ATE226887T1 - Aus schmelzgeprägten polyolefin/füllstoff ausgangsfolien hergestellte atmungsaktive folien/nwf-laminate mit hoher wasserdampfpermeabilität. - Google Patents
Aus schmelzgeprägten polyolefin/füllstoff ausgangsfolien hergestellte atmungsaktive folien/nwf-laminate mit hoher wasserdampfpermeabilität.Info
- Publication number
- ATE226887T1 ATE226887T1 AT97935263T AT97935263T ATE226887T1 AT E226887 T1 ATE226887 T1 AT E226887T1 AT 97935263 T AT97935263 T AT 97935263T AT 97935263 T AT97935263 T AT 97935263T AT E226887 T1 ATE226887 T1 AT E226887T1
- Authority
- AT
- Austria
- Prior art keywords
- films
- polyethylenes
- filler
- nwf
- laminates
- Prior art date
Links
- 239000000945 filler Substances 0.000 title abstract 4
- 230000035699 permeability Effects 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- 239000004698 Polyethylene Substances 0.000 abstract 6
- 229920000573 polyethylene Polymers 0.000 abstract 6
- -1 polyethylenes Polymers 0.000 abstract 5
- 239000002131 composite material Substances 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/005—Shaping by stretching, e.g. drawing through a die; Apparatus therefor characterised by the choice of materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0032—Ancillary operations in connection with laminating processes increasing porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0036—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/06—Embossing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
- B29K2023/0608—PE, i.e. polyethylene characterised by its density
- B29K2023/0641—MDPE, i.e. medium density polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/08—Copolymers of ethylene
- B29K2023/083—EVA, i.e. ethylene vinyl acetate copolymer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/16—Fillers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0012—Mechanical treatment, e.g. roughening, deforming, stretching
- B32B2038/0028—Stretching, elongating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/10—Fibres of continuous length
- B32B2305/20—Fibres of continuous length in the form of a non-woven mat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/31—Heat sealable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Woven Fabrics (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/691,106 USH2000H1 (en) | 1996-08-01 | 1996-08-01 | Method for making polyolefin/filler films having increased WVTR |
| PCT/US1997/013580 WO1998005502A1 (en) | 1996-08-01 | 1997-07-31 | Breathable film/nwf-laminates having high wvtr prepared from melt embossed polyolefin/filler precursor films |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE226887T1 true ATE226887T1 (de) | 2002-11-15 |
Family
ID=24775186
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT97935263T ATE226887T1 (de) | 1996-08-01 | 1997-07-31 | Aus schmelzgeprägten polyolefin/füllstoff ausgangsfolien hergestellte atmungsaktive folien/nwf-laminate mit hoher wasserdampfpermeabilität. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | USH2000H1 (de) |
| EP (1) | EP0921943B1 (de) |
| AT (1) | ATE226887T1 (de) |
| AU (1) | AU740098B2 (de) |
| CA (1) | CA2261610A1 (de) |
| DE (1) | DE69716744T2 (de) |
| WO (1) | WO1998005502A1 (de) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6776947B2 (en) * | 1996-07-31 | 2004-08-17 | Exxonmobil Chemical Company | Process of adjusting WVTR of polyolefin film |
| US6258308B1 (en) | 1996-07-31 | 2001-07-10 | Exxon Chemical Patents Inc. | Process for adjusting WVTR and other properties of a polyolefin film |
| DE19709352C2 (de) * | 1997-03-07 | 1999-01-14 | Corovin Gmbh | Folie aus Kunststoff mit mineralischen Zusatzstoffen sowie Verfahren zu deren Herstellung |
| US5932497A (en) * | 1997-09-15 | 1999-08-03 | Kimberly-Clark Worldwide, Inc. | Breathable elastic film and laminate |
| US6506695B2 (en) | 1998-04-21 | 2003-01-14 | Rheinische Kunststoffewerke Gmbh | Breathable composite and method therefor |
| US6953510B1 (en) | 1998-10-16 | 2005-10-11 | Tredegar Film Products Corporation | Method of making microporous breathable film |
| BR9914600B1 (pt) | 1998-10-16 | 2009-05-05 | processo para ajustar a taxa de transmissão de vapor d'água de um filme respirável. | |
| US6719742B1 (en) | 1998-12-30 | 2004-04-13 | Kimberly-Clark Worldwide, Inc. | Pattern embossed multilayer microporous films |
| US20040157075A1 (en) * | 2000-06-09 | 2004-08-12 | Building Materials Investment Corporation | Single ply thermoplastic polyolefin (TPO) roofing membranes having superior heat seam peel strengths and low temperature flexibility |
| DE20101769U1 (de) | 2001-01-31 | 2001-05-31 | Ewald Doerken GmbH & Co., 58313 Herdecke | Schutzfolie |
| WO2002103099A1 (en) * | 2001-06-19 | 2002-12-27 | Kappler Safety Group | Vapor permeable, liquid impermeable composite fabric and fabrication process |
| US7972981B2 (en) * | 2002-03-15 | 2011-07-05 | Fiberweb, Inc. | Microporous composite sheet material |
| US20030211309A1 (en) * | 2002-05-08 | 2003-11-13 | Vifan Usa, Inc. | Polypropylene films |
| US6896843B2 (en) | 2002-08-30 | 2005-05-24 | Kimberly-Clark Worldwide, Inc. | Method of making a web which is extensible in at least one direction |
| US7226880B2 (en) | 2002-12-31 | 2007-06-05 | Kimberly-Clark Worldwide, Inc. | Breathable, extensible films made with two-component single resins |
| US7220478B2 (en) | 2003-08-22 | 2007-05-22 | Kimberly-Clark Worldwide, Inc. | Microporous breathable elastic films, methods of making same, and limited use or disposable product applications |
| US7270723B2 (en) | 2003-11-07 | 2007-09-18 | Kimberly-Clark Worldwide, Inc. | Microporous breathable elastic film laminates, methods of making same, and limited use or disposable product applications |
| US20060040091A1 (en) * | 2004-08-23 | 2006-02-23 | Bletsos Ioannis V | Breathable low-emissivity metalized sheets |
| US7439290B2 (en) * | 2005-01-12 | 2008-10-21 | Equistar Chemicals, Lp | Linear low density polyethylene compositions and films |
| BRPI0707178A2 (pt) | 2006-01-27 | 2011-04-26 | Clopay Plastic Prod Co | materiais respiráveis e respectivos métodos de formação |
| US20080096452A1 (en) * | 2006-09-19 | 2008-04-24 | Tredegar Film Products Corporation | Breathable Laminate With A High Abrasion Resistance and Method of Manufacturing the Same |
| ES2592530T3 (es) | 2011-06-17 | 2016-11-30 | Fiberweb, Llc | Artículo de múltiples capas permeable al vapor, sustancialmente impermeable al agua |
| US10369769B2 (en) | 2011-06-23 | 2019-08-06 | Fiberweb, Inc. | Vapor-permeable, substantially water-impermeable multilayer article |
| DK2723568T3 (en) | 2011-06-23 | 2017-10-23 | Fiberweb Llc | Vapor permeable, essentially all water impermeable, multilayer |
| WO2012178011A2 (en) | 2011-06-24 | 2012-12-27 | Fiberweb, Inc. | Vapor-permeable, substantially water-impermeable multilayer article |
| DE102012219593B4 (de) | 2011-10-25 | 2024-06-20 | Vector Foiltec Gmbh | Folienelement für ein eine Folie aufweisendes Gebäudeumhüllungselement sowie Verfahren und Vorrichtung zur Herstellung eines derartigen Gebäudeumhüllungselementes |
| US9492332B2 (en) | 2014-05-13 | 2016-11-15 | Clopay Plastic Products Company, Inc. | Breathable and microporous thin thermoplastic film |
