WO2018157841A1 - Additive manufacturing method for interlayer-strengthened continuous fibre composite material - Google Patents

Additive manufacturing method for interlayer-strengthened continuous fibre composite material Download PDF

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WO2018157841A1
WO2018157841A1 PCT/CN2018/077787 CN2018077787W WO2018157841A1 WO 2018157841 A1 WO2018157841 A1 WO 2018157841A1 CN 2018077787 W CN2018077787 W CN 2018077787W WO 2018157841 A1 WO2018157841 A1 WO 2018157841A1
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interlayer
continuous fiber
additive manufacturing
composite material
printing
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PCT/CN2018/077787
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French (fr)
Chinese (zh)
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单忠德
刘丰
吴晓川
李志坤
张群
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北京机科国创轻量化科学研究院有限公司
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing

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  • the invention relates to an inter-layer enhanced continuous fiber composite additive manufacturing method, and belongs to the technical field of cross-section of composite materials and additive manufacturing.
  • continuous fiber reinforced composite materials have far superior to the specific stiffness and specific strength of metal materials, and also have good thermal stability and design properties, so they are widely used in aerospace vehicles. , high-tech fields such as ships and medical care.
  • the traditional composite material manufacturing technology is mainly composed of two steps of prefabrication manufacturing and substrate infiltration and solidification. In order to achieve good wetting of the matrix, the high strength and high modulus of the continuous fiber reinforced composite parts are effectively improved.
  • the manufacturing process of the composite material is complicated, especially the subsequent molding process of the substrate infiltrating the preform is complicated, and takes a long time and consumes high energy.
  • the additive manufacturing technology is to form the final part by using the layer-by-layer manufacturing method of raw materials.
  • the additive manufacturing technology is applied to the manufacture of composite materials, the manufacturing process is simple, and the material utilization rate is high.
  • the curing of the composite material is completed at the same time as the preform is woven, without shortening the manufacturing cycle of the composite material and reducing the manufacturing cost.
  • the additive manufacturing method for continuous fiber reinforced composites is not perfect, especially for the development of high performance of composite parts.
  • the existing continuous fiber reinforced composite additive manufacturing method has not solved the problem of low interlayer strength of composite materials. .
  • the invention provides an interlayer-reinforced continuous fiber composite additive manufacturing method, which improves the bonding performance of the continuous fiber and the substrate by the inter-layer compacting process for pressing the printing material, and on the basis of the interlayer auxiliary mechanism Short fiber placement is carried out between the printing layers, and the fiber reinforced between the layer and the layer is realized by the short fibers laid between the layers, thereby effectively improving the interlayer bonding strength of the composite parts, and also improving the overall The fiber volume fraction of the part, thereby improving the overall performance of the continuous fiber reinforced composite.
  • the invention mainly provides an interlayer-reinforced continuous fiber composite additive manufacturing method, which utilizes a rolling structure to improve the interface bonding property between a continuous fiber and a substrate, and at the same time realizes compounding by laying the interlayer short fibers.
  • the interlayer reinforcement of the material improves the interlayer properties of the composite material while increasing the volume fraction of the material fiber, thereby realizing the high-performance and high-efficiency additive manufacturing of the continuous fiber reinforced composite material.
  • the invention provides an interlayer-reinforced continuous fiber composite additive manufacturing method, and the specific steps are as follows:
  • the selected continuous fiber and the base wire are drawn into the printing nozzle by the wire drawing mechanism, and extruded from the nozzle by melt extrusion;
  • the CAD drive is used to control the print head to perform continuous fiber composite printing on the workbench;
  • the workbench is lowered by a certain height
  • the workbench or the finished print layer is preheated before the printhead performs continuous fiber composite printing.
  • the compacting mechanism can be used to compact the printing material in real time along the scanning path.
  • the continuous fiber and the short fiber are one or more of carbon fiber, aramid fiber, nylon fiber, ceramic fiber, glass fiber, and carbon nanotube fiber.
  • the wire guiding mechanism can perform fiberizing and preheating of the continuous fibers.
  • the compacting mechanism can heat the pressure roller.
  • the print head can perform printing of printing materials and supporting materials.
