AR079290A1 - FUNGICIDE BLENDS - Google Patents

FUNGICIDE BLENDS

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Publication number
AR079290A1
AR079290A1 ARP100104093A AR079290A1 AR 079290 A1 AR079290 A1 AR 079290A1 AR P100104093 A ARP100104093 A AR P100104093A AR 079290 A1 AR079290 A1 AR 079290A1
Authority
AR
Argentina
Prior art keywords
independently
haloalkyl
alkoxy
alkyl
alkylcarbonyl
Prior art date
Application number
Other languages
Spanish (es)
Inventor
Andrew Edmund Taggi
Vann Gregory
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of AR079290A1 publication Critical patent/AR079290A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/501,3-Diazoles; Hydrogenated 1,3-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/581,2-Diazines; Hydrogenated 1,2-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

También se describe un método para controlar las enfermedades de las plantas provocadas por patogenos fungicos de la planta que comprende aplicar a la planta o parte de ésta, o a la semilla de la planta, una cantidad eficaz como fungicida de un compuesto de la formula (1), un N-oxido, o sal de éste (por ejemplo, como un componente en la composicion) antes mencionado. Se describe también una composicion que comprende: (a) al menos un compuesto seleccionado de los compuestos de la formula (1) descritos anteriormente. N-oxidos, y sales de éste; y al menos un compuesto o agente para el control de las plagas de invertebrados. Reivindicacion 1: Una composicion fungicida que comprende: (a) al menos un compuesto seleccionado de los compuestos de la formula (1), N-oxidos, y sales de éstos, en donde: Q1 es fenilo, tienilo, tiazolilo, pirazolilo, imidazolilo, piridinilo, piridazinilo, pirimidinilo, quinolinil o bencilo, cada uno se sustituye opcionalmente con hasta 4 sustituyentes que se seleccionan independientemente de R3 en los miembros anulares del átomo de carbono y R4 en los miembros anulares del átomo de nitrogeno; Q2 es fenilo, tienilo, tiazolilo, pirazolilo, imidazolilo, piridinilo, piridazinilo, pirimidinilo, quinolinil o bencilo, cada uno se sustituye opcionalmente con hasta 4 sustituyentes que se seleccionan independientemente de R6 en los miembros anulares del átomo de carbono y R5 en los miembros anulares del átomo de nitrogeno; R1 y R2 son independientemente halogeno, ciano, nitro, alquilo C1-3, alquenilo C2-3, alquinilo C2-3, ciclopropilo, haloalquilo C1-3, haloalquenilo C2-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, haloalquiltio C1-3 o hidroxialquilo C1-7; cada R3 y R5 es independientemente halogeno, ciano, hidroxi, nitro, alquilo C1-7, alquenilo C2-7, alquinilo C2-7, cianoalquilo C2-7, haloalquilo C1-7, haloalquenilo C2-7, cicloalquilo C3-7, halocicloalquilo C3-7, alquilcicloalquilo C4-10, cicloalquilalquilo C4-10, cicloalquilcicloalquilo C6-14, cicloalcoxi C3-7, halocicloalcoxi C3-7, alcoxi C1-7, cianoalcoxi C2-7, haloalcoxi C1-7, alquiltio C1-6, haloalquiltio C1-7, alquilsulfinilo C1-7, alquilsulfonilo C1-7, haloalquilsulfinilo C1-7, haloalquilsulfonilo C1-7, alquilamino C1-7, dialquilamino C2-7, alquilcarbonilo C2-7 alcoxicarbonilo C3-7, aminocarbonilo, alquilaminocarbonilo C2-7, dialquilaminocarbonilo C3-7, alquilcarbonilamino C2-7, trialquilsililo C3-10, -SCN, C(=S)NH2 o -X-U-Z; cada R4 y R6 es independientemente ciano, alquilo C1-6, alquenilo C3-6, alquinilo C3-6, haloalquilo C1-6, cicloalquilo C3-6, alcoxi C1-6, alcoxialquilo C2-6, alquilcarbonilo C2-6, alcoxicarbonilo C2-6, alquilaminoalquilo C2-6 o dialquilaminoalquilo