AR119263A1 - HETEROCYCLIC DERIVATIVES WITH SULFUR-CONTAINING SUBSTITUENTS ACTIVE AS PESTICIDES - Google Patents

HETEROCYCLIC DERIVATIVES WITH SULFUR-CONTAINING SUBSTITUENTS ACTIVE AS PESTICIDES

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Publication number
AR119263A1
AR119263A1 ARP200100530A ARP200100530A AR119263A1 AR 119263 A1 AR119263 A1 AR 119263A1 AR P200100530 A ARP200100530 A AR P200100530A AR P200100530 A ARP200100530 A AR P200100530A AR 119263 A1 AR119263 A1 AR 119263A1
Authority
AR
Argentina
Prior art keywords
ring
alkyl
formula
ring system
group
Prior art date
Application number
ARP200100530A
Other languages
Spanish (es)
Inventor
Anke Buchholz
Daniel Emery
Indira Sen
Vikas Sikervar
Andr Stoller
Sebastian Rendler
Michel Muehlebach
Original Assignee
Syngenta Crop Protection Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Crop Protection Ag filed Critical Syngenta Crop Protection Ag
Publication of AR119263A1 publication Critical patent/AR119263A1/en

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Abstract

Compuestos de fórmula (1) donde los sustituyentes son tal como se definen en la reivindicación 1. Además, la presente se refiere a composiciones agroquímicas que comprenden compuestos de fórmula (1), a la preparación de estas composiciones y al uso de los compuestos o las composiciones en agricultura u horticultura para combatir, prevenir o controlar plagas de animales, incluyendo artrópodos y, en particular, insectos, moluscos, nematodos o representantes del orden Acarina. Reivindicación 1: Un compuesto de fórmula (1), donde R² es haloalquilo C₁₋₆, haloalquenilo C₂₋₆ o haloalquilsulfonilo C₁₋₄; R⁶ es alquilo C₁₋₆; Q es un radical seleccionado a partir del grupo que consiste en la fórmula Qa y Qb del grupo de fórmulas (2), en donde la flecha indica el punto de unión al anillo de pirimidinona; y en donde A representa CH o N; X es S, SO, SO₂ o SO(NH); R¹ es alquilo C₁₋₄ o cicloalquil C₃₋₆-alquilo C₁₋₄; Q¹ es hidrógeno, halógeno, haloalquilo C₁₋₆, cicloalquilo C₃₋₆, cicloalquilo C₃₋₆ monosustituido por ciano, cianoalquilo C₁₋₃, cianoalcoxi C₁₋₆, haloalcoxi C₁₋₆, -N(R⁴)₂, -N(R⁴)COR⁵, -N(R⁴)CON(R⁴)₂, (oxazolidin-2-ona)-3-ilo o 2-piridiloxi; o Q¹ es un sistema de anillos aromáticos de cinco a seis miembros unido mediante un átomo de carbono del anillo al anillo que contiene el sustituyente A, dicho sistema de anillo está no sustituido o está monosustituido o polisustituido por sustituyentes seleccionados a partir del grupo que consiste en halógeno, ciano, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxilo C₁₋₄, haloalcoxilo C₁₋₄ alquilsulfanilo C₁₋₄, alquilsulfinilo C₁₋₄ y alquilsulfonilo C₁₋₄ y dicho sistema de anillo puede contener 1, 2 ó 3 heteroátomos en el anillo seleccionados a partir del grupo que consiste en nitrógeno, oxígeno y azufre, donde dicho sistema de anillo puede no contener más de un átomo de oxígeno en el anillo y no más de un átomo de azufre en el anillo; o Q¹ es un sistema de anillos aromáticos de cinco miembros unido mediante un átomo de nitrógeno del anillo al anillo que contiene el sustituyente A, dicho sistema de anillo está no sustituido o está monosustituido o polisustituido por sustituyentes seleccionados a partir del grupo constituido por halógeno, ciano, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxilo C₁₋₄, haloalcoxilo C₁₋₄, alquilsulfanilo C₁₋₄, alquilsulfinilo C₁₋₄ y alquilsulfonilo C₁₋₄; y dicho sistema de anillo contiene 1, 2 ó 3 heteroátomos en el anillo seleccionados a partir del grupo constituido por nitrógeno, oxígeno y azufre, donde dicho sistema de anillo contiene al menos un átomo de nitrógeno de anillo y puede no contener más de un átomo de oxígeno en el anillo y no más de un átomo de azufre en el anillo; R³ es hidrógeno, halógeno o alquilo C₁₋₄; R⁴ es independientemente