AR081139A1 - HERBICIDE URACILES - Google Patents

HERBICIDE URACILES

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Publication number
AR081139A1
AR081139A1 ARP110101458A AR081139A1 AR 081139 A1 AR081139 A1 AR 081139A1 AR P110101458 A ARP110101458 A AR P110101458A AR 081139 A1 AR081139 A1 AR 081139A1
Authority
AR
Argentina
Prior art keywords
alkyl
ring
elements
halogen
independently
Prior art date
Application number
Other languages
Spanish (es)
Inventor
Thomas Paul Selby
Wonpyo Hong
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of AR081139A1 publication Critical patent/AR081139A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/52—Two oxygen atoms
    • C07D239/54—Two oxygen atoms as doubly bound oxygen atoms or as unsubstituted hydroxy radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring

Abstract

También se describen las composiciones que contienen los compuestos de la Formula 1 y los métodos para controlar la vegetacion no deseada, que comprende poner la vegetacion no deseada, o su entorno, en contacto con una cantidad eficaz de un compuesto o de una composicion de la presente solicitud. Reivindicacion 1: Un compuesto, caracterizado porque se selecciona entre la formula (1), N-oxidos y sus sales, en donde R1 es H, amino o alquilo C1-3; X1 es H o halogeno; X2 es halogeno, ciano, amino, nitro, -CF3 o -C(=S)NH2; W1 es O o S; A es un fenilo, piridinilo o anillo pirimidinilo, el anillo sustituido opcionalmente con hasta 4 sustituyentes seleccionados independientemente de R2; W2 es O, S o N(R9); cada R2 es independientemente halogeno, ciano, alquilo C1-6, haloalquilo C1-6, alcoxi C1-6 o haloalcoxi C1-6; R3 es alquileno C1-3 sustituido con por lo menos un R5; o R3 es -C(=O)-; W3 es O o S; R4 es H, -OR6, -SR6, -NR7R8 u -O-M+; M+ es un cation de metales alcalinos o cation de amonio agrícola adecuado; cada R5 es independientemente halogeno, ciano, hidroxi, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, alquiltio C1-6, alquilamino C1-6, dialquilamino C2-8 o alcoxicarbonilo C2-6; R6 es H, alquilo C1-6, alquenilo C2-6, alquinilo C3-6, haloalquilo C2-6, haloalquenilo C2-6, haloalquinilo C3-6, alcoxialquilo C2-6, alcoxicarboniloalquilo C3-8, alquilamino C1-6, dialquilamino C2-8, -N=C(R10)(R11), dialcoxialquilo C3-10, alcoxialcoxialquilo C3-10, alquiltioalquilo C2-8, alquilsulfiniloalquilo C2-8, alquilsulfoniloalquilo C2-8, cianoalquilo C2-6, trialquilsililo C3-10, trialquilsililo(alquilo) C4-11, trialquilsililo(alquenilo) C5-12, trialquilsililo(alquinilo) C5-12, trialquilsililo(alcoxialquilo) C5-12, alquilcarboniloamino C2-8, haloalcoxialquilo C2-6, haloalcoxicarboniloalquilo C3-8, alquilcarboniloalquilo C3-8, alquenilooxialquilo C3-8, alquenilooxicarboniloalquilo C3-8, haloalquenilooxialquilo C3-8, alquilaminoalquilo C2-6, dialquilaminoalquilo C3-8, aminocarboniloalquilo C2-6, alquilaminoalquilcarboniloalquilo C3-8 o dialquiloaminocarboniloalquilo C3-8; o R6 es GA, -(CR12R13)qTGA, GB o -(CR14R15)uTGB; o R5 y R6 se toman juntos como alquileno C1-3 para forma, incluyendo los átomos para el que dicho R5 y R6 están unidos, a un anillo de 4- a 7 elementos, dicho anillo opcionalmente sustituido con hasta dos sustituyente seleccionados a partir de halogeno, alquilo C1-6 o haloalquilo C1-6; cada q y u es independientemente un numero entero seleccionado entre 1 hasta 4; cada T es independientemente una union directa, -O-, -S- o -N(R18)-; GA es un fenilo o bencilo; o