AR100192A1 - 3-PHENYL-4-FLUOROBENZOIL PIRAZOLES SUBSTITUTED HERBICIDE COMPOUNDS - Google Patents

3-PHENYL-4-FLUOROBENZOIL PIRAZOLES SUBSTITUTED HERBICIDE COMPOUNDS

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Publication number
AR100192A1
AR100192A1 ARP150101257A ARP150101257A AR100192A1 AR 100192 A1 AR100192 A1 AR 100192A1 AR P150101257 A ARP150101257 A AR P150101257A AR P150101257 A ARP150101257 A AR P150101257A AR 100192 A1 AR100192 A1 AR 100192A1
Authority
AR
Argentina
Prior art keywords
optionally substituted
alkyl
haloalkyl
haloalkenyl
cycloalkylalkyl
Prior art date
Application number
ARP150101257A
Other languages
Spanish (es)
Inventor
Paul Selby Thomas
Andrew Travis David
Duncan Satterfield Andrew
Ryan Deprez Nicholas
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of AR100192A1 publication Critical patent/AR100192A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/28—Two oxygen or sulfur atoms
    • C07D231/30—Two oxygen or sulfur atoms attached in positions 3 and 5
    • C07D231/32—Oxygen atoms
    • C07D231/36—Oxygen atoms with hydrocarbon radicals, substituted by hetero atoms, attached in position 4

