AR096672A1 - Compuestos de tipo estrobilurina para combatir hongos fitopatogénicos - Google Patents

Compuestos de tipo estrobilurina para combatir hongos fitopatogénicos

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Publication number
AR096672A1
AR096672A1 ARP140102336A ARP140102336A AR096672A1 AR 096672 A1 AR096672 A1 AR 096672A1 AR P140102336 A ARP140102336 A AR P140102336A AR P140102336 A ARP140102336 A AR P140102336A AR 096672 A1 AR096672 A1 AR 096672A1
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AR
Argentina
Prior art keywords
alkyl
cycloalkyl
alkoxy
groups
halogen
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ARP140102336A
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English (en)
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Basf Se
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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Abstract

Reivindicación 1: Compuestos caracterizados porque tienen la fórmula (1) en donde: R¹ es halógeno, ciano, C₁₋₆-alquilo, C₁₋₆-alcoxi, C₂₋₆-alquenilo, C₂₋₆-alqueniloxi, C₂₋₆-alquinilo, C₃₋₆-alquiniloxi, C₁₋₆-alquiltio, C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfonilo, C₃₋₆-cicloalquilo o C₃₋₆-cicloalquil-C₁₋₄-alquilo; en donde las porciones alifáticas de R¹ son no sustituidas o sustituidas con 1, 2, 3 o hasta la cantidad máxima de grupos R¹ᵃ idénticos o diferentes; en donde R¹ᵃ es halógeno, hidroxi, ciano, nitro, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₁₋₄-haloalquilo o C₁₋₄-haloalcoxi; R² es halógeno, hidroxi, ciano, C₁₋₆-alquilo, C₁₋₆-alcoxi, C₂₋₆-alquenilo, C₂₋₆-alqueniloxi, C₂₋₆-alquinilo, C₃₋₆-alquiniloxi, C₃₋₆-cicloalquilo o C₃₋₆-cicloalquil-C₁₋₄-alquilo; en donde las porciones alifáticas de R² son no sustituidas o sustituidas con 1, 2, 3 o hasta la cantidad máxima de grupos R²ᵃ idénticos o diferentes; en donde R²ᵃ es halógeno, hidroxi, ciano, nitro, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₁₋₄-haloalquilo o C₁₋₄-haloalcoxi; r es 0, 1, 2 ó 3; L es un grupo divalente seleccionado de -OCH₂-, -CH₂- y -CH₂CH₂-, en donde el enlace representado en el lado izquierdo del grupo -OCH₂- está unido a R³, y el enlace representado en el lado derecho está unido al anillo de fenilo; R³ es fenilo o un heterociclo aromático de 5 ó 6 miembros, en donde los átomos miembros del anillo del heterociclo incluyen, además de átomos de carbono, 1, 2, 3 ó 4 heteroátomos seleccionados independientemente de N, O y S como átomos miembros del anillo; en donde los grupos cíclicos R³ son no sustituidos o sustituidos con 1, 2, 3, 4 o hasta la cantidad máxima posible de grupos R³ᵃ idénticos o diferentes; en donde R³ᵃ es amino, halógeno, hidroxi, nitro, ciano, carboxilo, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquenilo, C₂₋₆-alqueniloxi, C₃₋₆-alquiniloxi, C₁₋₆-alcoxiimino-C₁₋₄-alquilo, C₂₋₆-alqueniloxiimino-C₁₋₄-alquilo, C₃₋₆-alquiniloxiimino-C₁₋₄-alquilo, C₁₋₆-alquilamino, C(=O)-(C₁₋₆-alquilo), C(=O)-(C₁₋₆-alcoxi), fenilo, naftilo o un heterociclo saturado, parcialmente insaturado o aromático monocíclico o bicíclico de 3 a 10 miembros, en donde los átomos del miembro del anillo del heterociclo incluyen además de átomos de carbono 1, 2, 3 ó 4 heteroátomos seleccionados independientemente de N, O y S como átomos miembros del anillo; y en donde 1 ó 2 átomos del miembro del anillo de carbono del carbociclo y heterociclo se pueden reemplazar por 1 ó 2 grupos seleccionados independientemente de C(=O) y C(=S); y en donde los grupos fenilo y heterociclilo R³ᵃ antes mencionados se unen a R³ mediante un enlace directo, un átomo de oxígeno o azufre, los últimos dos átomos forman un enlace entre los dos residuos; y en donde los grupos alifáticos o cíclicos R³ᵃ son no sustituidos o sustituidos con 1, 2, 3 o hasta la cantidad máxima posible de grupos R³ᵇ idénticos o diferentes; en donde R³ᵇ es