  • the laying of the short fibers is carried out by air flow or spiral feeding.
  • the equipment has high automation level and the preparation process is controllable, which can realize the rapid manufacture of large-scale and complex structural parts of continuous fiber reinforced composite materials.
  • the interlayer strength of the bonding interface region can be effectively improved, and the fiber volume fraction of the composite material is increased, thereby realizing high-performance manufacturing of the continuous fiber reinforced composite material.
  • the auxiliary mechanism is used to preheat the existing printing layer along the scanning path, which not only improves the bonding performance between the printing layer and the layer, but also releases the stress in the printing layer, thereby effectively avoiding the large composite material system. Deformation problems such as warpage of the piece.
  • Figure 1 is a schematic view showing a method of manufacturing an additive according to the present invention
  • Figure 2 is a schematic view of the manufacture of continuous fiber reinforced composite parts by additive manufacturing.
  • the selected carbon fiber and ABS wire are drawn into the printing nozzle by the wire drawing mechanism, and extruded from the nozzle by melt extrusion;
  • the carbon fiber/ABS composite material is printed on the workbench by the CAD drive control printing nozzle;
  • the workbench After completing one layer printing of the workpiece, the workbench is lowered by a certain height;
  • step E Repeat step E, step F, step G, and step H to achieve additive manufacturing of the article.

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Abstract

Disclosed is an additive manufacturing method for an interlayer-strengthened continuous fibre composite material, belonging to the intersecting field of composite materials and additive manufacturing. The steps are: establishing a CAD model for a continuous fibre strengthened composite material product, acquiring ratio data, model profile data and scanning path data about continuous fibres and a substrate of the product, a thread guiding mechanism (1) pulling threads to a print head (2), controlling the print head (2) via CAD drive to perform continuous fibre composite material printing on a workbench (3), laying short fibres between layers through an interlayer auxiliary head (5), using a compaction mechanism (7) to perform compaction of print layers (4), realising additive manufacturing of a continuous fibre strengthened composite material product. The method improves the manufacturing efficiency of continuous fibre strengthened composite material and fibre/resin interface bonding strength, laying short fibres between print layers (4) realises layer-to-layer bonding performance of a composite material product, realising interlayer strengthening of an additive manufactured composite material, improving the material fibre volume fraction, thereby realising high performance, and highly efficient additive manufacturing of continuous fibre strengthened composite material.

Description

一种层间增强的连续纤维复合材料增材制造方法Interlayer enhanced continuous fiber composite additive manufacturing method 技术领域Technical field
本发明涉及一种层间增强的连续纤维复合材料增材制造方法,属于复合材料与增材制造的交叉技术领域。The invention relates to an inter-layer enhanced continuous fiber composite additive manufacturing method, and belongs to the technical field of cross-section of composite materials and additive manufacturing.
背景技术Background technique
连续纤维增强复合材料作为新一代先进复合材料,具备了远高于金属材料的比刚度、比强度,同时还具有热稳定性好、可设计性强等材料特性,因此被广泛应用于空天飞行器、船舶、医疗等高新技术领域。传统的复合材料制造技术主要是由预制体制造和基体浸润固化两个工序构成,为实现基体对于预制体的良好浸润,从而有效提高连续纤维增强复合材料制件的高强度、高模量,传统的复合材料制造工艺过程较复杂,尤其是后续基体浸润预制体的成型过程较为繁复,且耗时长、耗能高。As a new generation of advanced composite materials, continuous fiber reinforced composite materials have far superior to the specific stiffness and specific strength of metal materials, and also have good thermal stability and design properties, so they are widely used in aerospace vehicles. , high-tech fields such as ships and medical care. The traditional composite material manufacturing technology is mainly composed of two steps of prefabrication manufacturing and substrate infiltration and solidification. In order to achieve good wetting of the matrix, the high strength and high modulus of the continuous fiber reinforced composite parts are effectively improved. The manufacturing process of the composite material is complicated, especially the subsequent molding process of the substrate infiltrating the preform is complicated, and takes a long time and consumes high energy.
