US20230354690A1 - Organic electroluminescent materials and devices - Google Patents
Organic electroluminescent materials and devices Download PDFInfo
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- US20230354690A1 US20230354690A1 US18/153,542 US202318153542A US2023354690A1 US 20230354690 A1 US20230354690 A1 US 20230354690A1 US 202318153542 A US202318153542 A US 202318153542A US 2023354690 A1 US2023354690 A1 US 2023354690A1
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- alkyl
- aromatic
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- 239000000463 material Substances 0.000 title description 85
- 150000001875 compounds Chemical class 0.000 claims abstract description 78
- 125000003118 aryl group Chemical group 0.000 claims abstract description 66
- 239000000203 mixture Substances 0.000 claims abstract description 43
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 41
- 125000001424 substituent group Chemical group 0.000 claims abstract description 41
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 37
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims abstract description 22
- 125000003367 polycyclic group Chemical group 0.000 claims abstract description 16
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 11
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Chemical group COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000009472 formulation Methods 0.000 claims abstract description 5
- 239000003446 ligand Substances 0.000 claims description 138
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 132
- 239000010410 layer Substances 0.000 claims description 89
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 85
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 65
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 60
- -1 amino, silyl Chemical group 0.000 claims description 44
- 125000001072 heteroaryl group Chemical group 0.000 claims description 30
- 229910052751 metal Inorganic materials 0.000 claims description 23
- 239000002184 metal Substances 0.000 claims description 23
- 239000002019 doping agent Substances 0.000 claims description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 125000003342 alkenyl group Chemical group 0.000 claims description 18
- 125000000304 alkynyl group Chemical group 0.000 claims description 18
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims description 18
- 239000012044 organic layer Substances 0.000 claims description 18
- 125000000392 cycloalkenyl group Chemical group 0.000 claims description 16
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 claims description 14
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 claims description 14
- 125000002252 acyl group Chemical group 0.000 claims description 14
- 125000003545 alkoxy group Chemical group 0.000 claims description 14
- 125000004104 aryloxy group Chemical group 0.000 claims description 14
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 14
- 229910052805 deuterium Inorganic materials 0.000 claims description 14
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical compound C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 14
- 125000004404 heteroalkyl group Chemical group 0.000 claims description 14
- 150000002527 isonitriles Chemical class 0.000 claims description 14
- 150000002825 nitriles Chemical class 0.000 claims description 14
- FVZVCSNXTFCBQU-UHFFFAOYSA-N phosphanyl Chemical group [PH2] FVZVCSNXTFCBQU-UHFFFAOYSA-N 0.000 claims description 14
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 claims description 14
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 14
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 14
- 150000004820 halides Chemical class 0.000 claims description 13
- 150000001735 carboxylic acids Chemical class 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 150000002431 hydrogen Chemical class 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- SLGBZMMZGDRARJ-UHFFFAOYSA-N Triphenylene Natural products C1=CC=C2C3=CC=CC=C3C3=CC=CC=C3C2=C1 SLGBZMMZGDRARJ-UHFFFAOYSA-N 0.000 claims description 8
- 125000005580 triphenylene group Chemical group 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 238000006467 substitution reaction Methods 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- WIUZHVZUGQDRHZ-UHFFFAOYSA-N [1]benzothiolo[3,2-b]pyridine Chemical compound C1=CN=C2C3=CC=CC=C3SC2=C1 WIUZHVZUGQDRHZ-UHFFFAOYSA-N 0.000 claims description 6
