AR113969A1 - SUBSTITUTED THIOPHENYLURACILS AS WELL AS THEIR SALTS AND THEIR USE AS ACTIVE INGREDIENTS HERBICIDES - Google Patents

SUBSTITUTED THIOPHENYLURACILS AS WELL AS THEIR SALTS AND THEIR USE AS ACTIVE INGREDIENTS HERBICIDES

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AR113969A1
AR113969A1 ARP180103713A ARP180103713A AR113969A1 AR 113969 A1 AR113969 A1 AR 113969A1 AR P180103713 A ARP180103713 A AR P180103713A AR P180103713 A ARP180103713 A AR P180103713A AR 113969 A1 AR113969 A1 AR 113969A1
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Argentina
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haloalkyl
cycloalkyl
alkoxy
aryl
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Lmmen Peter Dr
Rosinger Christopher Hugh Dr
Machettira Anu Bheemaiah Dr
Gatzweiler Elmar Dr
Dietrich Hansjrg Dr
Beffa Roland Dr
Willms Lothar Dr
Heinemann Ines Dr
Frackenpohl Jens Dr
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Bayer Ag
Bayer Cropscience Ag
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/52—Two oxygen atoms
    • C07D239/54—Two oxygen atoms as doubly bound oxygen atoms or as unsubstituted hydroxy radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems

Abstract

Reivindicación 1: Tiofeniluracilos sustituidos de la fórmula general (1) o sus sales, caracterizados porque R¹ representa alquilo C₁₋₈, amino, bis-[alquil C₁₋₈]amino; R² representa hidrógeno, alquilo C₁₋₈; R³ representa hidrógeno, halógeno, alcoxi C₁₋₈; R⁴ representa halógeno, ciano, NO₂, C(O)NH₂, C(S)NH₂, haloalquilo C₁₋₈, alquinilo C₂₋₈; R⁵ y R⁶ representan, de modo independiente entre sí, hidrógeno, halógeno, alquilo C₁₋₈, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquilo C₁₋₁₀, haloalquenilo C₂₋₈, haloalquinilo C₂₋₈, halocicloalquilo C₃₋₁₀, cicloalquenilo C₄₋₁₀, halocicloalquenilo C₄₋₁₀, alcoxi C₁₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-alquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, cicloalquenil C₄₋₁₀-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, alquil C₁₋₈-tio-alquilo C₁₋₈, haloalquil C₁₋₈-tio-alquilo C₁₋₈, alquil C₁₋₈-carbonil-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, C(O)R⁸⁵, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈, o R⁵ y R⁶ con el átomo de carbono al que están unidos, forman un anillo monocíclico o bicíclico de 3 a 10 miembros completamente saturado o parcialmente saturado, opcionalmente interrumpido por heteroátomos y opcionalmente sustituido, o R⁵ y R⁶ con el átomo de carbono al que están unidos, forman un enlace doble sustituido opcionalmente con R⁸¹ y R⁸², de acuerdo con la fórmula (2); R²⁰ representa hidrógeno, flúor, cloro, bromo, trifluorometilo, alcoxi C₁₋₈; m representa 0, 1, 2; Q representa los grupos Q-1 a Q-16 representado en el grupo de fórmulas (3), en donde R⁷, R⁸, R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴, R¹⁵, R¹⁶, R¹⁷, R¹⁸, R¹⁹, R²⁰, R²¹, R²², R²³, R²⁴, R²⁵, R²⁶, R²⁷, R²⁸, R²⁹, R³⁰, R³¹, R³², R³³, R³⁴, R³⁵, R³⁶, R³⁷, R³⁸, R³⁹, R⁴⁰, R⁴¹, R⁴², R⁴³, R⁴⁴, R⁴⁵, R⁴⁸, R⁴⁹, R⁵⁰, R⁵¹, R⁵⁴, R⁵⁵, R⁵⁶, R⁵⁷, R⁵⁸, R⁵⁹, R⁶⁰, R⁶¹, R⁶², R⁶³ y R⁶⁴ así como A¹, A², A³, A⁴, A⁵, A⁶, A⁷ y A⁸ tienen cada uno el significado de acuerdo con las siguientes definiciones y en donde la flecha representa un enlace con el grupo carbonilo; X representa O (oxígeno) o los grupos N-R⁶⁹ o N-O-R⁷⁰ y en donde R⁶⁹ y R⁷⁰ en los grupos N-R⁶⁹ y N-O-R⁷⁰ tienen, de modo independiente entre sí, los significados según las siguientes definiciones; R⁷ representa cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquenilo C₂₋₈, haloalquinilo C₂₋₈, halocicloalquilo C₃₋₁₀, alcoxi C₁₋₈-alquilo C₁₋₈, hidroxialquilo, aril-alcoxi