增材制造技术是将原材料采用逐层累加的制造方式形成最终的制件,相比于传统的复合材料制造技术,将增材制造技术应用于复合材料的制造,制造过程简单,材料利用率高,在预制体织造的同时完成复合材料的固化成型,无需缩短了复合材料的制造周期,降低了制造成本。但是针对连续纤维增强复合材料的增材制造方法尚不完善,尤其面向复合材料制件高性能的发展需求,现有的连续纤维增强复合材料增材制造方法尚未解决复合材料层间强度低的问题。The additive manufacturing technology is to form the final part by using the layer-by-layer manufacturing method of raw materials. Compared with the traditional composite material manufacturing technology, the additive manufacturing technology is applied to the manufacture of composite materials, the manufacturing process is simple, and the material utilization rate is high. The curing of the composite material is completed at the same time as the preform is woven, without shortening the manufacturing cycle of the composite material and reducing the manufacturing cost. However, the additive manufacturing method for continuous fiber reinforced composites is not perfect, especially for the development of high performance of composite parts. The existing continuous fiber reinforced composite additive manufacturing method has not solved the problem of low interlayer strength of composite materials. .
本发明提出一种层间增强的连续纤维复合材料增材制造方法,通过对打印材料施压的层间紧实工艺提高了连续纤维和基体的结合性能,在此基础上,采用层间辅助机构在打印层之间进行短纤维铺放,通过层间铺放的短纤维实现层与层之间结合界面区的纤维增强,有效提高了复合材料制件的层间结合强度,同时还提高了整体制件的纤维体积分数,从而提高连续纤维增强复合材料的综合性能。The invention provides an interlayer-reinforced continuous fiber composite additive manufacturing method, which improves the bonding performance of the continuous fiber and the substrate by the inter-layer compacting process for pressing the printing material, and on the basis of the interlayer auxiliary mechanism Short fiber placement is carried out between the printing layers, and the fiber reinforced between the layer and the layer is realized by the short fibers laid between the layers, thereby effectively improving the interlayer bonding strength of the composite parts, and also improving the overall The fiber volume fraction of the part, thereby improving the overall performance of the continuous fiber reinforced composite.
发明内容Summary of the invention
本发明主要是提供一种层间增强的连续纤维复合材料增材制造方法,该增材制造方法利用滚压结构提高连续纤维与基体的界面结合性能,同时利用层间短纤维的铺放实现复合材料的层间增强,提高复合材料层间性能的同时提高材料纤维体积分数,从而实现连续纤维增强复合材料制件的高性能、高效增材制造。The invention mainly provides an interlayer-reinforced continuous fiber composite additive manufacturing method, which utilizes a rolling structure to improve the interface bonding property between a continuous fiber and a substrate, and at the same time realizes compounding by laying the interlayer short fibers. The interlayer reinforcement of the material improves the interlayer properties of the composite material while increasing the volume fraction of the material fiber, thereby realizing the high-performance and high-efficiency additive manufacturing of the continuous fiber reinforced composite material.
本发明提供了一种层间增强的连续纤维复合材料增材制造方法,具体步骤如下:The invention provides an interlayer-reinforced continuous fiber composite additive manufacturing method, and the specific steps are as follows:
①建立连续纤维增强复合材料制件的CAD模型;1 Establish a CAD model of continuous fiber reinforced composite parts;
②根据CAD模型获取所述制件的连续纤维和基体的配比数据、模型轮廓数据和扫描路径数据;2 obtaining the ratio data, the model contour data and the scan path data of the continuous fiber and the matrix of the workpiece according to the CAD model;
③选取适用于所述制件的连续纤维和基体丝材布置于引丝机构上;3 selecting a continuous fiber and a base wire suitable for the part to be arranged on the wire guiding mechanism;
④选取的连续纤维和基体丝材由引丝机构牵引导入打印喷头,通过熔融挤压从喷嘴挤出;4 The selected continuous fiber and the base wire are drawn into the printing nozzle by the wire drawing mechanism, and extruded from the nozzle by melt extrusion;
⑤根据所述制件的模型轮廓数据和扫描路径数据,通过CAD驱动控制打印喷头在工作台上进行连续纤维复合材料打印;5 according to the model profile data and the scan path data of the workpiece, the CAD drive is used to control the print head to perform continuous fiber composite printing on the workbench;
⑥通过CAD驱动控制层间辅助喷头与打印喷头随动,沿所述制件的扫描路径进行指定短纤维的铺放;6 through the CAD drive to control the interlayer auxiliary nozzle and the printing nozzle to follow, along the scanning path of the workpiece to specify the placement of short fibers;
⑦通过CAD驱动压实机构与层间辅助喷头随动,沿所述制件的扫描路径进行短纤维层的压实;7 following the driving of the compacting mechanism and the interlayer auxiliary nozzle by the CAD, and compacting the short fiber layer along the scanning path of the workpiece;
⑧完成所述制件的一层打印后,所述工作台下降一定高度;8 after completing one layer printing of the workpiece, the workbench is lowered by a certain height;
⑨重复步骤⑤、步骤⑥和步骤⑦,实现所述制件的增材制造。9 Repeat steps 5, 6, and 7 to achieve additive manufacturing of the article.
