ATE123748T1 - Verfahren zur oxidation aliphatischer kohlenwasserstoffe in gegenwart eines festen heterogenen katalysators und katalysator. - Google Patents

Verfahren zur oxidation aliphatischer kohlenwasserstoffe in gegenwart eines festen heterogenen katalysators und katalysator.

Info

Publication number
ATE123748T1
ATE123748T1 AT90201980T AT90201980T ATE123748T1 AT E123748 T1 ATE123748 T1 AT E123748T1 AT 90201980 T AT90201980 T AT 90201980T AT 90201980 T AT90201980 T AT 90201980T AT E123748 T1 ATE123748 T1 AT E123748T1
Authority
AT
Austria
Prior art keywords
catalyst
oxidation
aliphatic hydrocarbons
aliphatic hydrocarbon
oxide
Prior art date
Application number
AT90201980T
Other languages
English (en)
Inventor
Bijan Khazai
Edwin G Vrieland
Graig B Murchison
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ATE123748T1 publication Critical patent/ATE123748T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
    • C03C14/004—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of particles or flakes
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2214/00—Nature of the non-vitreous component
    • C03C2214/04—Particles; Flakes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT90201980T 1989-07-20 1990-07-19 Verfahren zur oxidation aliphatischer kohlenwasserstoffe in gegenwart eines festen heterogenen katalysators und katalysator. ATE123748T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/383,107 US4973791A (en) 1989-07-20 1989-07-20 Process of oxidizing aliphatic hydrocarbons employing an alkali-promoted molybdate catalyst
US07/505,751 US5146031A (en) 1989-07-20 1990-04-06 Process of oxidizing aliphatic hydrocarbons employing a molybdate catalyst composition

Publications (1)

Publication Number Publication Date
ATE123748T1 true ATE123748T1 (de) 1995-06-15

Family

ID=27010048

Family Applications (1)

Application Number Title Priority Date Filing Date
AT90201980T ATE123748T1 (de) 1989-07-20 1990-07-19 Verfahren zur oxidation aliphatischer kohlenwasserstoffe in gegenwart eines festen heterogenen katalysators und katalysator.

Country Status (11)

Country Link
US (2) US4973791A (de)
EP (1) EP0409355B1 (de)
JP (1) JPH0374335A (de)
KR (1) KR0178978B1 (de)
CN (2) CN1026099C (de)
AT (1) ATE123748T1 (de)
AU (1) AU633942B2 (de)
BR (1) BR9003542A (de)
CA (1) CA2021573C (de)
DE (1) DE69020055T2 (de)
MX (1) MX172821B (de)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4814545A (en) * 1988-09-19 1989-03-21 Eastman Kodak Company Process for removing impurities from an aromatic stream
US4973791A (en) * 1989-07-20 1990-11-27 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing an alkali-promoted molybdate catalyst
US5258347A (en) * 1989-07-20 1993-11-02 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing a molybdate catalyst composition
US5302773A (en) * 1989-07-20 1994-04-12 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing a molybdate catalyst encapsulated in a hard, glassy silica matrix
WO1991006366A1 (en) * 1989-10-31 1991-05-16 Dow Benelux N.V. Supported catalyst, method for the preparation thereof, and use thereof for the dehydrogenation of hydrocarbons
US5276257A (en) * 1992-07-09 1994-01-04 The Dow Chemical Company Process for converting butadiene to styrene or ethylbenzene or both using catalysts containing molybdenum
US5733836A (en) * 1996-03-22 1998-03-31 Phillips Petroleum Company Compositions comprising inorganic oxide and process for producing mercaptans
US6521808B1 (en) * 2000-02-17 2003-02-18 The Ohio State University Preparation and use of a catalyst for the oxidative dehydrogenation of lower alkanes
CN101081362B (zh) * 2006-05-31 2010-09-08 中国石油化工股份有限公司 一种含镁铝复合物的载体及其制备方法
KR101419995B1 (ko) * 2012-01-20 2014-07-15 삼성토탈 주식회사 노르말-부탄의 산화적 탈수소화 반응 촉매용 마그네시아-지르코니아 복합담체의 제조방법, 그에 의해 제조된 마그네시아-지르코니아 복합담체에 담지된 마그네슘 오르소바나데이트 촉매의 제조방법 및 상기 촉매를 이용한 노르말-부텐과 1,3-부타디엔의 제조방법
JP2014177408A (ja) * 2013-03-13 2014-09-25 Mitsubishi Chemicals Corp 共役ジエンの製造方法
KR102497673B1 (ko) * 2015-03-18 2023-02-09 디아이씨 가부시끼가이샤 스피넬 입자 및 그 제조 방법 그리고 상기 스피넬 입자를 포함하는 조성물 및 성형물
CN109415220B (zh) * 2016-06-23 2021-06-18 Dic株式会社 尖晶石颗粒及其制造方法、及包含前述尖晶石颗粒的组合物和成形物
JP6965562B2 (ja) * 2017-05-11 2021-11-10 Dic株式会社 スピネル粒子の製造方法、スピネル粒子、並びに前記スピネル粒子を含む樹脂組成物および成形物
CN113209965B (zh) * 2021-03-24 2022-08-09 西南化工研究设计院有限公司 一种轻烷烃脱氢制烯烃的催化剂及其制备方法和用途
CN115888681B (zh) * 2022-12-23 2024-07-30 南京克米斯璀新能源科技有限公司 用于顺式间戊二烯异构为反式间戊二烯的催化剂及其制备方法和应用

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2408146A (en) * 1941-09-19 1946-09-24 Jasco Inc Dehydrogenation of hydrocarbons
US2666086A (en) * 1949-11-14 1954-01-12 Phillips Petroleum Co Preparation of iron dehydrogenation catalysts
US3180903A (en) * 1958-08-21 1965-04-27 California Research Corp Process of dehydrogenation with catalyst rejuvenation
US3119111A (en) * 1961-02-13 1964-01-21 Shell Oil Co Oxidative dehydrogenation of alkanes
US3488402A (en) * 1967-05-18 1970-01-06 Sinclair Research Inc Dehydrogenation of hydrocarbons using dehydrogenation-oxidation catalyst system
US3642930A (en) * 1968-12-30 1972-02-15 Standard Oil Co Ohio Process for the manufacture of isoprene from isoamylenes and methyl butanols and catalyst therefor
SU471781A1 (ru) * 1969-12-15 1978-07-05 Предприятие П/Я В-8585 Способ получени диолефиновых углеводородов
US3678144A (en) * 1970-06-12 1972-07-18 Corning Glass Works Silicate bodies containing coprecipitated oxides
JPS5118918B1 (de) * 1970-10-02 1976-06-14
US3769238A (en) * 1970-10-09 1973-10-30 Tauster S Aromatization catalyst
US3867305A (en) * 1971-10-26 1975-02-18 Union Carbide Corp Amorphous hydrocarbon conversion catalysts and process for preparing same
JPS5327710B2 (de) * 1972-06-09 1978-08-10
US3862256A (en) * 1972-08-07 1975-01-21 Anatoly Lvovich Isailingold Method for preparing mono- and di-olefine hydrocarbons
US4172854A (en) * 1974-07-01 1979-10-30 Petro-Tex Chemical Corporation Dehydrogenation process and catalyst
IN148558B (de) * 1977-04-14 1981-04-04 Shell Int Research
CA1108114A (en) * 1977-04-14 1981-09-01 Gregor H. Riesser Dehydrogenation catalyst
FR2411169A1 (fr) * 1977-12-12 1979-07-06 Shell France Procede de deshydrogenation sans oxydation et composition catalytique pour la mise en oeuvre de ce procede
US4309361A (en) * 1977-12-20 1982-01-05 Standard Oil Company Ammoxidation of olefins with novel antimonate catalysts
US4170570A (en) * 1978-01-03 1979-10-09 Standard Oil Company (Ohio) Process for preparing oxidation catalysts
US4229604A (en) * 1979-02-05 1980-10-21 Tmenov Dzantemir N Process for producing unsaturated hydrocarbons
US4250346A (en) * 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
JPS56150023A (en) * 1980-04-22 1981-11-20 Nippon Zeon Co Ltd Preparation of conjugated diolefin
US4629719A (en) * 1980-11-17 1986-12-16 Phillips Petroleum Company Olefin disproportionation catalyst
DE3173077D1 (en) * 1981-01-15 1986-01-09 Ici Plc Catalyst, catalyst support and oxychlorination process
US4388223A (en) * 1981-04-06 1983-06-14 Euteco Impianti S.P.A. Catalyst for the conversion of unsaturated hydrocarbons into diolefins or unsaturated aldehydes and nitriles, and process for preparing the same
US4746753A (en) * 1981-04-29 1988-05-24 The Standard Oil Company Preparation of acrylonitrile from propylene, oxygen and ammonia in the presence of an alkali metal promoted bismuth, cerium, molybdenum, tungsten catalyst
JPS5811041A (ja) * 1981-07-13 1983-01-21 Nitto Chem Ind Co Ltd アンチモン含有金属酸化物触媒の製法
US4430517A (en) * 1981-12-02 1984-02-07 Uop Inc. Dehydrogenation process using a catalytic composition
US4532083A (en) * 1982-10-29 1985-07-30 The Standard Oil Company Multiply promoted Sn/Sb oxide catalysts
US4476245A (en) * 1982-11-29 1984-10-09 Atlantic Richfield Company Preparative process for alkaline earth metal, aluminum-containing spinels
US4471070A (en) * 1982-11-29 1984-09-11 Atlantic Richfield Company Preparative process for alkaline earth metal, aluminum-containing spinels
US4522937A (en) * 1982-11-29 1985-06-11 Atlantic Richfield Company Preparative process for alkaline earth metal, aluminum-containing spinels
US4506032A (en) * 1983-03-22 1985-03-19 Uop Inc. Dehydrogenation catalyst composition
US4547615A (en) * 1983-06-16 1985-10-15 Nippon Zeon Co. Ltd. Process for producing conjugated diolefins
US4559320A (en) * 1984-05-04 1985-12-17 Phillips Petroleum Company Catalysts for olefin conversions
US4596787A (en) * 1985-04-11 1986-06-24 Union Carbide Corporation Process for preparing a supported catalyst for the oxydehydrogenation of ethane to ethylene
DE3521766A1 (de) * 1985-06-19 1987-01-02 Basf Ag Wabenfoermiger katalysator, seiner herstellung und seine verwendung
US4790982A (en) * 1986-04-07 1988-12-13 Katalistiks International, Inc. Metal-containing spinel composition and process of using same
US4728635A (en) * 1986-04-07 1988-03-01 Katalistiks International Inc. Alkaline earth metal spinels and processes for making
US4797381A (en) * 1987-07-30 1989-01-10 The Standard Oil Company Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts
US4973791A (en) * 1989-07-20 1990-11-27 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing an alkali-promoted molybdate catalyst

Also Published As

Publication number Publication date
US4973791A (en) 1990-11-27
CN1052172C (zh) 2000-05-10
CN1026099C (zh) 1994-10-05
AU5971690A (en) 1991-01-24
CA2021573A1 (en) 1991-01-21
CN1048843A (zh) 1991-01-30
US5146031A (en) 1992-09-08
KR0178978B1 (ko) 1999-05-15
CA2021573C (en) 2000-11-07
EP0409355A1 (de) 1991-01-23
BR9003542A (pt) 1991-11-12
MX172821B (es) 1994-01-14
DE69020055D1 (de) 1995-07-20
DE69020055T2 (de) 1995-09-21
JPH0374335A (ja) 1991-03-28
AU633942B2 (en) 1993-02-11
EP0409355B1 (de) 1995-06-14
KR910002743A (ko) 1991-02-26
CN1093948A (zh) 1994-10-26

Similar Documents

Publication Publication Date Title
ATE123748T1 (de) Verfahren zur oxidation aliphatischer kohlenwasserstoffe in gegenwart eines festen heterogenen katalysators und katalysator.
BR9913437A (pt) Processo autotérmico para a produção de olefinas, catalisador para o processo, e processo para sintetizar ou regenerar o catalisador
CA1199041A (en) Olefin bond isomerisation process
ES2024072B3 (es) Procedimiento para preparar catalizadores que contienen un metal del grupo del platino, y sus usos
CA2468152A1 (en) Nox reduction composition for use in fcc processes
ATE247686T1 (de) Zusammensetzungen, gegenstände und verfahren zur entfernung von sauerstoff mit verbesserten physikalischen eigenschaften
MY125370A (en) Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems
DE3882886D1 (de) Verfahren und katalysator fuer die umwandlung von synthesegas zu kohlenwasserstoffen.
DE69322129D1 (de) Verfahren zur katalytischen Kohlenwasserstoffteiloxidation
DE3887469D1 (de) Verfahren zur Herstellung von Olefinen.
GB1430568A (en) Method of decomposing halohydrocarbons
ATE195922T1 (de) Verfahren zur katalytischen teiloxydation von kohlenwasserstoff
CA2014559A1 (en) Catalysts for oxidation of carbon monoxide
ATE109760T1 (de) Verfahren zur herstellung von kohlenwasserstoffen.
ATE261925T1 (de) Schwefel-enthaltender promoter für oxidative dehydrierungsverfahren von kohlenwasserstoffen
US4465788A (en) Olefin oligomerization with an activated catalyst
US4511750A (en) Olefin oligomerization with an activated catalyst
CA2014152A1 (en) Process for the preparation of an alkyl methacrylate
KR100197450B1 (ko) 올레핀-함유 하이드로포르밀화 공급원료를 탈황시키는 방법
US3439060A (en) Selective removal of cyclopentadiene from a mixture containing at least one other hydrocarbon
ATE39945T1 (de) Verfahren zur wasserstoffbehandlung von kohlenwasserstoffeinsaetzen.
GB2258826A (en) Process for the activation of a catalyst
GB749850A (en) Improvements in cobalt molybdate catalysts
DE69414494D1 (de) Verfahren zur Teiloxidation von Kohlenwasserstoffen
Szakács et al. On the mechanism of the selective oxidation of butane and 1-butene on vanadyl phosphates

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties