ATE198631T1 - NON-CHROMATED OXIDE COATINGS FOR ALUMINUM SUBSTRATES - Google Patents
NON-CHROMATED OXIDE COATINGS FOR ALUMINUM SUBSTRATESInfo
- Publication number
- ATE198631T1 ATE198631T1 AT93914728T AT93914728T ATE198631T1 AT E198631 T1 ATE198631 T1 AT E198631T1 AT 93914728 T AT93914728 T AT 93914728T AT 93914728 T AT93914728 T AT 93914728T AT E198631 T1 ATE198631 T1 AT E198631T1
- Authority
- AT
- Austria
- Prior art keywords
- cobalt
- conversion coating
- solution
- hexavalent complex
- iii hexavalent
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/56—Treatment of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
- C23C22/66—Treatment of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
- Chemically Coating (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Insulated Metal Substrates For Printed Circuits (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
(A) A process for forming a cobalt conversion coating on a metal substrate, thereby imparting corrosion resistance and paint adhesion properties. The invention was developed as a replacement for the prior art chromic acid process. The process includes the steps of: (a) providing a cobalt conversion solution comprising an aqueous solution containing a soluble cobalt-III hexavalent complex, the concentration of the cobalt-III hexavalent complex being from about 0.01 mole per liter of solution to the solubility limit of the cobalt-III hexavalent complex; and (b) contacting the substrate with the solution for a sufficient amount of time, whereby the cobalt conversion coating is formed. The substrate may be aluminum or aluminum alloy, as well as Cd plated, Zn plated, Zn-Ni plated, and steel. The cobalt-III hexavalent complex may be present in the form of Mem(Co(R)6)n, wherein Me is Na, Li, K, Ca, Zn, Mg, or Mn, and wherein m is 2 or 3, n is 1 or 2, and R is a carboxylate having from 1 to 5 C atoms. (B) A chemical conversion coating solution for producing the cobalt conversion coating on a metal substrate, the solution including an aqueous solution containing a soluble cobalt-III hexavalent complex, the concentration of the cobalt-III hexavalent complex being from about 0.01 mole per liter of solution to the solubility limit of the cobalt-III hexavalent complex. (C) A coated article exhibiting acceptable corrosion resistance and paint adhesion properties, the article including: (a) a metal substrate; and (b) a cobalt conversion coating formed on the substrate, the cobalt conversion coating including aluminum oxide Al2O3 as the largest volume percent, and cobalt oxides CoO, Co2O3, and Co3O4.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/903,853 US5411606A (en) | 1990-05-17 | 1992-06-25 | Non-chromated oxide coating for aluminum substrates |
CNB931017378A CN1138873C (en) | 1992-06-25 | 1993-01-18 | Non-chromated oxide coating for aluminum substrates |
PCT/EP1993/001630 WO1994000619A1 (en) | 1992-06-25 | 1993-06-23 | Non-chromated oxide coating for aluminum substrates |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE198631T1 true ATE198631T1 (en) | 2001-01-15 |
Family
ID=36793885
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT93914728T ATE198631T1 (en) | 1992-06-25 | 1993-06-23 | NON-CHROMATED OXIDE COATINGS FOR ALUMINUM SUBSTRATES |