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

La presente solicitud describe compuestos, las composiciones que contienen los compuestos y los métodos para controlar vegetación indeseada o su medio ambiente; el método comprende la etapa de poner la vegetación indeseada o su medio ambiente en contacto con una cantidad eficaz de un compuesto o una composición de la presente. Reivindicación 1: Un compuesto seleccionado de la fórmula (1), N-óxidos y sales de estos, caracterizado porque X¹ es halógeno, -CF₃, -CF₂H, -OCF₃, -OCF₂H, -SCHF₂ o -CºCH; X² es halógeno, -CF₃, -CF₂H, -OCF₃, -OCF₂H, -SCHF₂ o -CºCH; X³ es H o halógeno; n es 1, 2, 3, 4 ó 5; P es H, alquilo C₁₋₇, alquenilo C₃₋₇, alquinilo C₃₋₇, cicloalquilo C₃₋₇, haloalquilo C₁₋₇, haloalquenilo C₂₋₇, haloalquinilo C₃₋₇, alcoxialquilo C₂₋₇, cicloalquilalquilo C₄₋₇, alcoxi C₁₋₇, alcoxialcoxialquilo C₃₋₇, alquilcarbonilalquilo C₃₋₇, alcoxicarbonilalquilo C₃₋₇, halocicloalquilalquilo C₄₋₇, haloalcoxialquilo C₂₋₇, alquiltioalquilo C₂₋₇, alquilsulfonilalquilo C₂₋₇, alquilsulfinilalquilo C₂₋₇, haloalquiltioalquilo C₂₋₇, haloalquilsulfonilalquilo C₂₋₇, haloalquilsulfinilalquilo C₂₋₇, haloalcoxicarbonilalquilo C₃₋₇, haloalquilcarbonilalquilo C₃₋₇, alquilaminoalquilo C₂₋₇, dialquilaminoalquilo C₃₋₇, cianoalquilo C₂₋₇, nitroalquilo C₁₋₇, amino, hidroxilo, CH₂OH, C(=O)R¹, SO₂R², C(=O)NR³R⁴, SO₂NR³R⁴, CO₂R⁵, CH(OR⁶)₂, CH(CO₂CH₃)₂ o CH(CO₂C₂H₅)₂; R¹ es H, alquilo C₁₋₇, alquenilo C₂₋₇, alquinilo C₂₋₇, cicloalquilo C₃₋₇, haloalquilo C₁₋₇, haloalquenilo C₃₋₇, alcoxialquilo C₂₋₇ o cicloalquilalquilo C₄₋₇; o fenilo opcionalmente sustituido con R⁷; o bencilo opcionalmente sustituido en miembros del anillo con R⁷; o piridilo opcionalmente sustituido con R⁷; R² es H, alquilo C₁₋₇, alquenilo C₂₋₇, alquinilo C₂₋₇, cicloalquilo C₃₋₇, haloalquilo C₁₋₇, haloalquenilo C₃₋₇, alcoxialquilo C₂₋₇ o cicloalquilalquilo C₄₋₇; o fenilo opcionalmente sustituido con R⁷; o bencilo opcionalmente sustituido en miembros del anillo con R⁷; o piridilo opcionalmente sustituido con R⁷; R³ es H, alquilo C₁₋₇, alquenilo C₂₋₇, alquinilo C₂₋₇, cicloalquilo C₃₋₇, haloalquilo C₁₋₇, haloalquenilo C₃₋₇, alcoxialquilo C₂₋₇ o cicloalquilalquilo C₄₋₇; o fenilo opcionalmente sustituido con R⁷; o bencilo opcionalmente sustituido en miembros del anillo con R⁷; o piridilo opcionalmente sustituido con R⁷; R⁴ es H o alquilo C₁₋₄; R⁵ es alquilo C₁₋₇, alquenilo C₃₋₇, alquinilo C₃₋₇, cicloalquilo C₃₋₇, haloalquilo C₂₋₇, haloalquenilo C₃₋₇, alcoxialquilo C₂₋₇ o cicloalquilalquilo C₄₋₇; o fenilo opcionalmente sustituido con R⁷; o bencilo opcionalmente sustituido en miembros del anillo con R⁷; o piridilo opcionalmente sustituido con R⁷; R⁶ es alquilo C₁₋₃; o dos R⁶ se toman conjuntamente como -(CH₂)₂-, -(CH₂)₃- o -CH₂CH(CH₃)- para formar un anillo; y R⁷ es halógeno, ciano, alquilo C₁₋₂, haloalquilo C₁₋₃, haloalcoxi C₁₋₃ o alcoxi C₁₋₃.The present application describes compounds, the compositions containing the compounds and the methods for controlling unwanted vegetation or its environment; The method comprises the step of putting the unwanted vegetation or its environment in contact with an effective amount of a compound or a composition of the present. Claim 1: A compound selected from the formula (1), N-oxides and salts thereof, characterized in that X¹ is halogen, -CF₃, -CF₂H, -OCF₃, -OCF₂H, -SCHF₂ or -CºCH; X² is halogen, -CF₃, -CF₂H, -OCF₃, -OCF₂H, -SCHF₂ or -CºCH; X³ is H or halogen; n is 1, 2, 3, 4 or 5; P is H, C₁₋₇ alkyl, C₃₋₇ alkenyl, C₃₋₇ alkynyl, C₃₋₇ cycloalkyl, C₁₋₇ haloalkyl, C₃₋₇ haloalkenyl, C₂₋₇ alkoxyalkyl, C₄₋₇ cycloalkylalkyl, alkoxy C₁₋₇, alkoxyalkoxyalkyl C₃₋₇, alkylcarbonylalkyl C₃₋₇, alkoxycarbonylalkyl C₃₋₇, halocycloalkylalkyl C₄₋₇, haloalkoxyalkyl C₂₋₇, alkylthioalkyl C₂₋₇, alkylsulfonylalkyl C₂₋₇, alkylsulfinylalkyl C₂₋₇, haloalkyl alkyl alkylalkyl C₂₋₇, haloalkylsulfinylalkyl C₂₋₇, haloalkoxycarbonylalkyl C₃₋₇, haloalkylcarbonylalkyl C₃₋₇, alkylaminoalkyl C₂₋₇, dialkylaminoalkyl C₃₋₇, cyanoalkyl C₂₋₇, nitroalkyl C₁₋₇, amino, hydroxyl, CH₂OH, C (= O) R¹, SO₂R², C (= O) NR³R⁴, SO₂NR³R⁴, CO₂R⁵, CH (OR⁶) ₂, CH (CO₂CH₃) ₂ or CH (CO₂C₂H₅) ₂; R¹ is H, C₁₋₇ alkyl, C₂₋₇ alkenyl, C₂₋₇ alkynyl, C₃₋₇ cycloalkyl, C₁₋₇ haloalkyl, C₃₋₇ haloalkenyl, C₂₋₇ alkoxyalkyl or C₄₋₇ cycloalkylalkyl; or phenyl optionally substituted with R⁷; or optionally substituted benzyl in ring members with R⁷; or pyridyl optionally substituted with R⁷; R² is H, C₁₋₇ alkyl, C₂₋₇ alkenyl, C₂₋₇ alkynyl, C₃₋₇ cycloalkyl, C₁₋₇ haloalkyl, C₃₋₇ haloalkenyl, C₂₋₇ alkoxyalkyl or C₄₋₇ cycloalkylalkyl; or phenyl optionally substituted with R⁷; or optionally substituted benzyl in ring members with R⁷; or pyridyl optionally substituted with R⁷; R³ is H, C₁₋₇ alkyl, C₂₋₇ alkenyl, C₂₋₇ alkynyl, C₃₋₇ cycloalkyl, C₁₋₇ haloalkyl, C₃₋₇ haloalkenyl, C₂₋₇ alkoxyalkyl or C₄₋₇ cycloalkylalkyl; or phenyl optionally substituted with R⁷; or optionally substituted benzyl in ring members with R⁷; or pyridyl optionally substituted with R⁷; R⁴ is H or C₁₋₄ alkyl; R⁵ is C₁₋₇ alkyl, C₃₋₇ alkenyl, C₃₋₇ alkynyl, C₃₋₇ cycloalkyl, C₂₋₇ haloalkyl, C₃₋₇ haloalkenyl, C₂₋₇ alkoxyalkyl or C₄₋₇ cycloalkylalkyl; or phenyl optionally substituted with R⁷; or optionally substituted benzyl in ring members with R⁷; or pyridyl optionally substituted with R⁷; R⁶ is C₁₋₃ alkyl; or two R⁶ are taken together as - (CH₂) ₂-, - (CH₂) ₃- or -CH₂CH (CH₃) - to form a ring; and R⁷ is halogen, cyano, C₁₋₂ alkyl, C₁₋₃ haloalkyl, C₁₋₃ haloalkoxy or C₁₋₃ alkoxy.

