AR107450A1 - MOLECULES THAT HAVE PESTICIDE USEFULNESS, COMPOSITIONS AND PROCESSES RELATED TO THE SAME - Google Patents

MOLECULES THAT HAVE PESTICIDE USEFULNESS, COMPOSITIONS AND PROCESSES RELATED TO THE SAME

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Publication number
AR107450A1
AR107450A1 ARP170100195A ARP170100195A AR107450A1 AR 107450 A1 AR107450 A1 AR 107450A1 AR P170100195 A ARP170100195 A AR P170100195A AR P170100195 A ARP170100195 A AR P170100195A AR 107450 A1 AR107450 A1 AR 107450A1
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AR
Argentina
Prior art keywords
alkyl
group
haloalkyl
alkoxy
molecules
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ARP170100195A
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Spanish (es)
Inventor
John Herbert
Gerald B Watson
Raghuram Tangirala
Joshodeep Boruwa
William C Lo
Jim Hunter
Xin Gao
Thomas Barton
Paul Renee Lplae
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Dow Agrosciences Llc
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Application filed by Dow Agrosciences Llc filed Critical Dow Agrosciences Llc
Publication of AR107450A1 publication Critical patent/AR107450A1/en

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Abstract

La presente se relaciona con el campo de moléculas que tienen utilidad de plaguicidas contra las plagas en la Phyla Arthropoda Mollusca y Nematoda, procesos para producir estas moléculas, productos intermedios utilizados en dichos procesos, composiciones que contienen dichas moléculas y procesos del uso de dichas moléculas y composiciones contra estas plagas. Estas moléculas y composiciones se pueden utilizar por ejemplo, como acaricidas, insecticidas, miticidas, molusquicidas y nematicidas. Reivindicación 1: Una molécula que tiene la fórmula (1), en donde: (A) R¹, R⁵, R⁶, R⁹, y R¹² cada uno se seleccionan independientemente del grupo que consiste en H, F, Cl, Br, I, CN, C₁₋₄ alquilo, C₁₋₄ haloalquilo, C₁₋₄ alcoxi, y C₁₋₄ haloalcoxi; (B) R² se selecciona del grupo que consiste en H, F, Cl, Br, I, CN, C₁₋₄ alquilo, C₁₋₄ haloalquilo, C₁₋₄ alcoxi, y C₁₋₄ haloalcoxi; (C) R³ y R⁴ cada uno se seleccionan independientemente del grupo que consiste en (D), H, F, Cl, Br, I, CN, C(O)H, C₁₋₄ alquilo, C₂₋₄ alquenilo, C₂₋₄ alquinilo, C₁₋₄ haloalquilo, C₁₋₄ alcoxi y C₁₋₄ haloalcoxi; (D) R³ y R⁴ juntos opcionalmente pueden formar un enlace de 3 a 5 miembros saturados o no saturados, enlace de heterohidrocarbil, que puede contener uno o más heteroátomos seleccionados del grupo que consiste en nitrógeno, azufre y oxígeno, en donde dicho enlace de heterohidrocarbil puede estar opcionalmente sustituido con uno o más sustituyentes seleccionados independientemente del grupo que consiste en H, F, Cl, Br, I, CN y OH; (E) R⁷ es C₁₋₆ haloalquilo; (F) R⁸ se selecciona del grupo que consiste en H, C₁₋₄ alquilo, C₁₋₄ haloalquilo y C₁₋₄ alcoxi; (G) R¹⁰ se selecciona del grupo que consiste en F, Cl, Br, I, C₁₋₄ alquilo, C₂₋₄ alquenilo, C₂₋₄ alquinilo, C₁₋₄ haloalquilo, C₁₋₄ alcoxi y C₁₋₄ haloalcoxi; (H) R¹¹ se selecciona del grupo que consiste en H, F, Cl, Br, I, C₁₋₄ alquilo, o C₁₋₄ haloalquilo; (I) L es un enlazador que se selecciona del grupo que consiste en C₁₋₈ alquilo, C₁₋₄ alcoxi, C₃₋₆ cicloalquilo-C₁₋₄ alquilo, C₁₋₄ alquilo-C₃₋₆ cicloalcoxi, C₁₋₄ alquilo-S-C₁₋₄ alquilo, C₁₋₄ alquilo-S(O)-C₁₋₄ alquilo, y C₁₋₄ alquilo-S(O)₂-C₁₋₄ alquilo, en donde cada alquilo, alcoxi y cicloalquilo se pueden sustituir opcionalmente con uno o más sustituyentes seleccionados independientemente del grupo que consiste en F, Cl, Br, I, CN, OH, oxetanil, C(=O)NHC₁₋₄ haloalquilo, y C₁₋₄ alcoxi; (J) n se selecciona del grupo que consiste en 0, 1 y 2; (K) R¹³ se selecciona del grupo que consiste en C₁₋₄ alquilo, C₂₋₄ alquenilo, C₁₋₄ haloalquilo, C₁₋₄ alcoxi, C₁₋₄ haloalcoxi, fenil, benzil, C₁₋₄ alquilo-C₃₋₆ cicloalquilo, y NHC₁₋₄ haloalquilo, en donde cada alquilo, alquenilo, haloalquilo, alcoxi, haloalcoxi, fenil y cicloalquilo se pueden sustituir opcionalmente con uno o más sustituyentes seleccionados independientemente del grupo que consiste en F, Cl, Br, I, CN, y OH; y sales de adición de ácido agrícolamente aceptables, derivados de la sal, solvatos, derivados de ésteres, polimorfos cristalinos, isótopos, estereoisómeros resueltos y tautómeros, de las moléculas de la fórmula (1).This is related to the field of molecules that are useful for pesticides against pests in Phyla Arthropoda Mollusca and Nematoda, processes to produce these molecules, intermediate products used in said processes, compositions containing said molecules and processes for the use of said molecules and compositions against these pests. These molecules and compositions can be used, for example, as acaricides, insecticides, miticides, molluscicides and nematicides. Claim 1: A molecule having the formula (1), wherein: (A) R¹, R⁵, R⁶, R⁹, and R¹² are each independently selected from the group consisting of H, F, Cl, Br, I, CN , C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, and C₁₋₄ haloalkoxy; (B) R² is selected from the group consisting of H, F, Cl, Br, I, CN, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, and C₁₋₄ haloalkoxy; (C) R³ and R⁴ are each independently selected from the group consisting of (D), H, F, Cl, Br, I, CN, C (O) H, C₁₋₄ alkyl, C₂₋₄ alkenyl, C₂₋ ₄ alkynyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy and C₁₋₄ haloalkoxy; (D) R³ and R⁴ together may optionally form a 3 to 5 saturated or unsaturated, heterohydrocarbyl bond, which may contain one or more heteroatoms selected from the group consisting of nitrogen, sulfur and oxygen, wherein said bond of heterohydrocarbyl may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN and OH; (E) R⁷ is C₁₋₆ haloalkyl; (F) R⁸ is selected from the group consisting of H, C₁₋₄ alkyl, C₁₋₄ haloalkyl and C₁₋₄ alkoxy; (G) R¹⁰ is selected from the group consisting of F, Cl, Br, I, C₁₋₄ alkyl, C₂₋₄ alkenyl, C₂₋₄ alkynyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy and C₁₋₄ haloalkoxy; (H) R¹¹ is selected from the group consisting of H, F, Cl, Br, I, C₁₋₄ alkyl, or C₁₋₄ haloalkyl; (I) L is a linker that is selected from the group consisting of C₁₋₈ alkyl, C₁₋₄ alkoxy, C₃₋₆ cycloalkyl-C₁₋₄ alkyl, C₁₋₄ alkyl-C₃₋₆ cycloalkoxy, C₁₋₄ alkyl- S-C₁₋₄ alkyl, C₁₋₄ alkyl-S (O) -C₁₋₄ alkyl, and C₁₋₄ alkyl-S (O) ₂-C₁₋₄ alkyl, where each alkyl, alkoxy and cycloalkyl can be substituted optionally with one or more substituents independently selected from the group consisting of F, Cl, Br, I, CN, OH, oxetanil, C (= O) NHC₁₋₄ haloalkyl, and C₁₋₄ alkoxy; (J) n is selected from the group consisting of 0, 1 and 2; (K) R¹³ is selected from the group consisting of C₁₋₄ alkyl, C₂₋₄ alkenyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, phenyl, benzyl, C₁₋₄ alkyl-C₃₋₆ cycloalkyl, and NHC₁₋₄ haloalkyl, wherein each alkyl, alkenyl, haloalkyl, alkoxy, haloalkoxy, phenyl and cycloalkyl may optionally be substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, I, CN, and OH ; and agriculturally acceptable acid addition salts, salt derivatives, solvates, ester derivatives, crystalline polymorphs, isotopes, resolved stereoisomers and tautomers, of the molecules of the formula (1).

ARP170100195A 2016-01-25 2017-01-25 MOLECULES THAT HAVE PESTICIDE USEFULNESS, COMPOSITIONS AND PROCESSES RELATED TO THE SAME AR107450A1 (en)

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US201662286535P 2016-01-25 2016-01-25

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AR107450A1 true AR107450A1 (en) 2018-05-02

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