C₁₋₈-alquilo C₁₋₈, heteroaril-alcoxi C₁₋₈-alquilo C₁₋₈, heterociclil-alcoxi C₁₋₈-alquilo C₁₋₈, alquenil C₂₋₈-oxi-alquilo C₁₋₈, alquinil C₂₋₈-oxi-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-alquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, C(O)R¹⁹, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸⁵C(O)O-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈, R⁸³R⁸⁴NC(N=H)NH-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, R⁸⁶S(O)-alquilo C₁₋₈, R⁸⁶SO₂-alquilo C₁₋₈, o R⁵ y R⁷ forman, con los átomos de carbono a los que están unidos, un anillo monocíclico o bicíclico de 3 a 8 miembros completamente saturado o parcialmente saturado, opcionalmente interrumpido por heteroátomos y opcionalmente sustituido; R⁸ representa alcoxi C₁₋₈, alquenil C₂₋₈-oxi, alquinil C₂₋₈-oxi, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquenilo C₂₋₈, haloalquinilo C₂₋₈, halocicloalquilo C₃₋₁₀, alcoxi C₁₋₈-alquilo C₁₋₈, hidroxialquilo, aril-alcoxi C₁₋₈-alquilo C₁₋₈, heteroaril-alcoxi C₁₋₈-alquilo C₁₋₈, heterociclil-alcoxi C₁₋₈-alquilo C₁₋₈, alquenil C₂₋₈-oxi-alquilo C₁₋₈, alquinil C₂₋₈-oxi-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-alquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, C(O)R⁸⁵, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, alquenil C₂₋₈-oxi-alquilo C₁₋₈, alquinil C₂₋₈-oxi-alquilo C₁₋₈, aril-alquil C₁₋₈-oxi-alquilo C₁₋₈, R⁸⁵C(O)O-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈, R⁸³R⁸⁴NC(N=H)NH-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, R⁸⁶S(O)-alquilo C₁₋₈, R⁸⁶SO₂-alquilo C₁₋₈; R⁹ y R⁶⁹ representan, de modo independiente entre sí, hidrógeno, alquilo C₁₋₈, cicloalquilo C₃₋₈, ciano-alquilo C₁₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquil C₁₋₈-sulfonilo, arilsulfonilo, heteroarilsulfonilo, cicloalquil C₃₋₈-sulfonilo, heterociclilsulfonilo, aril-alquil C₁₋₈-sulfonilo, alquil C₁₋₈-carbonilo, arilcarbonilo, heteroarilcarbonilo, cicloalquil C₃₋₈-carbonilo, heterociclilcarbonilo, alcoxi C₁₋₈-carbonilo, alcoxi C₁₋₈, alquenil C₂₋₈-oxi, aril-alcoxi C₁₋₈-carbonilo, haloalquil C₁₋₈-carbonilo, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquilo C₁₋₈, halo-alquinilo C₂₋₈, halo-alquenilo C₂₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, amino, alquil C₁₋₈-amino, bis[alquil C₁₋₈]amino, alcoxi C₁₋₈-alcoxi C₁₋₈-alquilo C₁₋₈, heteroaril-alquil C₁₋₈-sulfonilo, heterociclil-alquil C₁₋₈-sulfonilo, alquenil C₂₋₈-oxicarbonilo, alquinil C₂₋₈-oxicarbonilo, alquil C₁₋₈-aminocarbonilo, cicloalquil C₃₋₈-aminocarbonilo, bis-[alquil C₁₋₈]aminocarbonilo; R¹⁰ y R¹¹ representan, de modo independiente entre sí, alquilo C₁₋₈, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquilo C₁₋₁₀, haloalquenilo C₂₋₈, haloalquinilo C₂₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-alquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, alquil C₁₋₈-tio-alquilo C₁₋₈, haloalquil C₁₋₈-tio-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈, en donde R¹⁰ y R¹¹ no representan al mismo tiempo alquilo C₁₋₈, o R¹⁰ y R¹¹ con el átomo de carbono al que están unidos, forman un anillo monocíclico o bicíclico de 3 a 10 miembros completamente saturado o parcialmente saturado, opcionalmente interrumpido por heteroátomos y opcionalmente sustituido; R¹² y R¹³ representan, de modo independiente entre sí, flúor, alquilo C₁₋₈, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquilo C₁₋₁₀, haloalquenilo C₂₋₈, haloalquinilo C₂₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-alquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, alquil C₁₋₈-tio-alquilo C₁₋₈, haloalquil C₁₋₈-tio-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, C(O)R⁸⁵, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈, o