进一步地,在打印喷头进行连续纤维复合材料打印之前,对工作台或已完成打印层进行预热。Further, the workbench or the finished print layer is preheated before the printhead performs continuous fiber composite printing.
进一步地,所述的进行连续纤维复合材料打印,可采用压实机构沿扫描路径对打印材料进行实时压实。Further, in the continuous fiber composite printing, the compacting mechanism can be used to compact the printing material in real time along the scanning path.
进一步地,所述的连续纤维和短纤维为碳纤维、芳纶纤维、尼龙纤维、陶瓷纤维、玻璃纤维、碳纳米管纤维中的一种或多种。Further, the continuous fiber and the short fiber are one or more of carbon fiber, aramid fiber, nylon fiber, ceramic fiber, glass fiber, and carbon nanotube fiber.
进一步地,所述的引丝机构可对连续纤维进行展纤和预加热。Further, the wire guiding mechanism can perform fiberizing and preheating of the continuous fibers.
进一步地,所述的压实机构可对压辊进行加热。Further, the compacting mechanism can heat the pressure roller.
进一步地,所述的打印喷头可进行打印材料和支撑材料的打印。Further, the print head can perform printing of printing materials and supporting materials.
进一步地,所述的短纤维的铺放采用气流导出或螺旋送料方式。Further, the laying of the short fibers is carried out by air flow or spiral feeding.
本发明有益的效果是:The beneficial effects of the present invention are:
⒈设备自动化水平高,制备过程可控,可实现连续纤维增强复合材料大型、复杂结构制件的快速制造。1. The equipment has high automation level and the preparation process is controllable, which can realize the rapid manufacture of large-scale and complex structural parts of continuous fiber reinforced composite materials.
⒉通过在打印层与层之间铺放短纤维,可有效提高结合界面区的层间强度,同时提高复合材料制件纤维体积分数,从而实现连续纤维增强复合材料制件的高性能制造。2. By laying short fibers between the printing layer and the layer, the interlayer strength of the bonding interface region can be effectively improved, and the fiber volume fraction of the composite material is increased, thereby realizing high-performance manufacturing of the continuous fiber reinforced composite material.
⒊在新一层打印之前,采用辅助机构沿扫描路径对已有打印层进行预热,不仅提高了打印层与层之间的结合性能,还可以释放打印层内应力,有效避免大型复合材料制件的翘曲等变形问题。3. Before the new layer is printed, the auxiliary mechanism is used to preheat the existing printing layer along the scanning path, which not only improves the bonding performance between the printing layer and the layer, but also releases the stress in the printing layer, thereby effectively avoiding the large composite material system. Deformation problems such as warpage of the piece.
附图说明DRAWINGS
构成本申请的一部分的说明书附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings, which are incorporated in the claims of the claims In the drawing:
图1为本发明增材制造方法示意图;Figure 1 is a schematic view showing a method of manufacturing an additive according to the present invention;
图2为增材制造连续纤维增强复合材料制件示意图。Figure 2 is a schematic view of the manufacture of continuous fiber reinforced composite parts by additive manufacturing.