hidrógeno, alquilo C₁₋₄ o cicloalquilo C₃₋₆; R⁵ es alquilo C₁₋₆, haloalquilo C₁₋₆ o cicloalquilo C₃₋₆ o una sal, estereoisómero, enantiómero, tautómero o N-óxido agroquímicamente aceptable de un compuesto de fórmula (1). Reivindicación 15: Un compuesto de fórmula (3) o un compuesto de fórmula (4), o una sal del mismo, en la que Q¹ y R¹ son como se han definido en la fórmula (1) de la reivindicación 1. Reivindicación 16: Un compuesto de fórmula (5), o una forma tautomérica del mismo, en donde R² es fluoroalquilo C₁₋₆ y Rˣ es alquilo C₁₋₆.Compounds of formula (1) where the substituents are as defined in claim 1. Furthermore, the present relates to agrochemical compositions comprising compounds of formula (1), to the preparation of these compositions and to the use of the compounds or compositions in agriculture or horticulture to combat, prevent or control animal pests, including arthropods and, in particular, insects, molluscs, nematodes or representatives of the order Acarina. Claim 1: A compound of formula (1), wherein R² is C₁₋₆ haloalkyl, C₂₋₆ haloalkenyl or C₁₋₄ haloalkylsulfonyl; R⁶ is C₁₋₆ alkyl; Q is a radical selected from the group consisting of formula Qa and Qb from the group of formulas (2), wherein the arrow indicates the point of attachment to the pyrimidinone ring; and wherein A represents CH or N; X is S, SO, SO₂ or SO(NH); R¹ is C₁₋₄ alkyl or C₃₋₆ cycloalkyl-C₁₋₄ alkyl; Q¹ is hydrogen, halogen, C₁₋₆ haloalkyl, C₃₋₆ cycloalkyl, C₃₋₆ cycloalkyl monosubstituted by cyano, C₁₋₃ cyanoalkyl, C₁₋₆ cyanoalkoxy, C₁₋₆ haloalkoxy, -N(R⁴)₂, -N(R⁴ )COR⁵, -N(R⁴)CON(R⁴)₂, (oxazolidin-2-one)-3-yl or 2-pyridyloxy; or Q¹ is a five to six membered aromatic ring system attached via a ring carbon atom to the ring containing substituent A, which ring system is unsubstituted or monosubstituted or polysubstituted by substituents selected from the group consisting of in halogen, cyano, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄ alkylsulfanyl, C₁₋₄ alkylsulfinyl and C₁₋₄ alkylsulfonyl and said ring system may contain 1, 2 or ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, wherein said ring system may contain no more than one oxygen ring atom and no more than one sulfur ring atom; or Q¹ is a five-membered aromatic ring system linked via a ring nitrogen atom to the ring containing substituent A, which ring system is unsubstituted or mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄ alkylsulfanyl, C₁₋₄ alkylsulfinyl, and C₁₋₄ alkylsulfonyl; and said ring system contains 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, wherein said ring system contains at least one ring nitrogen atom and may not contain more than one ring atom. of ring oxygen and not more than one ring sulfur atom; R³ is hydrogen, halogen or C₁₋₄ alkyl; R⁴ is independently hydrogen, C₁₋₄ alkyl or C₃₋₆ cycloalkyl; R⁵ is C₁₋₆ alkyl, C₁₋₆ haloalkyl or C₃₋₆ cycloalkyl or an agrochemically acceptable salt, stereoisomer, enantiomer, tautomer or N-oxide of a compound of formula (1). Claim 15: A compound of formula (3) or a compound of formula (4), or a salt thereof, wherein Q¹ and R¹ are as defined in formula (1) of claim 1. Claim 16: A compound of formula (5), or a tautomeric form thereof, wherein R² is C₁₋₆ fluoroalkyl and Rˣ is C₁₋₆ alkyl.

ARP200100530A 2019-02-28 2020-02-27 HETEROCYCLIC DERIVATIVES WITH SULFUR-CONTAINING SUBSTITUENTS ACTIVE AS PESTICIDES AR119263A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IN201911007909 2019-02-28

Publications (1)

Publication Number Publication Date
AR119263A1 true AR119263A1 (en) 2021-12-09

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
ARP200100530A AR119263A1 (en) 2019-02-28 2020-02-27 HETEROCYCLIC DERIVATIVES WITH SULFUR-CONTAINING SUBSTITUENTS ACTIVE AS PESTICIDES

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