AR118197A1 - HETEROCYCLIC DERIVATIVES WITH SUBSTITUENTS CONTAINING ACTIVE SULFUR AS PESTICIDES - Google Patents

HETEROCYCLIC DERIVATIVES WITH SUBSTITUENTS CONTAINING ACTIVE SULFUR AS PESTICIDES

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Publication number
AR118197A1
AR118197A1 ARP200100526A ARP200100526A AR118197A1 AR 118197 A1 AR118197 A1 AR 118197A1 AR P200100526 A ARP200100526 A AR P200100526A AR P200100526 A ARP200100526 A AR P200100526A AR 118197 A1 AR118197 A1 AR 118197A1
Authority
AR
Argentina
Prior art keywords
ring
formula
alkyl
ring system
group
Prior art date
Application number
ARP200100526A
Other languages
Spanish (es)
Inventor
Anke Buchholz
Andr Stoller
Indira Sen
Sebastian Rendler
Michel Muehlebach
Daniel Emery
Vikas Sikervar
Original Assignee
Syngenta Crop Protection Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Crop Protection Ag filed Critical Syngenta Crop Protection Ag
Publication of AR118197A1 publication Critical patent/AR118197A1/en

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Abstract

Compuestos de fórmula (1), donde los sustituyentes son tal como se definen en la reivindicación 1. Además, la presente se refiere a composiciones agroquímicas que comprenden compuestos de fórmula (1), a la preparación de estas composiciones y al uso de los compuestos o las composiciones en agricultura u horticultura para combatir, prevenir o controlar plagas de animales, incluyendo artrópodos y, en particular, insectos, moluscos, nematodos o representantes del orden Acarina. Reivindicación 1: Un compuesto de fórmula (1), donde G¹ y G² son, independientemente entre sí, CH o N; R² es haloalquilo C₁₋₆, haloalquilsulfanilo C₁₋₄, haloalquilsulfinilo C₁₋₄, haloalquilsulfonilo C₁₋₄ o haloalcoxi C₁₋₆, haloalquilsulfoniloxi C₁₋₄; Q es un radical seleccionado a partir del grupo constituido por la fórmula (2) y (3), donde la flecha indica el punto de unión al átomo de nitrógeno del anillo bicíclico; y donde A representa CH o N; X es S, SO o SO₂; R¹ es alquilo C₁₋₄ o cicloalquil C₃₋₆-alquilo C₁₋₄; Q¹ es hidrógeno, halógeno, haloalquilo C₁₋₆, cicloalquilo C₃₋₆, cicloalquilo C₃₋₆ monosustituido por ciano, cianoalquilo C₁₋₆, cianoalcoxi C₁₋₆, haloalcoxi C₁₋₆, -N(R⁴)₂, -N(R⁴)C(=O)R⁵, -N(R⁴)CON(R⁴)₂, (oxazolidin-2-ona)-3-ilo o 2-piridiloxi; o Q¹ es un sistema de anillo aromático de cinco a seis miembros unido mediante un átomo de carbono del anillo al anillo que contiene el sustituyente A, dicho sistema de anillo está no sustituido o está monosustituido o polisustituido por sustituyentes seleccionados a partir del grupo que consiste en halógeno, ciano, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxilo C₁₋₄, haloalcoxilo C₁₋₄, alquilsulfanilo C₁₋₄, alquilsulfinilo C₁₋₄ y alquilsulfonilo C₁₋₄ y dicho sistema de anillo puede contener 1, 2 ó 3 heteroátomos en el anillo seleccionados a partir del grupo que consiste en nitrógeno, oxígeno y azufre, donde dicho sistema de anillo puede no contener más de un átomo de oxígeno en el anillo y no más de un átomo de azufre en el anillo; o Q¹ es un sistema de anillo aromático de cinco miembros unido mediante un átomo de nitrógeno del anillo al anillo que contiene el sustituyente A, dicho sistema de anillo está no sustituido o está monosustituido o polisustituido por sustituyentes seleccionados a partir del grupo constituido por halógeno, ciano, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxilo C₁₋₄, haloalcoxilo C₁₋₄, alquilsulfanilo C₁₋₄, alquilsulfinilo C₁₋₄ y alquilsulfonilo C₁₋₄; y dicho sistema de anillo contiene 1, 2 ó 3 heteroátomos en el anillo seleccionados a partir del grupo constituido por nitrógeno, oxígeno y azufre, donde dicho sistema de anillo puede no contener más de un átomo de oxígeno en el anillo y no más de un átomo de azufre en el anillo; R³ es hidrógeno, halógeno o alquilo C₁₋₄; cada R⁴ es independientemente hidrógeno, alquilo C₁₋₄ o cicloalquilo C₃₋₆; y R⁵ es alquilo C₁₋₆, haloalquilo C₁₋₆ o cicloalquilo C₃₋₆; o una sal, estereoisómero, enantiómero, tautómero o N-óxido agroquímicamente aceptable de un compuesto de fórmula (1). Reivindicación 20: Los compuestos de fórmula (4), donde R² y G¹ son tal como se definen en la fórmula (1) anterior; LG² es un grupo saliente, por ejemplo Br, Cl o I; y R es alquilo C₁₋₆, bencilo o fenilo. Reivindicación 21: Compuesto de fórmula (5), donde R², G¹, G² y Q son tal como se definen en la fórmula (1) anterior; y Rᵃ es hidrógeno, alquilo C₁₋₆, bencilo o fenilo. Reivindicación 22: Compuestos de fórmula (6), donde R¹ y X son tal como se definen en la fórmula (1) anterior; y Q¹ᵃ es 1-cianociclopropilo, 1-ciano-1-metil-etilo o 2-piridiloxilo.Compounds of formula (1), where the substituents are as defined in claim 1. Furthermore, the present refers to agrochemical compositions comprising compounds of formula (1), to the preparation of these compositions and to the use of the compounds or compositions in agriculture or horticulture to combat, prevent or control pests of animals, including arthropods and, in particular, insects, mollusks, nematodes or representatives of the order Acarina. Claim 1: A compound of formula (1), where G¹ and G² are, independently of each other, CH or N; R² is C₁₋₆ haloalkyl, C₁₋₄ haloalkylsulfanyl, C₁₋₄ haloalkylsulfinyl, C₁₋₄ haloalkylsulfonyl or C₁₋₆ haloalkoxy, C₁₋₄ haloalkylsulfonyloxy; Q is a radical selected from the group consisting of formula (2) and (3), where the arrow indicates the point of attachment to the nitrogen atom of the bicyclic ring; and where A represents CH or N; X is S, SO or SO₂; R¹ is C₁₋₄ alkyl or C₃₋₆ cycloalkyl-C₁₋₄ alkyl; Q¹ is hydrogen, halogen, C₁₋₆ haloalkyl, C₃₋₆ cycloalkyl, C₃₋₆ cycloalkyl monosubstituted by cyano, C₁₋₆ cyanoalkyl, C₁₋₆ cyanoalkoxy, C₁₋₆ haloalkoxy, -N (R⁴) ₂, -N (R⁴ ) C (= O) R⁵, -N (R⁴) CON (R⁴) ₂, (oxazolidin-2-one) -3-yl or 2-pyridyloxy; or Q¹ is a five to six membered aromatic ring system attached via a ring carbon atom to the ring containing substituent A, said ring system is unsubstituted or is monosubstituted or polysubstituted by substituents selected from the group consisting in halogen, cyano, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄ alkylsulfanyl, C₁₋₄ alkylsulfinyl and C₁₋₄ alkylsulfonyl and said ring system may contain 1, 2 or 3 ring heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, wherein said ring system may contain no more than one ring oxygen atom and no more than one ring sulfur atom; or Q¹ is a five-membered aromatic ring system attached through a ring nitrogen atom to the ring containing substituent A, said ring system is unsubstituted or monosubstituted or polysubstituted by substituents selected from the group consisting of halogen, cyano, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄ alkylsulfanyl, C₁₋₄ alkylsulfinyl, and C₁₋₄ alkylsulfonyl; and said ring system contains 1, 2 or 3 heteroatoms in the ring selected from the group consisting of nitrogen, oxygen and sulfur, where said ring system may contain no more than one oxygen atom in the ring and no more than one sulfur atom in the ring; R³ is hydrogen, halogen or C₁₋₄ alkyl; each R⁴ is independently hydrogen, C₁₋₄ alkyl, or C₃₋₆ cycloalkyl; and R⁵ is C₁₋₆ alkyl, C₁₋₆ haloalkyl, or C₃₋₆ cycloalkyl; or an agrochemically acceptable salt, stereoisomer, enantiomer, tautomer or N-oxide of a compound of formula (1). Claim 20: Compounds of formula (4), where R² and G¹ are as defined in formula (1) above; LG² is a leaving group, for example Br, Cl or I; and R is C₁₋₆ alkyl, benzyl, or phenyl. Claim 21: Compound of formula (5), where R², G¹, G² and Q are as defined in formula (1) above; and Rᵃ is hydrogen, C₁₋₆ alkyl, benzyl, or phenyl. Claim 22: Compounds of formula (6), where R¹ and X are as defined in formula (1) above; and Q¹ᵃ is 1-cyanocyclopropyl, 1-cyano-1-methyl-ethyl, or 2-pyridyloxy.

ARP200100526A 2019-02-28 2020-02-26 HETEROCYCLIC DERIVATIVES WITH SUBSTITUENTS CONTAINING ACTIVE SULFUR AS PESTICIDES AR118197A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IN201911007906 2019-02-28

Publications (1)

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AR118197A1 true AR118197A1 (en) 2021-09-22

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Family Applications (1)

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AR (1) AR118197A1 (en)

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