AR028816A1 - "N-ALCOXIAMINS IMPEDED REPLACED WITH HYDROXY, COMPOSITION, PROCESS TO STABILIZE AN ORGANIC POLYMER OR RECORDING MATERIAL AGAINST DAMAGES PRODUCED BY LIGHT, OXYGEN AND / OR HEAT, AND PROCESS TO PREPARE NES. - Google Patents

"N-ALCOXIAMINS IMPEDED REPLACED WITH HYDROXY, COMPOSITION, PROCESS TO STABILIZE AN ORGANIC POLYMER OR RECORDING MATERIAL AGAINST DAMAGES PRODUCED BY LIGHT, OXYGEN AND / OR HEAT, AND PROCESS TO PREPARE NES.

Info

Publication number
AR028816A1
AR028816A1 ARP000100764A ARP000100764A AR028816A1 AR 028816 A1 AR028816 A1 AR 028816A1 AR P000100764 A ARP000100764 A AR P000100764A AR P000100764 A ARP000100764 A AR P000100764A AR 028816 A1 AR028816 A1 AR 028816A1
Authority
AR
Argentina
Prior art keywords
stabilize
oxygen
recording material
heat
light
Prior art date
Application number
ARP000100764A
Other languages
Spanish (es)
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/257,711 external-priority patent/US6271377B1/en
Priority claimed from US09/315,704 external-priority patent/US6166212A/en
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of AR028816A1 publication Critical patent/AR028816A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/98—Nitrogen atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Hydrogenated Pyridines (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)
  • Saccharide Compounds (AREA)

Abstract

Las aminas impedidas sustituidas en el átomo N con una porcion ûO-E-OH son especialmente efectivas para estabilizar composiciones de poliolefinas y revestimientos para automotores contra los efectos deletéreos de la radiacion actínica, oxidativa y térmica en las que la presencia del grupo OH en los compuestos agrega propiedades importantes que no se pueden obtener mediante el uso de porciones ûO û E - normales. Se preparan convenientemente mediante la reaccion del correspondiente compuesto N - oxilo con un alcohol en presencia de un peroxido o de un hidroperoxido orgánico y una cantidad catalítica de una sal de metal o complejo metal û ligando. Las formulas de las aminas son 1 a 30 donde los sustituyentes tienen los significados dados en la memoria descriptiva. Proceso para estabilizar un polímero orgánico o material de registro contra los danos producidos por la luz, el oxígeno y/o el calor y composiciones que contienen las aminas. Las aminas impedidas sustituidas en el átomo N con una porcion ûO û E û OH son especialmente efectivas para estabilizar composiciones de poliolefinas y revestimientos para automotores contra los efectos deletéreos de la radiacion actínica, oxidativa y térmica en las que la presencia del grupo OH en los compuestos agrega propiedades importantes que no se pueden obtener mediante el uso de porciones ûO û E- normales. Se preparan convenientemente mediante la reaccion del correspondiente compuesto N û oxilo con un alcohol en presencia de un peroxido o de un hidroperoxido orgánico y una cantidad catalítica de una sal de metal o complejo metal û ligando.The hindered amines substituted on the N atom with an ûO-E-OH portion are especially effective in stabilizing automotive polyolefin compositions and coatings against the deleterious effects of actinic, oxidative and thermal radiation in which the presence of the OH group in the Compounds add important properties that cannot be obtained by using ûO û E - normal portions. They are conveniently prepared by reacting the corresponding N-oxyl compound with an alcohol in the presence of an peroxide or an organic hydroperoxide and a catalytic amount of a metal salt or metal û ligand complex. The amines formulas are 1 to 30 where the substituents have the meanings given in the specification. Process to stabilize an organic polymer or recording material against damage caused by light, oxygen and / or heat and compositions containing amines. The hindered amines substituted on the N atom with a ûO û E û OH portion are especially effective in stabilizing automotive polyolefin compositions and coatings against the deleterious effects of actinic, oxidative and thermal radiation in which the presence of the OH group in the Compounds add important properties that cannot be obtained through the use of ûO û E-normal portions. They are conveniently prepared by reacting the corresponding N û oxyl compound with an alcohol in the presence of an peroxide or an organic hydroperoxide and a catalytic amount of a metal salt or metal û ligand complex.

