AT274264B - Synthetic slag-forming mixture for raw block casting - Google Patents

Synthetic slag-forming mixture for raw block casting

Info

Publication number
AT274264B
AT274264B AT605867A AT605867A AT274264B AT 274264 B AT274264 B AT 274264B AT 605867 A AT605867 A AT 605867A AT 605867 A AT605867 A AT 605867A AT 274264 B AT274264 B AT 274264B
Authority
AT
Austria
Prior art keywords
sep
forming mixture
raw block
synthetic slag
slag
Prior art date
Application number
AT605867A
Other languages
German (de)
Original Assignee
Vitkovice Zelezarny
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vitkovice Zelezarny filed Critical Vitkovice Zelezarny
Priority to AT605867A priority Critical patent/AT274264B/en
Application granted granted Critical
Publication of AT274264B publication Critical patent/AT274264B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Description

  

   <Desc/Clms Page number 1> 
 



  Synthetisches schlackenbildendes Gemisch zum Rohblockabguss 
 EMI1.1 
 

 <Desc/Clms Page number 2> 

 Materialien mit hohem Isoliervermögen, wie z. B. Vermikulit, Perlit, Kieselgur u. a., enthält. Die Wirkung des Gemisches kann vorteilhaft durch Zusätze von alkalischen, die Aktivität der Gemischkomponenten bei der Entstehung einer Polykomponentenschmelze erhöhenden Schmelzmitteln reguliert werden. 



   Bei der Berührung des schlackenbildenden Gemisches mit Flussstahl bilden die einzelnen Gemischkomponenten auf dem Stahlbadspiegel eine Schmelze, deren Zusammensetzung in der ersten Phase der benutzten   Hochofen- oder andern Hüttenschlacke   entspricht. Der Schmelzpunkt und der physischchemische Charakter, insbesondere die Viskosität dieser Schlacke, sinkt fortschreitend herab, wie sich die Schmelze, in Übereinstimmung mit den betreffenden Zustandsdiagrammen, mit aus den anorganischen Isolierkomponenten entstehenden Silicium- und Aluminiumoxyden sättigt. Die Geschwindigkeit des angeführten Chemismus kann einigermassen durch Zusätze von Alkalien, z. B. alkalischen Carbonaten, günstig beeinflusst werden, da diese den   Gemischschmelzpunkt weiter   herabsetzen.

   Bei diesen Prozessen macht sich günstig geltend das Isoliervermögen der anorganischen Auflockerungsstoffe, die Wärmeverluste am Stahlbadspiegel verhindern. 



   Im Vergleich zu den bekannten Mischungen schliesst die erfindungsgemässe synthetische Schlacke die Gefahr der Stahlaufkohlung aus, was besonders bei der Erzeugung von schwer herzustellenden kohlenstoffarmen Stählen von Vorteil ist. Die Schlacke ist bei den verschiedensten Stahlsorten und insbesondere Rohblockformaten und-formen, einschliesslich der für die Entstehung von Oberflächenfehlern stark anfälligen Rundrohblöcke, verwendbar ; die Verringerung von Oberflächenfehlern hat dann ein gesteigertes Stahlausbringen zur Folge. Weiters wird die Lebensdauer des Kokillenparkes, im Vergleich zum Gebrauch von Kokillenanstrichen, beträchtlich verlängert. Und schliesslich wird die Arbeitshygiene verbessert. 



   Beispiele für erfindungsgemässe   Schlackenmischungen :   
 EMI2.1 
 
<tb> 
<tb> Beispiel <SEP> 1 <SEP> : <SEP> 
<tb> 80% <SEP> feingemahlene <SEP> Hochofenschlacke <SEP> 
<tb> 20% <SEP> Vermikulit.
<tb> 



  Beispiel <SEP> 2 <SEP> : <SEP> 
<tb> 75% <SEP> Hochofenschlacke <SEP> von < <SEP> 0, <SEP> 1 <SEP> mm <SEP> Korngrösse
<tb> 20% <SEP> gemahlener <SEP> Keramsit.
<tb> 



  5% <SEP> calcinierte <SEP> Soda
<tb> Beispiel <SEP> 3 <SEP> : <SEP> 
<tb> 60% <SEP> gemahlene <SEP> Hochofenschlacke
<tb> 35% <SEP> Perlit
<tb> 5% <SEP> calcinierte <SEP> Soda.
<tb> 




   <Desc / Clms Page number 1>
 



  Synthetic slag-forming mixture for raw block casting
 EMI1.1
 

 <Desc / Clms Page number 2>

 Materials with high insulating properties, such as B. vermiculite, perlite, kieselguhr u. a., contains. The effect of the mixture can advantageously be regulated by adding alkaline melting agents which increase the activity of the mixture components when a polycomponent melt is formed.



