AT214641B - Process for the polymerization of olefinic compounds in the presence of catalysts based on boron trialkyl - Google Patents
Process for the polymerization of olefinic compounds in the presence of catalysts based on boron trialkylInfo
- Publication number
- AT214641B AT214641B AT566559A AT566559A AT214641B AT 214641 B AT214641 B AT 214641B AT 566559 A AT566559 A AT 566559A AT 566559 A AT566559 A AT 566559A AT 214641 B AT214641 B AT 214641B
- Authority
- AT
- Austria
- Prior art keywords
- polymerization
- catalysts based
- olefinic compounds
- boron
- boron trialkyl
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 5
- 238000006116 polymerization reaction Methods 0.000 title claims description 4
- 239000003054 catalyst Substances 0.000 title description 4
- 150000001875 compounds Chemical class 0.000 title description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title description 2
- 229910052796 boron Inorganic materials 0.000 title description 2
- 239000012736 aqueous medium Substances 0.000 claims 1
- 239000002609 medium Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 description 4
- -1 ethylene, propylene Chemical group 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical group COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical group CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Description
<Desc/Clms Page number 1>
Verfahren zur Polymerisation von olefinischen Verbindungen in Gegenwart von Katalysatoren auf Basis von Bortrialkyl
EMI1.1
EMI1.2
EMI1.3
560624, Nr. 562444oder Gruppen. wie die Halogene, Ester-, Äther- und CN-Gruppen bedeuten, in Gegenwart eines Katalysators, bestehend aus organischen Derivaten des Bors der allgemeinen Formel BR, worin R ein Alkylradikal ist sowie in Gegenwart einer kleinen Menge von Salzen bestimmter Metalle polymerisiert und/oder copolymerisiert.
Als solche Metalle sind insbesondere zu erwähnen Kadmium, Silber, Nickel, Chrom, Kupfer und Kobalt. Man verwendet diese Metalle zweckmässig in Form ihrer Salze, insbesondere als Chloride. Die Menge der zuzusetzenden Aktivatoren kann zwischen 0, 3 und 3 Gew.-. bezogen auf die Menge des oder der zu polymerisierenden Monomeren, betragen.
Als Verbindungen, die in Gegenwart derartiger Katalysatorsysteme polymerisiert werden können, sind unter anderem zu erwähnen die Olefine, wie Äthylen, Propylen und Butylen, die Isoolefine, die Dienkohlenwasserstoffe, Styrol und seine im aromatischen Kern substituierten Derivate, Vinylchlorid, Vinylidenchlorid, Trichloräthylen, Perchloräthylen, Vinylfluorid, Vinylidenfluorid, Trifluoräthylen,
EMI1.4
Ester derAcrylsäure und derenHalogensubstitutionsprodukte, Ester der Methacrylsäure und deren Halogensubstitutionsprodukte, Allylhalogenide und-ester, Acrylnitril, Methacrylnitril, Vinylpyridin usw.
Die der angegebenen allgemeinen Formel entsprechenden Monomeren können ebenso auch untereinander nach dem erfindungsgemässen Verfahren copolymerisiert werden. Man erhält auf diese Weise je nach den Arbeitsbedingungen binäre oder ternäre Copolymeren.
<Desc/Clms Page number 2>
EMI2.1
EMI2.2
<Desc / Clms Page number 1>
Process for the polymerization of olefinic compounds in the presence of catalysts based on boron trialkyl
EMI1.1
EMI1.2
EMI1.3
560624, No. 562444 or groups. as the halogens, ester, ether and CN groups mean, in the presence of a catalyst consisting of organic derivatives of boron of the general formula BR, where R is an alkyl radical and polymerized and / or in the presence of a small amount of salts of certain metals copolymerized.
As such metals, cadmium, silver, nickel, chromium, copper and cobalt should be mentioned in particular. These metals are expediently used in the form of their salts, in particular as chlorides. The amount of activators to be added can be between 0.3 and 3 wt. based on the amount of the monomer or monomers to be polymerized.
Compounds that can be polymerized in the presence of such catalyst systems include the olefins, such as ethylene, propylene and butylene, the isoolefins, the diene hydrocarbons, styrene and its derivatives substituted in the aromatic nucleus, vinyl chloride, vinylidene chloride, trichlorethylene, perchlorethylene, Vinyl fluoride, vinylidene fluoride, trifluoroethylene,
EMI1.4
Esters of acrylic acid and its halogen substitution products, esters of methacrylic acid and its halogen substitution products, allyl halides and esters, acrylonitrile, methacrylonitrile, vinyl pyridine, etc.
The monomers corresponding to the general formula given can also be copolymerized with one another by the process according to the invention. In this way, depending on the working conditions, binary or ternary copolymers are obtained.
<Desc / Clms Page number 2>
EMI2.1
EMI2.2
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE214641X | 1958-08-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT214641B true AT214641B (en) | 1961-04-25 |
Family
ID=3865998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT566559A AT214641B (en) | 1958-08-02 | 1959-08-01 | Process for the polymerization of olefinic compounds in the presence of catalysts based on boron trialkyl |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT214641B (en) |
-
1959
- 1959-08-01 AT AT566559A patent/AT214641B/en active
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