ARP150101257A 2014-04-28 2015-04-27 3-PHENYL-4-FLUOROBENZOIL PIRAZOLES SUBSTITUTED HERBICIDE COMPOUNDS AR100192A1 (en)

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US201461985430P 2014-04-28 2014-04-28

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AR100192A1 true AR100192A1 (en) 2016-09-14

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AR (1) AR100192A1 (en)
TW (1) TW201620879A (en)
WO (1) WO2015167795A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015179038A2 (en) 2014-05-23 2015-11-26 E. I. Du Pont De Nemours And Company Sulfonyl hydrazide compounds and a regio-selective process to prepare 4-aroyl pyrazole derivatives
WO2023137309A2 (en) 2022-01-14 2023-07-20 Enko Chem, Inc. Protoporphyrinogen oxidase inhibitors

Family Cites Families (21)

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Publication number Priority date Publication date Assignee Title
US2891855A (en) 1954-08-16 1959-06-23 Geigy Ag J R Compositions and methods for influencing the growth of plants
US3235361A (en) 1962-10-29 1966-02-15 Du Pont Method for the control of undesirable vegetation
US3060084A (en) 1961-06-09 1962-10-23 Du Pont Improved homogeneous, readily dispersed, pesticidal concentrate
US3299566A (en) 1964-06-01 1967-01-24 Olin Mathieson Water soluble film containing agricultural chemicals
US3309192A (en) 1964-12-02 1967-03-14 Du Pont Method of controlling seedling weed grasses
US4144050A (en) 1969-02-05 1979-03-13 Hoechst Aktiengesellschaft Micro granules for pesticides and process for their manufacture
US3920442A (en) 1972-09-18 1975-11-18 Du Pont Water-dispersible pesticide aggregates
US4172714A (en) 1976-12-20 1979-10-30 E. I. Du Pont De Nemours And Company Dry compactible, swellable herbicidal compositions and pellets produced therefrom
GB2095558B (en) 1981-03-30 1984-10-24 Avon Packers Ltd Formulation of agricultural chemicals
DE3246493A1 (en) 1982-12-16 1984-06-20 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING WATER-DISPERSIBLE GRANULES
US5180587A (en) 1988-06-28 1993-01-19 E. I. Du Pont De Nemours And Company Tablet formulations of pesticides
EP0777964B1 (en) 1989-08-30 2001-11-14 Kynoch Agrochemicals (Proprietary) Limited Preparation of a dosage device
ES2065680T3 (en) 1990-03-12 1995-02-16 Du Pont PESTICIDE GRANULES DISPERSIBLE IN WATER OR SOLUBLE IN WATER FROM HEAT ACTIVATED BINDERS.
DE69122201T2 (en) 1990-10-11 1997-02-06 Sumitomo Chemical Co Pesticides composition
EP0822187A4 (en) 1995-02-07 1998-05-13 Nissan Chemical Ind Ltd Pyrazole derivatives and herbicides
TW200724033A (en) 2001-09-21 2007-07-01 Du Pont Anthranilamide arthropodicide treatment
TW200738701A (en) 2005-07-26 2007-10-16 Du Pont Fungicidal carboxamides
BR112012020311B1 (en) 2010-02-17 2019-01-29 Takeda Pharmaceutical Company Limited fused heterocyclic compound having a strong cell division cycle 7 inhibitory activity (cdc7), and, medicament comprising the same
WO2013062887A1 (en) 2011-10-26 2013-05-02 Merck Sharp & Dohme Corp. Substituted pyridine derivatives useful as gpr131 agonists
US8822464B2 (en) 2011-11-28 2014-09-02 Boehringer Ingelheim International Gmbh N-aryl-piperazine derivatives and their use as positive allosteric modulators of mGluR5 receptors
AU2013277368A1 (en) * 2012-06-22 2015-01-15 E. I. Du Pont De Nemours And Company Fungicidal 4-methylanilino pyrazoles

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WO2015167795A1 (en) 2015-11-05

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