AR034319A1 - SUBSTITUTED BENZOILCICLOHEXENONES, PROCEDURE FOR OBTAINING HERBICIDAL COMPOSITIONS, USE OF THESE COMPOUNDS TO CONTROL INDESEABLE PLANTS, AND METHOD FOR THE CONTROL OF INDESEABLE PLANTS - Google Patents

SUBSTITUTED BENZOILCICLOHEXENONES, PROCEDURE FOR OBTAINING HERBICIDAL COMPOSITIONS, USE OF THESE COMPOUNDS TO CONTROL INDESEABLE PLANTS, AND METHOD FOR THE CONTROL OF INDESEABLE PLANTS

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AR034319A1
AR034319A1 ARP020101568A ARP020101568A AR034319A1 AR 034319 A1 AR034319 A1 AR 034319A1 AR P020101568 A ARP020101568 A AR P020101568A AR P020101568 A ARP020101568 A AR P020101568A AR 034319 A1 AR034319 A1 AR 034319A1
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Argentina
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alkylthio
alkyl
compounds
alkylamino
alkoxy
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ARP020101568A
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Spanish (es)
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Bayer Ag
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    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/06—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D239/08—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms directly attached in position 2
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    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07C233/30—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by doubly-bound oxygen atoms
    • C07C233/33—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by doubly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
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    • C07C233/61—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of rings other than six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by doubly-bound oxygen atoms
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    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
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    • C07C275/38—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by doubly-bound oxygen atoms
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    • C07C317/34—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring
    • C07C317/38—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring with the nitrogen atom of at least one amino group being part of any of the groups, X being a hetero atom, Y being any atom, e.g. N-acylaminosulfones
    • C07C317/42—Y being a hetero atom
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    • C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/10—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/38—Nitrogen atoms
    • C07D277/44—Acylated amino or imino radicals
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    • C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
    • C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
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    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
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    • C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
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    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
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    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/22—All rings being cycloaliphatic the ring system containing eight carbon atoms, e.g. pentalene

