AR045336A1 - PROCEDURE FOR THE REGENERATION OF A HYDROGENATION CATALYST - Google Patents

PROCEDURE FOR THE REGENERATION OF A HYDROGENATION CATALYST

Info

Publication number
AR045336A1
AR045336A1 ARP040102800A ARP040102800A AR045336A1 AR 045336 A1 AR045336 A1 AR 045336A1 AR P040102800 A ARP040102800 A AR P040102800A AR P040102800 A ARP040102800 A AR P040102800A AR 045336 A1 AR045336 A1 AR 045336A1
Authority
AR
Argentina
Prior art keywords
regeneration
hydrogenation catalyst
oxychlorination
vcm
procedure
Prior art date
Application number
ARP040102800A
Other languages
Spanish (es)
Original Assignee
Solvay
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay filed Critical Solvay
Publication of AR045336A1 publication Critical patent/AR045336A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/04—Chloro-alkenes
    • C07C21/06—Vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C01B7/03—Preparation from chlorides
    • C01B7/035—Preparation of hydrogen chloride from chlorides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C01B7/07—Purification ; Separation
    • C01B7/0706—Purification ; Separation of hydrogen chloride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
    • C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procedimiento para la regeneración de un catalizador de hidrogenación usado que comprende al menos un metal catalítico elegido entre el grupo siguiente: Ru, Rb, Pd, Os, Ir, y Pt, sobre un soporte inerte, estando dicho procedimiento constituido esencialmente por un tratamiento térmico en presencia de O a una temperatura comprendida entre 300 y 700ºC. Reivindicación 9: Procedimiento de síntesis de cloruro de vinilo monómero (VCM) por acoplamiento de una cloración directa y de uno oxicloración de etileno para formar DCEa que se transforma principalmente en VCM y en HCl por pirólisis, conteniendo dicho HCl trazas de acetileno y reciclándose en la oxicloración después de la hidrogenación de estas trazas de acetileno en presencia de un catalizador regenerado por un procedimiento según una cualquiera de las reivindicaciones precedentes.Process for the regeneration of a used hydrogenation catalyst comprising at least one catalytic metal chosen from the following group: Ru, Rb, Pd, Os, Ir, and Pt, on an inert support, said process being essentially constituted by a heat treatment in the presence of O at a temperature between 300 and 700 ° C. Claim 9: Synthesis process of monomeric vinyl chloride (VCM) by coupling a direct chlorination and an oxychlorination of ethylene to form DCEa that is mainly transformed into VCM and HCl by pyrolysis, said HCl containing acetylene traces and being recycled into Oxychlorination after hydrogenation of these acetylene traces in the presence of a catalyst regenerated by a process according to any one of the preceding claims.

ARP040102800A 2003-08-08 2004-08-05 PROCEDURE FOR THE REGENERATION OF A HYDROGENATION CATALYST AR045336A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0309800 2003-08-08

Publications (1)

Publication Number Publication Date
AR045336A1 true AR045336A1 (en) 2005-10-26

Family

ID=34130584

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP040102800A AR045336A1 (en) 2003-08-08 2004-08-05 PROCEDURE FOR THE REGENERATION OF A HYDROGENATION CATALYST

Country Status (15)

Country Link
EP (1) EP1658137A1 (en)
JP (1) JP2007501691A (en)
KR (1) KR20060056980A (en)
CN (1) CN1832801A (en)
AR (1) AR045336A1 (en)
BR (1) BRPI0413286A (en)
CA (1) CA2534760A1 (en)
EA (1) EA008672B1 (en)
EG (1) EG24366A (en)
MX (1) MXPA06001446A (en)
MY (1) MY149389A (en)
NO (1) NO20060496L (en)
TW (1) TW200510062A (en)
UA (1) UA84436C2 (en)
WO (1) WO2005014168A1 (en)

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US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
JP2007525477A (en) 2003-07-15 2007-09-06 ジーアールティー インコーポレイテッド Synthesis of hydrocarbons
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
CN100355718C (en) * 2005-09-21 2007-12-19 扬子石油化工股份有限公司 Regeneration method of catalyst of hydrofinishing terephthalic acid
US7718158B2 (en) 2005-10-13 2010-05-18 Lyondell Chemical Technology, L.P. Polymer-encapsulated ion-exchange resin
CA2641348C (en) 2006-02-03 2014-12-23 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
MY153701A (en) 2006-02-03 2015-03-13 Grt Inc Separation of light gases from halogens
KR101236099B1 (en) * 2006-12-12 2013-02-21 주식회사 엘지화학 Novel method for the production of vinyl chloride monomer
US8921625B2 (en) 2007-02-05 2014-12-30 Reaction35, LLC Continuous process for converting natural gas to liquid hydrocarbons
WO2008148113A1 (en) 2007-05-24 2008-12-04 Grt, Inc. Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
JP4610664B1 (en) 2009-07-09 2011-01-12 Ｊｘ日鉱日石エネルギー株式会社 Method for producing regenerated hydrotreating catalyst and method for producing petroleum product
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
CN104399492A (en) * 2014-11-17 2015-03-11 张立军 Palladium catalyst roasting regenerating process
CN105712835A (en) * 2014-12-03 2016-06-29 青岛海晶化工集团有限公司 Method for preparing VCM via balanced oxychlorination

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB811820A (en) * 1957-04-30 1959-04-15 Englehard Ind Inc Catalytic hydrogenation of acetylene
NL243457A (en) * 1958-09-20
DE2438153A1 (en) * 1974-08-08 1976-02-19 Degussa Selective acetylene removal from hydrogen chloride - by hydrogenation at platinum metal catalyst on non-porous silica-contg. carrier
US5332705A (en) * 1992-06-19 1994-07-26 Exxon Chemical Patents Inc. Regeneration of acetylene converter catalysts by hydrogen stripping
DE19535402A1 (en) * 1995-09-23 1997-03-27 Basf Ag Palladium-containing supported catalyst for the selective catalytic hydrogenation of acetylene in hydrocarbon streams

Also Published As

Publication number Publication date
BRPI0413286A (en) 2006-10-10
EG24366A (en) 2009-03-05
WO2005014168A1 (en) 2005-02-17
KR20060056980A (en) 2006-05-25
NO20060496L (en) 2006-03-07
EP1658137A1 (en) 2006-05-24
TW200510062A (en) 2005-03-16
CN1832801A (en) 2006-09-13
MY149389A (en) 2013-08-30
MXPA06001446A (en) 2006-05-19
EA008672B1 (en) 2007-06-29
UA84436C2 (en) 2008-10-27
JP2007501691A (en) 2007-02-01
CA2534760A1 (en) 2005-02-17
EA200600378A1 (en) 2006-06-30

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