ARP000100764A 1999-02-25 2000-02-23 "N-ALCOXIAMINS IMPEDED REPLACED WITH HYDROXY, COMPOSITION, PROCESS TO STABILIZE AN ORGANIC POLYMER OR RECORDING MATERIAL AGAINST DAMAGES PRODUCED BY LIGHT, OXYGEN AND / OR HEAT, AND PROCESS TO PREPARE NES. AR028816A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/257,711 US6271377B1 (en) 1999-02-25 1999-02-25 Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith
US09/315,704 US6166212A (en) 1999-05-20 1999-05-20 Process for the synthesis of N-(hydroxyalkoxy) substituted hindered amine stabilizers

Publications (1)

Publication Number Publication Date
AR028816A1 true AR028816A1 (en) 2003-05-28

Family

ID=26946156

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP000100764A AR028816A1 (en) 1999-02-25 2000-02-23 "N-ALCOXIAMINS IMPEDED REPLACED WITH HYDROXY, COMPOSITION, PROCESS TO STABILIZE AN ORGANIC POLYMER OR RECORDING MATERIAL AGAINST DAMAGES PRODUCED BY LIGHT, OXYGEN AND / OR HEAT, AND PROCESS TO PREPARE NES.

Country Status (18)

Country Link
JP (1) JP4757977B2 (en)
KR (1) KR100676473B1 (en)
CN (1) CN1230424C (en)
AR (1) AR028816A1 (en)
AU (1) AU773104B2 (en)
BE (1) BE1013530A5 (en)
BR (1) BR0000666B1 (en)
CA (1) CA2299754C (en)
DE (1) DE10008367B4 (en)
ES (1) ES2195674B1 (en)
FR (1) FR2790259B1 (en)
GB (2) GB0003326D0 (en)
IN (1) IN2000CH00150A (en)
IT (1) IT1319167B1 (en)
MX (1) MXPA00001961A (en)
NL (1) NL1014414C2 (en)
RU (1) RU2243216C2 (en)
TW (1) TW491876B (en)

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GB2377703B (en) * 1998-12-14 2003-06-18 Ciba Sc Holding Ag Sterically hindered amine compounds
US6376584B1 (en) * 1999-02-25 2002-04-23 Ciba Specialty Chemicals Corporation Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith
TWI273115B (en) * 2000-12-12 2007-02-11 Ciba Sc Holding Ag Improved weatherability of flame retardant polyolefin
DE10106543A1 (en) * 2001-02-13 2002-08-22 Basf Ag Coating compositions
US20030040593A1 (en) * 2001-04-26 2003-02-27 Nobuya Saegusa Vinyl-polymerizable monomer having tertiary hydroxyl group and polymer
JP4562324B2 (en) * 2001-07-06 2010-10-13 株式会社Ａｄｅｋａ Stabilized polyurethane resin
ITMI20012081A1 (en) 2001-10-09 2003-04-09 3V Sigma Spa LIQUID COMPOSITIONS OF STABILIZED PEROXIDES
MXPA05009108A (en) * 2003-02-26 2005-10-20 Ciba Sc Holding Ag Water compatible sterically hindered alkoxyamines and hydroxy substituted alkoxyamines.
CN1823042B (en) * 2003-07-14 2010-06-23 西巴特殊化学品控股有限公司 Hydrogen peroxide catalyzed process for the preparation of sterically hindered N-hydrocarbyloxyamines
US7595011B2 (en) 2004-07-12 2009-09-29 Ciba Specialty Chemicals Corporation Stabilized electrochromic media
US7410936B2 (en) 2004-08-23 2008-08-12 Ciba Specialty Chemicals Corporation Stabilized body care products, household products, textiles and fabrics
US20070072965A1 (en) * 2005-09-23 2007-03-29 Mouhcine Kanouni Color fast polyurethanes
US8481726B2 (en) 2006-07-05 2013-07-09 Basf Se Process for the preparation of sterically hindered nitroxyl ethers
EP2035381B1 (en) * 2006-07-05 2010-12-29 Basf Se Process for the preparation of sterically hindered nitroxyl ethers
CN101484423B (en) * 2006-07-05 2011-09-07 西巴控股有限公司 Process for the preparation of sterically hindered nitroxyl ethers
EP2467424A1 (en) * 2009-08-18 2012-06-27 Basf Se Photovoltaic module with stabilized polymeric encapsulant
EP2708574A1 (en) * 2012-09-18 2014-03-19 Clariant International Ltd. Oxygen scavenging plastic material
JP6216890B2 (en) * 2013-09-30 2017-10-18 サートゥンティード コーポレーション Antifouling and VOC removal paint and use thereof
CA2940970C (en) 2014-02-28 2019-03-19 Exxonmobil Chemical Patents Inc. Mooney viscosity stable brominated elastomers
SA116370295B1 (en) * 2015-02-20 2016-12-06 باسف اس اى Light stabilized polyolefin films, tapes and monofilaments
TW201718742A (en) * 2015-07-20 2017-06-01 巴地斯公司 Flame-retardant polyolefin systems
CN105085376B (en) * 2015-09-07 2018-01-05 江苏裕兴薄膜科技股份有限公司 A kind of glycol monomer and its polyester copolymer containing hindered amine group
US10767073B2 (en) * 2016-10-18 2020-09-08 Ppg Industries Ohio, Inc. Curable film-forming compositions containing hydroxyl functional, branched acrylic polymers and multilayer composite coatings
KR102201293B1 (en) * 2019-05-15 2021-01-11 한국신발피혁연구원 Urethane acrylate hybrid coating composition for weather strips
CN112126060B (en) * 2019-06-25 2022-05-31 北京天罡助剂有限责任公司 Polymeric high-molecular steric hindrance amine and preparation method thereof
CN110606986B (en) * 2019-09-20 2020-05-22 杭州聚丰新材料有限公司 Silicone rubber cross-linking agent, and preparation method and application thereof
CN110903237A (en) * 2019-12-16 2020-03-24 兰州精细化工有限责任公司 Preparation method of bis (1-octyloxy-2, 2,6, 6-tetramethyl-4-piperidyl) sebacate
US20230095019A1 (en) 2019-12-27 2023-03-30 Diahachi Chemical Industry Co., Ltd. Flame retardant composition and flame-retardant thermoplastic resin composition containing said flame retardant composit
CN112778990B (en) * 2021-02-05 2022-06-03 西南石油大学 Sewage mixing temporary plugging agent for oilfield water injection well and preparation method thereof
CN113582914B (en) * 2021-08-02 2023-11-03 天津利安隆新材料股份有限公司 Preparation method of hydroxyl-containing hindered amine light stabilizer
KR102497017B1 (en) * 2021-08-26 2023-02-07 강남제비스코 주식회사 AcrylPolyol type Surfacer composition for LiDAR reflectance
CN115746688B (en) * 2021-12-06 2023-05-23 烟台大学 Powdered self-repairing flame-retardant low-VOC polyurethane coating key material and application thereof
CN114940684B (en) * 2022-05-24 2023-07-21 浙江大学温州研究院 White light-emitting copper halide complex and preparation method and application thereof
CN116082705B (en) * 2022-12-05 2023-09-12 苏州易昇光学材料股份有限公司 Anti-yellowing self-repairing gel