R¹² y R¹³ con el átomo de carbono al que están unidos, forman un anillo monocíclico o bicíclico de 3 a 10 miembros completamente saturado o parcialmente saturado, opcionalmente interrumpido por heteroátomos y opcionalmente sustituido, o R¹² y R¹³ con el átomo de carbono al que están unidos, forman un grupo exometileno; R¹⁴ representa hidrógeno, alquilo C₁₋₈, haloalquilo C₁₋₈, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₁₋₈, alquinilo C₂₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, haloalcoxi C₁₋₈-alquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, alquil C₁₋₈-tio-alquilo C₁₋₈, haloalquil C₁₋₈-tio-alquilo C₁₋₈, alquil C₁₋₈-carbonil-alquilo C₁₋₈, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈; A¹ representa un enlace directo, O (oxígeno), S (azufre), CR⁷¹R⁷², N-H o los grupos N-R⁶⁹ o N-O-R⁷⁰ y en donde R⁶⁹, R⁷⁰, R⁷¹ y R⁷² en los grupos CR⁷¹R⁷², N-R⁶⁹ y N-O-R⁷⁰ tienen, de modo independiente entre sí, los significados según las definiciones precedentes o siguientes; R¹⁵, R¹⁶, R¹⁷, R¹⁸, R²⁸, R²⁹, R³⁰ y R³¹ representan, de modo independiente entre sí, hidrógeno, alquilo C₁₋₈, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquilo C₁₋₁₀, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, R⁸⁵O-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, alquil C₁₋₈-carbonil-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, C(O)R⁸⁵, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈; R¹⁹, R²⁷, R³², R³⁹ y R⁴⁸ representan, de modo independiente entre sí, hidrógeno, alquilo C₁₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquilo C₁₋₈, aril-alquilo C₁₋₈, heteroaril-alquilo C₁₋₈, heterociclil-alquilo C₁₋₈, R⁸⁵O-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈; A² representa O (oxígeno), S (azufre), SO, SO₂, CR⁷¹R⁷², N-H o los grupos N-R⁶⁹ o N-O-R⁷⁰ y en donde R⁶⁹, R⁷⁰, R⁷¹ y R⁷² en los grupos CR⁷¹R⁷², N-R⁶⁹ y N-O-R⁷⁰ tienen, de modo independiente entre sí, los significados según las definiciones precedentes o siguientes; R²¹, R²², R²³, R²⁴, R²⁵, R²⁶, R³³, R³⁴, R³⁵, R³⁶, R³⁷ y R³⁸ representan, de modo independiente entre sí, hidrógeno, alquilo C₁₋₈, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, haloalquilo C₁₋₁₀, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, R⁸⁵O-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈; A³ y A⁴ representan, de modo independiente entre sí, un enlace directo, O (oxígeno), S (azufre), N-H o los grupos CR⁷¹R⁷², CR⁷³R⁷⁴CR⁷⁵R⁷⁶, N-R⁶⁹ o N-O-R⁷⁰, en donde R⁶⁹, R⁷⁰, R⁷¹, R⁷², R⁷³, R⁷⁴, R⁷⁵ y R⁷⁶ en los grupos CR⁷¹R⁷², CR⁷³R⁷⁴CR⁷⁵R⁷⁶, N-R⁶⁹ y N-O-R⁷⁰ tienen, de modo independiente entre sí, los significados según las definiciones precedentes o siguientes y en donde A³ y A⁴ no representan al mismo tiempo oxígeno, azufre o una combinación de azufre y oxígeno; R⁴², R⁴³, R⁴⁴ y R⁴⁵ representan, de modo independiente entre sí, hidrógeno, alquilo C₁₋₈, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, haloalquilo C₁₋₁₀, R⁸⁵O-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈, o R⁴⁴ y R⁴⁵ forman, con los átomos de carbono a los que están unidos, un anillo monocíclico o bicíclico de 3 a 10 miembros completamente saturado o parcialmente saturado, opcionalmente interrumpido por heteroátomos y opcionalmente sustituido; A⁵ representa O (oxígeno), S (azufre), N-H o los grupos CR⁷¹R⁷², CR⁷³R⁷⁴CR⁷⁵R⁷⁶, N-R⁶⁹ o N-O-R⁷⁰, en donde R⁶⁹, R⁷⁰, R⁷¹, R⁷², R⁷³, R⁷⁴, R⁷⁵ y R⁷⁶ en los grupos CR⁷¹R⁷², CR⁷³R⁷⁴CR⁷⁵R⁷⁶, N-R⁶⁹ y N-O-R⁷⁰ tienen, de modo independiente entre sí, los significados según las definiciones precedentes o siguientes; R⁴⁸, R⁴⁹, R⁵⁰, R⁵¹, R⁵⁴ y