AR042436A1 - Compuestos de haloalqueno, proceso para su producion y pesticidas que los contienen - Google Patents

Compuestos de haloalqueno, proceso para su producion y pesticidas que los contienen

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Publication number
AR042436A1
AR042436A1 ARP030104573A ARP030104573A AR042436A1 AR 042436 A1 AR042436 A1 AR 042436A1 AR P030104573 A ARP030104573 A AR P030104573A AR P030104573 A ARP030104573 A AR P030104573A AR 042436 A1 AR042436 A1 AR 042436A1
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AR
Argentina
Prior art keywords
substituted
alkyl
atom
halogen
phenylalkyl
Prior art date
Application number
ARP030104573A
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English (en)
Original Assignee
Ishihara Sangyo Kaisha
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Application filed by Ishihara Sangyo Kaisha filed Critical Ishihara Sangyo Kaisha
Publication of AR042436A1 publication Critical patent/AR042436A1/es

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    • C07D209/00Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
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    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/06Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
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    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
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    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • C07C233/13Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
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    • C07C233/20Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a carbon atom of an acyclic unsaturated carbon skeleton
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    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14The ring being saturated

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Abstract

Un proceso para producir estos compuestos, un pesticida que contiene estos compuestos de haloalqueno como ingrediente activo y un método para combatir las pestes. Reivindicación 1: Un compuesto de haloalqueno representado por la fórmula (1) o su sal: en la cual cada uno de X1 y X2 es halógeno, Y es un átomo de hidrógeno, halógeno, alquilo, haloalquilo o fenilo, n es desde 0 hasta 5, A es un átomo de oxígeno o un átomo de azufre, G es un átomo de hidrógeno, alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo, siempre que cuando Y es un átomo de hidrógeno o un átomo de halógeno y A es un átomo de oxígeno, G es alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo, y Q es un grupo heterocíclico de 5 a 12 miembros (el grupo heterocíclico puede estar sustituido) que contiene un heteroátomo opcional seleccionado de un átomos de oxígeno, un átomo de azufre y un átomo de nitrógeno, alquilo que puede estar sustituido con W, alquenilo que puede estar sustituido con W, alquinilo que puede estar sustituido con W, o cicloalquilo que puede estar sustituido con W, donde W es halógeno, alcoxi, alquiltio, hidroxi, ciano, nitro o fenilo que puede estar sustituido, siempre que: (1) un caso en el cual X1 y X2 son, en forma simultánea, átomos de flúor, Y es un átomo de hidrógeno, un átomo de cloro o un átomo de bromo, n es desde 1 hasta 5, A es un átomo de oxígeno, G es alquilo, y Q es piridilo que puede estar sustituido con halógeno, 2,2-dimetil-2,3-dihidrobenzofuranilo, alquilo que puede estar sustituido con W, alquenilo que puede estar sustituido con W, alquinilo que puede estar sustituido con W, o cicloalquilo que puede estar sustituido con W; (2) un caso en el cual X1 y X2 son, en forma simultánea, átomos de flúor, Y es un átomo de hidrógeno o halógeno, n es 0, A es un átomo de oxígeno, G es alquilo, y Q es piridilo, benzotiazolilo (ambos pueden estar sustituidos con halógeno, alquilo o haloalquilo), alquilo sustituido con fenilo que puede estar sustituido, o cicloalquilo que puede estar sustituido con W; (3) un caso en el cual X1, X2 e Y son, en forma simultánea, átomos de flúor, y A es un átomo de oxígeno; y (4) un caso en el cual, X1 y X2 son, en forma simultánea, átomos de flúor, Y es un grupo metilo, n es 1, A es un átomo de oxígeno, G es un átomo de hidrógeno, y Q es un grupo 2-propinilo, se excluyen. Reivindicación 8: Un proceso para producir un compuesto de haloalqueno representado por la fórmula (1) o su sal: en la cual cada uno de X1 y X2 es halógeno, Y es un átomo de hidrógeno, halógeno, alquilo, haloalquilo o fenilo, n es desde 0 hasta 5, A es un átomo de oxígeno