其中,上述附图包括以下附图标记:Wherein, the above figures include the following reference numerals:
1—引丝机构 2—打印喷头 3—工作台 4—打印层 5—层间辅助喷头 6—纤维短切原丝 7—压实机构1—Threading mechanism 2—Printing head 3—Working table 4—Printing layer 5—Interlayer auxiliary nozzle 6—Fiber chopped strand 7—Compacting mechanism
具体实施方式detailed description
本发明层间增强的连续纤维增强复合材料增材制造方法具体步骤如下:The specific steps of the method for manufacturing the inter-layer reinforced continuous fiber reinforced composite additive according to the present invention are as follows:
A、建立连续纤维增强复合材料制件的CAD模型;A. Establish a CAD model of continuous fiber reinforced composite parts;
B、根据CAD模型获取制件的连续碳纤维和ABS树脂的配比数据、模型轮廓数据和扫描路径数据;B. Obtaining the ratio data, model contour data and scan path data of the continuous carbon fiber and ABS resin of the workpiece according to the CAD model;
C、选取T300型号1K碳纤维和ABS树脂丝材布置于引丝机构上;C. Select T300 model 1K carbon fiber and ABS resin wire to be arranged on the wire guiding mechanism;
D、选取的碳纤维和ABS丝材由引丝机构牵引导入打印喷头,通过熔融挤压从喷嘴挤出;D. The selected carbon fiber and ABS wire are drawn into the printing nozzle by the wire drawing mechanism, and extruded from the nozzle by melt extrusion;
E、根据制件的模型轮廓数据和扫描路径数据,通过CAD驱动控制打印喷头在工作台上进行碳纤维/ABS复合材料打印;E. According to the model profile data and the scan path data of the workpiece, the carbon fiber/ABS composite material is printed on the workbench by the CAD drive control printing nozzle;
F、通过CAD驱动控制压实机构与打印喷头随动,沿所述制件的扫描路径进行打印材料的压实;F. controlling the compacting mechanism and the printing nozzle by the CAD drive, and compacting the printing material along the scanning path of the workpiece;
G、通过CAD驱动控制层间辅助喷头与打印喷头随动,沿所述制件的扫描路径进行碳纤维短切原丝的铺放;G. Controlling the interlayer auxiliary nozzle and the printing nozzle by the CAD drive, and performing the carbon fiber chopped strand along the scanning path of the workpiece;
H、通过CAD驱动压实机构与层间辅助喷头随动,沿扫描路径进行短切碳纤维层的压实;H. The compaction of the chopped carbon fiber layer along the scanning path is carried out by the CAD driving compacting mechanism and the interlayer auxiliary nozzle;
I、完成所述制件的一层打印后,工作台下降一定高度;I. After completing one layer printing of the workpiece, the workbench is lowered by a certain height;
J、重复步骤E、步骤F、步骤G和步骤H,实现所述制件的增材制造。J. Repeat step E, step F, step G, and step H to achieve additive manufacturing of the article.
上述实施例是对本发明的上述内容作进一步的说明,不应将此理解为本发明上述主题的范围仅限于上述实施例。凡基于上述内容所实现的技术均属于本发明的范围。The above-mentioned embodiments are further described in the above description of the present invention, and the scope of the above-mentioned subject matter of the present invention should not be construed as being limited to the above embodiments. The techniques implemented based on the above are all within the scope of the invention.

