AT64719B - Process for separating neon from gas mixtures. - Google Patents
Process for separating neon from gas mixtures.Info
- Publication number
- AT64719B AT64719B AT64719DA AT64719B AT 64719 B AT64719 B AT 64719B AT 64719D A AT64719D A AT 64719DA AT 64719 B AT64719 B AT 64719B
- Authority
- AT
- Austria
- Prior art keywords
- neon
- electrodes
- gas mixtures
- separating
- gases
- Prior art date
Links
- 229910052754 neon Inorganic materials 0.000 title claims description 11
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 7
- 239000000203 mixture Substances 0.000 title claims description 7
- 239000007789 gas Substances 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000001307 helium Substances 0.000 description 3
- 229910052734 helium Inorganic materials 0.000 description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B23/00—Noble gases; Compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Discharge Lamp (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Description
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Verfahren zur Abscheidung von Neon aus Gasgemischen.
Man hat festgestellt, dass in einem Behälter, der mit Elektroden aus Kohle oder einem Metall, wie Eisen, Kupfer usw., versehen und mit verdünnten Gasen, wie Stickstoff,' Sauerstoff, Helium usw., gefüllt ist, diese Gase verhältnismässig schnell absorbiert werden, wenn man eine dauernde elektrische Entladung zwischen den Elektroden übergehen lässt.
Man hat indessen gefunden, dass, wenn der Inhalt des Behälters von Neon gebildet wird, die Absorption desselben bei gleichem Verdtinnl1ngsgradc ausnahmsweise beträchtlich
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Elektroden ist.
Die Ertindung betrifft ein Verfahren zum Abscheiden des Neon aus den Gasen, mit denen es gemischt ist und beruht auf den oben bemerkten Erscheinungen. Aus den vorstehenden Angaben folgt, und es ist auch tatsächlich festgestellt worden, dass bei Einführung eines Gemisches von Neon mit anderen Gasen unter einem Druck von mehreren Millimetern Quecksilbersäule in einen geschlossenen, mit Elektroden versehenen Behälter und beim Hindurchschicken eines dauernden Stromes elektrischer Entladungen durch die Elektroden, die fremden Gase bedeutend schneller als das Neon absorbiert werden, so dass dieses schliesslich in gereinigtem Zustande zurückbleibt oder doch wenigstens so rein,
dass in dem Spektrum des übrigbleibenden Gases höchstens etwas Wasserstoff oder Argon bemerkt werden kann, wenn derartige Gase in dem Gemisch vorhanden waren.
Um die Reinigung zu erleichtern, kann man vorteilhaft zuvor die Elektroden und die Wände des Behälters von okkludierten Gasen befreien. die die BeschaffL'ubeit des zu reinigenden Inhaltes unerwünschterweise verschlechtern würden. Zu diesem Zweck macht
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die Sache auch noch weiter treiben mit Hilfe einer zwei-oder dreimaligen Reinigung des Behälters vermittelst des Gasgemisches, das gereinigt werden soll. wobei nach jedem Reinigungsvorgang die Luftpumpe in Tätigkeit gesetzt w ; rd unter dem Durchgang von Strom, Zu einer weiteren Beschleunigung der Absorption der fremden Gase kann es gleich-
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Zustande in dem Behälter selbst, in dem es gewonnen ist, verwendet werden soll.
Das ist besonders der Fall, wenn es sich darum handelt, verdünnte Gasräume zu erzielen. die besonders leicht für elektrische Entladungen durchlässig sind ; es ist bekanntlich eines der bemerkenswertesten Kennzeichen des Neon. das man in interessanter Weise bei Detektoren für Hertzsche Wellen. bei Leuchtröhren und dgl. verwendet.
Die Wichtigkeit des Verfahrens tritt besonders hervor, wenn man bedenkt, dass mit seiner Hilfe die Alhsclleidung des Neon von dem Helium ermöglicht wird, obgleich diese beiden Gase in chemischer Hinsicht in gleicher Weise inert sind und auch das Verfahren der Absorption mittels Kohle bei der Temperatur von nüssiger Luft die Trennnung nicht gestatten, da ja das Helium noch weniger leicht von der Kohle absorbiert wird als das Neon.
**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.
<Desc / Clms Page number 1>
Process for separating neon from gas mixtures.
It has been found that in a container which is provided with electrodes made of carbon or a metal such as iron, copper etc. and filled with dilute gases such as nitrogen, oxygen, helium etc., these gases are absorbed relatively quickly when a permanent electrical discharge is allowed to pass between the electrodes.
It has been found, however, that if the contents of the container are made up of neon, the absorption thereof is exceptionally considerable for the same degree of dilution
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Electrodes is.
The invention relates to a method of separating the neon from the gases with which it is mixed and is based on the phenomena noted above. From the foregoing it follows, and it has actually been established, that when a mixture of neon with other gases is introduced under a pressure of several millimeters of mercury into a closed container provided with electrodes and when a continuous current of electrical discharges is passed through the electrodes , the foreign gases are absorbed significantly faster than the neon, so that this ultimately remains in a purified state or at least so pure,
that in the spectrum of the remaining gas at most a little hydrogen or argon can be noticed if such gases were present in the mixture.
In order to facilitate cleaning, the electrodes and the walls of the container can advantageously be freed from occluded gases beforehand. which would undesirably worsen the quality of the content to be cleaned. To this end makes
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drive the matter even further with the help of a two or three-time cleaning of the container by means of the gas mixture that is to be cleaned. the air pump being activated after each cleaning process; rd under the passage of electricity, it can lead to a further acceleration of the absorption of the foreign gases
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Condition in the container itself in which it is obtained is intended to be used.
This is particularly the case when it comes to achieving diluted gas spaces. which are particularly easily permeable to electrical discharges; it is known to be one of the most remarkable hallmarks of neon. which is interestingly the case with Hertzian wave detectors. used in fluorescent tubes and the like.
The importance of the process becomes particularly apparent when one considers that it enables the neon to be separated from helium, although these two gases are chemically inert in the same way, and so is the process of absorption by means of carbon at the temperature of Do not allow nutty air to separate, since helium is even less easily absorbed by carbon than neon.
** WARNING ** End of DESC field may overlap beginning of CLMS **.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR64719X | 1912-06-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT64719B true AT64719B (en) | 1914-05-11 |
Family
ID=8697749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT64719D AT64719B (en) | 1912-06-24 | 1913-06-10 | Process for separating neon from gas mixtures. |
Country Status (2)
| Country | Link |
|---|---|
| AT (1) | AT64719B (en) |
| GB (1) | GB191313561A (en) |
-
1913
- 1913-06-10 AT AT64719D patent/AT64719B/en active
- 1913-06-11 GB GB191313561D patent/GB191313561A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| GB191313561A (en) |
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