KR970021237A - Flame retardant polyolefin resin composition for wire coating - Google Patents

Flame retardant polyolefin resin composition for wire coating Download PDF

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Publication number
KR970021237A
KR970021237A KR1019950034470A KR19950034470A KR970021237A KR 970021237 A KR970021237 A KR 970021237A KR 1019950034470 A KR1019950034470 A KR 1019950034470A KR 19950034470 A KR19950034470 A KR 19950034470A KR 970021237 A KR970021237 A KR 970021237A
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KR
South Korea
Prior art keywords
flame retardant
weight
resin composition
polyolefin resin
retardant polyolefin
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Application number
KR1019950034470A
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Korean (ko)
Inventor
김연철
허만생
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황선두
삼성종합화학 주식회사
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Application filed by 황선두, 삼성종합화학 주식회사 filed Critical 황선두
Priority to KR1019950034470A priority Critical patent/KR970021237A/en
Publication of KR970021237A publication Critical patent/KR970021237A/en

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Abstract

본 발명의 전선피복용 난연성 폴리올레핀 수지 조성물은 밀도(23℃)가 0.900∼0.925g/㎤이고 용융지수(190℃, 2.16kg)가 0.1∼4.0g/10분인 폴리에틸렌과 용융수지가 0.1∼4.0g/10분이고 공단량체 함량이 5∼30중량%인 에틸렌공중합체를 사용하며, 이들 기초 수지는 전체 수지 조성물에 대하여 40∼60중량%가 사용된다. 폴리에틸렌은 기초수지에 대하여 40∼70중량%로 사용되고, 에틸렌공중합체는 기초 수지에 대하여 30∼60중량%로 사용된다. 본 발명에서는 전체 수지 조성물에 대하여 약 0.1∼0.3중량%의 산화방지제, 금속수산화물인 무기난연제와 삼산화안티몬, 적인 등의 난연조제가 약 35.0∼55.0중량%, 0.5∼3.0중량%의 활제 및 2.0∼4.5중량%의 카본블랙이 사용된다.The flame retardant polyolefin resin composition for wire coating according to the present invention has a polyethylene having a density (23 ° C.) of 0.900 to 0.925 g / cm 3 and a melt index (190 ° C., 2.16 kg) of 0.1 to 4.0 g / 10 minutes and a melt resin of 0.1 to 4.0 g. Ethylene copolymers having a / 10 min and comonomer content of 5 to 30 wt% are used, and these base resins are used at 40 to 60 wt% based on the total resin composition. Polyethylene is used at 40 to 70% by weight based on the base resin, and ethylene copolymer is used at 30 to 60% by weight based on the base resin. In the present invention, about 0.1 to 0.3% by weight of the antioxidant, flame retardant aids such as metal hydroxide inorganic flame retardant and antimony trioxide, red, etc. are about 35.0 to 55.0% by weight, 0.5 to 3.0% by weight of lubricant and 2.0 to 4.5% by weight of carbon black is used.

Description

전선피복용 난연성 폴리올레핀 수지조성물Flame retardant polyolefin resin composition for wire coating

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (5)