un anillo heteroaromático de 5 a 6 miembros, cada fenilo, bencilo o anillo heteroaromático opcionalmente sustituido con hasta 4 sustituyentes seleccionados independientemente a partir de R16 en elementos de anillo de carbono y R17 en elementos de anillo de nitrogeno; GB es un anillo carbocíclico no aromático o parcialmente aromático de 3 a 7 elementos, seleccionado del grupo que consiste de -N(R17)-, -N=N-, -C(=O)-, -O- y -S-, dicho anillo sustituido opcionalmente con hasta 4 sustituyentes seleccionados a partir de R16; R7 es H, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-8, alcoxicarboniloalquilo C3-8, alcoxi C1-6 o dialquiloaminosulfonilo C2-8; o un anillo fenilo o bencilo, cada uno opcionalmente sustituido con hasta cinco sustituyentes seleccionados entre alquilo C1-3, -CF3 y alcoxi C1-3 en elementos del anillo; R8 es H o alquilo C1-3; o un par de R7 y R8 unidos al mismo átomo de nitrogeno se toman junto con el átomo de nitrogeno para formar un anillo heterocíclico de 3 a 7 elementos que contiene elementos del anillo seleccionados entre átomos de carbono y opcionalmente hasta 3 heteroátomos seleccionados entre hasta 2 O, hasta 2 S y hasta 2 N, el anillo opcionalmente sustituido con hasta 4 sustituyentes independientemente seleccionados a partir de halogeno, ciano, alquilo C1-3 y alcoxi C1-3 en elementos del anillo de átomos de carbono y alquilo C1-3 en elementos del anillo de átomos de nitrogeno; R9 es H o alquilo C1-3; R10 y R11 son cada uno independientemente H o alquilo C1-3; cada R12, R13, R14 y R15 es independientemente H o alquilo C1-3 o un R12 y un R13 se toman juntas como un átomo de oxigeno para formar, con el átomo de carbono al que están unidas dicho un R12 y un R13, una porcion de carbonilo; un R14 y un R15 se toman juntos como un átomo de oxigeno para formar, con el átomo de carbono al que están unidas dicho un R12 y un R13, una porcion de carbonilo; R16 es halogeno alquilo C1-3, -CF3 o alcoxi C1-3; cada R17 es H o alquilo C1-3; y R18 es H o alquilo C1-3.Also described are the compositions containing the compounds of Formula 1 and the methods for controlling unwanted vegetation, which comprises bringing the unwanted vegetation, or its surroundings, into contact with an effective amount of a compound or a composition of the present request Claim 1: A compound, characterized in that it is selected from the formula (1), N-oxides and their salts, wherein R 1 is H, amino or C 1-3 alkyl; X1 is H or halogen; X2 is halogen, cyano, amino, nitro, -CF3 or -C (= S) NH2; W1 is O or S; A is a phenyl, pyridinyl or pyrimidinyl ring, the ring optionally substituted with up to 4 substituents independently selected from R2; W2 is O, S or N (R9); each R2 is independently halogen, cyano, C1-6 alkyl, C1-6 haloalkyl, C1-6 alkoxy or C1-6 haloalkoxy; R3 is C1-3 alkylene substituted with at least one R5; or R3 is -C (= O) -; W3 is O or S; R4 is H, -OR6, -SR6, -NR7R8 or -O-M +; M + is an alkali metal cation or suitable agricultural ammonium cation; each R5 is independently halogen, cyano, hydroxy, C1-6 haloalkyl, C1-6 alkoxy, C1-6 haloalkoxy, C1-6 alkylthio, C1-6 alkylamino, C2-8 dialkylamino or C2-6 alkoxycarbonyl; R6 is H, C1-6 alkyl, C2-6 alkenyl, C3-6 alkynyl, C2-6 haloalkyl, C2-6 haloalkenyl, C3-6 haloalkynyl, C2-6 alkoxyalkyl, C3-8 alkoxycarbonylalkyl, C1-6 alkylamino, dialkylamino C2-8, -N = C (R10) (R11), C3-10 dialkoxyalkyl, C3-10 alkoxyalkoxyalkyl, C2-8 alkylthioalkyl, C2-8 