AR042436A1 - Compuestos de haloalqueno, proceso para su producion y pesticidas que los contienen - Google Patents

Compuestos de haloalqueno, proceso para su producion y pesticidas que los contienen

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Publication number
AR042436A1
AR042436A1 ARP030104573A ARP030104573A AR042436A1 AR 042436 A1 AR042436 A1 AR 042436A1 AR P030104573 A ARP030104573 A AR P030104573A AR P030104573 A ARP030104573 A AR P030104573A AR 042436 A1 AR042436 A1 AR 042436A1
Authority
AR
Argentina
Prior art keywords
substituted
alkyl
atom
halogen
phenylalkyl
Prior art date
Application number
ARP030104573A
Other languages
English (en)
Original Assignee
Ishihara Sangyo Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ishihara Sangyo Kaisha filed Critical Ishihara Sangyo Kaisha
Publication of AR042436A1 publication Critical patent/AR042436A1/es

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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C233/09—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to carbon atoms of an acyclic unsaturated carbon skeleton
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    • C07C233/00—Carboxylic acid amides
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    • C07C233/12—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
    • C07C233/13—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/20—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a carbon atom of an acyclic unsaturated carbon skeleton
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/24—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton
    • C07C255/29—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton containing cyano groups and acylated amino groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/39—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton at least one of the nitrogen atoms being part of any of the groups, X being a hetero atom, Y being any atom
    • C07C323/40—Y being a hydrogen or a carbon atom
    • C07C323/41—Y being a hydrogen or an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/38—Amides of thiocarboxylic acids
    • C07C327/40—Amides of thiocarboxylic acids having carbon atoms of thiocarboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C327/44—Amides of thiocarboxylic acids having carbon atoms of thiocarboxamide groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of an unsaturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
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    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
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    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/56—Nitrogen atoms
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    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/75—Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates
    • C—CHEMISTRY; METALLURGY
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    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
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    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
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    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
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    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/04—Systems containing only non-condensed rings with a four-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
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Abstract