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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Benzoilciclohexenonas substituidas que tienen la fórmula (1), en la que: Q significa O ó S; R1 significa hidrógeno, halógeno o significa alquilo, alquiltio o arilo substituidos respectiva y opcionalmente; R2 significa hidrógeno, halógeno o alquilo opcionalmente substituido, o junto con R1 significa O ó alcanodiilo (alquileno); R3 significa hidrógeno, nitro, ciano, carboxilo, carbamoilo, tiocarbamoilo, halógeno o significa alquilo, alcoxi, alquiltio, alquilsulfinilo, alquilsulfonilo, alquilamino, dialquilamino, dialquilaminocarbonilo o dialquilaminosulfonilo substituidos respectiva y opcionalmente; R4 significa hidrógeno, nitro, ciano, carboxilo, carbamoilo, tiocarbamoilo, halógeno o significa alquilo, alcoxi, alquiltio, alquilsulfinilo, alquilsulfonilo, alquilamino, dialquilamino, dialquilaminocarbonilo o dialquilaminosulfonilo substituidos respectiva y opcionalmente; R5 significa hidrógeno o significa alquilo, alcoxi, alquiltio, alquilsulfinilo, alquilsulfonilo, alquenilo, alquinilo, cicloalquilo, cicloalquilalquilo, arilo, ariltio, arilsulfinilo, arilsulfonilo, arilalquilo substituidos respectiva y opcionalmente, o significa el agrupamiento -C(Q)-Z; Y significa hidroxilo, halógeno o significa alcoxi, alquiltio, alquilsulfinilo, alquilsulfonilo, alquilcarboniloxi, alcoxicarboniloxi, alquilaminocarboniloxi, alquilsulfoniloxi, alqueniloxi, alquiniloxi, ariloxi, ariltio, arilsulfinilo, arilsulfonilo, arilcarboniloxi, arilcarbonilalcoxi, arilsulfoniloxi, arilalcoxi, arilalquiltio, arilalquilsulfinilo o arilalquilsulfonilo; y Z significa hidrógeno, amino, cianoamino, nitroamino, hidroxiamino, hidrazino o significa alquilo, alquilcarbonilo, alcoxi, alcoxicarbonilo, alquiltio, alquilamino, alcoxiamino, alquilhidrazino, alquilcarbonilhidrazino, alcoxicarbonilhidrazino, alquilsulfonilhidrazino, dialquilamino, N-alquil-alcoxiamino, dialquilhidrazino, alquenilo, alqueniloxi, alquenilamino, alqueniloxiamino, alquinilo, alquiniloxi, alquilnilamino, cicloalquilo, cicloalquiloxi, cicloalquilamino, cicloalquilhidrazino, cicloalquilalquilo, cicloalquilalcoxi, cicloalquilalquilamino, arilo, arilcarbonilo, ariloxi, ariloxicarbonilo, ariltio, arilamino, arilhidrazino, arilalquilo, arilalcoxi, arilalquiltio, arilalquilamino, heterociclilo, heterocicliloxi, heterocicliltio, heterociclilamino, el agrupamiento -N=(heterociclilo), heterociclilalquilo, heterociclilalcoxi, heterociclilalquiltio o heterociclilalquilamino substituidos respectiva y opcionalmente; con la inclusión de todas las posibles formas tautómeras de los compuestos de la fórmula general (1) y de las posibles sales de los compuestos de la fórmula general (1), con excepción de los compuestos N-[2,6-dicloro-3-[(3,3-dimetil-2,6-dioxo-ciclohexil)-carbonil]fenil-acetamida, N-[2-cloro-3-[2,6-dioxo-ciclohexil)-carbonil]-4-nitro-fenil]-acetamida, N-[2-cloro-3-[(2,6-dioxo-ciclohexil)-carbonil]-fenil]-acetamida y N-[2,6-dicloro-3-[(2,6-dioxo-ciclohexil)-carbonil]-fenil]-acetamida; procedimiento para su obtención, composiciones herbicidas, empleo de estos compuestos para controlar las plantas indeseables, y método para el control de plantas indeseables.Substituted benzoylcyclohexenones having the formula (1), in which: Q means O or S; R1 means hydrogen, halogen or means alkyl, alkylthio or aryl substituted respectively and optionally; R2 means hydrogen, halogen or optionally substituted alkyl, or together with R1 means O or alkanediyl (alkylene); R3 means hydrogen, nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, halogen or means alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, dialkylaminocarbonyl or dialkylaminosulfonyl respectively and optionally substituted; R4 means hydrogen, nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, halogen or means alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, dialkylaminocarbonyl or dialkylaminosulfonyl respectively and optionally substituted; R5 means hydrogen or means alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, aryl, arylthio, arylsulfinyl, arylsulfonyl, aryl alkyl respectively and optionally substituted, or means the grouping -C (Q) -Z; Y represents hydroxyl, halogen or alkoxy means, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylcarbonyloxy, alkoxycarbonyloxy, alkylaminocarbonyloxy, alkylsulphonyloxy, alkenyloxy, alkynyloxy, aryloxy, arylthio, arylsulfinyl, arylsulfonyl, arylcarbonyloxy, arilcarbonilalcoxi, arylsulfonyloxy, arylalkoxy, arylalkylthio, arylalkylsulfinyl or arylalkylsulfonyl; and Z means hydrogen, amino, cyanoamino, nitroamino, hydroxyamino, hydrazino or means alkyl, alkylcarbonyl, alkoxy, alkoxycarbonyl, alkylthio, alkylamino, alkoxyamino, alkylhydrazino, alkylcarbonylhydrazino, alkoxycarbonylhydrazino, alkylsulfonylhydrazino, dialkylamino, N-alkylalkyl, alkylamino, alkylamino alkenyloxy, alkenylamino, alqueniloxiamino, alkynyl, alkynyloxy, alquilnilamino, cycloalkyl, cycloalkyloxy, cycloalkylamino, cicloalquilhidrazino, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylalkylamino, aryl, arylcarbonyl, aryloxy, aryloxycarbonyl, arylthio, arylamino, arylhydrazino, arylalkyl, arylalkoxy, arylalkylthio, arylalkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, the grouping -N = (heterocyclyl), heterocyclylalkyl, heterocyclylalkoxy, heterocyclylalkylthio or heterocyclylalkylamino respectively and optionally substituted; with the inclusion of all possible tautomeric forms of the compounds of the general formula (1) and of the possible salts of the compounds of the general formula (1), with the exception of the compounds N- [2,6-dichloro-3 - [(3,3-Dimethyl-2,6-dioxo-cyclohexyl) -carbonyl] phenyl-acetamide, N- [2-chloro-3- [2,6-dioxo-cyclohexyl) -carbonyl] -4-nitro- phenyl] -acetamide, N- [2-chloro-3 - [(2,6-dioxo-cyclohexyl) -carbonyl] -phenyl] -acetamide and N- [2,6-dichloro-3 - [(2,6- dioxo-cyclohexyl) -carbonyl] -phenyl] -acetamide; procedure for obtaining, herbicidal compositions, use of these compounds to control undesirable plants, and method for the control of undesirable plants.

ARP020101568A 2001-05-16 2002-04-29 SUBSTITUTED BENZOILCICLOHEXENONES, PROCEDURE FOR OBTAINING HERBICIDAL COMPOSITIONS, USE OF THESE COMPOUNDS TO CONTROL INDESEABLE PLANTS, AND METHOD FOR THE CONTROL OF INDESEABLE PLANTS AR034319A1 (en)

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Application Number Priority Date Filing Date Title
DE10123887 2001-05-16
DE10138576A DE10138576A1 (en) 2001-05-16 2001-08-06 New substituted benzoylcyclohexenone derivatives useful as antimicrobials and herbicides, especially for selective application in transgenic crops

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ES2349257T3 (en) 2010-12-29
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ATE476421T1 (en) 2010-08-15

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