ATE141923T1 - Verfahren zur abtrennung von metallorganischen verbindungen und/oder metallcarbonylen aus ihren lösungen in organischen medien - Google Patents

Verfahren zur abtrennung von metallorganischen verbindungen und/oder metallcarbonylen aus ihren lösungen in organischen medien

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Publication number
ATE141923T1
ATE141923T1 AT89122627T AT89122627T ATE141923T1 AT E141923 T1 ATE141923 T1 AT E141923T1 AT 89122627 T AT89122627 T AT 89122627T AT 89122627 T AT89122627 T AT 89122627T AT E141923 T1 ATE141923 T1 AT E141923T1
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Austria
Prior art keywords
organic
separation
solutions
metal
carbonyls
Prior art date
Application number
AT89122627T
Other languages
German (de)
English (en)
Inventor
Helmut Dr Dipl-Chem Bahrmann
Michael Dr Dipl-Chem Haubs
Willi Dr Dipl-Chem Kreuder
Thomas Dipl-Ing Mueller
Original Assignee
Hoechst Ag
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Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
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Publication of ATE141923T1 publication Critical patent/ATE141923T1/de

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    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
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    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
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    • B01D61/24—Dialysis ; Membrane extraction
    • B01D61/243—Dialysis
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
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AT89122627T 1988-12-20 1989-12-08 Verfahren zur abtrennung von metallorganischen verbindungen und/oder metallcarbonylen aus ihren lösungen in organischen medien ATE141923T1 (de)

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Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5288818A (en) * 1991-08-20 1994-02-22 Exxon Chemical Patents Inc. Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5215667A (en) * 1991-08-20 1993-06-01 Exxon Chemical Patents Inc. Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
GB9119955D0 (en) * 1991-09-18 1991-10-30 Imperial College Treatment of aqueous supplies containing organic material
DE59206996D1 (de) * 1991-10-26 1996-10-02 Hoechst Ag Hydrophile, asymmetrische, chemikalienbeständige Polyaramidmembran
IT1256360B (it) * 1992-09-01 1995-12-01 Enichem Spa Processo per la separazione di catalizzatori in soluzioni organiche per mezzo di membrane semipermeabili
US5395979A (en) * 1993-02-25 1995-03-07 Exxon Chemical Patents Inc. Method for separating catalyst from a hydroformylation reaction product using alkylated ligands
US5298669A (en) * 1993-03-23 1994-03-29 Exxon Chemical Patent Inc. Perstraction sweep stream for a membrane reactor
KR970703805A (ko) * 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
DE19619527A1 (de) * 1996-05-15 1997-11-20 Hoechst Ag Katalysatorsysteme auf der Basis von Rhodium-Komplexverbindungen mit Diphosphin-Liganden und ihre Verwendung bei der Herstellung von Aldehyden
US5618436A (en) * 1996-02-16 1997-04-08 Condea Vista Company Process for clarifying metal alkyls
DE19609337C2 (de) * 1996-03-11 1998-11-19 Hoechst Ag Verfahren zur Herstellung von Aldehyden mittels eines Rhodium und substituierte Diphenyldiphosphane enthaltenden Katalysatorsystems
EP0810029B1 (de) * 1996-05-15 2001-11-14 Celanese Chemicals Europe GmbH Verfahren zur Herstellung von Aldehyden
EP0823282B1 (de) * 1996-05-15 2001-11-14 Celanese Chemicals Europe GmbH Verfahren zur Herstellung von Aldehyden
DE19619528A1 (de) * 1996-05-15 1997-11-20 Hoechst Ag Substituierte Diphosphine und ein Verfahren zu ihrer Herstellung
DE60002526T3 (de) 1999-07-02 2007-08-09 Mitsubishi Gas Chemical Co., Inc. Herstellung von Tricyclodecandicarbaldehyd, Pentacyclopentadecandicarbaldehyd und der entsprechenden Dimethanole
MXPA05002283A (es) 2002-08-31 2005-06-08 Oxeno Olefinchemie Gmbh Procedimiento para la hidroformilacion de compuestos olefinicamente insaturados, en particular olefinas, en presencia de esteres de acido carbonico ciclicos.
DE102006003618A1 (de) * 2006-01-26 2007-08-02 Oxeno Olefinchemie Gmbh Verfahren zur Abtrennung von Metall-Komplexkatalysatoren aus Telomerisationsgemischen
GB2437519B (en) * 2006-04-28 2010-04-21 Imp Innovations Ltd Method for separation
GB201012083D0 (en) 2010-07-19 2010-09-01 Imp Innovations Ltd Thin film composite membranes for separation
GB201012080D0 (en) 2010-07-19 2010-09-01 Imp Innovations Ltd Asymmetric membranes for use in nanofiltration
GB201117950D0 (en) 2011-10-18 2011-11-30 Imp Innovations Ltd Membranes for separation
DE102012223572A1 (de) * 2012-12-18 2014-06-18 Evonik Industries Ag Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren
DE102013215004A1 (de) * 2013-07-31 2015-02-05 Evonik Industries Ag Membrankaskade mit sinkender Trenntemperatur
TWI669317B (zh) 2014-09-22 2019-08-21 德商贏創德固賽有限責任公司 反應性單體的改良製造方法
WO2024204207A1 (ja) * 2023-03-28 2024-10-03 旭化成株式会社 原料液流濃縮システム及び原料液流濃縮方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1266180A (enExample) * 1969-12-19 1972-03-08
US3853754A (en) * 1972-07-20 1974-12-10 Du Pont Membrane separation of homogeneous catalysts from nitrile solutions
US3966595A (en) * 1972-07-20 1976-06-29 E. I. Du Pont De Nemours And Company Method of making group VIII metal complex compounds
US3957504A (en) * 1974-11-11 1976-05-18 Allied Chemical Corporation Membrane hydro-metallurgical extraction process
US4544484A (en) * 1983-06-24 1985-10-01 E. I. Du Pont De Nemours And Company Reverse osmosis membrane quenching
DE3802030A1 (de) * 1988-01-25 1989-07-27 Hoechst Ag Makroporoese, asymmetrische, hydrophile membran aus polyaramid

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JPH02231435A (ja) 1990-09-13
US5174899A (en) 1992-12-29
BR8906575A (pt) 1990-09-04
KR900009674A (ko) 1990-07-05
EP0374615A3 (de) 1991-05-02
AU621968B2 (en) 1992-03-26
EP0374615B1 (de) 1996-08-28
ES2092471T3 (es) 1996-12-01
KR930002965B1 (ko) 1993-04-16
EP0374615A2 (de) 1990-06-27
USRE35292E (en) 1996-07-09
HUT52709A (en) 1990-08-28
DE3842819A1 (de) 1990-06-21
JPH0480013B2 (enExample) 1992-12-17
CA2006021A1 (en) 1990-06-20
CA2006021C (en) 1996-06-11
HU202771B (en) 1991-04-29
HU896491D0 (en) 1990-03-28
DE58909716D1 (de) 1996-10-02
AU4685889A (en) 1990-06-28

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