   When the slag-forming mixture comes into contact with mild steel, the individual mixture components form a melt on the steel bath level, the composition of which in the first phase corresponds to that of the blast furnace or other slag used. The melting point and the physico-chemical character, in particular the viscosity of this slag, gradually decrease as the melt, in accordance with the relevant state diagrams, is saturated with silicon and aluminum oxides formed from the inorganic insulating components. The speed of the listed chemistry can be increased to some extent by the addition of alkalis, e.g. B. alkaline carbonates, are favorably influenced, as these further lower the melting point of the mixture.

   In these processes, the insulating properties of the inorganic loosening substances, which prevent heat loss at the steel bath level, are beneficial.



   Compared to the known mixtures, the synthetic slag according to the invention eliminates the risk of steel carburization, which is particularly advantageous when producing low-carbon steels that are difficult to produce. The slag can be used with a wide variety of steel types and in particular raw block formats and shapes, including round raw blocks which are highly susceptible to the formation of surface defects; the reduction of surface defects then results in an increased steel output. Furthermore, the service life of the mold park is considerably extended compared to the use of mold paints. And finally, work hygiene is improved.



   Examples of slag mixtures according to the invention:
 EMI2.1
 
<tb>
<tb> Example <SEP> 1 <SEP>: <SEP>
<tb> 80% <SEP> finely ground <SEP> blast furnace slag <SEP>
<tb> 20% <SEP> vermiculite.
<tb>



  Example <SEP> 2 <SEP>: <SEP>
<tb> 75% <SEP> blast furnace slag <SEP> of <<SEP> 0, <SEP> 1 <SEP> mm <SEP> grain size
<tb> 20% <SEP> ground <SEP> ceramite.
<tb>



  5% <SEP> calcined <SEP> soda
<tb> Example <SEP> 3 <SEP>: <SEP>
<tb> 60% <SEP> ground <SEP> blast furnace slag
<tb> 35% <SEP> perlite
<tb> 5% <SEP> calcined <SEP> soda.
<tb>


 

Claims (1)

PATENTANSPRUCH : Synthetisches schlackenbildendes Gemisch zum Rohblock-Kokillenguss auf der Basis von Alumi- nium-Calcium-Silikaten, das gegebenenfalls Schmelzmittel, wie z. B. Soda, enthält, dadurch gekennzeichnet, dass das Gemisch 5 bis 60 grew.-% voluminöse, anorganische, kohlenstofffreie Materialien mit hohem Isoliervermögen, wie z. B. Vermikulit, Perlit, Kieselgur u. a., enthält. PATENT CLAIM: Synthetic slag-forming mixture for raw block chill casting based on aluminum-calcium silicates, which optionally contains flux, such as B. Soda, contains, characterized in that the mixture grew .-% voluminous, inorganic, carbon-free materials with high insulating properties, such as. B. vermiculite, perlite, kieselguhr u. a., contains.
AT605867A 1967-06-29 1967-06-29 Synthetic slag-forming mixture for raw block casting AT274264B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT605867A AT274264B (en) 1967-06-29 1967-06-29 Synthetic slag-forming mixture for raw block casting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT605867A AT274264B (en) 1967-06-29 1967-06-29 Synthetic slag-forming mixture for raw block casting

Publications (1)

Publication Number Publication Date
AT274264B true AT274264B (en) 1969-09-10

Family

ID=3582438

Family Applications (1)

Application Number Title Priority Date Filing Date
AT605867A AT274264B (en) 1967-06-29 1967-06-29 Synthetic slag-forming mixture for raw block casting

Country Status (1)

Country Link
AT (1) AT274264B (en)

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