R⁵⁵ representan, de modo independiente entre sí, hidrógeno, alquilo C₁₋₈, cicloalquilo C₃₋₈, alquenilo C₂₋₈, haloalquilo C₁₋₁₀, R⁸⁵O-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈, o R⁵⁰ y R⁵⁴ forman, con los átomos de carbono a los que están unidos, un anillo monocíclico o bicíclico de 5 a 10 miembros completamente saturado o parcialmente saturado, opcionalmente interrumpido por heteroátomos y opcionalmente sustituido; R⁵⁶, R⁵⁷, R⁵⁸, R⁵⁹, R⁶⁰ y R⁶¹ representan, de modo independiente entre sí, hidrógeno, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquenilo C₂₋₈, haloalquinilo C₂₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, R⁸⁵O-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈ y en donde R⁵⁶, R⁵⁷, R⁵⁸, R⁵⁹, R⁶⁰ y R⁶¹ son distintos de hidrógeno en al menos un caso; R⁶² representa haloalquilo C₁₋₈, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquenilo C₂₋₈, haloalquinilo C₂₋₈, halocicloalquilo C₃₋₁₀, R⁸⁵O-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, C₍O₎OR⁸⁵, C(O)NR⁸³R⁸⁴, C(O)R¹⁹, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸⁵C(O)O-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈, R⁸³R⁸⁴NC(N=H)NH-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, R⁸⁶S(O)-alquilo C₁₋₈, R⁸⁶SO₂-alquilo C₁₋₈; R⁶³ y R⁶⁴ representan, de modo independiente entre sí, flúor, alquilo C₁₋₈, haloalquilo C₁₋₈, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, haloalquenilo C₂₋₈, haloalquinilo C₂₋₈, halocicloalquilo C₃₋₁₀, R⁸⁵O-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, heteroarilo, heteroaril-alquilo C₁₋₈, heterociclilo, heterociclil-alquilo C₁₋₈, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈, R⁸⁵C(O)O-alquilo C₁₋₈, R⁸³R⁸⁴N-alquilo C₁₋₈, R⁸³R⁸⁴NC(N=H)NH-alquilo C₁₋₈, R⁸⁶S-alquilo C₁₋₈, R⁸⁶S(O)-alquilo C₁₋₈, R⁸⁶SO₂-alquilo C₁₋₈, y en donde R⁶³ y R⁶⁴ son distintos de alquilo C₁₋₈ en al menos un caso; A⁶ y A⁸ representan, de modo independiente entre sí, un grupo CR⁶⁵R⁶⁶, en donde R⁶⁵ y R⁶⁶ en el grupo CR⁶⁵R⁶⁶ tienen, de modo independiente entre sí, los significados según las siguientes definiciones; A⁷ representa un enlace directo, O (oxígeno), N-H o los grupos CR⁷¹R⁷², OCR⁶⁷R⁶⁸, (N-R⁶⁹)CR⁶⁷R⁶⁸, CR⁷³R⁷⁴CR⁷⁵R⁷⁶, CR⁷¹R⁷²CR⁷³R⁷⁴CR⁷⁵R⁷⁶, OCR⁷⁷R⁷⁸CR⁷⁹R⁸⁰, CR⁷⁷R⁷⁸OCR⁷⁹R⁸⁰, (N-R⁶⁹)CR⁷⁷R⁷⁸CR⁷⁹R⁸⁰, CR⁷⁷R⁷⁸(N-R⁶⁹)CR⁷⁹R⁸⁰ o N-R⁶⁹, en donde R⁶⁷, R⁶⁸, R⁶⁹, R⁷⁰, R⁷¹, R⁷², R⁷³ R⁷⁴, R⁷⁵, R⁷⁶, R⁷⁷, R⁷⁸, R⁷⁹ y R⁸⁰ en los grupos CR⁷¹R⁷², OCR⁶⁷R⁶⁸, (N-R⁶⁹)CR⁶⁷R⁶⁸, CR⁷³R⁷⁴CR⁷⁵R⁷⁶, CR⁷¹R⁷²CR⁷³R⁷⁴CR⁷⁵R⁷⁶, OCR⁷⁷R⁷⁸CR⁷⁹R⁸⁰, CR⁷⁷R⁷⁸OCR⁷⁹R⁸⁰, (N-R⁶⁹)CR⁷⁷R⁷⁸CR⁷⁹R⁸⁰, CR⁷⁷R⁷⁸(N-R⁶⁹)CR⁷⁹R⁸⁰, N-R⁶⁹ tienen, de modo independiente entre sí, los significados según las definiciones precedentes o siguientes; R⁶⁵ y R⁶⁶ representan, de modo independiente entre sí, hidrógeno, alquilo C₁₋₈, cicloalquilo C₃₋₈, haloalquilo C₁₋₈; R⁶⁷, R⁶⁸, R⁷⁷, R⁷⁸, R⁷⁹ y R⁸⁰ representan, de modo independiente entre sí, hidrógeno, alquilo C₁₋₈, cicloalquilo C₃₋₈, haloalquilo C₁₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, arilo, aril-alquilo C₁₋₈; R⁷⁰ representa hidrógeno, alquilo C₁₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, haloalcoxi C₁₋₈-alquilo C₁₋₈, alquil C₁₋₈-tio-alquilo C₁₋₈, arilo, aril-alquilo C₁₋₈, R⁸⁵O(O)C-alquilo C₁₋₈, R⁸³R⁸⁴N(O)C-alquilo C₁₋₈; R¹⁴ y R⁶⁹ en el caso de que X represente N-R⁶⁹, forman con el átomo de nitrógeno, al que están unidos, un anillo monocíclico o bicíclico de 4 a 10 miembros completamente saturado u opcionalmente interrumpido por heteroátomos y opcionalmente sustituido, o R¹⁴ y R⁷⁰ en el caso de que X represente N-O-R⁷⁰, forman con el átomo de nitrógeno, al que están unidos, un anillo monocíclico o bicíclico de 4 a 10 miembros