halógeno, hidroxi, nitro, ciano, carboxilo, C₁₋₆-alquilo, C₁₋₆-alcoxi, C₂₋₆-alquenilo, C₂₋₆-alqueniloxi, C₂₋₆-alquinilo, C₃₋₆-alquiniloxi, C₁₋₆-alcoxiimino-C₁₋₄-alquilo, C₂₋₆-alqueniloxiimino-C₁₋₄-alquilo, C₃₋₆-alquiniloxiimino-C₁₋₄-alquilo, C₁₋₆-alquiltio, C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfonilo, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquenilo, fenilo o un heterociclo saturado, parcialmente insaturado o aromático de 5 ó 6 miembros; en donde los átomos miembros del anillo del heterociclo incluyen, además de átomos de carbono, 1, 2 ó 3 heteroátomos seleccionados independientemente de N, O y S como átomos miembros del anillo; y en donde 1 ó 2 átomos miembros del anillo de carbono del carbociclo o heterociclo se pueden reemplazar por 1 ó 2 grupos seleccionados independientemente de C(=O) y C(=S); y en donde los grupos R³ᵇ cíclicos se unen a R³ᵃ mediante un enlace directo, un átomo de oxígeno o azufre, en donde los últimos dos átomos forman un ligador entre dichos residuos; y en donde los grupos R³ᵇ alifáticos o cíclicos son no sustituidos o sustituidos con 1, 2 ó 3 o hasta la cantidad máxima posible de grupos idénticos o diferentes seleccionados de halógeno, C₁₋₆-alquilo y C₁₋₆-haloalquilo; Q es un grupo divalente seleccionado de -O-, -S-, -(NQᵃ)-, -(CQᵇQᶜ)-, -C(=N-O-Qᵃ)-, -C(=O)- y -C(=S)-; en donde Qᵃ es hidrógeno, C₁₋₆-alquilo, C₁₋₆-alcoxi, C₂₋₆-alquenilo, C₂₋₆-alqueniloxi, C₂₋₆-alquiniloxi, C₂₋₆-alquinilo, C₃₋₆-cicloalquilo, fenilo-C₁₋₄-alquilo, heteroaril-C₁₋₄-alquilo o C₃₋₆-cicloalquil-C₁₋₄-alquilo; en donde las porciones alifáticas de Qᵃ son no sustituidas o sustituidas con 1, 2, 3 o hasta la cantidad máxima de grupos idénticos o diferentes seleccionados de halógeno, hidroxi, ciano, nitro, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₁₋₄-haloalquilo y C₁₋₄-haloalcoxi; Qᵇ, Qᶜ se seleccionan independientemente de hidrógeno, halógeno, ciano, C₁₋₆-alquilo, C₁₋₆-alcoxi, C₂₋₆-alquenilo, C₂₋₆-alqueniloxi, C₂₋₆-alquiniloxi, C₂₋₆-alquinilo, C₃₋₆-cicloalquilo y C₃₋₆-cicloalquil-C₁₋₄-alquilo; en donde las porciones alifáticas de Qᵇ y/o Qᶜ son no sustituidas o sustituidas con 1, 2, 3 o hasta la cantidad máxima de grupos idénticos o diferentes seleccionados de halógeno, hidroxi, ciano, nitro, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₁₋₄-haloalquilo y C₁₋₄-haloalcoxi; o Qᵇ y Qᶜ, junto con el átomo de carbono al que están unidos forman un carbociclo saturado o parcialmente insaturado de 3, 4, 5, 6 ó 7 miembros o un heterociclo saturado o parcialmente insaturado de 3. 4, 5, 6 ó 7 miembros, en donde el heterociclo incluye, además de átomos de carbono, 1, 2, 3 ó 4 heteroátomos seleccionados independientemente de N, O y S como átomos miembros del anillo; y en donde 1 ó 2 átomos miembros del anillo de carbono del carbociclo o heterociclo se pueden reemplazar por 1 ó 2 grupos seleccionados independientemente de C(=O) y C(=S); y en donde el carbociclo y heterociclo son no sustituidos o sustituidos con 1, 2, 3 ó 4 grupos idénticos o diferentes seleccionados de halógeno, hidroxi, ciano, nitro, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₁₋₄-haloalquilo y C₁₋₄-haloalcoxi; RN es hidrógeno, C₁₋₆-alquilo, C₁₋₆-alcoxi, C₃₋₆-cicloalquilo, fenil-C₁₋₄-alquilo, heteroaril-C₁₋₄-alquilo, (C=O)-(C₁₋₆-alquilo) o (C=O)-(C₁₋₆-alcoxi); en donde las porciones alifáticas de RN son no sustituidas o sustituidas con 1, 2, 3 o hasta la cantidad máxima de grupos RNᵃ idénticos o diferentes; en donde RNᵃ es halógeno, hidroxi, ciano, nitro, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₃₋₆-cicloalquilo, C₁₋₄-haloalquilo o C₁₋₄-haloalcoxi; W es O ó S; Y es hidrógeno, hidroxi, amino, C₁₋₆-alquilo, C₁₋₆-alcoxi, C₂₋₆-alquenilo C₂₋₆-alqueniloxi, C₂₋₆-alquinilo, C₃₋₆-alquiniloxi, C₃₋₆-cicloalquilo, C₃₋₆-cicloalcoxi, C₁₋₆-alquilamino, C₁₋₆-alquilamino, C₁₋₆-dialquilamino C₃₋₆-cicloalquilamino o C₃₋₆-dicicloalquilamino; en donde las porciones alifáticas y cíclicas de Y son no sustituidas o sustituidas con 1, 2, 3 o hasta la cantidad máxima de grupos idénticos o diferentes seleccionados de halógeno, ciano, nitro, C₁₋₄-alquilo, C₁₋₄-alcoxi,
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