AR011562A1 - Un proceso para la oxidacion en fase liquida de butano para producir acido acetico y un reactor para llevar a cabo dicho proceso - Google Patents

Un proceso para la oxidacion en fase liquida de butano para producir acido acetico y un reactor para llevar a cabo dicho proceso

Info

Publication number
AR011562A1
AR011562A1 ARP980100281A ARP980100281A AR011562A1 AR 011562 A1 AR011562 A1 AR 011562A1 AR P980100281 A ARP980100281 A AR P980100281A AR P980100281 A ARP980100281 A AR P980100281A AR 011562 A1 AR011562 A1 AR 011562A1
Authority
AR
Argentina
Prior art keywords
liquid
reaction
reaction zone
gas
butane
Prior art date
Application number
ARP980100281A
Other languages
English (en)
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10806385&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AR011562(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Publication of AR011562A1 publication Critical patent/AR011562A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2219/0011—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00186—Controlling or regulating processes controlling the composition of the reactive mixture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un proceso para la oxidacion en fase líquida de butano para producir ácido acético por reaccion de oxígeno y butano en presencia de un catalizador decobalto en una composicion de reaccion líquida en una zona de reaccion de oxidacion, que se lleva a cabo a una temperatura en la zona de reaccion delorden de 120 a 180°C, al mismo tiempo que se mantiene de forma continua una concentracion de oxígeno por toda la zona de reaccion equivalente a una presionparcial de oxígeno superior 2 bares,y una concentracion de catalizador de cobalto para la oxidacion en la composicion de reaccion líquida de por lomenos 0,12% en peso de cobalto y hasta su límite de solubilidad en la composicion de reaccion líquida. Un reactor adecuadopara usarse en laproduccion de ácido acético comprende dos zonas de reaccion en donde una primera zona de reaccion es capaz de alojar una primera composicion de reaccionlíquida en recirculacion sin ninguna interfase gas/líquido con una fasegaseosa de cabeza y una segunda zona de reaccion capaz de alojar una segundacomposicion de reaccion líquida con una interfase gas/líquido y con una fase gaseosa de cabeza, estando adaptada dicha primera zona de reaccion para alojarun medio de entrada para el gas y/o líquido y un medio deflector adaptado para utilizarse en la dispersion por toda la primera zona de reaccion del gas/líquido introducidos a través del medio de entrada.
ARP980100281A 1997-01-22 1998-01-22 Un proceso para la oxidacion en fase liquida de butano para producir acido acetico y un reactor para llevar a cabo dicho proceso AR011562A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9701251.2A GB9701251D0 (en) 1997-01-22 1997-01-22 Process

Publications (1)

Publication Number Publication Date
AR011562A1 true AR011562A1 (es) 2000-08-30

Family

ID=10806385

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP980100281A AR011562A1 (es) 1997-01-22 1998-01-22 Un proceso para la oxidacion en fase liquida de butano para producir acido acetico y un reactor para llevar a cabo dicho proceso

Country Status (16)

Country Link
US (1) US6057475A (es)
EP (1) EP0966422A1 (es)
JP (1) JP2001508453A (es)
KR (1) KR20000070341A (es)
CN (1) CN1250433A (es)
AR (1) AR011562A1 (es)
AU (1) AU5672798A (es)
BR (1) BR9806967A (es)
CA (1) CA2278012A1 (es)
GB (1) GB9701251D0 (es)
ID (1) ID22136A (es)
NO (1) NO993543L (es)
TW (1) TW453988B (es)
WO (1) WO1998032725A1 (es)
YU (1) YU33699A (es)
ZA (1) ZA98496B (es)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6215027B1 (en) * 1998-10-20 2001-04-10 Praxair Technology, Inc. Ballast gas use in liquid phase oxidation
DE10206168A1 (de) * 2002-02-14 2003-08-21 Guehring Joerg Kupplung für mudular aufgebaute Werkzeughalterarme
US7371894B2 (en) * 2004-09-02 2008-05-13 Eastman Chemical Company Optimized liquid-phase oxidation
US7741515B2 (en) 2004-09-02 2010-06-22 Eastman Chemical Company Optimized liquid-phase oxidation
US7608732B2 (en) * 2005-03-08 2009-10-27 Eastman Chemical Company Optimized liquid-phase oxidation
US7507857B2 (en) * 2004-09-02 2009-03-24 Eastman Chemical Company Optimized liquid-phase oxidation
US7361784B2 (en) * 2004-09-02 2008-04-22 Eastman Chemical Company Optimized liquid-phase oxidation
US7692036B2 (en) * 2004-11-29 2010-04-06 Eastman Chemical Company Optimized liquid-phase oxidation
US7608733B2 (en) * 2004-09-02 2009-10-27 Eastman Chemical Company Optimized liquid-phase oxidation
US7568361B2 (en) * 2004-09-02 2009-08-04 Eastman Chemical Company Optimized liquid-phase oxidation
US7692037B2 (en) 2004-09-02 2010-04-06 Eastman Chemical Company Optimized liquid-phase oxidation
KR101281347B1 (ko) * 2004-09-02 2013-07-02 그루포 페트로테멕스 에스.에이. 데 씨.브이. 최적화된 액상 산화 방법
US7683210B2 (en) * 2004-09-02 2010-03-23 Eastman Chemical Company Optimized liquid-phase oxidation
US7495125B2 (en) * 2004-09-02 2009-02-24 Eastman Chemical Company Optimized liquid-phase oxidation
US7504535B2 (en) * 2004-09-02 2009-03-17 Eastman Chemical Company Optimized liquid-phase oxidation
US7589231B2 (en) * 2004-09-02 2009-09-15 Eastman Chemical Company Optimized liquid-phase oxidation
US7572936B2 (en) * 2004-09-02 2009-08-11 Eastman Chemical Company Optimized liquid-phase oxidation
US7390921B2 (en) * 2004-09-02 2008-06-24 Eastman Chemical Company Optimized liquid-phase oxidation
US7563926B2 (en) * 2004-09-02 2009-07-21 Eastman Chemical Company Optimized liquid-phase oxidation
US7582793B2 (en) * 2004-09-02 2009-09-01 Eastman Chemical Company Optimized liquid-phase oxidation
US7381836B2 (en) * 2004-09-02 2008-06-03 Eastman Chemical Company Optimized liquid-phase oxidation
US7910769B2 (en) * 2004-09-02 2011-03-22 Eastman Chemical Company Optimized liquid-phase oxidation
US7482482B2 (en) * 2004-09-02 2009-01-27 Eastman Chemical Company Optimized liquid-phase oxidation
US7572932B2 (en) * 2004-09-02 2009-08-11 Eastman Chemical Company Optimized liquid-phase oxidation
US20060047153A1 (en) * 2004-09-02 2006-03-02 Wonders Alan G Optimized liquid-phase oxidation
US7586000B2 (en) * 2004-09-02 2009-09-08 Eastman Chemical Company Optimized liquid-phase oxidation
US7399882B2 (en) * 2004-09-02 2008-07-15 Eastman Chemical Company Optimized liquid-phase oxidation
JP2006248951A (ja) * 2005-03-09 2006-09-21 Daicel Chem Ind Ltd 脂肪族飽和カルボン酸の製造法
US7884232B2 (en) * 2005-06-16 2011-02-08 Eastman Chemical Company Optimized liquid-phase oxidation
US7355068B2 (en) * 2006-01-04 2008-04-08 Eastman Chemical Company Oxidation system with internal secondary reactor

