AT526296A8 - Metallorganische gerüstverbindungen - Google Patents

Metallorganische gerüstverbindungen Download PDF

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Publication number
AT526296A8
AT526296A8 ATA50439/2022A AT504392022A AT526296A8 AT 526296 A8 AT526296 A8 AT 526296A8 AT 504392022 A AT504392022 A AT 504392022A AT 526296 A8 AT526296 A8 AT 526296A8
Authority
AT
Austria
Prior art keywords
organicmetallic
framework compounds
hbtc
bpe
bpy
Prior art date
Application number
ATA50439/2022A
Other languages
English (en)
Other versions
AT526296B1 (de
AT526296A1 (de
Inventor
Eder Dominik
NAGHDI Shaghayegh
ZENDEHBAD Mohammad
Original Assignee
Univ Wien Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Wien Tech filed Critical Univ Wien Tech
Priority to ATA50439/2022A priority Critical patent/AT526296B1/de
Priority to EP23737852.6A priority patent/EP4539978A1/de
Priority to PCT/AT2023/060191 priority patent/WO2023245215A1/de
Priority to JP2024574815A priority patent/JP2025521328A/ja
Priority to US18/874,003 priority patent/US20250367636A1/en
Publication of AT526296A1 publication Critical patent/AT526296A1/de
Application granted granted Critical
Publication of AT526296B1 publication Critical patent/AT526296B1/de
Publication of AT526296A8 publication Critical patent/AT526296A8/de

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0233Compounds of Cu, Ag, Au
    • B01J20/0237Compounds of Cu
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • B01J20/28064Surface area, e.g. B.E.T specific surface area being in the range 500-1000 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28071Pore volume, e.g. total pore volume, mesopore volume, micropore volume being less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078Pore diameter
    • B01J20/28083Pore diameter being in the range 2-50 nm, i.e. mesopores
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3085Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3425Regenerating or reactivating of sorbents or filter aids comprising organic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/345Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3475Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/288Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/08Copper compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • C02F2101/163Nitrates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nanotechnology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)

Abstract

Metallorganische Gerüstverbindung, umfassend Cu2(Hbtc)2(bpe)2](bpe) und/oder Cu2(Hbtc)2(bpy)2(H2O)2]‘(bpy), wobei bpe für 1,2- Bis(4-pyridyl)ethan, Hbtc für Benzol- 1,3,5- tricarboxylat und bpy für 4,4'-Bipyridin steht; sowie die Verwendung dieser Verbindungen als Adsorptionsmittel.
ATA50439/2022A 2022-06-20 2022-06-20 Metallorganische gerüstverbindungen AT526296B1 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ATA50439/2022A AT526296B1 (de) 2022-06-20 2022-06-20 Metallorganische gerüstverbindungen
EP23737852.6A EP4539978A1 (de) 2022-06-20 2023-06-20 Metallorganische gerüstverbindungen für die entfernung von nitrat aus wässrigen lösungen
PCT/AT2023/060191 WO2023245215A1 (de) 2022-06-20 2023-06-20 Metallorganische gerüstverbindungen für die entfernung von nitrat aus wässrigen lösungen
JP2024574815A JP2025521328A (ja) 2022-06-20 2023-06-20 水溶液から硝酸塩を除去するための金属有機構造体
US18/874,003 US20250367636A1 (en) 2022-06-20 2023-06-20 Metal-organic frameworks for the removal of nitrate from aqueous solutions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ATA50439/2022A AT526296B1 (de) 2022-06-20 2022-06-20 Metallorganische gerüstverbindungen

Publications (3)

Publication Number Publication Date
AT526296A1 AT526296A1 (de) 2024-01-15
AT526296B1 AT526296B1 (de) 2024-11-15
AT526296A8 true AT526296A8 (de) 2024-11-15

Family

ID=87136774

Family Applications (1)

Application Number Title Priority Date Filing Date
ATA50439/2022A AT526296B1 (de) 2022-06-20 2022-06-20 Metallorganische gerüstverbindungen

Country Status (5)

Country Link
US (1) US20250367636A1 (de)
EP (1) EP4539978A1 (de)
JP (1) JP2025521328A (de)
AT (1) AT526296B1 (de)
WO (1) WO2023245215A1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119144004B (zh) * 2024-08-12 2025-10-28 兰州大学 一种m-hof材料及其制备方法和在氢氧根离子识别中的应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102250129B (zh) * 2010-05-19 2014-01-01 中国科学院大连化学物理研究所 一种多孔配位聚合物材料及其制备和应用
DE102014215568A1 (de) * 2014-08-06 2016-02-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Herstellung eines Adsorbens aus metallorganischen Gerüststrukturen (MOF)
AU2021101446A4 (en) * 2021-03-21 2021-05-13 Mohd Afzal A method for synthesizing carboxylate decorated metal organic frameworks using solvothermal conditions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102250129B (zh) * 2010-05-19 2014-01-01 中国科学院大连化学物理研究所 一种多孔配位聚合物材料及其制备和应用
DE102014215568A1 (de) * 2014-08-06 2016-02-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Herstellung eines Adsorbens aus metallorganischen Gerüststrukturen (MOF)
AU2021101446A4 (en) * 2021-03-21 2021-05-13 Mohd Afzal A method for synthesizing carboxylate decorated metal organic frameworks using solvothermal conditions

Also Published As

Publication number Publication date
AT526296B1 (de) 2024-11-15
US20250367636A1 (en) 2025-12-04
JP2025521328A (ja) 2025-07-08
AT526296A1 (de) 2024-01-15
WO2023245215A1 (de) 2023-12-28
EP4539978A1 (de) 2025-04-23

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