completamente saturado y opcionalmente sustituido; R⁷¹ y R⁷² representan, de modo independiente entre sí, hidrógeno, halógeno, hidroxi, alquilo C₁₋₈, cicloalquilo C₃₋₈, haloalquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₁₋₈, alcoxi C₁₋₈, haloalcoxiClaim 1: Substituted thiophenyluracils of the general formula (1) or their salts, characterized in that R¹ represents C₁₋₈ alkyl, amino, bis- [C₁₋₈ alkyl] amino; R² represents hydrogen, C₁₋₈ alkyl; R³ represents hydrogen, halogen, C₁₋₈ alkoxy; R⁴ represents halogen, cyano, NO₂, C (O) NH₂, C (S) NH₂, C₁₋₈ haloalkyl, C₂₋₈ alkynyl; R⁵ and R⁶ represent, independently of each other, hydrogen, halogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₁₋₁₀ haloalkyl, C₂₋₈ haloalkenyl, C₂₋₈ haloalkynyl, C₃₋₁₀ halocycloalkyl, C₄₋₁₀ cycloalkenyl, C₄₋₁₀ halocycloalkenyl, C₁₋₈ alkoxy, C₁₋₈ alkoxy-C₁₋₈ alkyl, C₁₋₈ alkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ alkyl, aryl, aryl-C₁₋₈ alkyl, heteroaryl, heteroaryl-C₁₋₈ alkyl, C₄₋₁₀ cycloalkenyl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl, C₁₋₈ alkyl-thio-C₁₋₈ alkyl, C₁₋₈ haloalkyl-thio-C₁₋₈ alkyl, C₁₋₈ alkyl-carbonyl-C₁₋₈ alkyl, C₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, C (O) R⁸⁵, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl, or R⁵ and R⁶ with the carbon atom at the which are attached, form a fully saturated or partially saturated 3- to 10-membered monocyclic or bicyclic ring, optionally interrupted by heteroatoms and optionally s usstituted, or R⁵ and R⁶ with the carbon atom to which they are attached, form a double bond optionally substituted with R⁸¹ and R⁸², according to formula (2); R²⁰ represents hydrogen, fluorine, chlorine, bromine, trifluoromethyl, C₁₋₈ alkoxy; m represents 0, 1, 2; Q represents the groups Q-1 to Q-16 represented in the group of formulas (3), where R⁷, R⁸, R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴, R¹⁵, R¹⁶, R¹⁷, R¹⁸, R¹⁹, R²⁰ , R²¹, R²², R²³, R²⁴, R²⁵, R²⁶, R²⁷, R²⁸, R²⁹, R³⁰, R³¹, R³², R³³, R³⁴, R³⁵, R³⁶, R³⁷, R³⁸, R³⁹, R⁴⁰, R⁴¹, R⁴², R⁴³, R⁴⁴, R⁴⁵ , R⁴⁸, R⁴⁹, R⁵⁰, R⁵¹, R⁵⁴, R⁵⁵, R⁵⁶, R⁵⁷, R⁵⁸, R⁵⁹, R⁶⁰, R⁶¹, R⁶², R⁶³ and R⁶⁴ as well as A¹, A², A³, A⁴, A⁵, A⁶, A⁷ and A⁸ each have the meaning according to the following definitions and wherein the arrow represents a bond with the carbonyl group; X represents O (oxygen) or the N-R⁶⁹ or N-O-R⁷⁰ groups and where R⁶⁹ and R⁷⁰ in the N-R⁶⁹ and N-O-R⁷⁰ groups have, independently of each other, the meanings according to the following definitions; R⁷ represents C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₂₋₈ haloalkenyl, C₂₋₈ haloalkynyl, C₃₋₁₀ halocycloalkyl, C₁₋₈ alkoxy-C₁₋ alkyl ₈, hydroxyalkyl, aryl-C₁₋₈ alkoxy-C₁₋₈ alkyl, heteroaryl-C₁₋₈ alkoxy-C₁₋₈ alkyl, heterocyclyl-C₁₋₈ alkoxy-C₁₋₈ alkyl, alkenyl C₂₋₈-oxy-C₁₋ alkyl ₈, C₂₋₈-alkynyl-C ox-oxy-alkyl, C alco-alkoxy-C₁₋₈-haloalkyl, C₁₋₈-haloalkoxy-C₁₋₈-haloalkyl, C₁₋₈-haloalkoxy-C₁₋₈-alkyl, aryl, aryl-C₁-alkyl ₋₈, heteroaryl, heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl, C₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, C (O) R¹⁹, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸⁵C (O) O-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl, R⁸³R⁸⁴NC (N = H) NH-C₁₋₈ alkyl, R⁸⁶S-C₁₋₈ alkyl, R⁸⁶S (O) -C₁₋₈alkyl, R⁸⁶SO₂-C₁₋₈ alkyl, or R⁵ and R⁷ form, with the carbon atoms to which they are attached, a fully saturated or partially saturated 3- to 8-membered monocyclic or bicyclic ring, optionally interrupted by heteroatom os and optionally substituted; R⁸ represents C₁₋₈ alkoxy, C₂₋₈ alkenyl-oxy, C₂₋₈ alkynyl-oxy, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₂₋₈ haloalkenyl , C₂₋₈ haloalkynyl, C₃₋₁₀ halocycloalkyl, C₁₋₈ alkoxy-C₁₋₈ alkyl, hydroxyalkyl, aryl-C₁₋₈ alkoxy-C₁₋₈ alkyl, heteroaryl-C₁₋₈ alkoxy-C₁₋₈ alkyl, heterocyclyl-alkoxy C₁₋₈-C₁₋₈ alkyl, C₂₋₈ alkenyl-oxy-C₁₋₈ alkyl, C₂₋₈ alkynyl-C oxy-alkyl, C₁₋₈ alkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-haloalkyl ₋₈, C₁₋₈ haloalkoxy-C₁₋₈ alkyl, aryl, aryl-C₁₋₈ alkyl, heteroaryl, heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl, C₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, C (O) R⁸⁵, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, C₁₋₈ alkenyl-oxy-C₁₋₈ alkyl, C-oxy-C₁₋₈ alkynyl, aryl-C₁₋₈ alkyl- C₁₋₈ oxy-alkyl, R⁸⁵C (O) O-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl, R⁸³R⁸⁴NC (N = H) NH-C₁₋₈ alkyl, R⁸⁶S-C₁₋₈ alkyl, R⁸⁶S (O) - C₁₋₈ alkyl, R⁸⁶SO₂-C₁₋₈ alkyl; R⁹ and R⁶⁹ independently represent hydrogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, cyano-C₁₋₈ alkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₁₋₈ alkyl sulfonyl, arylsulfonyl, heteroarylsulfonyl , C₃₋₈-cycloalkyl-sulfonyl, heterocyclylsulfonyl, aryl-C₁₋₈-alkyl-sulfonyl, C₁₋₈-alkyl-carbonyl, arylcarbonyl, heteroarylcarbonyl, C₃₋₈-cycloalkyl-carbonyl, heterocyclylcarbonyl, C₁₋₈-alkoxy-carbonyl, C₁₋₈-alkoxy , C₂₋₈-alkenyl-oxy, aryl-C₁₋₈-alkoxy-carbonyl, C₁₋₈-haloalkyl-carbonyl, C₂₋₈-alkenyl, C₂₋₈-alkynyl, C₁₋₈-haloalkyl, C₂₋₈-halo-alkynyl, C₂-halo-alkenyl ₋₈, C₁₋₈ alkoxy-C₁₋₈ alkyl, amino, C₁₋₈ alkyl-amino, bis [C₁₋₈ alkyl] amino, C₁₋₈ alkoxy-C₁₋₈ alkoxy-C₁₋₈ alkyl, heteroaryl-C₁ alkyl ₋₈-sulfonyl, heterocyclyl-C₁₋₈-alkyl-sulfonyl, C₂₋₈-alkenyl-oxycarbonyl, C₂₋₈-alkynyl-oxycarbonyl, C₁₋₈-alkyl-aminocarbonyl, C₃₋₈-cycloalkyl-aminocarbonyl, bis- [C₁₋₈-alkyl] aminocarbonyl; R¹⁰ and R¹¹ independently represent C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₁₋₁₀ haloalkyl, C₂₋₈ haloalkenyl , C₂₋₈ haloalkynyl, C₁₋₈ alkoxy-C₁₋₈ alkyl, C₁₋₈ alkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ alkyl, aryl, aryl- C₁₋₈ alkyl, heteroaryl, heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl, C₁₋₈ alkyl-thio-C₁₋₈ alkyl, C₁₋₈ haloalkyl-thio-C₁₋₈ alkyl, C₍O ₎OR⁸⁵, C (O) NR⁸³R⁸⁴, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl, where R¹⁰ and R¹¹ do not represent C₁ alkyl at the same time ₋₈, or R¹⁰ and R¹¹ with the carbon atom to which they are attached, form a fully saturated or partially saturated 3- to 10-membered monocyclic or bicyclic ring, optionally interrupted by heteroatoms and optionally substituted; R¹² and R¹³ represent, independently of one another, fluorine, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₁₋₁₀ haloalkyl, C₂ haloalkenyl ₋₈, C₂₋₈ haloalkynyl, C₁₋₈ alkoxy-C₁₋₈ alkyl, C₁₋₈ alkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ alkyl, aryl, aryl-C₁₋₈ alkyl, heteroaryl, heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl, C₁₋₈ alkyl-thio-C₁₋₈ alkyl, haloalkyl C₁₋₈-thio-C₁₋₈ alkyl, C ₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, C (O) R⁸⁵, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl, or R¹² and R¹³ with the carbon atom to which they are attached, they form a fully saturated or partially saturated 3- to 10-membered monocyclic or bicyclic ring, optionally interrupted by heteroatoms and optionally substituted, or R¹² and R¹³ with the carbon atom to which they are attached, form an exomethylene group; R¹⁴ represents hydrogen, C₁₋₈ alkyl, C₁₋₈ haloalkyl, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₁₋₈ alkenyl, C₂₋₈ alkynyl, C₁₋₈ alkoxy-C₁₋₈ alkyl, haloalkoxy C₁₋₈-C₁₋₈ alkyl, aryl, aryl-C₁₋₈ alkyl, heteroaryl, heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl, C₁₋₈ alkyl-thio-C₁₋₈ alkyl, haloalkyl C₁ ₋₈-thio-C₁₋₈ alkyl, C₁₋₈ alkyl-carbonyl-C₁₋₈ alkyl, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl ; A¹ represents a direct bond, O (oxygen), S (sulfur), CR⁷¹R⁷², NH or the groups N-R⁶⁹ or NO-R⁷⁰ and where R⁶⁹, R⁷⁰, R⁷¹ and R⁷² in the groups CR⁷¹R⁷², N-R⁶⁹ and NO- R⁷⁰ have, independently of each other, the meanings according to the preceding or following definitions; R¹⁵, R¹⁶, R¹⁷, R¹⁸, R²⁸, R²⁹, R³⁰ and R³¹ represent, independently of each other, hydrogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₁₋₁₀ haloalkyl, C₁₋₈ alkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ haloalkyl, aryl, aryl-C₁₋₈ alkyl, heteroaryl, heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl, R⁸⁵O-C₁₋₈ alkyl, R⁸⁶S-C₁₋₈ alkyl, C₁₋₈ alkyl-carbonyl-C₁₋₈ alkyl, C₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, C (O) R⁸⁵ , R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl; R¹⁹, R²⁷, R³², R³⁹ and R⁴⁸ represent, independently of each other, hydrogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₁₋₈ haloalkyl, aryl -C₁₋₈ alkyl, heteroaryl-C₁₋₈ alkyl, heterocyclyl-C₁₋₈ alkyl, R⁸⁵O-C₁₋₈ alkyl, R⁸⁶S-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl; A² represents O (oxygen), S (sulfur), SO, SO₂, CR⁷¹R⁷², NH or the groups N-R⁶⁹ or NO-R⁷⁰ and where R⁶⁹, R⁷⁰, R⁷¹ and R⁷² in the groups CR⁷¹R⁷², N-R⁶⁹ and NO- R⁷⁰ have, independently of each other, the meanings according to the preceding or following definitions; R²¹, R²², R²³, R²⁴, R²⁵, R²⁶, R³³, R³⁴, R³⁵, R³⁶, R³⁷ and R³⁸ represent, independently of each other, hydrogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁ alkyl ₋₈, C₂₋₈ alkenyl, C₁₋₁₀ haloalkyl, aryl, aryl-C₁₋₈ alkyl, heteroaryl, heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl, R⁸⁵O-C₁₋₈ alkyl, R⁸⁶S-alkyl C₁₋₈, C₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl; A³ and A⁴ represent, independently of each other, a direct bond, O (oxygen), S (sulfur), NH or the groups CR⁷¹R⁷², CR⁷³R⁷⁴CR⁷⁵R⁷⁶, N-R⁶⁹ or NO-R⁷⁰, where R⁶⁹, R⁷⁰, R⁷¹, R⁷² , R⁷³, R⁷⁴, R⁷⁵ and R⁷⁶ in the groups CR⁷¹R⁷², CR⁷³R⁷⁴CR⁷⁵R⁷⁶, N-R⁶⁹ and NO-R⁷⁰ have, independently of each other, the meanings according to the preceding or following definitions and where A³ and A⁴ do not represent oxygen at the same time , sulfur or a combination of sulfur and oxygen; R⁴², R⁴³, R⁴⁴ and R⁴⁵ represent, independently of each other, hydrogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₁₋₁₀ haloalkyl, R⁸⁵O-alkyl C₁₋₈, R⁸⁶S-C₁₋₈ alkyl, C₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋ alkyl ₈, or R⁴⁴ and R⁴⁵ form, with the carbon atoms to which they are attached, a fully saturated or partially saturated 3- to 10-membered monocyclic or bicyclic ring, optionally interrupted by heteroatoms and optionally substituted; A⁵ represents O (oxygen), S (sulfur), NH or the groups CR⁷¹R⁷², CR⁷³R⁷⁴CR⁷⁵R⁷⁶, N-R⁶⁹ or NO-R⁷⁰, where R⁶⁹, R⁷⁰, R⁷¹, R⁷², R⁷³, R⁷⁴, R⁷⁵ and R⁷⁶ in the CR⁷¹R⁷² groups, CR⁷³R⁷⁴CR⁷⁵R⁷⁶, N-R⁶⁹ and NO-R⁷⁰ have, independently of each other, the meanings according to the preceding or following definitions; R⁴⁸, R⁴⁹, R⁵⁰, R⁵¹, R⁵⁴ and R⁵⁵ represent, independently of each other, hydrogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₂₋₈ alkenyl, C₁₋₁₀ haloalkyl, R⁸⁵O-C₁₋₈ alkyl, R⁸⁶S- C₁₋₈ alkyl, C₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl, or R⁵⁰ and R⁵⁴ they form, with the carbon atoms to which they are attached, a fully saturated or partially saturated 5 to 10 membered monocyclic or bicyclic ring, optionally interrupted by heteroatoms and optionally substituted; R⁵⁶, R⁵⁷, R⁵⁸, R⁵⁹, R⁶⁰, and R⁶¹ independently of one another represent hydrogen, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₂₋₈ haloalkenyl , C₂₋₈ haloalkynyl, C₁₋₈ alkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ haloalkyl, aryl, aryl-C₁₋₈ alkyl, heteroaryl, heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁ alkyl ₋₈, R⁸⁵O-C₁₋₈ alkyl, R⁸⁶S-C₁₋₈ alkyl, C₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl and where R⁵⁶ , R⁵⁷, R⁵⁸, R⁵⁹, R⁶⁰, and R⁶¹ are other than hydrogen in at least one case; R⁶² represents C₁₋₈ haloalkyl, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₂₋₈ haloalkenyl, C₂₋₈ haloalkynyl, C₃₋₁₀ halocycloalkyl, R⁸⁵O-alkyl C₁₋₈, C₁₋₈ alkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ haloalkyl, aryl, aryl-C₁₋₈ alkyl, heteroaryl, heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl , C₍O₎OR⁸⁵, C (O) NR⁸³R⁸⁴, C (O) R¹⁹, R⁸⁵O (O) C-C-alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸⁵C (O) O-C₁₋ alkyl ₈, R⁸³R⁸⁴N-C₁₋₈ alkyl, R⁸³R⁸⁴NC (N = H) NH-C₁₋₈ alkyl, R⁸⁶S-C₁₋₈ alkyl, R⁸⁶S (O) -C₁₋₈alkyl, R⁸⁶SO₂-C₁₋₈ alkyl; R⁶³ and R⁶⁴ represent, independently of each other, fluorine, C₁₋₈ alkyl, C₁₋₈ haloalkyl, C₃₋₈ cycloalkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₂ haloalkenyl ₋₈, C₂₋₈ haloalkynyl, C₃₋₁₀ halocycloalkyl, R⁸⁵O-C₁₋₈ alkyl, C₁₋₈ alkoxy-C₁₋₈ haloalkyl, C₁₋₈ haloalkoxy-C₁₋₈ haloalkyl, aryl, aryl-C₁₋₈ alkyl, heteroaryl , heteroaryl-C₁₋₈ alkyl, heterocyclyl, heterocyclyl-C₁₋₈ alkyl, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl, R⁸⁵C (O) O-C₁₋₈ alkyl, R⁸³R⁸⁴N-C₁₋₈ alkyl, R⁸³R⁸⁴NC (N = H) NH-C₁₋₈ alkyl, R⁸⁶S-C₁₋₈ alkyl, R⁸⁶S (O) -C₁₋₈ alkyl, R⁸⁶SO₂-C₁₋₈ alkyl, and where R⁶³ and R⁶⁴ they are other than C₁₋₈ alkyl in at least one instance; A⁶ and A⁸ represent, independently of each other, a group CR⁶⁵R en, where R grupo and R grupo in the group CR⁶⁵R⁶⁶ have, independently of each other, the meanings according to the following definitions; A⁷ represents a direct bond, O (oxygen), NH or the groups CR⁷¹R⁷², OCR⁶⁷R⁶⁸, (N-R⁶⁹) CR⁶⁷R⁶⁸, CR⁷³R⁷⁴CR⁷⁵R⁷⁶, CR⁷¹R⁷²CR⁷³R⁷⁴CR⁷⁵R⁷⁶, OCR⁷⁷R⁷⁸CR⁷⁹R⁸⁰, CR⁷⁷R⁷⁸OCR⁷⁹R⁸⁰, (N-R⁶⁹) CR⁷⁷R-CR⁷⁵R⁷⁹, (N-R⁶⁹) CR⁷⁷R-CR⁷⁵R⁷⁹ -R⁶⁹, where R⁶⁷, R⁶⁸, R⁶⁹, R⁷⁰, R⁷¹, R⁷², R⁷³ R⁷⁴, R⁷⁵, R⁷⁶, R⁷⁷, R⁷⁸, R⁷⁹ and R⁸⁰ in the groups CR⁷¹R⁷², OCR⁶⁷R⁶⁸, (N-R⁶⁹) CR⁶⁷R⁶⁸, CR⁷³R⁷⁴CR⁷⁵R⁷⁶, CR⁷¹R⁷²CR⁷³R⁷⁴CR⁷⁵R⁷⁶, CR⁷¹R⁷²CR⁷³R⁷⁴CR⁷⁵R⁷⁶ , CR⁷⁷R⁷⁸OCR⁷⁹R⁸⁰, (N-R⁶⁹) CR⁷⁷R⁷⁸CR⁷⁹R⁸⁰, CR⁷⁷R⁷⁸ (N-R⁶⁹) CR⁷⁹R⁸⁰, N-R⁶⁹ have, independently of each other, the meanings according to the preceding or following definitions; R⁶⁵ and R⁶⁶ represent, independently of one another, hydrogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₁₋₈ haloalkyl; R⁶⁷, R⁶⁸, R⁷⁷, R⁷⁸, R⁷⁹ and R⁸⁰ represent, independently of each other, hydrogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₁₋₈ haloalkyl, C₁₋₈ alkoxy-C₁₋₈ alkyl, aryl, aryl- C₁₋₈ alkyl; R⁷⁰ represents hydrogen, C₁₋₈ alkyl, C₃₋₈ cycloalkyl-C₁₋₈ alkyl, C₂₋₈ alkenyl, C₂₋₈ alkynyl, C₁₋₈ alkoxy-C₁₋₈ alkyl, C₁₋₈ haloalkoxy-C₁₋₈ alkyl, alkyl C₁₋₈-thio-C₁₋₈ alkyl, aryl, aryl-C₁₋₈ alkyl, R⁸⁵O (O) C-C₁₋₈ alkyl, R⁸³R⁸⁴N (O) C-C₁₋₈ alkyl; R¹⁴ and R⁶⁹ in the case that X represents N-R⁶⁹, form with the nitrogen atom, to which they are attached, a monocyclic or bicyclic ring of 4 to 10 members completely saturated or optionally interrupted by heteroatoms and optionally substituted, or R¹⁴ and R⁷⁰ in the case that X represents NO-R⁷⁰, form with the nitrogen atom, to which they are attached, a completely saturated and optionally substituted 4 to 10 membered monocyclic or bicyclic ring; R⁷¹ and R⁷² represent, independently of each other, hydrogen, halogen, hydroxy, C₁₋₈ alkyl, C₃₋₈ cycloalkyl, C₁₋₈ haloalkyl, C₂₋₈ alkenyl, C₁₋₈ alkynyl, C₁₋₈ alkoxy, haloalkoxy

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