o un átomo de azufre, G es un átomo de hidrógeno, alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo, siempre que cuando Y es un átomo de hidrógeno o un átomo de halógeno y A es un átomo de oxígeno, G es alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquenilo, alquinilo, haloalquinilo o fenilalquinilo, y Q es un grupo heterocíclico de 5 a 12 miembros (el grupo heterocíclico puede estar sustituido) que contiene un heteroátomo opcional seleccionado de un átomo de oxígeno, un átomo de azufre y un átomo de nitrógeno, alquilo que puede estar sustituido con W, alquenilo que puede estar sustituido con W, alquinilo que puede estar sustituido con W, o cicloalquilo que puede estar sustituido con W, donde W es halógeno, alcoxi, alquiltio, hidroxi, ciano, nitro o fenilo que puede estar sustituido, siempre que: (1) un caso en el cual X1 y X2 son, en forma simultánea, átomos de flúor, Y es un átomo de hidrógeno, un átomo de cloro o un átomo de bromo, n es desde 1 hasta 5, A es un átomo de oxígeno, G es alquilo, y Q es piridilo que puede estar sustituido con halógeno, 2,2-dimetil-2,3-dihidrobenzofuranilo, alquilo que puede estar sustituido con W, alquenilo que puede estar sustituido con W, alquinilo que puede estar sustituido con W, o cicloalquilo que puede estar sustituido con W; (2) un caso en el cual X1 y X2 son, en forma simultánea, átomos de flúor, Y es un átomo de hidrógeno o halógeno, n es 0, A es un átomo de oxígeno, G es alquilo, y Q es piridilo, benzotiazolilo (ambos pueden estar sustituidos con halógeno, alquilo o haloalquilo), alquilo sustituido con fenilo que puede estar sustituido, o cicloalquilo que puede estar sustituido con W; (3) un caso en el cual X1, X2 e Y son, en forma simultánea, átomos de flúor, y A es un átomo de oxígeno; y (4) un caso en el cual, X1 y X2 son, en forma simultánea, átomos de flúor, Y es un grupo metilo, n es 1, A es un átomo de oxígeno, G es un átomo de hidrógeno, y Q es un grupo 2-propinilo, se excluyen, que comprende (1) hacer reaccionar un compuesto representado por la fórmula (2), en la cual X1, X2, Y, y n son como se los definió precedentemente, con un compuesto representado por la fórmula (3) o su sal, en la cual G y Q son como se los definió precedentemente; o (2) hacer reaccionar un compuesto representado por la fórmula (4), en la cual X1, X2, Y, y n son como se los definió precedentemente, con un compuesto representado por la fórmula (3) o su sal, en la cual G y Q so como se los definió precedentemente; o (3) hacer reaccionar un compuesto representado por la fórmula (5), en la cual X1, X2, Y y n son como se los definió precedentemente, y Z es alquilo C1-4, con un compuesto representado por la fórmula (3) o su sal, en la cual G y Q son como se los definió precedentemente; o (4) hacer reaccionar un compuesto representado por la fórmula (6), en la cual X1, X2, Y, n y Q son como se definieron precedentemente, con un compuesto representado por la fórmula: G1-X3, en la cual G1 es alquilo, haloalquilo, fenilalquilo, acilo, alquenilo, haloalquenilo, fenilalquilo, alquinilo, haloalquinilo o fenilalquinilo, y X3 es halógeno; o (5) hacer reaccionar un compuesto representado por la fórmula (6), en la cual X1, X2, Y, N y Q son como se los definió precedentemente, con un compuesto representado por la fórmula: G2-OSO2-U, en la cual G2 es alquilo, y U es alquilo, haloalquilo, alcoxi, fenilo, fenilo sustituido con halógeno, o fenilo sustituido con alquilo; o (6) hacer reaccionar un compuesto representado por la fórmula (7), en la cual X1, X2, Y, n , G y Q son como se los definió precedentemente, con un agente tionizante.
ARP030104573A 2002-12-11 2003-12-11 Compuestos de haloalqueno, proceso para su producion y pesticidas que los contienen AR042436A1 (es)

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CN104163792B (zh) * 2013-05-20 2017-04-12 湖南化工研究院 N‑吡啶酰胺类化合物及其制备方法与应用
CN111909031B (zh) * 2020-08-14 2021-10-15 华东师范大学 一种偕二氟烯基取代的烷基羧酸类化合物及其合成方法
CN112694436B (zh) * 2020-12-30 2022-07-08 济南周行医药科技有限公司 一种槟榔碱的合成方法

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US4950666A (en) * 1989-03-30 1990-08-21 Fmc Corporation Difluoroalkane and difluoroalkenylalkane pesticides
DE3941966A1 (de) * 1989-12-15 1991-06-20 Schering Ag Halogenierte olefine, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel
ES2123553T3 (es) * 1991-03-01 1999-01-16 Monsanto Co Compuestos fluoroalquenilo y su uso como repelentes de plagas.
DE19531300A1 (de) * 1995-08-25 1997-02-27 Bayer Ag Fluorbutensäureamide

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