- DHFABSXGNHDNCO-UHFFFAOYSA-N dibenzoselenophene Chemical compound C1=CC=C2C3=CC=CC=C3[se]C2=C1 DHFABSXGNHDNCO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- BPMFPOGUJAAYHL-UHFFFAOYSA-N 9H-Pyrido[2,3-b]indole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=N1 BPMFPOGUJAAYHL-UHFFFAOYSA-N 0.000 claims description 2
- 125000003636 chemical group Chemical group 0.000 claims description 2
- 230000005281 excited state Effects 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 505
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 22
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 21
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 19
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 230000000903 blocking effect Effects 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 12
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 12
- 150000003384 small molecules Chemical class 0.000 description 12
- 230000032258 transport Effects 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 230000004888 barrier function Effects 0.000 description 10
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 10
- 238000004770 highest occupied molecular orbital Methods 0.000 description 10
- 238000004768 lowest unoccupied molecular orbital Methods 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene sulfoxide Natural products C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 9
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 9
- 239000011541 reaction mixture Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 8
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 8
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 238000002347 injection Methods 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 150000004696 coordination complex Chemical class 0.000 description 7
- 238000000151 deposition Methods 0.000 description 7
- 239000000284 extract Substances 0.000 description 7
- 239000000741 silica gel Substances 0.000 description 7
- 229910002027 silica gel Inorganic materials 0.000 description 7
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 6
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 6
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 6
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 6
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 6
- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 description 6
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 6
- WDECIBYCCFPHNR-UHFFFAOYSA-N chrysene Chemical compound C1=CC=CC2=CC=C3C4=CC=CC=C4C=CC3=C21 WDECIBYCCFPHNR-UHFFFAOYSA-N 0.000 description 6
- 125000004122 cyclic group Chemical group 0.000 description 6
- 125000000623 heterocyclic group Chemical group 0.000 description 6
- 230000005525 hole transport Effects 0.000 description 6
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 6
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
- 239000011368 organic material Substances 0.000 description 6
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 6
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 6
- 239000004305 biphenyl Substances 0.000 description 5
- 235000010290 biphenyl Nutrition 0.000 description 5
- 239000000412 dendrimer Substances 0.000 description 5
- 229920000736 dendritic polymer Polymers 0.000 description 5
- 239000012634 fragment Substances 0.000 description 5
- VVVPGLRKXQSQSZ-UHFFFAOYSA-N indolo[3,2-c]carbazole Chemical compound C1=CC=CC2=NC3=C4C5=CC=CC=C5N=C4C=CC3=C21 VVVPGLRKXQSQSZ-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 230000005693 optoelectronics Effects 0.000 description 5
- 150000002894 organic compounds Chemical class 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 4
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical compound [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000003111 delayed effect Effects 0.000 description 4
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 description 4
- 229960005544 indolocarbazole Drugs 0.000 description 4
- 229910052741 iridium Inorganic materials 0.000 description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 4
- 235000019341 magnesium sulphate Nutrition 0.000 description 4
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- MFRIHAYPQRLWNB-UHFFFAOYSA-N sodium tert-butoxide Chemical compound [Na+].CC(C)(C)[O-] MFRIHAYPQRLWNB-UHFFFAOYSA-N 0.000 description 4