밀도(23℃)가 0.900∼0.925g/㎤이고 용융지수(190℃, 2.16kg)가 0.1∼4.0g/분인 선형 저밀도 폴리에틸렌과 용융수지가 0.1∼4.Og/분이고 공단량체 함량이 5∼30중량%인 에틸렌 공중합체로 이루어지는 기초수지 40∼60중량%; 금속 수산화물인 무기 난연제 35∼55중량%; 산화방지제로서 2,2′-옥사미도 비스-에틸-3-(3,5-디-tert-부틸-4-히드록시페닐)-프로피오네이트 0.1∼0.3중량%; 스테아린산 아연 및 스테아린산 칼슘으로 이루어지는 활제 0.5∼3.0중량%; 및 카본 블랙 2.0∼4.5중량%; 로 이루어지는 것을 특징으로 하는 전선피복용 난연성 폴리올레핀 수지 조성물.Linear low density polyethylene with a density (23 ° C) of 0.900 to 0.925 g / cm 3 and melt index (190 ° C, 2.16 kg) of 0.1 to 4.0 g / min, and a melt of 0.1 to 4.0 g / min and a comonomer content of 5 to 30 40 to 60% by weight of a base resin consisting of an ethylene copolymer which is% by weight; 35 to 55% by weight of an inorganic flame retardant which is a metal hydroxide; 0.1 to 0.3% by weight of 2,2'-oxamido bis-ethyl-3- (3,5-di-tert-butyl-4-hydroxyphenyl) -propionate as an antioxidant; 0.5 to 3.0% by weight of a lubricant consisting of zinc stearate and calcium stearate; And carbon black 2.0 to 4.5 wt%; Flame retardant polyolefin resin composition for electric wire coating comprising a. 제1항에 있어서, 상기 기초수지는 40∼70중량%의 선형저밀도 폴리에틸렌과 60∼30중량%의 에틸렌공중합체로 이루어지는 것을 특징으로 하는 전선피복용 난연성 폴리레핀 수지 조성물.The flame retardant polyolefin resin composition for wire coating according to claim 1, wherein the base resin is composed of 40 to 70% by weight of linear low density polyethylene and 60 to 30% by weight of ethylene copolymer. 제1항에 있어서, 상기 무기 난연제는 수산화 마그네슘, 수산화 알루미늄 및 수산화칼슘으로 이루어지는 군으로부터 선택되는 것을 특징으로 하는 전선피복용 난연성 폴리올레핀 수지 조성물.The flame retardant polyolefin resin composition according to claim 1, wherein the inorganic flame retardant is selected from the group consisting of magnesium hydroxide, aluminum hydroxide and calcium hydroxide. 제1항에 있어서, 상기 카본 블랙은 입자 크기가 20mm이하이고, pH가 3.0∼8.0의 범위이며, 표면적이 80∼l5O㎡/g이고, DBP 흡수성이 100∼200cc/100g인 것을 특징으로 하는 전선피복용 난연성 폴리올레핀 수지 조성물.The electric wire according to claim 1, wherein the carbon black has a particle size of 20 mm or less, a pH of 3.0 to 8.0, a surface area of 80 to 50 m 2 / g, and a DBP absorbency of 100 to 200 cc / 100 g. Flame retardant polyolefin resin composition for coating. 제3항에 있어서, 상기 무기 난연제는 삼산화안티몬 또는 적인을 난연조제로서 더 포함하는 것을 특징으로 하는 전선피복용 난연성 폴리올레핀 수지 조성물.The flame retardant polyolefin resin composition according to claim 3, wherein the inorganic flame retardant further comprises antimony trioxide or red phosphorus as a flame retardant aid. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950034470A 1995-10-09 1995-10-09 Flame retardant polyolefin resin composition for wire coating KR970021237A (en)

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KR1019950034470A KR970021237A (en) 1995-10-09 1995-10-09 Flame retardant polyolefin resin composition for wire coating

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Application Number Priority Date Filing Date Title
KR1019950034470A KR970021237A (en) 1995-10-09 1995-10-09 Flame retardant polyolefin resin composition for wire coating

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100544306B1 (en) * 2003-03-28 2006-01-23 엘에스전선 주식회사 flame retardant resin composition for cable sheath
KR100666257B1 (en) * 2005-01-28 2007-01-09 엘에스전선 주식회사 Composition and for production flame retardant insulating material of halogen free type which has superior heat resistance
WO2014123327A1 (en) * 2013-02-06 2014-08-14 Sk Innovation Co.,Ltd. Non-crosslinked polyethylene composition for power cable

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61283638A (en) * 1985-06-11 1986-12-13 Hitachi Cable Ltd Flame-retardant electrical insulating composition
JPS62201953A (en) * 1986-02-28 1987-09-05 Tatsuta Electric Wire & Cable Co Ltd Heat-resistant polyolefin composition
JPS62215644A (en) * 1986-03-14 1987-09-22 Mitsubishi Cable Ind Ltd Flame-retardant resin composition
JPS62230810A (en) * 1986-03-31 1987-10-09 Tatsuta Electric Wire & Cable Co Ltd Electron radiation crosslinked polyethylene composition
JPH04359940A (en) * 1991-06-06 1992-12-14 Nippon Petrochem Co Ltd Flame-retardant resin composition excellent in moldability

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61283638A (en) * 1985-06-11 1986-12-13 Hitachi Cable Ltd Flame-retardant electrical insulating composition
JPS62201953A (en) * 1986-02-28 1987-09-05 Tatsuta Electric Wire & Cable Co Ltd Heat-resistant polyolefin composition
JPS62215644A (en) * 1986-03-14 1987-09-22 Mitsubishi Cable Ind Ltd Flame-retardant resin composition
JPS62230810A (en) * 1986-03-31 1987-10-09 Tatsuta Electric Wire & Cable Co Ltd Electron radiation crosslinked polyethylene composition
JPH04359940A (en) * 1991-06-06 1992-12-14 Nippon Petrochem Co Ltd Flame-retardant resin composition excellent in moldability

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100544306B1 (en) * 2003-03-28 2006-01-23 엘에스전선 주식회사 flame retardant resin composition for cable sheath
KR100666257B1 (en) * 2005-01-28 2007-01-09 엘에스전선 주식회사 Composition and for production flame retardant insulating material of halogen free type which has superior heat resistance
WO2014123327A1 (en) * 2013-02-06 2014-08-14 Sk Innovation Co.,Ltd. Non-crosslinked polyethylene composition for power cable

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