AR090855A1 - HYDROGENATION CATALYSTS, METHOD FOR PREPARING THEM AND USES OF THE SAME TO PREPARE HYDROGEN PEROXIDE - Google Patents

HYDROGENATION CATALYSTS, METHOD FOR PREPARING THEM AND USES OF THE SAME TO PREPARE HYDROGEN PEROXIDE

Info

Publication number
AR090855A1
AR090855A1 ARP130101404A ARP130101404A AR090855A1 AR 090855 A1 AR090855 A1 AR 090855A1 AR P130101404 A ARP130101404 A AR P130101404A AR P130101404 A ARP130101404 A AR P130101404A AR 090855 A1 AR090855 A1 AR 090855A1
Authority
AR
Argentina
Prior art keywords
catalyst
weight
support
hydrogen peroxide
preparing
Prior art date
Application number
ARP130101404A
Other languages
Spanish (es)
Inventor
Dournel Pierre
Lemaire Arnaud
Ganhy Jean-Pierre
Original Assignee
Solvay
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay filed Critical Solvay
Publication of AR090855A1 publication Critical patent/AR090855A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/035—Precipitation on carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/022—Preparation from organic compounds
    • C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Un catalizador de hidrogenación basado en paladio sobre un soporte de óxido de silicio (SiO₂), sobre un soporte de óxido de aluminio (Al₂O₃), o sobre un soporte de aluminosilicato, en donde el catalizador comprende una cantidad de paladio entre 1,5 y 2,5% en peso con respecto al peso del catalizador y una cantidad de plata entre 0,1 y 0,5% en peso con respecto al peso del catalizador, y en donde preferentemente el catalizador además comprende oro en una cantidad de hasta 0,1% en peso con respecto al peso del catalizador. El soporte preferido en una forma de realización de la presente es un soporte de óxido de aluminio d (d-Al₂O₃). El catalizador se puede usar en múltiples tipos de hidrogenación, y preferentemente se propone el catalizador para usar en la fabricación de peróxido de hidrógeno mediante el proceso de autooxidación.A hydrogenation catalyst based on palladium on a support of silicon oxide (SiO₂), on a support of aluminum oxide (Al₂O₃), or on an aluminosilicate support, wherein the catalyst comprises an amount of palladium between 1.5 and 2.5% by weight with respect to the weight of the catalyst and an amount of silver between 0.1 and 0.5% by weight with respect to the weight of the catalyst, and wherein preferably the catalyst further comprises gold in an amount of up to 0 , 1% by weight with respect to the weight of the catalyst. The preferred support in an embodiment of the present is an aluminum oxide support d (d-Al₂O₃). The catalyst can be used in multiple types of hydrogenation, and preferably the catalyst is proposed for use in the manufacture of hydrogen peroxide by the autoxidation process.

ARP130101404A 2012-04-27 2013-04-25 HYDROGENATION CATALYSTS, METHOD FOR PREPARING THEM AND USES OF THE SAME TO PREPARE HYDROGEN PEROXIDE AR090855A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12165962 2012-04-27

Publications (1)

Publication Number Publication Date
AR090855A1 true AR090855A1 (en) 2014-12-10

Family

ID=48095882

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP130101404A AR090855A1 (en) 2012-04-27 2013-04-25 HYDROGENATION CATALYSTS, METHOD FOR PREPARING THEM AND USES OF THE SAME TO PREPARE HYDROGEN PEROXIDE

Country Status (5)

Country Link
AR (1) AR090855A1 (en)
BR (1) BR112014026394A2 (en)
CL (1) CL2014002910A1 (en)
UY (1) UY34766A (en)
WO (1) WO2013160163A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112018003025A2 (en) * 2015-08-18 2018-09-18 Solvay Gold-containing catalyst for selective deoxygenation of quinone epoxides
CN106179427B (en) * 2016-07-06 2019-06-18 江苏晶晶新材料有限公司 A kind of efficient and long life regenerating anthraquinone degradation products catalyst and preparation method thereof
CN109833869A (en) * 2017-11-29 2019-06-04 中国科学院大连化学物理研究所 A kind of slurry bed hydrogenation catalyst and its preparation method and application
CN108892108A (en) * 2018-09-03 2018-11-27 江山市双氧水有限公司 A kind of process system of hydride storage tank involved in the dilute product process units of hydrogen peroxide
CN115397817A (en) 2020-03-23 2022-11-25 巴斯夫欧洲公司 DIBC-free H for the production of propylene oxide 2 O 2
EP3906998A1 (en) 2020-05-05 2021-11-10 BASF Corporation Supported transition metal nanoparticle catalyst and use thereof as a hydrogenation catalyst
US11712689B2 (en) * 2020-06-08 2023-08-01 University Of South Carolina High activity platinum and nickel yolk-shell catalysts

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2158525A (en) 1935-10-10 1939-05-16 Ig Farbenindustrie Ag Production of hydrogen peroxide
IT360853A (en) 1937-04-07
JPS495120B1 (en) * 1969-10-03 1974-02-05
JP2000510042A (en) 1996-05-14 2000-08-08 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー Catalyst composition having nanoparticulate metal on refractory support
BR9712193A (en) 1996-10-04 1999-08-31 . Hydrogenation catalysts based on palladium, platinum or rhodium, on a support of zirconium and silicon oxides, manufacturing process and use of them, and hydrogen peroxide manufacturing process.
DE19642770A1 (en) 1996-10-16 1998-04-23 Basf Ag Process for the production of hydrogen peroxide
US6346228B1 (en) 1999-02-19 2002-02-12 Council Of Scientific And Industrial Research Hydrophobic multicomponent catalyst useful for direct oxidation of hydrogen to hydrogen peroxide
DE19912733A1 (en) 1999-03-20 2000-09-21 Degussa Process for the production of hydrogen peroxide by direct synthesis
US6448199B1 (en) 2000-09-05 2002-09-10 Council Of Scientific & Industrial Research Hydrophobic composite Pd-membrane catalyst useful for non-hazardous direct oxidation of hydrogen by oxygen to hydrogen peroxide and method of its preparation
US6432376B1 (en) 2000-09-05 2002-08-13 Council Of Scientific & Industrial Research Membrane process for the production of hydrogen peroxide by non-hazardous direct oxidation of hydrogen by oxygen using a novel hydrophobic composite Pd-membrane catalyst
EP1195197B1 (en) 2000-10-06 2015-07-08 Akzo Nobel N.V. Catalyst carrier comprising a fibre paper impregnated with micro fibres, process for its production and its uses
DE10153546A1 (en) 2001-10-30 2003-05-22 Degussa Direct synthesis of hydrogen peroxide and its integration in oxidation processes
US20100152022A1 (en) 2008-12-17 2010-06-17 Qi Sun Catalyst regeneration method

Also Published As

Publication number Publication date
WO2013160163A1 (en) 2013-10-31
UY34766A (en) 2013-09-30
BR112014026394A2 (en) 2017-06-27
CL2014002910A1 (en) 2015-01-30

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