Country Status (18)
Country | Link |
---|---|
EP (1) | EP0646187B1 (en) |
JP (1) | JP3345010B2 (en) |
CN (2) | CN1138873C (en) |
AT (1) | ATE198631T1 (en) |
AU (1) | AU687740B2 (en) |
BR (1) | BR9306602A (en) |
CA (1) | CA2138790C (en) |
DE (1) | DE69329853T2 (en) |
DK (1) | DK0646187T3 (en) |
ES (1) | ES2152950T3 (en) |
GR (1) | GR3035554T3 (en) |
MX (1) | MX9303745A (en) |
NO (1) | NO315522B1 (en) |
NZ (1) | NZ253699A (en) |
RU (1) | RU2135637C1 (en) |
SG (1) | SG43169A1 (en) |
WO (1) | WO1994000619A1 (en) |
ZA (1) | ZA934544B (en) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5551994A (en) * | 1990-05-17 | 1996-09-03 | The Boeing Company | Non-chromated oxide coating for aluminum substrates |
DK0523288T3 (en) * | 1991-07-19 | 1999-08-02 | Boeing Co | Non-chromated oxide coatings for aluminum substrates |
US5948178A (en) * | 1995-01-13 | 1999-09-07 | Henkel Corporation | Composition and process for forming a solid adherent protective coating on metal surfaces |
WO1996021753A1 (en) * | 1995-01-13 | 1996-07-18 | Henkel Corporation | Composition and process for forming a solid adherent protective coating on metal surfaces |
ZA962178B (en) * | 1995-03-22 | 1996-07-29 | Henkel Corp | Compositions and processes for forming a solid adherent protective coating on metal surfaces |
FR2752851B1 (en) * | 1996-09-02 | 1998-11-13 | Cfpi Ind | BATH AND METHOD FOR PHOSPHATION OF METAL SUBSTRATES, CONCENTRATE FOR THE PREPARATION OF THIS BATH AND METAL SUBSTRATES TREATED WITH THE BATH AND METHOD |
US5873953A (en) * | 1996-12-26 | 1999-02-23 | The Boeing Company | Non-chromated oxide coating for aluminum substrates |
US6315823B1 (en) | 1998-05-15 | 2001-11-13 | Henkel Corporation | Lithium and vanadium containing sealing composition and process therewith |
AU2002361689A1 (en) | 2002-01-04 | 2003-07-30 | University Of Dayton | Non-toxic corrosion protection pigments based on cobalt |
US7235142B2 (en) | 2002-01-04 | 2007-06-26 | University Of Dayton | Non-toxic corrosion-protection rinses and seals based on cobalt |
US7294211B2 (en) | 2002-01-04 | 2007-11-13 | University Of Dayton | Non-toxic corrosion-protection conversion coats based on cobalt |
FR2856079B1 (en) * | 2003-06-11 | 2006-07-14 | Pechiney Rhenalu | SURFACE TREATMENT METHOD FOR ALUMINUM ALLOY TILES AND BANDS |
CN1309864C (en) * | 2004-09-29 | 2007-04-11 | 广州擎天油漆化工实业有限公司 | Environmental protective process for forming transforming film on aluminium and aluminium alloy surface |
CN100372972C (en) * | 2005-11-03 | 2008-03-05 | 复旦大学 | Method of growing metal organic compound on solid surface |
CN103184445A (en) * | 2011-12-28 | 2013-07-03 | 上海航天精密机械研究所 | Chemical oxidation solution composition for aluminium-alloy surface and chemical oxidation process |
CN103266315B (en) * | 2013-05-31 | 2015-05-13 | 海安县申菱电器制造有限公司 | Preparation of aluminum alloy cobalt salt chemical conversion coating treating fluid |
CN103266314B (en) * | 2013-05-31 | 2015-05-13 | 海安县申菱电器制造有限公司 | Method for treating aluminum alloy cobalt salt chemical conversion coating |
CN104846309A (en) * | 2015-05-09 | 2015-08-19 | 安徽鼎恒再制造产业技术研究院有限公司 | High-strength Co3O4-SiC coating materials and preparation method thereof |