C3-6; cada X es independientemente O, S(=O)n, NR7 o un enlace directo; cada U es independientemente alquileno C1-6, alquenileno C2-6, alquinileno C3-6, cicloalquileno C3-6 o cicloalquileno C3-6, en donde hasta 3 átomos de carbono son que se seleccionan independientemente de C(=O), cada uno se sustituye opcionalmente con hasta 5 sustituyentes que se seleccionan independientemente de halogeno, ciano, nitro, hidroxi, alquilo C1-6, haloalquilo C1-6, alcoxi C1-6 y haloalcoxi C1-6; cada Z es independientemente NR8aR8b, OR9 o S(=O)nR10; cada R7 es independientemente H, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C2-6, alcoxicarbonilo C2-6, (alquiltio)carbonilo C2-6, alcoxi(tiocarbonilo) C2-6, cicloalquilcarbonilo C4-8, cicloalcoxicarbonilo C4-8, (cicloalquilo)carbonilo C4-8 o cicloalcoxi(tiocarbonilo) C4-8; cada R8a y R8b es independientemente H, alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, alquinilo C3-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquilcarbonilo C2-6, alcoxicarbonilo C2-6, (alquiltio)carbonilo C2-6, alcoxi(tiocarbonilo) C2-6, cicloalquilcarbonilo C4-8, cicloalcoxicarbonilo C4-8, (cicloalquiltio)carbonilo C4-8 o cicloalcoxi(tiocarbonilo) C4-8; cada R9 y R10 es independientemente H, alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, alquinilo C3-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquilcarbonilo C2-6, alcoxicarbonilo C2-6, (alquiltio)carbonilo C2-6, alcoxi(tiocarbonilo) C2-6, cicloalquilcarbonilo C4-8, cicloalcoxicarbonilo C4-8, (cicloalquiltio)carbonilo C4-8 o cicloalcoxi(tiocarbonilo) C4-8; cada n es independientemente 0, 1 o 2; y (b) al menos un compuesto fungicida adicional. Reivindicacion 16: Un compuesto seleccionado de los compuestos de la formula (1) como se definio en la reivindicacion 1, N-oxidos, y sales de éste; siempre y cuando Q1 es fenilo, tienilo, tiazolil, pirazolilo, imidazolilo, piridinilo, piridazinilo, pirimidinilo, quinolinilo o bencilo, cada uno se sustituye opcionalmente con hasta 4 sustituyentes seleccionados independientemente de R3a en los miembros del anillo del átomo de carbono y R4a en los miembros del anillo del átomo de nitrogeno; en donde cada R3a es independientemente halogeno, ciano, hidroxi, nitro, alquilo C1-7, alquenilo C2-7, alquinilo C2-7, haloalquilo C1-7, haloalquenilo C2-7, cicloalquilo C3-7, halocicloalquilo C3-7, alquilcicloalquilo C4-10, cicloalquilalquilo C4-10, cicloalquilcicloalquilo C6-14, cicloalcoxi C3-7, halocicloalcoxi C3-7, alcoxi C1-7, haloalcoxi C1-7, alquiltio C1-6, haloalquiltio C1-7, alquilsulfinilo C1-7, alquilsulfonilo C1-7, haloalquilsulfinilo C1-7, haloalquilsulfonilo C1-7, alquilamino C1-7, dialquilamino C2-7, alquilcarbonilo C2-7, alcoxicarbonilo C2-7, alquilcarbonilamino C2-7, trialquilsililo C3-10, -SCN, C(=S)NH2 o -X-U-Z; y cada R4a es independientemente ciano, alquilo C1-6, alquenilo C3-6, alquinilo C3-6, cicloalquilo C3-6, alcoxi C1-6, alcoxialquilo C2-6, alquilcarbonilo C2-6, alcoxicarbonilo C2-6, alquilaminoalquilo C2-6, o dialquilaminoalquilo C3-6; entonces Q2 es fenilo, tienilo, tiazolilo, pirazolilo, imidazolilo, piridinilo, piridazinilo, pirimidinilo, quinolinilo o bencilo, cada uno sustituido con 1 a 4 sustituyentes que se seleccionan independientemente de R5 en los miembros anulares del átomo de carbono y R6 en los miembros anulares del átomo de nitrogeno; siempre y cuando al menos un sustituyente sea cianoalquilo C2-7, cianoalcoxi C2-7, aminocarbonilo, alquilaminocarbonilo C2-7 o dialquilaminocarbonilo C3-7 en un