AT382366B - Process for the preparation of novel alpha-amino- hydroxyalkyl nitriles - Google Patents
Process for the preparation of novel alpha-amino- hydroxyalkyl nitrilesInfo
- Publication number
- AT382366B AT382366B AT76885A AT76885A AT382366B AT 382366 B AT382366 B AT 382366B AT 76885 A AT76885 A AT 76885A AT 76885 A AT76885 A AT 76885A AT 382366 B AT382366 B AT 382366B
- Authority
- AT
- Austria
- Prior art keywords
- preparation
- amino
- nitriles
- straight
- chain
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention relates to a process for the preparation of novel alpha-aminohydroxyalkyl nitriles of the general formula VI in which R1 is a straight-chain or branched alkyl radical having 1 to 4 carbon atoms and R2 is a straight-chain or branched alkyl radical having 1 to 6 carbon atoms, which carries a primary or secondary hydroxyl group, in which a ketone of the general formula VII in which R1 and R2 have the above meaning is reacted with ammonia and cyanide ions in the presence of an ammonium halide in a solvent, and the amino nitrile VI obtained in this way is removed and extracted from the resulting residue if desired with an organic solvent. The novel compounds, e.g. 2-amino-5-hydroxy-2- methylvaleronitrile of melting point 52degreeC, are valuable starting materials for the preparation (by oxidation with, for example, chlorine or hypochlorite) of azo initiators for free-radical polymerization. <IMAGE>
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT76885A AT382366B (en) | 1985-03-15 | 1985-03-15 | Process for the preparation of novel alpha-amino- hydroxyalkyl nitriles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT76885A AT382366B (en) | 1985-03-15 | 1985-03-15 | Process for the preparation of novel alpha-amino- hydroxyalkyl nitriles |
Publications (2)
Publication Number | Publication Date |
---|---|
ATA76885A ATA76885A (en) | 1986-07-15 |
AT382366B true AT382366B (en) | 1987-02-25 |
Family
ID=3499252
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT76885A AT382366B (en) | 1985-03-15 | 1985-03-15 | Process for the preparation of novel alpha-amino- hydroxyalkyl nitriles |
Country Status (1)
Country | Link |
---|---|
AT (1) | AT382366B (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB806931A (en) * | 1955-05-25 | 1959-01-07 | Du Pont | Improvements in or relating to the production of 5-(4-hydroxybutyl) hydantoin and intermediates therefor |
US4132729A (en) * | 1977-11-14 | 1979-01-02 | E. I. Du Pont De Nemours And Company | Purification of 2-amino-2,4-dimethyl-4-methoxy pentanenitrile |
-
1985
- 1985-03-15 AT AT76885A patent/AT382366B/en not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB806931A (en) * | 1955-05-25 | 1959-01-07 | Du Pont | Improvements in or relating to the production of 5-(4-hydroxybutyl) hydantoin and intermediates therefor |
US4132729A (en) * | 1977-11-14 | 1979-01-02 | E. I. Du Pont De Nemours And Company | Purification of 2-amino-2,4-dimethyl-4-methoxy pentanenitrile |
Also Published As
Publication number | Publication date |
---|---|
ATA76885A (en) | 1986-07-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1063264A3 (en) | Reaction product, process of producing same, electrophotographic photoconductor using same, electrophotographic apparatus having the photoconductor, and process cartridge for electrophotographic apparatus | |
IL62687A (en) | 3-bromo-4-fluorobenzoylcyanide and a method of preparation of acyl cyanides | |
DK165973B (en) | TETRACARBONIC ACID TETRACHLORIDES USED AS BASIC MATERIALS FOR THE PREPARATION OF SHADOWABLE SUBSTANCES IN XENTIC CONTRACTORS | |
FR2382440A1 (en) | PROCESS FOR OBTAINING METALLIC PHENATES, ESPECIALLY CALCIUM PHENATES | |
RU2005105947A (en) | SULFIDE ORE FLOTORAGENT | |
KR870004026A (en) | Process for preparing piperazino isothiazolone | |
DE69501487T2 (en) | Manufacture of thioamides | |
AT382366B (en) | Process for the preparation of novel alpha-amino- hydroxyalkyl nitriles | |
US2688020A (en) | Preparation of dihydrouracils | |
DK0452952T3 (en) | Process for the preparation of benzylamines | |
GB1426166A (en) | Fluorinated anilines | |
EP0083077B1 (en) | Fluorine-containing aminocarboxylic acid compounds and their preparation and use | |
EP0337600A3 (en) | Benzoylurea derivative, process for producing the same, insecticide containing the same, reaction intermediate of the same and process for producing the intermediate | |
US4356309A (en) | N-Alkylated 2-(2-pyridyl)imidazoles useful as metallurgical extractants | |
US2686203A (en) | Nu-halo-tall-alkyl cyanamides | |
GB1354939A (en) | Process for the manufacture of 1,1,2-triphenylalk-1-enes | |
EP0031645B1 (en) | Process for the production of azo compounds | |
DE3461462D1 (en) | Process for the preparation of meta-substituted anilines | |
de Kimpe et al. | Reactivity of α‐Halogenated Imidoyl Cyanides1 | |
GB2008950A (en) | Treatment of plant virus diseases | |
EP0347757A3 (en) | Catalytic preparation of cyanoalkyl lactams | |
US4287344A (en) | N,N-bis-(decahydroquinolyl-N-methyl)imidazolin-2-thiones | |
PL230885A1 (en) | ||
Nishio et al. | Reaction of β-Sulfinyl and β-Sulfenyl α, β-Unsaturated Ketones with Diimines; Preparation of 1, 2-Dihydro-Pyrimidines | |
GB1560363A (en) | Process for the preparation of 2,4,5-trichloropyrimidine |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ELJ | Ceased due to non-payment of the annual fee | ||
UEP | Publication of translation of european patent specification | ||
REN | Ceased due to non-payment of the annual fee |