alkylsulfinylalkyl, C2-6 alkylsulfonylalkyl, C3-10alkylalkyl, C4-11 trialkylsilyl (alkyl), C5-12 trialkylsilyl (alkenyl) C5-12 trialkylsilyl (alkynyl), C5-12 trialkylsilyl (alkoxyalkyl) C2-6 alkylcarbonylamino, C3-8 haloalkoxycarbonylC3-8 alkyl, 8, C3-8 alkenyloxyalkyl, C3-8 alkenyloxycarbonylalkyl, C3-8 haloalkenyloxyalkyl, C2-6 alkylaminoalkyl, C3-8 dialkylaminoalkyl, C2-6 alkylaminoalkylcarbonylC3-8alkyl or C3-8alkylcarbonyl; or R6 is GA, - (CR12R13) qTGA, GB or - (CR14R15) uTGB; or R5 and R6 are taken together as C1-3 alkylene for form, including the atoms for which said R5 and R6 are attached, to a ring of 4- to 7 elements, said ring optionally substituted with up to two substituents selected from halogen, C1-6 alkyl or C1-6 haloalkyl; each q and u is independently an integer selected from 1 to 4; each T is independently a direct union, -O-, -S- or -N (R18) -; GA is a phenyl or benzyl; or a 5- to 6-membered heteroaromatic ring, each phenyl, benzyl or heteroaromatic ring optionally substituted with up to 4 substituents independently selected from R16 in carbon ring elements and R17 in nitrogen ring elements; GB is a non-aromatic or partially aromatic carbocyclic ring of 3 to 7 elements, selected from the group consisting of -N (R17) -, -N = N-, -C (= O) -, -O- and -S- , said ring optionally substituted with up to 4 substituents selected from R16; R 7 is H, C 1-6 alkyl, C 2-6 alkenyl, C 2-6 alkynyl, C 3-8 cycloalkyl, C 3-8 alkoxycarbonylalkyl, C 1-6 alkoxy or C 2-8 dialkyloaminosulfonyl; or a phenyl or benzyl ring, each optionally substituted with up to five substituents selected from C1-3 alkyl, -CF3 and C1-3 alkoxy in ring elements; R8 is H or C1-3 alkyl; or a pair of R7 and R8 attached to the same nitrogen atom are taken together with the nitrogen atom to form a heterocyclic ring of 3 to 7 elements containing ring elements selected from carbon atoms and optionally up to 3 heteroatoms selected from up to 2 Or, up to 2 S and up to 2 N, the ring optionally substituted with up to 4 substituents independently selected from halogen, cyano, C1-3 alkyl and C1-3 alkoxy in elements of the carbon atom ring and C1-3 alkyl in ring elements of nitrogen atoms; R9 is H or C1-3 alkyl; R10 and R11 are each independently H or C1-3 alkyl; each R12, R13, R14 and R15 is independently H or C1-3 alkyl or an R12 and an R13 are taken together as an oxygen atom to form, with the carbon atom to which said an R12 and an R13 are attached, a carbonyl portion; an R14 and an R15 are taken together as an oxygen atom to form, with the carbon atom to which said an R12 and an R13 are attached, a carbonyl portion; R16 is halogen C1-3 alkyl, -CF3 or C1-3 alkoxy; each R17 is H or C1-3 alkyl; and R18 is H or C1-3 alkyl.

ARP110101458 2010-04-27 2011-04-27 HERBICIDE URACILES AR081139A1 (en)

Applications Claiming Priority (1)

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US32836710P 2010-04-27 2010-04-27

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AR081139A1 true AR081139A1 (en) 2012-06-27

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Country Status (4)

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AR (1) AR081139A1 (en)
TW (1) TW201141380A (en)
UY (1) UY33357A (en)
WO (1) WO2011137088A1 (en)

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UY33357A (en) 2011-12-01
WO2011137088A1 (en) 2011-11-03
TW201141380A (en) 2011-12-01

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