Claims (8)

  1. 一种层间增强的连续纤维复合材料增材制造方法,其特征在于,具体步骤如下:An interlayer-reinforced continuous fiber composite additive manufacturing method, characterized in that the specific steps are as follows:
    ①建立连续纤维增强复合材料制件的CAD模型;1 Establish a CAD model of continuous fiber reinforced composite parts;
    ②根据CAD模型获取所述制件的连续纤维和基体的配比数据、模型轮廓数据和扫描路径数据;2 obtaining the ratio data, the model contour data and the scan path data of the continuous fiber and the matrix of the workpiece according to the CAD model;
    ③选取适用于所述制件的连续纤维和基体丝材布置于引丝机构上;3 selecting a continuous fiber and a base wire suitable for the part to be arranged on the wire guiding mechanism;
    ④选取的连续纤维和基体丝材由引丝机构牵引导入打印喷头,通过熔融挤压从喷嘴挤出;4 The selected continuous fiber and the base wire are drawn into the printing nozzle by the wire drawing mechanism, and extruded from the nozzle by melt extrusion;
    ⑤根据所述制件的模型轮廓数据和扫描路径数据,通过CAD驱动控制打印喷头在工作台上进行连续纤维复合材料打印;5 according to the model profile data and the scan path data of the workpiece, the CAD drive is used to control the print head to perform continuous fiber composite printing on the workbench;
    ⑥通过CAD驱动控制层间辅助喷头与打印喷头随动,沿所述制件的扫描路径进行指定短纤维的铺放;6 through the CAD drive to control the interlayer auxiliary nozzle and the printing nozzle to follow, along the scanning path of the workpiece to specify the placement of short fibers;
    ⑦通过CAD驱动压实机构与层间辅助喷头随动,沿所述制件的扫描路径进行短纤维层的压实;7 following the driving of the compacting mechanism and the interlayer auxiliary nozzle by the CAD, and compacting the short fiber layer along the scanning path of the workpiece;
    ⑧完成所述制件的一层打印后,所述工作台下降一定高度;8 after completing one layer printing of the workpiece, the workbench is lowered by a certain height;
    ⑨重复步骤⑤、步骤⑥和步骤⑦,实现所述制件的增材制造。9 Repeat steps 5, 6, and 7 to achieve additive manufacturing of the article.
  2. 根据权利要求1所述的层间增强的连续纤维复合材料增材制造方法,其特征在于,在打印喷头进行连续纤维复合材料打印之前,对工作台或已完成打印层进行预热。The interlayer enhanced continuous fiber composite additive manufacturing method according to claim 1, wherein the workbench or the completed print layer is preheated before the print head performs continuous fiber composite printing.
  3. 根据权利要求1所述的层间增强的连续纤维复合材料增材制造方法,其特征在于,所述的进行连续纤维复合材料打印,可采用压实机构沿扫描路径对打印材料进行实时压实。The interlayer-reinforced continuous fiber composite additive manufacturing method according to claim 1, wherein the continuous fiber composite printing is performed by using a compacting mechanism to perform real-time compaction of the printing material along the scanning path.
  4. 根据权利要求1所述的层间增强的连续纤维复合材料增材制造方法,其特征在于,所述的连续纤维和短纤维为碳纤维、芳纶纤维、尼龙纤维、陶瓷纤维、玻璃纤维、碳纳米管纤维中的一种或多种。The interlayer-reinforced continuous fiber composite additive manufacturing method according to claim 1, wherein the continuous fibers and short fibers are carbon fiber, aramid fiber, nylon fiber, ceramic fiber, glass fiber, carbon nanometer. One or more of the tube fibers.
  5. 根据权利要求1所述的层间增强的连续纤维复合材料增材制造方法,其特征在于,所述的引丝机构可对连续纤维进行展纤和预加热。The interlayer-reinforced continuous fiber composite additive manufacturing method according to claim 1, wherein the yarn guiding mechanism performs fiberizing and preheating of the continuous fibers.
  6. 根据权利要求1所述的层间增强的连续纤维复合材料增材制造方法,其特征在于,所述的压实机构可对压辊进行加热。The interlayer-reinforced continuous fiber composite additive manufacturing method according to claim 1, wherein said compacting mechanism heats the pressure roller.
  7. 根据权利要求1所述的层间增强的连续纤维复合材料增材制造方法,其特征在于,所述的打印喷头可进行打印材料和支撑材料的打印。The method of manufacturing an inter-layer reinforced continuous fiber composite additive according to claim 1, wherein said print head performs printing of a printing material and a support material.
  8. 根据权利要求1所述的层间增强的连续纤维复合材料增材制造方法,其特征在于,所述的短纤维的铺放可采用气流导出或螺旋送料方式。The interlayer-reinforced continuous fiber composite additive manufacturing method according to claim 1, wherein the short fibers are laid by air flow or spiral feed.
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