| PE20180807A1 (es) | 2015-07-10 | 2018-05-09 | Berry Plastics Corp | Pelicula transpirable microporosa y metodo para fabricar la pelicula transpirable microporosa |
| BR112018008995A8 (pt) | 2015-11-05 | 2019-02-26 | Berry Global Inc | processo para fabricar um filme multicamadas, processo para fabricar um filme não respirável multicamadas, filme multicamadas, filme não respirável multicamadas, filme parcialmente respirável multicamadas e produto de higiene pessoal |
| US11472085B2 (en) * | 2016-02-17 | 2022-10-18 | Berry Plastics Corporation | Gas-permeable barrier film and method of making the gas-permeable barrier film |
| ES2701915T3 (es) | 2016-03-22 | 2019-02-26 | Rkw Se | Procedimiento para la preparación de una cinta de película cargada |
| US11584111B2 (en) | 2018-11-05 | 2023-02-21 | Windmoeller & Hoelscher Kg | Breathable thermoplastic film with reduced shrinkage |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4350655A (en) | 1977-05-05 | 1982-09-21 | Biax Fiberfilm | Process for producing highly porous thermoplastic films |
| EP0066672B1 (de) | 1981-06-09 | 1987-09-02 | Mitsubishi Kasei Corporation | Verfahren zur Herstellung von porösen Folien oder Filmen |
| US4929303A (en) | 1987-03-11 | 1990-05-29 | Exxon Chemical Patents Inc. | Composite breathable housewrap films |
| US5055338A (en) | 1987-03-11 | 1991-10-08 | Exxon Chemical Patents Inc. | Metallized breathable films prepared from melt embossed polyolefin/filler precursor films |
| US4777073A (en) | 1987-03-11 | 1988-10-11 | Exxon Chemical Patents Inc. | Breathable films prepared from melt embossed polyolefin/filler precursor films |
| US5008204A (en) * | 1988-02-02 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for determining the compositional distribution of a crystalline copolymer |
| US5382630A (en) * | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution |
| US5169712A (en) | 1991-08-23 | 1992-12-08 | Amoco Corporation | Porous film composites |
| US5206075A (en) * | 1991-12-19 | 1993-04-27 | Exxon Chemical Patents Inc. | Sealable polyolefin films containing very low density ethylene copolymers |
| WO1995002630A1 (en) | 1993-07-16 | 1995-01-26 | Exxon Chemical Patents Inc. | Polymeric films with low water vapor transmission rates |
| JPH09501707A (ja) * | 1993-08-06 | 1997-02-18 | エクソン・ケミカル・パテンツ・インク | 重合触媒、その製造及び使用 |
| JP3109056B2 (ja) | 1993-10-19 | 2000-11-13 | 三菱化学株式会社 | 通気性樹脂フィルム |
| CA2148392A1 (en) | 1994-06-06 | 1995-12-07 | Ann Louise Mccormack | Stretch-thinned film and nonwoven laminate |
| US5955187A (en) * | 1995-06-06 | 1999-09-21 | Kimberly-Clark Worldwide, Inc. | Microporous film with liquid triggered barrier feature |
-
1996
- 1996-08-01 US US08/691,106 patent/USH2000H1/en not_active Abandoned
-
1997
- 1997-07-31 CA CA002261610A patent/CA2261610A1/en not_active Abandoned
- 1997-07-31 AU AU38247/97A patent/AU740098B2/en not_active Ceased
- 1997-07-31 EP EP97935263A patent/EP0921943B1/de not_active Expired - Lifetime
- 1997-07-31 AT AT97935263T patent/ATE226887T1/de not_active IP Right Cessation
- 1997-07-31 DE DE69716744T patent/DE69716744T2/de not_active Expired - Lifetime
- 1997-07-31 WO PCT/US1997/013580 patent/WO1998005502A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| DE69716744T2 (de) | 2003-03-20 |
| EP0921943A1 (de) | 1999-06-16 |
| USH2000H1 (en) | 2001-11-06 |
| AU740098B2 (en) | 2001-11-01 |
| AU3824797A (en) | 1998-02-25 |
| CA2261610A1 (en) | 1998-02-12 |
| WO1998005502A1 (en) | 1998-02-12 |
| EP0921943B1 (de) | 2002-10-30 |
| DE69716744D1 (de) | 2002-12-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |