AR011342A1 - Proceso para preparar un derivado de cianofosfonato o aminometilfosfonato - Google Patents
Proceso para preparar un derivado de cianofosfonato o aminometilfosfonatoInfo
- Publication number
- AR011342A1 AR011342A1 ARP970106296A ARP970106296A AR011342A1 AR 011342 A1 AR011342 A1 AR 011342A1 AR P970106296 A ARP970106296 A AR P970106296A AR P970106296 A ARP970106296 A AR P970106296A AR 011342 A1 AR011342 A1 AR 011342A1
- Authority
- AR
- Argentina
- Prior art keywords
- cyanophosphonate
- derivative
- derivatives
- synthesis
- produce
- Prior art date
Links
- UCDHYFZYUGDETN-UHFFFAOYSA-N cyanophosphonic acid Chemical class OP(O)(=O)C#N UCDHYFZYUGDETN-UHFFFAOYSA-N 0.000 title abstract 5
- MGRVRXRGTBOSHW-UHFFFAOYSA-N (aminomethyl)phosphonic acid Chemical compound NCP(O)(O)=O MGRVRXRGTBOSHW-UHFFFAOYSA-N 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 3
- 238000003786 synthesis reaction Methods 0.000 abstract 3
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 abstract 2
- 239000004009 herbicide Substances 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 abstract 1
- AGINPOJWTDKORT-UHFFFAOYSA-N [H]OP(=O)OC([H])([H])N Chemical class [H]OP(=O)OC([H])([H])N AGINPOJWTDKORT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003337 fertilizer Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- -1 halogen derivative of phosphorus Chemical class 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4068—Esters of pyrophosphonic acids; Esters of phosphonic acid anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3886—Acids containing the structure -C(=X)-P(=X)(XH)2 or NC-P(=X)(XH)2, (X = O, S, Se)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3895—Pyrophosphonic acids; phosphonic acid anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4062—Esters of acids containing the structure -C(=X)-P(=X)(XR)2 or NC-P(=X)(XR)2, (X = O, S, Se)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
Abstract
Comprende poner en contacto anhidrido fosforico y un cianuro en una mezcla de reaccion en condiciones adecuadas para producir un cianofosfonato;y opcionalmente, hidrogenar el derivado cianofosfonato en presencia de catalizadoradecua do bajo condiciones suficientes para producir un derivadoaminometilfosfonato. Los compuestos con contenido de fosforo tales como los derivados de cianofosfonato son precursores importantes para la síntesis decompuestos organofosforados,que tiene n numerosas aplicaciones, por ejemplo, en herbicidas, insecticidas, fertilizantes, retardadores de llama y pastificantes.Los derivados de cianofosfonato pueden ser convertidos en derivados de aminometilfosfonato, que han sidoprecursores par ticularmente importantes en lasíntesis de N-fosfonometilglicina, un herbicida comercial altamante eficaz (comercializado bajo la marca Roundup (TM)) util para el control de una granvariedad de malezas. Las síntesis de talescompuestos organofosf orados comunmente han usado un derivado halogeno de fosforo como material inicial.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3451296P | 1996-12-30 | 1996-12-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR011342A1 true AR011342A1 (es) | 2000-08-16 |
Family
ID=21876878
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP970106296A AR011342A1 (es) | 1996-12-30 | 1997-12-30 | Proceso para preparar un derivado de cianofosfonato o aminometilfosfonato |
Country Status (12)
Country | Link |
---|---|
US (1) | US5858317A (es) |
EP (1) | EP0948326B1 (es) |
JP (1) | JP2001507664A (es) |
AR (1) | AR011342A1 (es) |
AT (1) | ATE224186T1 (es) |
AU (1) | AU727126B2 (es) |
CA (1) | CA2276158A1 (es) |
DE (1) | DE69715666T2 (es) |
ES (1) | ES2184151T3 (es) |
IL (1) | IL130703A0 (es) |
WO (1) | WO1998029106A2 (es) |
ZA (1) | ZA9711676B (es) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2276158A1 (en) * | 1996-12-30 | 1998-07-09 | Monsanto Company | Method for preparing cyanophosphonate derivatives from phosphoric anhydride and cyanide |
US7155275B2 (en) * | 2004-10-18 | 2006-12-26 | Cardiac Pacemakers, Inc. | Method and apparatus for adjusting cardiac event detection threshold based on dynamic noise estimation |
US7947130B2 (en) | 2009-10-24 | 2011-05-24 | Wai Mun Lee | Troika acid semiconductor cleaning compositions and methods of use |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE300936C (es) * | ||||
US2402703A (en) * | 1942-08-06 | 1946-06-25 | Victor Chemical Works | Method of producing neutral esters of molecularly dehydrated phosphoric acids |
US2702299A (en) * | 1948-05-01 | 1955-02-15 | Monsanto Chemicals | Manufacture of tetraethyl pyrophosphate |
US3432277A (en) * | 1966-08-03 | 1969-03-11 | Du Pont | Derivatives of phosphinodithionic acid and method for their preparation |
DE2032712C3 (de) * | 1970-07-02 | 1978-10-19 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von w-Amino-alkanphosphonsäure bzw.- phosphinsäurederivaten |
JPS5838437B2 (ja) * | 1974-08-20 | 1983-08-23 | ニツポウカガク カブシキガイシヤ | ジアルキルシアノホスホネ−トノ セイゾウホウホウ |
US4221583A (en) * | 1978-12-22 | 1980-09-09 | Monsanto Company | N-Phosphonomethylglycinonitrile and certain derivatives thereof |
US4568432A (en) * | 1984-12-28 | 1986-02-04 | Monsanto Company | Process for preparing glyphosate and glyphosate derivatives |
GB9307234D0 (en) * | 1993-04-07 | 1993-06-02 | Zeneca Ltd | Process |
DK0717046T3 (da) * | 1994-07-01 | 2001-11-26 | Showa Denko Kk | Fremgangsmåde til fremstilling af phosphonsyrederivater |
GB9423254D0 (en) * | 1994-11-16 | 1995-01-04 | Zeneca Ltd | Process |
BR9714449A (pt) * | 1996-12-30 | 2000-03-21 | Monsanto Co | Método para a preparaçào de derivaods de fosfonato de aminometila através da hidrogenação de derivados de cianofosfonato |
EP0948504A1 (en) * | 1996-12-30 | 1999-10-13 | Monsanto Company | Preparation of cyanophosphonates from pyrophosphates and cyanide |
IL130700A (en) * | 1996-12-30 | 2002-11-10 | Monsanto Co | Cyanophosphorus compounds and their preparation |
WO1998029424A1 (en) * | 1996-12-30 | 1998-07-09 | Monsanto Company | Preparation of cyanophosphonates from phosphates and cyanide |
CA2276158A1 (en) * | 1996-12-30 | 1998-07-09 | Monsanto Company | Method for preparing cyanophosphonate derivatives from phosphoric anhydride and cyanide |
-
1997
- 1997-12-23 CA CA002276158A patent/CA2276158A1/en not_active Abandoned
- 1997-12-23 EP EP97954970A patent/EP0948326B1/en not_active Expired - Lifetime
- 1997-12-23 AT AT97954970T patent/ATE224186T1/de not_active IP Right Cessation
- 1997-12-23 US US08/996,949 patent/US5858317A/en not_active Expired - Fee Related
- 1997-12-23 AU AU61301/98A patent/AU727126B2/en not_active Ceased
- 1997-12-23 JP JP53011098A patent/JP2001507664A/ja active Pending
- 1997-12-23 WO PCT/US1997/023494 patent/WO1998029106A2/en active IP Right Grant
- 1997-12-23 IL IL13070397A patent/IL130703A0/xx unknown
- 1997-12-23 DE DE69715666T patent/DE69715666T2/de not_active Expired - Fee Related
- 1997-12-23 ES ES97954970T patent/ES2184151T3/es not_active Expired - Lifetime
- 1997-12-29 ZA ZA9711676A patent/ZA9711676B/xx unknown
- 1997-12-30 AR ARP970106296A patent/AR011342A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
WO1998029106A3 (en) | 1999-02-11 |
DE69715666D1 (de) | 2002-10-24 |
AU727126B2 (en) | 2000-11-30 |
IL130703A0 (en) | 2000-06-01 |
JP2001507664A (ja) | 2001-06-12 |
ES2184151T3 (es) | 2003-04-01 |
DE69715666T2 (de) | 2003-05-22 |
ZA9711676B (en) | 1999-06-15 |
EP0948326A2 (en) | 1999-10-13 |
AU6130198A (en) | 1998-07-31 |
ATE224186T1 (de) | 2002-10-15 |
CA2276158A1 (en) | 1998-07-09 |
WO1998029106A2 (en) | 1998-07-09 |
EP0948326B1 (en) | 2002-09-18 |
US5858317A (en) | 1999-01-12 |
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