Un proceso para producir estos compuestos, un pesticida que contiene estos compuestos de haloalqueno como ingrediente activo y un método para combatir las pestes. Reivindicación 1: Un compuesto de haloalqueno representado por la fórmula (1) o su sal: en la cual cada uno de X1 y X2 es halógeno, Y es un átomo de hidrógeno, halógeno, alquilo, haloalquilo o fenilo, n es desde 0 hasta 5, A es un átomo de oxígeno o un átomo de azufre, G es un átomo de hidrógeno, alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo, siempre que cuando Y es un átomo de hidrógeno o un átomo de halógeno y A es un átomo de oxígeno, G es alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo, y Q es un grupo heterocíclico de 5 a 12 miembros (el grupo heterocíclico puede estar sustituido) que contiene un heteroátomo opcional seleccionado de un átomos de oxígeno, un átomo de azufre y un átomo de nitrógeno, alquilo que puede estar sustituido con W, alquenilo que puede estar sustituido con W, alquinilo que puede estar sustituido con W, o cicloalquilo que puede estar sustituido con W, donde W es halógeno, alcoxi, alquiltio, hidroxi, ciano, nitro o fenilo que puede estar sustituido, siempre que: (1) un caso en el cual X1 y X2 son, en forma simultánea, átomos de flúor, Y es un átomo de hidrógeno, un átomo de cloro o un átomo de bromo, n es desde 1 hasta 5, A es un átomo de oxígeno, G es alquilo, y Q es piridilo que puede estar sustituido con halógeno, 2,2-dimetil-2,3-dihidrobenzofuranilo, alquilo que puede estar sustituido con W, alquenilo que puede estar sustituido con W, alquinilo que puede estar sustituido con W, o cicloalquilo que puede estar sustituido con W; (2) un caso en el cual X1 y X2 son, en forma simultánea, átomos de flúor, Y es un átomo de hidrógeno o halógeno, n es 0, A es un átomo de oxígeno, G es alquilo, y Q es piridilo, benzotiazolilo (ambos pueden estar sustituidos con halógeno, alquilo o haloalquilo), alquilo sustituido con fenilo que puede estar sustituido, o cicloalquilo que puede estar sustituido con W; (3) un caso en el cual X1, X2 e Y son, en forma simultánea, átomos de flúor, y A es un átomo de oxígeno; y (4) un caso en el cual, X1 y X2 son, en forma simultánea, átomos de flúor, Y es un grupo metilo, n es 1, A es un átomo de oxígeno, G es un átomo de hidrógeno, y Q es un grupo 2-propinilo, se excluyen. Reivindicación 8: Un proceso para producir un compuesto de haloalqueno representado por la fórmula (1) o su sal: en la cual cada uno de X1 y X2 es halógeno, Y es un átomo de hidrógeno, halógeno, alquilo, haloalquilo o fenilo, n es desde 0 hasta 5, A es un átomo de oxígeno o un átomo de azufre, G es un átomo de hidrógeno, alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo, siempre que cuando Y es un átomo de hidrógeno o un átomo de halógeno y A es un átomo de oxígeno, G es alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo, y Q es un grupo heterocíclico de 5 a 12 miembros (el grupo heterocíclico puede estar sustituido) que contiene un heteroátomo opcional seleccionado de un átomo de oxígeno, un átomo de azufre y un átomo de nitrógeno, alquilo que puede estar sustituido con W, alquenilo que puede estar sustituido con W, alquinilo que puede estar sustituido con W, o cicloalquilo que puede estar sustituido con W, donde W es halógeno, alcoxi, alquiltio, hidroxi, ciano, nitro o fenilo que puede estar sustituido, siempre que: (1) un caso en el cual X1 y X2 son, en forma simultánea, átomos de flúor, Y es un átomo de hidrógeno, un átomo de cloro o un átomo de bromo, n es desde 1 hasta 5, A es un átomo de oxígeno, G es alquilo, y Q es piridilo que puede estar sustituido con halógeno, 2,2-dimetil-2,3-dihidrobenzofuranilo, alquilo que puede estar sustituido con W, alquenilo que puede estar sustituido con W, alquinilo que puede estar sustituido con W, o cicloalquilo que puede estar sustituido con W; (2) un caso en el cual X1 y X2 son, en forma simultánea, átomos de flúor, Y es un átomo de hidrógeno o halógeno, n es 0, A es un átomo de oxígeno, G es alquilo, y Q es piridilo, benzotiazolilo (ambos pueden estar sustituidos con halógeno, alquilo o haloalquilo), alquilo sustituido con fenilo que puede estar sustituido, o cicloalquilo que puede estar sustituido con W; (3) un caso en el cual X1, X2 e Y son, en forma simultánea, átomos de flúor, y A es un átomo de oxígeno; y (4) un caso en el cual, X1 y X2 son, en forma simultánea, átomos de flúor, Y es un grupo metilo, n es 1, A es un átomo de oxígeno, G es un átomo de hidrógeno, y Q es un grupo 2-propinilo, se excluyen, que comprende (1) hacer reaccionar un compuesto representado por la fórmula (2), en la cual X1, X2, Y, y n son como se los definió precedentemente, con un compuesto representado por la fórmula (3) o su sal, en la cual G y Q son como se los definió precedentemente; o (2) hacer reaccionar un compuesto representado por la fórmula (4), en la cual X1, X2, Y, y n son como se los definió precedentemente, con un compuesto representado por la fórmula (3) o su sal, en la cual G y Q so como se los definió precedentemente; o (3) hacer reaccionar un compuesto representado por la fórmula (5), en la cual X1, X2, Y y n son como se los definió precedentemente, y Z es alquilo C1-4, con un compuesto representado por la fórmula (3) o su sal, en la cual G y Q son como se los definió precedentemente; o (4) hacer reaccionar un compuesto representado por la fórmula (6), en la cual X1, X2, Y, n y Q son como se definieron precedentemente, con un compuesto representado por la fórmula: G1-X3, en la cual G1 es alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquilo, alquinilo, haloalquinilo o fenilalquinilo, y X3 es halógeno; o (5) hacer reaccionar un compuesto representado por la fórmula (6), en la cual X1, X2, Y, N y Q son como se los definió precedentemente, con un compuesto representado por la fórmula: G2-OSO2-U, en la cual G2 es alquilo, y U es alquilo, haloalquilo, alcoxi, fenilo, fenilo sustituido con halógeno, o fenilo sustituido con alquilo; o (6) hacer reaccionar un compuesto representado por la fórmula (7), en la cual X1, X2, Y, n , G y Q son como se los definió precedentemente, con un agente tionizante.
ARP030104573A 2002-12-11 2003-12-11 Compuestos de haloalqueno, proceso para su producion y pesticidas que los contienen AR042436A1 (es)

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CN104163792B (zh) * 2013-05-20 2017-04-12 湖南化工研究院 N‑吡啶酰胺类化合物及其制备方法与应用
CN111909031B (zh) * 2020-08-14 2021-10-15 华东师范大学 一种偕二氟烯基取代的烷基羧酸类化合物及其合成方法
CN112694436B (zh) * 2020-12-30 2022-07-08 济南周行医药科技有限公司 一种槟榔碱的合成方法

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US4950666A (en) * 1989-03-30 1990-08-21 Fmc Corporation Difluoroalkane and difluoroalkenylalkane pesticides
DE3941966A1 (de) * 1989-12-15 1991-06-20 Schering Ag Halogenierte olefine, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel
ES2123553T3 (es) * 1991-03-01 1999-01-16 Monsanto Co Compuestos fluoroalquenilo y su uso como repelentes de plagas.
DE19531300A1 (de) * 1995-08-25 1997-02-27 Bayer Ag Fluorbutensäureamide

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