AR077079A1 - Procesamiento de gases de hidrocarburos - Google Patents

Procesamiento de gases de hidrocarburos

Info

Publication number
AR077079A1
AR077079A1 ARP100102081A ARP100102081A AR077079A1 AR 077079 A1 AR077079 A1 AR 077079A1 AR P100102081 A ARP100102081 A AR P100102081A AR P100102081 A ARP100102081 A AR P100102081A AR 077079 A1 AR077079 A1 AR 077079A1
Authority
AR
Argentina
Prior art keywords
stream
heat
distillation
steam
feed
Prior art date
Application number
ARP100102081A
Other languages
English (en)
Inventor
John D Wilkinson
Kyle T Cuellar
Hank M Hudson
Joe T Lynch
Andrew F Johnke
W Larry Lewis
Original Assignee
Ortloff Engineers Ltd
Sme Products Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/689,616 external-priority patent/US9021831B2/en
Priority claimed from US12/717,394 external-priority patent/US9080811B2/en
Priority claimed from US12/750,862 external-priority patent/US8881549B2/en
Priority claimed from US12/772,472 external-priority patent/US9933207B2/en
Priority claimed from US12/781,259 external-priority patent/US9939195B2/en
Application filed by Ortloff Engineers Ltd, Sme Products Lp filed Critical Ortloff Engineers Ltd
Publication of AR077079A1 publication Critical patent/AR077079A1/es

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0209Natural gas or substitute natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0219Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0238Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0295Start-up or control of the process; Details of the apparatus used, e.g. sieve plates, packings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J5/00Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/02Processes or apparatus using separation by rectification in a single pressure main column system
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/30Processes or apparatus using separation by rectification using a side column in a single pressure column system
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/78Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/80Processes or apparatus using separation by rectification using integrated mass and heat exchange, i.e. non-adiabatic rectification in a reflux exchanger or dephlegmator
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/02Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00Processes characterised by the type or other details of the feed stream
    • F25J2210/12Refinery or petrochemical off-gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/02Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/12External refrigeration with liquid vaporising loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/60Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/40Vertical layout or arrangement of cold equipments within in the cold box, e.g. columns, condensers, heat exchangers etc.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Proceso y aparato para la recuperacion de etano, etileno, propano, propileno y componentes de hidrocarburos más pesados de una corriente de gas de hidrocarburos en un conjunto de calentamiento compacto. La corriente de gas se enfría y se divide en una primera y una segunda corriente. La primera corriente se enfría adicionalmente para condensarla sustancialmente por completo y luego, se la expande a una presion menor y se la suministra como alimentacion entre el primero y el segundo medios de absorcion dentro del conjunto de tratamiento. La segunda corriente se expande a una presion menor y se la suministra como una alimentacion del fondo al segundo medio de absorcion. Se recolecta una corriente de líquido de destilacion de la region inferior del segundo medio absorbente y se la dirige a un medio de transferencia de calor y de masa dentro del conjunto de calentamiento para calentarla y separar sus componentes volátiles mientras se enfría la corriente de gas. Se recoge una primera corriente de vapor de destilacion de la region superior del medio de transferencia de calor y masa y se enfría lo suficiente como para condensarla por lo menos parcialmente, formando una corriente de vapor residual y una corriente condensada. La corriente de condensado se suministra como alimentacion por la parte superior al primer medio de absorcion. De la region superior del primer medio de absorcion se recoge una segunda corriente de vapor de destilacion y se la dirige a uno o más medios para el intercambio de calor dentro del conjunto de procesamiento para calentarlo mientras se enfría la primera corriente de vapor de destilacion. La segunda corriente de vapor de destilacion calentada se combina con la corriente de vapor residual y la corriente combinada se dirige hacia los uno o más medios para el intercambio de calor que hay dentro del conjunto de procesamiento para calentarla mientras se enfría la corriente de gas y la primera corriente. Las cantidades y las temperaturas de la alimentacion en el primer y segundo medio absorbente son efectivas para mantener la temperatura de la region superior del primer medio absorbente en una temperatura a la cual pueden recuperarse las porciones mayores de los componentes deseados en la corriente del líquido de destilacion separado.
ARP100102081A 2009-06-11 2010-06-11 Procesamiento de gases de hidrocarburos AR077079A1 (es)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US18636109P 2009-06-11 2009-06-11
US12/689,616 US9021831B2 (en) 2009-02-17 2010-01-19 Hydrocarbon gas processing
US12/717,394 US9080811B2 (en) 2009-02-17 2010-03-04 Hydrocarbon gas processing
US12/750,862 US8881549B2 (en) 2009-02-17 2010-03-31 Hydrocarbon gas processing
US12/772,472 US9933207B2 (en) 2009-02-17 2010-05-03 Hydrocarbon gas processing
US12/781,259 US9939195B2 (en) 2009-02-17 2010-05-17 Hydrocarbon gas processing including a single equipment item processing assembly

Publications (1)

Publication Number Publication Date
AR077079A1 true AR077079A1 (es) 2011-07-27

Family

ID=56291174

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP100102081A AR077079A1 (es) 2009-06-11 2010-06-11 Procesamiento de gases de hidrocarburos

Country Status (14)

Country Link
EP (1) EP2440869A1 (es)
JP (1) JP5753535B2 (es)
KR (1) KR101687851B1 (es)
CN (1) CN102483299B (es)
AR (1) AR077079A1 (es)
AU (1) AU2010259129A1 (es)
BR (1) BRPI1011526A2 (es)
CA (1) CA2764144C (es)
CO (1) CO6480935A2 (es)
EA (1) EA027815B1 (es)
MX (1) MX355018B (es)
MY (1) MY158312A (es)
PE (1) PE20121305A1 (es)
WO (1) WO2010144217A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2764629C (en) * 2010-03-31 2017-05-30 Ortloff Engineers, Ltd. Hydrocarbon gas processing
MY179078A (en) * 2013-09-11 2020-10-27 Ortloff Engineers Ltd Hydrocarbon gas processing

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS546500B1 (es) * 1976-02-15 1979-03-29
US4889545A (en) * 1988-11-21 1989-12-26 Elcor Corporation Hydrocarbon gas processing
US5568737A (en) * 1994-11-10 1996-10-29 Elcor Corporation Hydrocarbon gas processing
MXPA03002804A (es) * 2000-10-02 2005-08-26 Elcor Corp Procesamiento de gas de hidrocarburos.
UA76750C2 (uk) * 2001-06-08 2006-09-15 Елккорп Спосіб зрідження природного газу (варіанти)
US6516631B1 (en) * 2001-08-10 2003-02-11 Mark A. Trebble Hydrocarbon gas processing
US6560989B1 (en) * 2002-06-07 2003-05-13 Air Products And Chemicals, Inc. Separation of hydrogen-hydrocarbon gas mixtures using closed-loop gas expander refrigeration
JP4571934B2 (ja) * 2003-02-25 2010-10-27 オートロフ・エンジニアーズ・リミテッド 炭化水素ガス処理
US7159417B2 (en) * 2004-03-18 2007-01-09 Abb Lummus Global, Inc. Hydrocarbon recovery process utilizing enhanced reflux streams
WO2005114076A1 (en) * 2004-04-26 2005-12-01 Ortloff Engineers, Ltd Natural gas liquefaction
US8919148B2 (en) * 2007-10-18 2014-12-30 Ortloff Engineers, Ltd. Hydrocarbon gas processing

Also Published As

Publication number Publication date
EA201270005A1 (ru) 2012-06-29
CA2764144A1 (en) 2010-12-16
WO2010144217A1 (en) 2010-12-16
CO6480935A2 (es) 2012-07-16
BRPI1011526A2 (pt) 2016-03-29
AU2010259129A2 (en) 2012-05-03
CN102483299B (zh) 2015-10-21
KR20120027488A (ko) 2012-03-21
PE20121305A1 (es) 2012-10-08
JP2012529623A (ja) 2012-11-22
EP2440869A1 (en) 2012-04-18
MX355018B (es) 2018-04-02
EA027815B1 (ru) 2017-09-29
AU2010259129A1 (en) 2012-02-23
CA2764144C (en) 2017-10-24
MY158312A (en) 2016-09-30
AU2010259129A9 (en) 2014-12-18
MX2011013068A (es) 2012-02-01
KR101687851B1 (ko) 2016-12-19
CN102483299A (zh) 2012-05-30
JP5753535B2 (ja) 2015-07-22

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