12-14 | 2009-06-18 | Coventya Gmbh | Galvanic bath, process for electrodeposition and use of a bipolar membrane for separation in a galvanic bath |
EP2096193B1 (en) | 2008-02-21 | 2013-04-03 | Atotech Deutschland GmbH | Process for the preparation of corrosion resistant zinc and zinc-nickel plated linear or complex shaped parts |
ES2404844T3 (en) | 2010-05-07 | 2013-05-29 | Dr.Ing. Max Schlötter Gmbh & Co. Kg | Regeneration of alkaline zinc-nickel electrolytes by eliminating cyanide ions |
DE102010044551A1 (en) * | 2010-09-07 | 2012-03-08 | Coventya Gmbh | Anode and their use in an alkaline electroplating bath |
DE202015002289U1 (en) | 2015-03-25 | 2015-05-06 | Hartmut Trenkner | Two-chamber electrodialysis cell with anion and cation exchange membrane for use as an anode in alkaline zinc and zinc alloy electrolytes for the purpose of metal deposition in electroplating plants |
EP3042985B1 (en) * | 2015-07-22 | 2019-04-10 | Dipsol Chemicals Co., Ltd. | Zinc alloy plating method |
EP3358045A1 (en) | 2017-02-07 | 2018-08-08 | Dr.Ing. Max Schlötter GmbH & Co. KG | Method for the galvanic deposition of zinc and zinc alloy layers from an alkaline coating bath with reduced degradation of organic bath additives |
ES2969188T3 (en) | 2017-06-14 | 2024-05-16 | Dr Ing Max Schloetter Gmbh & Co Kg | Procedure for galvanic deposition of zinc-nickel alloy coatings from an alkaline zinc-nickel alloy bath with reduced additive degradation |
CA3127517A1 (en) * | 2019-01-24 | 2020-07-30 | Atotech Deutschland Gmbh | Membrane anode system for electrolytic zinc-nickel alloy deposition |
CN114574860A (en) * | 2022-03-08 | 2022-06-03 | 南京南微电机有限公司 | Local nickel plating process and application thereof |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3718549A (en) † | 1971-06-14 | 1973-02-27 | Kewanee Oil Co | Alkaline nickel plating solutions |
US4889602B1 (en) † | 1986-04-14 | 1995-11-14 | Dipsol Chem | Electroplating bath and method for forming zinc-nickel alloy coating |
DE3712511C3 (en) * | 1986-04-14 | 1995-06-29 | Dipsol Chem | Alkaline cyanide-free electroplating bath and use of this bath |
JP2769614B2 (en) * | 1986-06-04 | 1998-06-25 | ディップソール 株式会社 | Zinc-nickel alloy plating bath |
JPS62240788A (en) * | 1986-04-14 | 1987-10-21 | Deitsupusoole Kk | Zinc-nickel alloy plating bath |
US4778572A (en) | 1987-09-08 | 1988-10-18 | Eco-Tec Limited | Process for electroplating metals |
DE4035316C2 (en) † | 1990-11-07 | 1993-11-04 | Daimler Benz Ag | METHOD FOR ELECTROLYTIC RECOVERY OF NICKEL FROM CHLORIDE-CONTAINING ELECTROLYTIC BATHS |
US5162079A (en) | 1991-01-28 | 1992-11-10 | Eco-Tec Limited | Process and apparatus for control of electroplating bath composition |
JPH059799A (en) * | 1991-07-05 | 1993-01-19 | Kawasaki Steel Corp | Method and device for supplying metal ion in sulfuric acid-bath zn-ni plating |
US5417840A (en) * | 1993-10-21 | 1995-05-23 | Mcgean-Rohco, Inc. | Alkaline zinc-nickel alloy plating baths |
JP3348963B2 (en) * | 1994-04-14 | 2002-11-20 | ディップソール株式会社 | Zinc-cobalt alloy alkaline plating bath and plating method using the plating bath |
US5883762A (en) † | 1997-03-13 | 1999-03-16 | Calhoun; Robert B. | Electroplating apparatus and process for reducing oxidation of oxidizable plating anions and cations |
DE19834353C2 (en) † | 1998-07-30 | 2000-08-17 | Hillebrand Walter Gmbh & Co Kg | Alkaline zinc-nickel bath |
-
2000
- 2000-06-15 DE DE60023190.9T patent/DE60023190T3/en not_active Expired - Lifetime
- 2000-06-15 AT AT00951046T patent/ATE306572T1/en not_active IP Right Cessation
- 2000-06-15 EP EP00951046.2A patent/EP1292724B2/en not_active Expired - Lifetime
- 2000-06-15 ES ES00951046T patent/ES2250166T5/en not_active Expired - Lifetime
- 2000-06-15 WO PCT/US2000/040208 patent/WO2001096631A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
EP1292724A4 (en) | 2004-09-08 |
EP1292724A1 (en) | 2003-03-19 |
EP1292724B2 (en) | 2015-12-23 |
ES2250166T3 (en) | 2006-04-16 |
EP1292724B1 (en) | 2005-10-12 |
DE60023190T2 (en) | 2006-07-13 |
ES2250166T5 (en) | 2016-05-20 |
WO2001096631A1 (en) | 2001-12-20 |
DE60023190D1 (en) | 2006-02-23 |
DE60023190T3 (en) | 2016-03-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |