AR015293A1 - Proceso continuo de flujo horizontal de polimerizacion por radicales libres para la manufactura de polimeros hidrosolubles a partir de monomeros ensolucion acuosa - Google Patents
Proceso continuo de flujo horizontal de polimerizacion por radicales libres para la manufactura de polimeros hidrosolubles a partir de monomeros ensolucion acuosaInfo
- Publication number
- AR015293A1 AR015293A1 ARP990102220A ARP990102220A AR015293A1 AR 015293 A1 AR015293 A1 AR 015293A1 AR P990102220 A ARP990102220 A AR P990102220A AR P990102220 A ARP990102220 A AR P990102220A AR 015293 A1 AR015293 A1 AR 015293A1
- Authority
- AR
- Argentina
- Prior art keywords
- polymers
- mixing
- polymerization
- solution
- horizontal flow
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/10—Aqueous solvent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La presente invencion se refiere a un proceso acuoso, continuo, de flujo horizontal, de direcciones multiples para la polimerizacion por radicales libresde monomeros para su posterior procesamiento a polímeros deshidratados que comprende los pasosde : a) preparar una solucion acuosa de uno o más monomeroshidrosolubles teniendo una concentracion de aproximadamente 5 a aproximadamente 80% en peso; b) alimentar de manera continua la solucion a un reactor alineadohorizontalmente que tenga unacavida d interior, un alojamiento exterior, un extremo de entrada, un extremo de salida y un dispositivo de transporte y mezcladentro de la cavidad interior; c) mezclar y contramezclar la solucion a medida que es transportada desde el extremo deentrada hac ia el extremo de salida através de la cavidad interior del reactor, mediante un dispositivo bajo condiciones de polimerizacion por radicales libres; y d) retirar de manera continua unasolucion polimérica por el extremo de salida delreactor. El proce so permite una polimerizacion eficiente de los monomeros en una solucion acuosa, en presenciade un catalizador de radicales libres, mediante un contramezclado. Utilizando este proceso, se obtienen polímeros hidrosolubles con unpeso molecular deaprox imadamente 3.000 a 30.000.000 y de preferencia de aproximadamente 500.000 a 10.000.000.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/075,684 US6103839A (en) | 1998-05-11 | 1998-05-11 | Horizontally flowing continuous free radical polymerization process for manufacturing water-soluble polymers from monomers in aqueous solution |
Publications (1)
Publication Number | Publication Date |
---|---|
AR015293A1 true AR015293A1 (es) | 2001-04-18 |
Family
ID=22127345
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP990102220A AR015293A1 (es) | 1998-05-11 | 1999-05-11 | Proceso continuo de flujo horizontal de polimerizacion por radicales libres para la manufactura de polimeros hidrosolubles a partir de monomeros ensolucion acuosa |
Country Status (5)
Country | Link |
---|---|
US (1) | US6103839A (es) |
AR (1) | AR015293A1 (es) |
AU (1) | AU3769099A (es) |
CO (1) | CO5040130A1 (es) |
WO (1) | WO1999058576A1 (es) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19941072A1 (de) * | 1999-08-30 | 2001-03-01 | Stockhausen Chem Fab Gmbh | Polymerisatzusammensetzung und ein Verfahren zu dessen Herstellung |
US6605674B1 (en) | 2000-06-29 | 2003-08-12 | Ondeo Nalco Company | Structurally-modified polymer flocculants |
US7666963B2 (en) * | 2005-07-21 | 2010-02-23 | Akzo Nobel N.V. | Hybrid copolymers |
CN100412099C (zh) * | 2005-11-07 | 2008-08-20 | 董延茂 | 一种复合式改性淀粉絮凝剂及其制备 |
US8674021B2 (en) | 2006-07-21 | 2014-03-18 | Akzo Nobel N.V. | Sulfonated graft copolymers |
NO20073821L (no) * | 2006-07-21 | 2008-01-22 | Akzo Nobel Chemicals Int Bv | Podede kopolymerer med lav molekylvekt |
WO2011025624A1 (en) | 2009-07-31 | 2011-03-03 | Akzo Nobel N.V. | Graft copolymers |
US8636918B2 (en) | 2011-08-05 | 2014-01-28 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale |
US8853144B2 (en) | 2011-08-05 | 2014-10-07 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage |
US8841246B2 (en) | 2011-08-05 | 2014-09-23 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage |
US8679366B2 (en) | 2011-08-05 | 2014-03-25 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale |
IN2014DN03123A (es) | 2011-11-04 | 2015-05-22 | Akzo Nobel Chemicals Int Bv | |
MX2014005089A (es) | 2011-11-04 | 2014-08-08 | Akzo Nobel Chemicals Int Bv | Copolimeros de dendrita de injerto, y metodos para producir los mismos. |
US8945314B2 (en) | 2012-07-30 | 2015-02-03 | Ecolab Usa Inc. | Biodegradable stability binding agent for a solid detergent |
US9365805B2 (en) | 2014-05-15 | 2016-06-14 | Ecolab Usa Inc. | Bio-based pot and pan pre-soak |
FR3029524B1 (fr) | 2014-12-08 | 2018-03-02 | Coatex | Procede continu d'esterification et ou d'amidification, sans solvant organique, d'un homopolymere ou copolymere acide |
EP3719107A1 (en) | 2016-05-23 | 2020-10-07 | Ecolab USA Inc. | Reduced misting acidic cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers |
ES2808999T3 (es) | 2016-05-23 | 2021-03-02 | Ecolab Usa Inc | Composiciones de limpieza antisépticas y desinfectantes alcalinas y neutras con reducción de la formación de neblina a través del uso de polímeros de emulsión de agua en aceite de alto peso molecular |
CN110392528A (zh) | 2017-03-01 | 2019-10-29 | 埃科莱布美国股份有限公司 | 通过高分子量聚合物减少吸入危险的消毒剂和杀菌剂 |
CN108503751B (zh) * | 2018-02-08 | 2020-09-18 | 西北民族大学 | 季铵化聚合物修饰的纳米淀粉复合颗粒材料的制备及应用 |
WO2021011451A1 (en) | 2019-07-12 | 2021-01-21 | Ecolab Usa Inc. | Reduced mist alkaline cleaner via the use of alkali soluble emulsion polymers |
CN113443691A (zh) * | 2021-07-20 | 2021-09-28 | 上海泓济环保科技股份有限公司 | 一种利用丙烯酸丁酯生产尾水制备聚丙烯酸钠絮凝剂的方法 |
CN114316107B (zh) * | 2022-01-07 | 2023-08-18 | 安徽富瑞雪化工科技股份有限公司 | 一种高吸水性树脂的新型生产方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT309789B (de) * | 1967-11-20 | 1973-09-10 | Buss Ag | Misch- und Knetvorrichtung für plastische Massen |
US3732193A (en) * | 1971-04-28 | 1973-05-08 | Nalco Chemical Co | Thin film process for polymerization of water soluble monomers |
AT315467B (de) * | 1971-05-17 | 1974-05-27 | Buss Ag | Misch- und Kneteinrichtung |
US4138539A (en) * | 1975-06-19 | 1979-02-06 | American Cyanamid Company | Process for water-soluble synthetic polymer in powder form |
US4046718A (en) * | 1976-06-17 | 1977-09-06 | The Dow Chemical Company | Polymerization method employing tubular reactor |
US4143222A (en) * | 1977-08-18 | 1979-03-06 | Nalco Chemical Company | Method of controlling the molecular weight of vinyl carboxylic acid-acrylamide copolymers |
US4110521A (en) * | 1977-09-21 | 1978-08-29 | Calgon Corporation | Continuous polymerization apparatus and process |
US4196272A (en) * | 1978-11-27 | 1980-04-01 | Nalco Chemical Company | Continuous process for the preparation of an acrylic acid-methyl acrylate copolymer in a tubular reactor |
DE3135196A1 (de) * | 1981-09-05 | 1983-03-17 | Merck Patent Gmbh, 6100 Darmstadt | Verfahren, mittel und vorrichtung zur bestimmung biologischer komponenten |
US4551515A (en) * | 1984-02-27 | 1985-11-05 | General Electric Company | Process for the continuous manufacture of silicone gums |
US4619979A (en) * | 1984-03-28 | 1986-10-28 | Minnesota Mining And Manufacturing Company | Continuous free radial polymerization in a wiped-surface reactor |
US4625001A (en) * | 1984-09-25 | 1986-11-25 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for continuous production of cross-linked polymer |
DE3514367A1 (de) * | 1985-04-20 | 1986-10-23 | Basf Ag, 6700 Ludwigshafen | Vorrichtung zur feststoffbettpolymerisation von monomeren |
US4812544A (en) * | 1985-09-10 | 1989-03-14 | The Lubrizol Corporation | Method of producing polymers of amido-sulfonic acid monomers with high energy agitators |
DE3537276A1 (de) * | 1985-10-19 | 1987-04-23 | Basf Ag | Verfahren zur kontinuierlichen herstellung von vernetzten feinteiligen gelfoermigen polymerisaten |
DE3544770A1 (de) * | 1985-12-18 | 1987-06-19 | Stockhausen Chem Fab Gmbh | Verfahren und vorrichtung zum kontinuierlichen herstellen von polymerisaten und copolymerisaten der acrylsaeure und/oder methacrylsaeure |
-
1998
- 1998-05-11 US US09/075,684 patent/US6103839A/en not_active Expired - Lifetime
-
1999
- 1999-04-28 WO PCT/US1999/009226 patent/WO1999058576A1/en active Application Filing
- 1999-04-28 AU AU37690/99A patent/AU3769099A/en not_active Abandoned
- 1999-05-07 CO CO99028330A patent/CO5040130A1/es unknown
- 1999-05-11 AR ARP990102220A patent/AR015293A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
CO5040130A1 (es) | 2001-05-29 |
US6103839A (en) | 2000-08-15 |
AU3769099A (en) | 1999-11-29 |
WO1999058576A1 (en) | 1999-11-18 |
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