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JPH0952975A (en) * 1995-08-18 1997-02-25 Clariant Internatl Ltd Stabilizing method for pigment and composition used therefor
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US5844025A (en) * 1996-12-02 1998-12-01 Ciba Specialty Chemicals Corporation 1,2-Bis-adducts of stable nitroxides with substituted ethylenes and stabilized compositions
TW509683B (en) * 1997-05-27 2002-11-11 Ciba Sc Holding Ag Triazine derivatives containing 2,2,6,6-tetramethyl-4-piperidyl groups
AU4614200A (en) * 1999-06-23 2001-01-09 Nof Corporation Vinylated alkoxyamine, use thereof, and process for producing the same
DE50004231D1 (en) * 1999-09-07 2003-12-04 Bayer Ag Functionalized alkoxyamine initiators

Also Published As

Publication number Publication date
FR2790259B1 (en) 2004-10-01
IT1319167B1 (en) 2003-09-26
BR0000666A (en) 2001-01-16
BE1013530A5 (en) 2002-03-05
CA2299754A1 (en) 2000-08-25
AU773104B2 (en) 2004-05-13
NL1014414A1 (en) 2000-08-28
ES2195674B1 (en) 2005-03-16
CN1273241A (en) 2000-11-15
GB0004127D0 (en) 2000-04-12
JP2000302758A (en) 2000-10-31
KR100676473B1 (en) 2007-02-05
NL1014414C2 (en) 2001-07-17
AU1945400A (en) 2000-09-14
CN1230424C (en) 2005-12-07
ITMI20000327A0 (en) 2000-02-23
MXPA00001961A (en) 2002-05-23
CA2299754C (en) 2010-02-09
RU2243216C2 (en) 2004-12-27
BR0000666B1 (en) 2011-03-09
ITMI20000327A1 (en) 2001-08-23
TW491876B (en) 2002-06-21
GB2347928B (en) 2001-11-28
FR2790259A1 (en) 2000-09-01
KR20010014505A (en) 2001-02-26
GB0003326D0 (en) 2000-04-05
ES2195674A1 (en) 2003-12-01
JP4757977B2 (en) 2011-08-24
DE10008367B4 (en) 2014-08-28
DE10008367A1 (en) 2000-08-31
GB2347928A (en) 2000-09-20
IN2000CH00150A (en) 2007-04-27

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