- 229930192474 thiophene Natural products 0.000 description 4
- KTZQTRPPVKQPFO-UHFFFAOYSA-N 1,2-benzoxazole Chemical compound C1=CC=C2C=NOC2=C1 KTZQTRPPVKQPFO-UHFFFAOYSA-N 0.000 description 3
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 3
- FLBAYUMRQUHISI-UHFFFAOYSA-N 1,8-naphthyridine Chemical compound N1=CC=CC2=CC=CN=C21 FLBAYUMRQUHISI-UHFFFAOYSA-N 0.000 description 3
- BNRDGHFESOHOBF-UHFFFAOYSA-N 1-benzoselenophene Chemical compound C1=CC=C2[se]C=CC2=C1 BNRDGHFESOHOBF-UHFFFAOYSA-N 0.000 description 3
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 3
- TZMSYXZUNZXBOL-UHFFFAOYSA-N 10H-phenoxazine Chemical compound C1=CC=C2NC3=CC=CC=C3OC2=C1 TZMSYXZUNZXBOL-UHFFFAOYSA-N 0.000 description 3
- BAXOFTOLAUCFNW-UHFFFAOYSA-N 1H-indazole Chemical compound C1=CC=C2C=NNC2=C1 BAXOFTOLAUCFNW-UHFFFAOYSA-N 0.000 description 3
- VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 description 3
- OLGGLCIDAMICTA-UHFFFAOYSA-N 2-pyridin-2-yl-1h-indole Chemical compound N1C2=CC=CC=C2C=C1C1=CC=CC=N1 OLGGLCIDAMICTA-UHFFFAOYSA-N 0.000 description 3
- QMEQBOSUJUOXMX-UHFFFAOYSA-N 2h-oxadiazine Chemical compound N1OC=CC=N1 QMEQBOSUJUOXMX-UHFFFAOYSA-N 0.000 description 3
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 3
- BWCDLEQTELFBAW-UHFFFAOYSA-N 3h-dioxazole Chemical compound N1OOC=C1 BWCDLEQTELFBAW-UHFFFAOYSA-N 0.000 description 3
- WVDHKJBDYOJGEU-UHFFFAOYSA-N 8-[4-(2-bicyclo[2.2.1]heptanyl)pyridin-2-yl]-2-methyl-[1]benzofuro[2,3-b]pyridine Chemical compound C12C(CC(CC1)C2)C1=CC(=NC=C1)C1=CC=CC2=C1OC1=NC(=CC=C12)C WVDHKJBDYOJGEU-UHFFFAOYSA-N 0.000 description 3
- WVDHKJBDYOJGEU-CGKHOQSBSA-N 8-[4-(2-deuterio-2-bicyclo[2.2.1]heptanyl)pyridin-2-yl]-2-(trideuteriomethyl)-[1]benzofuro[2,3-b]pyridine Chemical compound C12C(CC(CC1)C2)([2H])C1=CC(=NC=C1)C1=CC=CC2=C1OC1=NC(=CC=C12)C([2H])([2H])[2H] WVDHKJBDYOJGEU-CGKHOQSBSA-N 0.000 description 3
- CBJSLWAIZREYGR-UHFFFAOYSA-N 8-[5-(2-bicyclo[2.2.1]heptanyl)pyridin-2-yl]-2-methyl-[1]benzofuro[2,3-b]pyridine Chemical compound C12C(CC(CC1)C2)C=1C=CC(=NC=1)C1=CC=CC2=C1OC1=NC(=CC=C12)C CBJSLWAIZREYGR-UHFFFAOYSA-N 0.000 description 3
- CBJSLWAIZREYGR-CGKHOQSBSA-N 8-[5-(2-deuterio-2-bicyclo[2.2.1]heptanyl)pyridin-2-yl]-2-(trideuteriomethyl)-[1]benzofuro[2,3-b]pyridine Chemical compound C12C(CC(CC1)C2)([2H])C=1C=CC(=NC=1)C1=CC=CC2=C1OC1=NC(=CC=C12)C([2H])([2H])[2H] CBJSLWAIZREYGR-CGKHOQSBSA-N 0.000 description 3
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 3
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 3
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 3
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 3
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 3
- FBVBNCGJVKIEHH-UHFFFAOYSA-N [1]benzofuro[3,2-b]pyridine Chemical compound C1=CN=C2C3=CC=CC=C3OC2=C1 FBVBNCGJVKIEHH-UHFFFAOYSA-N 0.000 description 3
- QZLAKPGRUFFNRD-UHFFFAOYSA-N [1]benzoselenolo[3,2-b]pyridine Chemical compound C1=CN=C2C3=CC=CC=C3[se]C2=C1 QZLAKPGRUFFNRD-UHFFFAOYSA-N 0.000 description 3
- RFRXIWQYSOIBDI-UHFFFAOYSA-N benzarone Chemical compound CCC=1OC2=CC=CC=C2C=1C(=O)C1=CC=C(O)C=C1 RFRXIWQYSOIBDI-UHFFFAOYSA-N 0.000 description 3
- WCZVZNOTHYJIEI-UHFFFAOYSA-N cinnoline Chemical compound N1=NC=CC2=CC=CC=C21 WCZVZNOTHYJIEI-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 3
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 3
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- WCPAKWJPBJAGKN-UHFFFAOYSA-N oxadiazole Chemical compound C1=CON=N1 WCPAKWJPBJAGKN-UHFFFAOYSA-N 0.000 description 3
- AZHVQJLDOFKHPZ-UHFFFAOYSA-N oxathiazine Chemical compound O1SN=CC=C1 AZHVQJLDOFKHPZ-UHFFFAOYSA-N 0.000 description 3
- CQDAMYNQINDRQC-UHFFFAOYSA-N oxatriazole Chemical compound C1=NN=NO1 CQDAMYNQINDRQC-UHFFFAOYSA-N 0.000 description 3
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- H10K2101/00—Properties of the organic materials covered by group H10K85/00
- H10K2101/10—Triplet emission
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Definitions
- the claimed invention was made by, on behalf of, and/or in connection with one or more of the following parties to a joint university corporation research agreement: The Regents of the University of Michigan, Princeton University, University of Southern California, and the Universal Display Corporation. The agreement was in effect on and before the date the claimed invention was made, and the claimed invention was made as a result of activities undertaken within the scope of the agreement.