miembro anular de un átomo de carbono, o haloalquilo C1-6 en un miembro anular de un átomo de nitrogeno.A method is also described for controlling plant diseases caused by fungal pathogens of the plant which comprises applying to the plant or part of it, or to the seed of the plant, a fungicidal effective amount of a compound of the formula (1 ), an N-oxide, or salt thereof (for example, as a component in the composition) mentioned above. A composition comprising: (a) at least one compound selected from the compounds of the formula (1) described above is also described. N-oxides, and salts thereof; and at least one compound or agent for the control of invertebrate pests. Claim 1: A fungicidal composition comprising: (a) at least one compound selected from the compounds of the formula (1), N-oxides, and salts thereof, wherein: Q1 is phenyl, thienyl, thiazolyl, pyrazolyl, imidazolyl , pyridinyl, pyridazinyl, pyrimidinyl, quinolinyl or benzyl, each optionally substituted with up to 4 substituents that are independently selected from R3 in the ring members of the carbon atom and R4 in the ring members of the nitrogen atom; Q2 is phenyl, thienyl, thiazolyl, pyrazolyl, imidazolyl, pyridinyl, pyridazinyl, pyrimidinyl, quinolinyl or benzyl, each optionally substituted with up to 4 substituents that are independently selected from R6 in the ring members of the carbon atom and R5 in the members annular nitrogen atom; R1 and R2 are independently halogen, cyano, nitro, C1-3 alkyl, C2-3 alkenyl, C2-3 alkynyl, cyclopropyl, C1-3 haloalkyl, C2-3 haloalkenyl, C1-3 alkoxy, C1-3 haloalkoxy, C1 alkylthio -3, C1-3 haloalkylthio or C1-7 hydroxyalkyl; each R3 and R5 is independently halogen, cyano, hydroxy, nitro, C1-7 alkyl, C2-7 alkenyl, C2-7 alkynyl, C2-7 cyanoalkyl, C1-7 haloalkyl, C2-7 haloalkenyl, C3-7 cycloalkyl, halocycloalkyl C3-7, C4-10 alkylcycloalkyl, C4-10 cycloalkylalkyl, C6-14 cycloalkylalkyl, C3-7 cycloalkoxy, C3-7 halocycloalkoxy, C1-7 alkoxy, C2-7 cyanoalkoxy, C1-7 haloalkoxy, C1-6 alkylthio, haloalkylthio C1-7, C1-7 alkylsulfinyl, C1-7 alkylsulfonyl, C1-7 haloalkylsulfinyl, C1-7 haloalkylsulfonyl, C1-7 alkylamino, C2-7 dialkylamino, C2-7 alkylcarbonyl, aminocarbonyl, C2-7 alkylaminocarbonyl, C3-7 dialkylaminocarbonyl, C2-7 alkylcarbonylamino, C3-10 trialkylsilyl, -SCN, C (= S) NH2 or -XUZ; each R4 and R6 is independently cyano, C1-6 alkyl, C3-6 alkenyl, C3-6 alkynyl, C1-6 haloalkyl, C3-6 cycloalkyl, C1-6 alkoxy, C2-6 alkoxyalkyl, C2-6 alkylcarbonyl, C2 alkoxycarbonyl -6, C2-6 alkylaminoalkyl or C3-6 dialkylaminoalkyl; each X is independently O, S (= O) n, NR7 or a direct link; each U is independently C1-6 alkylene, C2-6 alkenylene, C3-6 alkynylene, C3-6 cycloalkylene or C3-6 cycloalkylene, wherein up to 3 carbon atoms are independently selected from C (= O), each it is optionally substituted with up to 5 substituents that are independently selected from halogen, cyano, nitro, hydroxy, C1-6 alkyl, C1-6 haloalkyl, C1-6 alkoxy and C1-6 haloalkoxy; each Z is independently NR8aR8b, OR9 or S (= O) nR10; each R7 is independently H, C1-6 alkyl, C1-6 haloalkyl, C2-6 alkylcarbonyl, C2-6 alkoxycarbonyl, C2-6 (alkylthio) carbonyl, C2-6 alkoxy (thiocarbonyl), C4-8 cycloalkylcarbonyl, C4- cycloalkoxycarbonyl 8, (C4-8 cycloalkyl) carbonyl or C4-8 cycloalkoxy (thiocarbonyl); each R8a and R8b is independently H, C1-6 alkyl, C1-6 haloalkyl, C2-6 alkenyl, C3-6 alkynyl, C3-6 cycloalkyl, C3-6 halocycloalkyl, C2-6 alkylcarbonyl, C2-6 alkoxycarbonyl, (alkylthio ) C2-6 carbonyl, C2-6 alkoxy (thiocarbonyl), C4-8 cycloalkylcarbonyl, C4-8 cycloalkoxycarbonyl, (C4-8 cycloalkylthio) carbonyl or C4-8 cycloalkoxy (thiocarbonyl); each R9 and R10 is independently H, C1-6 alkyl, C1-6 haloalkyl, C2-6 alkenyl, C3-6 alkynyl, C3-6 cycloalkyl, C3-6 halocycloalkyl, C2-6 alkylcarbonyl, C2-6 alkoxycarbonyl, (alkylthio ) C2-6 carbonyl, C2-6 alkoxy (thiocarbonyl), C4-8 cycloalkylcarbonyl, C4-8 cycloalkoxycarbonyl, (C4-8 cycloalkylthio) carbonyl or C4-8 cycloalkoxy (thiocarbonyl); each n is independently 0, 1 or 2; and (b) at least one additional fungicidal compound. Claim 16: A compound selected from the compounds of the formula (1) as defined in claim 1, N-oxides, and salts thereof; As long as Q1 is phenyl, thienyl, thiazolyl, pyrazolyl, imidazolyl, pyridinyl, pyridazinyl, pyrimidinyl, quinolinyl or benzyl, each is optionally substituted with up to 4 substituents independently selected from R3a in the ring members of the carbon atom and R4a in the ring members of the nitrogen atom; wherein each R3a is independently halogen, cyano, hydroxy, nitro, C1-7 alkyl, C2-7 alkenyl, C2-7 alkynyl, C1-7 haloalkyl, C2-7 haloalkenyl, C3-7 cycloalkyl, C3-7 halocycloalkyl, alkylcycloalkyl C4-10, C4-10 cycloalkylalkyl, C6-14 cycloalkylcycloalkyl, C3-7 cycloalkoxy, C3-7 halocycloalkoxy, C1-7 alkoxy, C1-7 haloalkoxy, C1-6 alkylthio, C1-7 haloalkylthio, C1-7 alkylsulfinyl, alkylsulfonyl C1-7, haloalkylsulfinyl C1-7, haloalkylsulfonyl C1-7, alkylamino C1-7, dialkylamino C2-7, alkylcarbonyl C2-7, alkoxycarbonyl C2-7, alkylcarbonylamino C2-7, trialkylsilyl C3-10, -SCN, C (= S) NH2 or -XUZ; and each R4a is independently cyano, C1-6 alkyl, C3-6 alkenyl, C3-6 alkynyl, C3-6 cycloalkyl, C1-6 alkoxy, C2-6 alkoxyalkyl, C2-6 alkylcarbonyl, C2-6 alkoxycarbonyl, C2- alkylaminoalkyl 6, or C 3-6 dialkylaminoalkyl; then Q2 is phenyl, thienyl, thiazolyl, pyrazolyl, imidazolyl, pyridinyl, pyridazinyl, pyrimidinyl, quinolinyl or benzyl, each substituted with 1 to 4 substituents that are independently selected from R5 in the ring members of the carbon atom and R6 in the members annular nitrogen atom; provided that at least one substituent is C2-7 cyanoalkyl, C2-7 cyanoalkoxy, aminocarbonyl, C2-7 alkylaminocarbonyl or C3-7 dialkylaminocarbonyl in an annular member of a carbon atom, or C1-6 haloalkyl in an annular member of a nitrogen atom.

ARP100104093 2009-11-04 2010-11-04 FUNGICIDE BLENDS AR079290A1 (en)

Applications Claiming Priority (2)

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US25801809P 2009-11-04 2009-11-04
US29795310P 2010-01-25 2010-01-25

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AR079290A1 true AR079290A1 (en) 2012-01-18

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TW (1) TW201117722A (en)
UY (1) UY32998A (en)
WO (1) WO2011056463A2 (en)

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TWI283164B (en) 2001-09-21 2007-07-01 Du Pont Anthranilamide arthropodicide treatment
CN101505747A (en) 2006-06-21 2009-08-12 杜邦公司 Pyrazinones as cellular proliferation inhibitors
EP2053044A1 (en) * 2007-10-26 2009-04-29 Syngenta Participations AG Novel imidazole derivatives
EP2053045A1 (en) * 2007-10-26 2009-04-29 Syngenta Participations AG Novel imidazole derivatives
GB0806745D0 (en) * 2008-04-14 2008-05-14 Syngenta Participations Ag Novel imidazole derivatives
PE20091953A1 (en) * 2008-05-08 2010-01-09 Du Pont SUBSTITUTED AZOLS AS FUNGICIDES

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UY32998A (en) 2011-06-30

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