AT224654B - Process for the preparation of low-water hydrates or salts free of water of crystallization - Google Patents

Process for the preparation of low-water hydrates or salts free of water of crystallization

Info

Publication number
AT224654B
AT224654B AT644360A AT644360A AT224654B AT 224654 B AT224654 B AT 224654B AT 644360 A AT644360 A AT 644360A AT 644360 A AT644360 A AT 644360A AT 224654 B AT224654 B AT 224654B
Authority
AT
Austria
Prior art keywords
water
crystallization
hydrate
poor
salts
Prior art date
Application number
AT644360A
Other languages
German (de)
Inventor
Walter Dr Spormann
Joachim Dr Heinke
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Application granted granted Critical
Publication of AT224654B publication Critical patent/AT224654B/en

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  • Seasonings (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Description

  

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  Verfahren zur Herstellung von wasserarmen Hydraten oder kristallwasserfreien Salzen 
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  Process for the preparation of low-water hydrates or salts free of water of crystallization
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Claims (1)

SalzePATENTANSPRÜCHE : 1. Verfahren zur Herstellung von wasserarmen Hydraten oder kristallwasserfreien Salzen aus wasser- reichen Hydraten durch Erwärmen in Stufen zwecks Abspaltung des Kristallwassers und Abtrennen des ausgeschiedenen wasserarmen Hydrats oder wasserfreien Salzes von der Mutterlauge, dadurch gekennzeichnet, dass man in der Anfangsstufe eine Temperatur mässig oberhalb des Umwandlungspunktes des wasserreichen Hydrats in das wasserarme Hydrat oder das kristallwasserfreie Salz und in der Endstufe eine wesentlich höhere Temperatur einhält, bei der das wasserarme Hydrat oder das kristallwasserfreie Salz eine möglichst kleine Löslichkeit aufweist und als kristallwasserhaltige Salze solche Salze ausser Natriumsulfitheptahydrat verwendet, Salts PATENT CLAIMS: 1. A process for the preparation of water-poor hydrates or salts free of water of crystallization from water-rich hydrates by heating in stages for the purpose of splitting off the water of crystallization and separating the precipitated water-poor hydrate or anhydrous salt from the mother liquor, characterized in that in the initial stage a temperature moderately above the Conversion point of the water-rich hydrate into the water-poor hydrate or the water-free salt and in the final stage maintains a much higher temperature at which the water-poor hydrate or the water-free salt has as low a solubility as possible and uses salts other than sodium sulfite heptahydrate as salts containing water of crystallization, die sich beim Erhitzen auf eine über einer Umwandlungstemperatur liegende Temperatur in ein wasserarmes Hydrat oder kristallwasserfreies Salz umwandeln und im Temperaturbereich oberhalb dieser Umwandlungstemperatur einen negativen Löslichkeitskoeffizienten besitzen. which, when heated to a temperature above a transformation temperature, convert into a water-poor hydrate or salt free of water of crystallization and have a negative solubility coefficient in the temperature range above this transformation temperature. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass man an die Anfangsstufe mindestens zwei Stufen anschliesst, in denen von Stufe zu Stufe ansteigende Temperaturen eingehalten werden. 2. The method according to claim 1, characterized in that the initial stage is followed by at least two stages in which temperatures increasing from stage to stage are maintained. 3. Verfahren nach den Ansprüchen 1 und 2, dadurch gekennzeichnet, dass man das kristallwasser- EMI2.1 3. Process according to claims 1 and 2, characterized in that the water of crystallization EMI2.1
AT644360A 1959-09-17 1960-08-23 Process for the preparation of low-water hydrates or salts free of water of crystallization AT224654B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE224654X 1959-09-17

Publications (1)

Publication Number Publication Date
AT224654B true AT224654B (en) 1962-12-10

Family

ID=5857066

Family Applications (1)

Application Number Title Priority Date Filing Date
AT644360A AT224654B (en) 1959-09-17 1960-08-23 Process for the preparation of low-water hydrates or salts free of water of crystallization

Country Status (1)

Country Link
AT (1) AT224654B (en)

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