ATE294T1 - METALLIC SULFURATED DITHIOPHOSPHATES AND THEIR USE AS ADDITIVES FOR LUBRICANT OILS. - Google Patents
METALLIC SULFURATED DITHIOPHOSPHATES AND THEIR USE AS ADDITIVES FOR LUBRICANT OILS.Info
- Publication number
- ATE294T1 ATE294T1 AT80400269T AT80400269T ATE294T1 AT E294 T1 ATE294 T1 AT E294T1 AT 80400269 T AT80400269 T AT 80400269T AT 80400269 T AT80400269 T AT 80400269T AT E294 T1 ATE294 T1 AT E294T1
- Authority
- AT
- Austria
- Prior art keywords
- percent
- metallic
- dithiophosphates
- weight
- additives
- Prior art date
Links
- 239000000654 additive Substances 0.000 title 1
- 239000000314 lubricant Substances 0.000 title 1
- 239000003921 oil Substances 0.000 title 1
- 239000010687 lubricating oil Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000005069 Extreme pressure additive Substances 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000005907 alkyl ester group Chemical group 0.000 abstract 1
- 239000007866 anti-wear additive Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 238000005987 sulfurization reaction Methods 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
- C10M137/10—Thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/14—Group 7
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/16—Groups 8, 9, or 10
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
- C10N2040/253—Small diesel engines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
- Saccharide Compounds (AREA)
Abstract
Metallic dithiophosphates obtained by the sulfurization of a composition containing: (A) from about 100 to 20 percent by weight of a metallic dithiophosphate of the formula: <IMAGE> in which R1 is an alkenyl or unsaturated cycloaliphatic radical, R2 and R3 are alkyl radicals, m is equal to the valence of the metal M, and M represents a metal of Groups IIB, IIIB, IVB, or VIII of the Periodic System of the Elements, preferably zinc; (B) from about zero to 80 percent of an R4-COOR5 alkyl ester in which R4 is an alkenyl radical and R5 an alkyl radical, by means of 0.5 to 10 percent by weight of sulfur, referred to the composition to be sulfurized. Use as extreme-pressure and anti-wear additives for lubricating oils, in an amount of between about 0.3 and 15 percent of the weight of lubricating oil.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7906059A FR2450869A1 (en) | 1979-03-09 | 1979-03-09 | SULFURIZED METAL DITHIOPHOSPHATES AND THEIR APPLICATION AS ADDITIVES FOR LUBRICATING OILS |
EP80400269A EP0016675B1 (en) | 1979-03-09 | 1980-02-27 | Sulfurized metal dithiophosphates and their application as additives in lubricating oils |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE294T1 true ATE294T1 (en) | 1981-10-15 |
Family
ID=9222945
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT80400269T ATE294T1 (en) | 1979-03-09 | 1980-02-27 | METALLIC SULFURATED DITHIOPHOSPHATES AND THEIR USE AS ADDITIVES FOR LUBRICANT OILS. |
Country Status (10)
Country | Link |
---|---|
US (1) | US4293430A (en) |
EP (1) | EP0016675B1 (en) |
JP (1) | JPS6021717B2 (en) |
AT (1) | ATE294T1 (en) |
BR (1) | BR8001371A (en) |
CA (1) | CA1133006A (en) |
DE (1) | DE3060033D1 (en) |
ES (1) | ES489288A1 (en) |
FR (1) | FR2450869A1 (en) |
ZA (1) | ZA801366B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4507215A (en) * | 1983-04-25 | 1985-03-26 | Lubrizol Corp | Phosphorus-containing metal salt/olefin compositions and reaction products of same with active sulfur |
US4579666A (en) * | 1983-04-25 | 1986-04-01 | The Lubrizol Corporation | Phosphorus-containing metal salt/olefin compositions and reaction products of same with active sulfur |
US4534872A (en) * | 1983-08-02 | 1985-08-13 | Mobil Oil Corporation | Multifunctional lubricant additives and compositions thereof |
US5026492A (en) * | 1989-09-07 | 1991-06-25 | Exxon Research & Engineering Company | Lubricating oil containing an alkyl alkoxyalkylxanthate and zinc dialkyldithiophosphate |
US5034141A (en) * | 1989-09-07 | 1991-07-23 | Exxon Research And Engineering Company | Lubricating oil containing a thiodixanthogen and zinc dialkyldithiophosphate |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2905683A (en) * | 1952-12-17 | 1959-09-22 | Lubrizol Corp | Ether containing esters of dithiophosphoric acid and salts thereof |
US2802856A (en) * | 1953-09-08 | 1957-08-13 | Lubrizol Corp | Methods of preparing tri-esters of thiophosphoric acids |
FR1310171A (en) * | 1960-12-20 | 1963-03-06 | ||
US3288819A (en) * | 1961-10-30 | 1966-11-29 | Standard Oil Co | Zinc salts of glycerol monoester dithiophosphates |
US3944495A (en) * | 1974-02-19 | 1976-03-16 | Texaco Inc. | Metal dialkyldithiophosphates |
US3899432A (en) * | 1974-06-03 | 1975-08-12 | Chevron Res | All-purpose lubricating oil composition with anti-chatter characteristics for wet disc brakes |
US4171268A (en) * | 1978-05-22 | 1979-10-16 | Mooney Chemicals, Inc. | Lubricant compositions containing zirconyl soaps |
-
1979
- 1979-03-09 FR FR7906059A patent/FR2450869A1/en active Granted
-
1980
- 1980-02-27 DE DE8080400269T patent/DE3060033D1/en not_active Expired
- 1980-02-27 AT AT80400269T patent/ATE294T1/en not_active IP Right Cessation
- 1980-02-27 EP EP80400269A patent/EP0016675B1/en not_active Expired
- 1980-02-29 US US06/126,161 patent/US4293430A/en not_active Expired - Lifetime
- 1980-03-07 ES ES489288A patent/ES489288A1/en not_active Expired
- 1980-03-07 BR BR8001371A patent/BR8001371A/en unknown
- 1980-03-07 ZA ZA00801366A patent/ZA801366B/en unknown
- 1980-03-07 CA CA347,287A patent/CA1133006A/en not_active Expired
- 1980-03-07 JP JP55028231A patent/JPS6021717B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE3060033D1 (en) | 1981-12-24 |
FR2450869B1 (en) | 1983-05-20 |
EP0016675A1 (en) | 1980-10-01 |
JPS55143997A (en) | 1980-11-10 |
ZA801366B (en) | 1981-03-25 |
BR8001371A (en) | 1980-11-11 |
FR2450869A1 (en) | 1980-10-03 |
CA1133006A (en) | 1982-10-05 |
US4293430A (en) | 1981-10-06 |
EP0016675B1 (en) | 1981-10-14 |
ES489288A1 (en) | 1980-08-16 |
JPS6021717B2 (en) | 1985-05-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
UEP | Publication of translation of european patent specification | ||
REN | Ceased due to non-payment of the annual fee |