- the present invention relates to compounds for use as emitters, and devices, such as organic light emitting diodes, including the same.
- Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.
- OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.
- phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels.
- the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs.
- the white OLED can be either a single EML device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.
- a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy) 3 , which has the following structure:
- organic includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices.
- Small molecule refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety.
- the core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter.
- a dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.
- top means furthest away from the substrate, while “bottom” means closest to the substrate.
- first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer.
- a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.
- solution processible means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.
- a ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material.
- a ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.
- a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level.
- IP ionization potentials
- a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative).
- a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative).
- the LUMO energy level of a material is higher than the HOMO energy level of the same material.
- a “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.
- a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.
- a composition comprising a first compound.
- the first compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature, and the first compound has at least one aromatic ring and at least one substituent R, where each of the at least one substituent R is directly bonded to one of the at least one aromatic rings.
- Each of the at least one substituent R has the formula of
- an organic light emitting diode/device is also provided.
- the OLED can include an anode, a cathode, and an organic layer, disposed between the anode and the cathode.
- the organic layer can include the first compound as described herein.
- the organic light emitting device is incorporated into one or more device selected from a consumer product, an electronic component module, and/or a lighting panel.
- a formulation containing the first compound as described herein is provided.
- FIG. 1 shows an organic light emitting device
- FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.
- an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode.
- the anode injects holes and the cathode injects electrons into the organic layer(s).
- the injected holes and electrons each migrate toward the oppositely charged electrode.
- an “exciton,” which is a localized electron-hole pair having an excited energy state is formed.
- Light is emitted when the exciton relaxes via a photoemissive mechanism.
- the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
- the initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
- FIG. 1 shows an organic light emitting device 100 .
- Device 100 may include a substrate 110 , an anode 115 , a hole injection layer 120 , a hole transport layer 125 , an electron blocking layer 130 , an emissive layer 135 , a hole blocking layer 140 , an electron transport layer 145 , an electron injection layer 150 , a protective layer 155 , a cathode 160 , and a barrier layer 170 .
- Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164 .
- Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in US 7,279,704 at cols. 6-10, which are incorporated by reference.
- each of these layers are available.
- a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety.
- An example of a p-doped hole transport layer is m-MTDATA doped with F 4 -TCNQ at a molar ratio of 50:1, as disclosed in U.S. Pat. Application Publication No. 2003/0230980, which is incorporated by reference in its entirety.
- Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety.
- An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Pat. Application Publication No. 2003/0230980, which is incorporated by reference in its entirety.
- the theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Pat. Application Publication No.
- FIG. 2 shows an inverted OLED 200 .
- the device includes a substrate 210 , a cathode 215 , an emissive layer 220 , a hole transport layer 225 , and an anode 230 .
- Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230 , device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200 .
- FIG. 2 provides one example of how some layers may be omitted from the structure of device 100 .
- FIGS. 1 and 2 The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of nonlimiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures.
- the specific materials and structures described are exemplary in nature, and other materials and structures may be used.
- Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers.
- hole transport layer 225 transports holes and injects holes into emissive layer 220 , and may be described as a hole transport layer or a hole injection layer.
- an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2 .
- OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety.
- PLEDs polymeric materials
- OLEDs having a single organic layer may be used.
- OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety.
- the OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2 .
- the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.
- any of the layers of the various embodiments may be deposited by any suitable method.
- preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety.
- OVPD organic vapor phase deposition
- OJP organic vapor jet printing
- Other suitable deposition methods include spin coating and other solution based processes.
- Solution based processes are preferably carried out in nitrogen or an inert atmosphere.
- preferred methods include thermal evaporation.
- Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used.
- the materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing.
- Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
- Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer.
- a barrier layer One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc.
- the barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge.
- the barrier layer may comprise a single layer, or multiple layers.
- the barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer.
- the barrier layer may incorporate an inorganic or an organic compound or both.
- the preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties.
- the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time.
- the weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95.
- the polymeric material and the non-polymeric material may be created from the same precursor material.
- the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
- Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays.
- Some examples of such consumer products include flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, laser printers, telephones, cell phones, tablets, phablets, personal digital assistants (PDAs), wearable device, laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, vehicles, a large area wall, theater or stadium screen, or a sign.