CN106868495B (en) * | 2017-01-23 | 2019-06-11 | 江苏理工学院 | A kind of recycling and reusing method of cobalt salt chemical oxidation waste liquid |
CN112533756A (en) * | 2018-06-28 | 2021-03-19 | 尼蓝宝股份有限公司 | Simultaneous surface modification and method for producing the same |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4381203A (en) * | 1981-11-27 | 1983-04-26 | Amchem Products, Inc. | Coating solutions for zinc surfaces |
US5298092A (en) * | 1990-05-17 | 1994-03-29 | The Boeing Company | Non-chromated oxide coating for aluminum substrates |
DE69126507T2 (en) * | 1990-11-30 | 1997-09-25 | Boeing Co | Chromate-free cobalt conversion coating |
DK0523288T3 (en) * | 1991-07-19 | 1999-08-02 | Boeing Co | Non-chromated oxide coatings for aluminum substrates |
-
1993
- 1993-01-18 CN CNB931017378A patent/CN1138873C/en not_active Expired - Fee Related
- 1993-06-22 MX MX9303745A patent/MX9303745A/en unknown
- 1993-06-23 EP EP93914728A patent/EP0646187B1/en not_active Expired - Lifetime
- 1993-06-23 CA CA002138790A patent/CA2138790C/en not_active Expired - Fee Related
- 1993-06-23 DK DK93914728T patent/DK0646187T3/en active
- 1993-06-23 NZ NZ253699A patent/NZ253699A/en not_active IP Right Cessation
- 1993-06-23 JP JP50204994A patent/JP3345010B2/en not_active Expired - Lifetime
- 1993-06-23 BR BR9306602A patent/BR9306602A/en not_active IP Right Cessation
- 1993-06-23 AT AT93914728T patent/ATE198631T1/en not_active IP Right Cessation
- 1993-06-23 SG SG1996004772A patent/SG43169A1/en unknown
- 1993-06-23 DE DE69329853T patent/DE69329853T2/en not_active Expired - Fee Related
- 1993-06-23 RU RU94046218A patent/RU2135637C1/en not_active IP Right Cessation
- 1993-06-23 AU AU45008/93A patent/AU687740B2/en not_active Expired
- 1993-06-23 WO PCT/EP1993/001630 patent/WO1994000619A1/en active IP Right Grant
- 1993-06-23 ES ES93914728T patent/ES2152950T3/en not_active Expired - Lifetime
- 1993-06-24 ZA ZA934544A patent/ZA934544B/en unknown
- 1993-06-25 CN CNB931075831A patent/CN1195893C/en not_active Expired - Fee Related
-
1994
- 1994-12-23 NO NO19945026A patent/NO315522B1/en unknown
-
2001
- 2001-03-09 GR GR20010400395T patent/GR3035554T3/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1080963A (en) | 1994-01-19 |
ZA934544B (en) | 1994-03-18 |
AU4500893A (en) | 1994-01-24 |
DE69329853T2 (en) | 2001-04-26 |
JPH07508311A (en) | 1995-09-14 |
SG43169A1 (en) | 1997-10-17 |
JP3345010B2 (en) | 2002-11-18 |
BR9306602A (en) | 1998-12-08 |
AU687740B2 (en) | 1998-03-05 |
NO945026L (en) | 1995-02-24 |
CA2138790C (en) | 2004-10-19 |
CN1090338A (en) | 1994-08-03 |
CN1138873C (en) | 2004-02-18 |
RU2135637C1 (en) | 1999-08-27 |
CN1195893C (en) | 2005-04-06 |
NZ253699A (en) | 1997-05-26 |
EP0646187A1 (en) | 1995-04-05 |
NO945026D0 (en) | 1994-12-23 |
ES2152950T3 (en) | 2001-02-16 |
WO1994000619A1 (en) | 1994-01-06 |
EP0646187B1 (en) | 2001-01-10 |
DK0646187T3 (en) | 2001-04-30 |
RU94046218A (en) | 1996-10-20 |
CA2138790A1 (en) | 1994-01-06 |
GR3035554T3 (en) | 2001-06-29 |
MX9303745A (en) | 1994-02-28 |
NO315522B1 (en) | 2003-09-15 |
DE69329853D1 (en) | 2001-02-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
UEP | Publication of translation of european patent specification | ||
REN | Ceased due to non-payment of the annual fee |