ATE166074T1 - TWO-DONE CATALYST SYSTEM FOR OLEFIN POLYMERIZATION - Google Patents
TWO-DONE CATALYST SYSTEM FOR OLEFIN POLYMERIZATIONInfo
- Publication number
- ATE166074T1 ATE166074T1 AT95910185T AT95910185T ATE166074T1 AT E166074 T1 ATE166074 T1 AT E166074T1 AT 95910185 T AT95910185 T AT 95910185T AT 95910185 T AT95910185 T AT 95910185T AT E166074 T1 ATE166074 T1 AT E166074T1
- Authority
- AT
- Austria
- Prior art keywords
- catalyst system
- olefin polymerization
- done
- done catalyst
- polypropylene
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
The present invention provides a catalyst system that exhibits unexpected control of desired properties in polyolefin products. The catalyst system includes a titanium-supported catalyst in combination with a mixture of tetraethoxysilane (TEOS) and dicyclopentyldimethoxy-silane (DCPMS). This catalyst system has been found to be effective in making polypropylene and polypropylene copolymers having relatively high melt flow rates and moderately broad molecular weight distribution.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US19221794A | 1994-02-04 | 1994-02-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE166074T1 true ATE166074T1 (en) | 1998-05-15 |
Family
ID=22708732
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT95910185T ATE166074T1 (en) | 1994-02-04 | 1995-02-06 | TWO-DONE CATALYST SYSTEM FOR OLEFIN POLYMERIZATION |
Country Status (11)
Country | Link |
---|---|
US (1) | US6111039A (en) |
EP (1) | EP0743960B1 (en) |
JP (1) | JP3095177B2 (en) |
CN (1) | CN1085219C (en) |
AT (1) | ATE166074T1 (en) |
CA (1) | CA2182717A1 (en) |
DE (1) | DE69502480T2 (en) |
ES (1) | ES2119401T3 (en) |
FI (1) | FI963081A (en) |
NO (1) | NO963236L (en) |
WO (1) | WO1995021203A1 (en) |
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0743960B1 (en) * | 1994-02-04 | 1998-05-13 | Exxon Chemical Patents Inc. | Dual donor catalyst system for the polymerization of olefins |
US6686433B1 (en) | 1994-02-04 | 2004-02-03 | Exxonmobil Chemical Patents Inc. | Dual donor catalyst system for the polymerization of olefins |
DE69506821T2 (en) * | 1994-04-11 | 1999-06-10 | Mitsui Chemicals, Inc., Tokio/Tokyo | METHOD FOR PRODUCING A PROPYLENE-POLYMER COMPOSITION AND PROPYLENE-POLYMER COMPOSITION |
JP3595864B2 (en) * | 1995-06-07 | 2004-12-02 | 住友化学工業株式会社 | Catalyst for α-olefin polymerization and method for producing α-olefin polymer |
FI104080B (en) * | 1996-05-15 | 1999-11-15 | Borealis As | Stereospecific catalyst system for olefin polymerization and multiphase polymerization processes employing this system |
US6057407A (en) * | 1997-01-08 | 2000-05-02 | Bp Amoco Corporation | High melt flow propylene polymer produced by gas-phase polymerization |
WO1999020663A2 (en) * | 1997-10-17 | 1999-04-29 | Exxon Chemical Patents Inc. | High impact, flexural moduli polymeric materials formed using sequential donors |
WO1999058585A1 (en) * | 1998-05-14 | 1999-11-18 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
US6087459A (en) * | 1998-05-14 | 2000-07-11 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
CN1137156C (en) * | 1999-12-06 | 2004-02-04 | 中国石油化工集团公司 | Catalyst for olefine polymerization and its formula and application |
US6399707B1 (en) | 2000-09-29 | 2002-06-04 | Exxonmobil Chemical Patents Inc. | Impact copolymer and plastomer blend |
US6566294B2 (en) | 2000-12-21 | 2003-05-20 | Exxonmobil Chemical Patents Inc. | Multi-donor catalyst system for the polymerization of olefins |
KR100421553B1 (en) * | 2000-12-27 | 2004-03-09 | 삼성아토피나주식회사 | A polymerization method of alpha-olefins |
ATE336522T1 (en) * | 2002-01-03 | 2006-09-15 | Innovene Usa Llc | GAS PHASE OLEFIN POLYMERIZATION PROCESS USING A DUAL DONOR ZIEGLER-NATTA CATALYST |
US7141635B2 (en) | 2002-06-14 | 2006-11-28 | Union Carbide Chemicals And Plastics Tech | Catalyst composition and polymerization process using mixtures of selectivity control agents |
US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
US7652094B2 (en) | 2002-08-12 | 2010-01-26 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
KR101008786B1 (en) * | 2002-08-12 | 2011-01-14 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Plasticized polyolefin compositions |
US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
US7622523B2 (en) * | 2002-08-12 | 2009-11-24 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
US7652092B2 (en) * | 2002-08-12 | 2010-01-26 | Exxonmobil Chemical Patents Inc. | Articles from plasticized thermoplastic polyolefin compositions |
WO2005005489A1 (en) | 2003-06-24 | 2005-01-20 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition and polymerization process using mixture of silane electron donors |
US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
WO2005035596A1 (en) | 2003-09-23 | 2005-04-21 | Dow Global Technologies Inc. | Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process |
WO2005035595A1 (en) | 2003-09-23 | 2005-04-21 | Dow Global Technologies Inc. | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
JP2007505983A (en) * | 2003-09-23 | 2007-03-15 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | Catalyst composition having mixed selectivity control agent and propylene polymerization method |
ATE547438T1 (en) | 2003-09-23 | 2012-03-15 | Union Carbide Chem Plastic | SELF-EXTINGUISHING CATALYST COMPOSITION WITH MONOCARBOXYLIC ACID AS INTERNAL DONATOR AND PROPYLENE POLYMERIZATION PROCESS |
WO2005030815A1 (en) | 2003-09-23 | 2005-04-07 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
EP1544218A1 (en) * | 2003-12-19 | 2005-06-22 | Borealis Technology Oy | Process for producing olefin polymers |
US20050234172A1 (en) * | 2004-04-19 | 2005-10-20 | Fina Technology, Inc. | Random copolymer-impact copolymer blend |
US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
US9145495B2 (en) * | 2005-07-01 | 2015-09-29 | Basell Poliolefine Italia S.R.L. | Propylene polymers having broad molecular weight distribution |
JP5438966B2 (en) | 2005-07-15 | 2014-03-12 | エクソンモービル・ケミカル・パテンツ・インク | Elastomer composition |
US7977435B2 (en) * | 2006-07-12 | 2011-07-12 | Lin Chon-Yie | Propylene polymer compositions and processes for making the same |
KR101040388B1 (en) | 2007-01-30 | 2011-06-09 | 주식회사 엘지화학 | Catalyst system for olefin polymerization comprising trioxasilocane and method for olefin polymerization using the same |
EP2118147A1 (en) * | 2007-03-06 | 2009-11-18 | Ineos USA, LLC | Gas-phase propylene polymerization process using staged addition of aluminum alkyl |
CN101125898A (en) | 2007-07-19 | 2008-02-20 | 中国科学院长春应用化学研究所 | Catalyst used for synthesizing polypropylene with wide molecular weight distribution |
US10322394B2 (en) * | 2007-08-24 | 2019-06-18 | W. R. Grace & Co.-Conn. | Catalyst composition with mixed selectivity control agent and method |
US7851554B2 (en) | 2008-10-27 | 2010-12-14 | Exxonmobil Chemical Patents Inc. | Propylene impact copolymers with balanced impact strength and stiffness |
CN101735351B (en) * | 2008-11-07 | 2011-10-05 | 中国石油天然气股份有限公司 | Method for preparing high-fluidity and wide-distribution polypropylene and product |
CN102134291B (en) * | 2010-01-22 | 2013-12-04 | 中国石油化工股份有限公司 | Method for preparing polypropylene with high melt strength |
BR112012018282B1 (en) | 2010-01-22 | 2020-04-07 | Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp | propylene homopolymer with high resistance to fusion, its use and its preparation process |
JP5640402B2 (en) * | 2010-03-08 | 2014-12-17 | 住友化学株式会社 | α-Olefin polymerization catalyst |
JP2013531711A (en) * | 2010-06-10 | 2013-08-08 | イネオス ユーエスエイ リミテッド ライアビリティ カンパニー | Control of H2 distribution in a horizontal stirred bed reactor |
US9902822B2 (en) * | 2012-10-31 | 2018-02-27 | Exxonmobil Chemical Patents Inc. | Articles comprising broad molecular weight distribution polypropylene resins |
CN103540020B (en) * | 2013-10-29 | 2018-08-28 | 中国石油化工股份有限公司 | A kind of Production method of lithium ion battery barrier membrane homo-polypropylene special material |
US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
US9428598B2 (en) | 2014-02-07 | 2016-08-30 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
CN108137718B (en) | 2015-08-07 | 2020-07-14 | Sabic环球技术有限责任公司 | Process for the polymerization of olefins |
US10696756B2 (en) | 2015-08-07 | 2020-06-30 | Sabic Global Technologies B.V. | Process for the polymerization of olefins |
WO2017025327A1 (en) * | 2015-08-07 | 2017-02-16 | Sabic Global Technologies B.V. | Process for the polymerization of olefins |
WO2019202800A1 (en) * | 2018-04-20 | 2019-10-24 | 東邦チタニウム株式会社 | Olefin polymer and method for producing olefin polymer |
CN114426596A (en) * | 2020-10-15 | 2022-05-03 | 中国石油化工股份有限公司 | Catalyst for olefin polymerization, application thereof, olefin polymerization method and polymer |
CN114437263B (en) * | 2020-10-20 | 2023-12-08 | 中国石油化工股份有限公司 | Low-VOC low-odor polypropylene resin and preparation method and application thereof |
WO2024025742A1 (en) | 2022-07-25 | 2024-02-01 | Exxonmobil Chemical Patents Inc. | Purged polymer, process and apparatus for production thereof |
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US4340704A (en) * | 1974-02-15 | 1982-07-20 | Montedison S.P.A. | Thermoplastic rubbers and process for preparing same |
IT1078995B (en) * | 1977-05-24 | 1985-05-08 | Montedison Spa | CATALYSTS FOR THE POLYMERIZATION OF OLEFINE |
JPS5571712A (en) * | 1978-11-24 | 1980-05-30 | Mitsubishi Petrochem Co Ltd | Preparation of modified polypropylene |
IT1127222B (en) * | 1979-11-14 | 1986-05-21 | Montedison Spa | CATALYST COMPONENTS FOR OLEFINE POLYMERIZATION |
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IT1190682B (en) * | 1982-02-12 | 1988-02-24 | Montedison Spa | CATALYSTS FOR THE POLYMERIZATION OF OLEFINE |
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JP3089713B2 (en) * | 1991-07-04 | 2000-09-18 | 住友化学工業株式会社 | Method for producing ethylene-propylene block copolymer |
TW300235B (en) * | 1992-12-04 | 1997-03-11 | Mitsui Petroleum Chemicals Ind | |
US5338801A (en) * | 1993-10-20 | 1994-08-16 | Himont Incorporated | Compositions of propylene polymer materials and olefin polymer materials with reduced gloss |
EP0743960B1 (en) * | 1994-02-04 | 1998-05-13 | Exxon Chemical Patents Inc. | Dual donor catalyst system for the polymerization of olefins |
CN1066162C (en) * | 1994-04-06 | 2001-05-23 | 埃克森化学专利公司 | Ethylene' alpha'-olefin block copolymers and method for producing same |
US5455303A (en) * | 1994-06-20 | 1995-10-03 | Montell North America Inc. | Linear low density polyethylene based compositions with improved optics |
US5552482A (en) * | 1995-09-08 | 1996-09-03 | Montell North America Inc. | Thermoplastic elastomers with improved extrusion performance |
WO2010079104A1 (en) * | 2009-01-07 | 2010-07-15 | Chr. Hansen A/S | Additive to food or drinking water containing botanical antioxidants together with probiotic microorganisms |
-
1995
- 1995-02-06 EP EP95910185A patent/EP0743960B1/en not_active Expired - Lifetime
- 1995-02-06 AT AT95910185T patent/ATE166074T1/en not_active IP Right Cessation
- 1995-02-06 ES ES95910185T patent/ES2119401T3/en not_active Expired - Lifetime
- 1995-02-06 JP JP07520806A patent/JP3095177B2/en not_active Expired - Fee Related
- 1995-02-06 WO PCT/US1995/001499 patent/WO1995021203A1/en active IP Right Grant
- 1995-02-06 DE DE69502480T patent/DE69502480T2/en not_active Expired - Fee Related
- 1995-02-06 CN CN95191937A patent/CN1085219C/en not_active Expired - Lifetime
- 1995-02-06 CA CA002182717A patent/CA2182717A1/en not_active Abandoned
-
1996
- 1996-08-02 NO NO963236A patent/NO963236L/en unknown
- 1996-08-05 FI FI963081A patent/FI963081A/en unknown
- 1996-12-19 US US08/770,618 patent/US6111039A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CN1156999A (en) | 1997-08-13 |
ES2119401T3 (en) | 1998-10-01 |
NO963236L (en) | 1996-09-25 |
FI963081A (en) | 1996-10-03 |
JPH09508657A (en) | 1997-09-02 |
CA2182717A1 (en) | 1995-08-10 |
CN1085219C (en) | 2002-05-22 |
JP3095177B2 (en) | 2000-10-03 |
MX9603216A (en) | 1997-07-31 |
NO963236D0 (en) | 1996-08-02 |
EP0743960B1 (en) | 1998-05-13 |
WO1995021203A1 (en) | 1995-08-10 |
US6111039A (en) | 2000-08-29 |
FI963081A0 (en) | 1996-08-05 |
EP0743960A1 (en) | 1996-11-27 |
DE69502480T2 (en) | 1998-12-10 |
DE69502480D1 (en) | 1998-06-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
UEP | Publication of translation of european patent specification | ||
REN | Ceased due to non-payment of the annual fee |