- PDAs personal digital assistants
- Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18° C. to 30° C., and more preferably at room temperature (20-25° C.), but could be used outside this temperature range, for example, from -40° C. to + 80° C.
- the materials and structures described herein may have applications in devices other than OLEDs.
- other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures.
- organic devices such as organic transistors, may employ the materials and structures.
- a polycyclic compound is an organic chemical featuring several closed rings of atoms, primarily carbon. These ring substructures comprises cycloalkanes, aromatics, and other ring types. They come in sizes of three atoms and upward, and in combinations of linkages that include tethering (such as in biaryls), fusing (edge-to-edge, such as in anthracene and steroids), links via a single atom (such as in spiro compounds), and bridged cyclics such as adamantane. Though “poly” literally means “many”, in this context polycyclic includes smaller rings such as bicyclic, tricyclic, and tetracyclic.
- halo includes fluorine, chlorine, bromine, and iodine.
- alkyl as used herein contemplates both straight and branched chain alkyl radicals.
- Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl,and the like. Additionally, the alkyl group may be optionally substituted.
- cycloalkyl as used herein contemplates cyclic alkyl radicals.
- Preferred cycloalkyl groups are those containing 3 to 10 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, adamantyl, and the like. Additionally, the cycloalkyl group may be optionally substituted.
- alkenyl as used herein contemplates both straight and branched chain alkene radicals.
- Preferred alkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl group may be optionally substituted.
- alkynyl as used herein contemplates both straight and branched chain alkyne radicals. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted.
- aralkyl or “arylalkyl” as used herein are used interchangeably and contemplate an alkyl group that has as a substituent an aromatic group. Additionally, the aralkyl group may be optionally substituted.
- heterocyclic group contemplates aromatic and non-aromatic cyclic radicals.
- Hetero-aromatic cyclic radicals also means heteroaryl.
- Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperdino, pyrrolidino, and the like, and cyclic ethers, such as tetrahydrofuran, tetrahydropyran, and the like. Additionally, the heterocyclic group may be optionally substituted.
- aryl or “aromatic group” as used herein contemplates single-ring groups and polycyclic ring systems.
- the polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is aromatic, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls.
- Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons.
- Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted.
- heteroaryl contemplates single-ring hetero-aromatic groups that may include from one to five heteroatoms.
- heteroaryl also includes polycyclic hetero-aromatic systems having two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls.
- Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms.
- Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, qui
- alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl may be unsubstituted or may be substituted with one or more substituents selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, cyclic amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
- substituted indicates that a substituent other than H is bonded to the relevant position, such as carbon.
- R 1 is mono-substituted
- one R 1 must be other than H.
- R 1 is di-substituted
- two of R 1 must be other than H.
- R 1 is hydrogen for all available positions.
- aza-dibenzofuran i.e. aza-dibenzofuran, aza-dibenzothiophene, etc.
- azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline.
- a composition comprising a first compound.
- the first compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature, and the first compound has at least one aromatic ring and at least one substituent R, where each of the at least one substituent R is directly bonded to one of the at least one aromatic rings.
- Each of the at least one substituent R has the formula of
- G 1 is SiR 1 R 2 . In some embodiments, G 1 is NR 1 . In some embodiments, G 1 is alkyl. In some such embodiments, G 1 is selected from the gourp consisiting of divalent methyl, ethyl, propyl, and butyl. In some embodiments, G 1 is fully or partially deuterated.
- G 2 is polycyclic alkyl. In some embodiments, G 2 is carborane. In some embodiments, G 2 contains at least one heteroatom. In some embodiments, G 2 includes at least one heterocyclic group.
- the first compound is capable of emitting light from a triplet excited state to a ground singlet state at room temperature.
- the first compound is a metal coordination complex having a metal-carbon bond.
- the metal is selected from the group consisting of Ir, Rh, Re, Ru, Os, Pt, Au, and Cu.
- the metal is Ir, while the metal is Pt is other embodiments.
- the first compound has the formula of M(L 1 ) x (L 2 ) y (L 3 ) z , where:
- the first compound has the structure M(L 1 ) x (L 2 ) y (L 3 ) z
- the first compound has the formula of Ir(L 1 ) 2 (L 2 ).