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GB721914A (en) * 1951-06-30 1955-01-12 Celanese Corp Oxidation of hydrocarbons
GB1020797A (en) * 1964-03-12 1966-02-23 Tekkosha Kabushiki Kaisha Improvements in the production of monocarboxylic lower fatty acids
US3483250A (en) * 1966-07-08 1969-12-09 Halcon International Inc Oxidation of n-butane
BE749000A (fr) * 1969-05-01 1970-09-16 Gulf Research & Dev Cy Procede pour la conversion de butane en acide
US3644512A (en) * 1969-10-10 1972-02-22 Gulf Research Development Co Process for converting butane to acetic acid
US4032570A (en) * 1971-11-08 1977-06-28 Gulf Research & Development Company Process for converting butane to acetic acid
US3923882A (en) * 1974-04-17 1975-12-02 Union Carbide Corp Production of acetic acid
GB1528771A (en) * 1975-07-21 1978-10-18 Bp Chem Int Ltd Cobalt-catalysed oxidation of c3 to c7 saturated aliphatic hydrocarbons to acetic acid
GB1531247A (en) * 1975-11-03 1978-11-08 Bp Chem Int Ltd Cobalt-catalysed oxidation of hydrocarbons
US4111986A (en) * 1977-04-19 1978-09-05 Standard Oil Company (Indiana) Butane oxidation to acetic acid
US4158740A (en) * 1978-03-20 1979-06-19 Gulf Research & Development Company Oxidation of butane to acetic acid
NO800968L (no) * 1979-04-06 1980-10-07 Bp Chem Int Ltd Kontinuerlig prosess for fremstilling av oksygenholdige organiske forbindelser inneholdende en vesentlig andel eddiksyre
US4337356A (en) * 1980-03-20 1982-06-29 Union Carbide Corporation Catalytic liquid-phase oxidation of butane
CA1224486A (en) * 1983-05-23 1987-07-21 David J. Schreck Liquid phase oxidation of alkanes
US4900480A (en) * 1986-10-21 1990-02-13 Union Carbide Corporation Gas-liquid mixing
JPH06116217A (ja) * 1992-10-02 1994-04-26 Kuraray Co Ltd （±）−シス−４−アミノシクロペント−２−エンカルボン酸誘導体の光学分割法
US5371283A (en) * 1993-12-22 1994-12-06 Praxair Technology, Inc. Terephthalic acid production

Also Published As

Publication number Publication date
ID22136A (id) 1999-09-09
AU5672798A (en) 1998-08-18
YU33699A (sh) 2001-03-07
WO1998032725A1 (en) 1998-07-30
US6057475A (en) 2000-05-02
TW453988B (en) 2001-09-11
CN1250433A (zh) 2000-04-12
NO993543D0 (no) 1999-07-19
JP2001508453A (ja) 2001-06-26
NO993543L (no) 1999-09-21
KR20000070341A (ko) 2000-11-25
BR9806967A (es) 2000-03-21
ZA98496B (en) 1999-07-21
EP0966422A1 (en) 1999-12-29
GB9701251D0 (en) 1997-03-12
CA2278012A1 (en) 1998-07-30

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