- L 1 has the formula selected from the group consisting of:
- L 2 has the formula:
- ligands L 1 and L 2 are different and each independently selected from the group consisting of:
- ligands L 1 and L 2 are each independently selected from the group consisting of:
- the first compound has the structure M(L 1 ) x (L 2 ) y (L 3 ) z
- the first compound has the formula of Pt(L 1 ) 2 or Pt(L 1 )(L 2 ).
- one L 1 is connected to the other L 1 or L 2 to form a tetradentate ligand.
- At least one of R a , R b , R c , and R d includes an alkyl or cycloalkyl group that is partially or fully deuterated.
- G 2 is selected from the group consisting of:
- each of the at least one substituent R is independently selected from the group consisting of:
- L 1 , L 2 , and L 3 are selected from the group consisting of:
- ligands L 1 and L 2 are different and each independently selected from the group consisting of:
- ligand L 1 is L A having the following structure:
- L A1 to L A2480 selected from the group consisting of L A1 to L A2480 as listed below:
- R G1 to R G169 have the following structures:
- the compound is Compound x selected from the group consisting of Compound 1 through Compound 2120400, where:
- H H H 201 CH 3 H H 202. H CH 3 H 203. H H CH 3 204. CH 3 CH 3 H 205. CH 3 H CH 3 206. H CH 3 CH 3 207. CH 3 CH 3 CH 3 208. H H H 209. CH 3 H H 210. H CH 3 H 211. H H CH 3 212. CH 3 CH 3 H 213. CH 3 H CH 3 214. H CH 3 CH 3 215. CH 3 CH 3 CH 3 216. H H H 217. CH 3 H H 218. H CH 3 H 219. H H CH 3 220. CH 3 CH 3 H 221. CH 3 H CH 3 222. H CH 3 CH 3 223. CH 3 CH 3 CH 3 224. H H H H 225. CH 3 H H 226.
- CH 3 CH 3 CH 3 280 H H H 281. CH 3 H H 282. H CH 3 H 283. H H CH 3 284. CH 3 CH 3 H 285. CH 3 H CH 3 286. H CH 3 CH 3 287. CH 3 CH 3 CH 3 288. H H H 289. CH 3 H H 290. H CH 3 H 291. H H CH 3 292. CH 3 CH 3 H 293. CH 3 H CH 3 294. H CH 3 CH 3 295. CH 3 CH 3 CH 3 296. H H H 297. CH 3 H H 298. H CH 3 H 299. H H CH 3 300. CH 3 CH 3 H 301. CH 3 H CH 3 302. H CH 3 CH 3 303. CH 3 CH 3 CH 3 304. H H H H 305. CH 3 H H 306.
- CD 2 C(CH 3 ) 3 H CD 2 C(CH 3 ) 2 CF 3 H 785.
- the first compound can be an emissive dopant.
- the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
- TADF thermally activated delayed fluorescence
- an organic light-emitting device comprising an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a first compound.
- the first compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature, and the first compound has at least one aromatic ring and at least one substituent R, where each of the at least one substituent R is directly bonded to one of the at least one aromatic rings.
- Each of the at least one substituent R has the formula of
- the OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel.
- the organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.
- the organic layer can also include a host.
- a host In some embodiments, two or more hosts are preferred.
- the hosts used maybe a) bipolar, b) electron transporting, c) hole transporting or d) wide band gap materials that play little role in charge transport.
- the host can include a metal complex.
- the host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan.
- Any substituent in the host can be an unfused substituent independently selected from the group consisting of C n H 2n+1 , OC n H 2n+1 , OAr 1 , N(C n H 2n+1 ) 2 , N(Ar 1 )(Ar 2 ), CH ⁇ CH—C n H 2n+1 , C ⁇ C—C n H 2n+1 , Ar 1 , Ar 1 —Ar 2 , and C n H 2n —Ar 1 , or the host has no substitution.
- n can range from 1 to 10; and Ar 1 and Ar 2 can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof.
- the host can be an inorganic compound.
- a Zn containing inorganic material e.g. ZnS.
- the host can be a compound comprising at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
- the host can include a metal complex.
- the host can be, but is not limited to, a specific compound selected from the group consisting of:
- a formulation that comprises the first compound is described.
- the formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, and an electron transport layer material, disclosed herein.
- the materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device.
- emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present.
- the materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.
- a charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity.
- the conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved.
- Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.
- Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804 and US2012146012.
- a hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material.
- the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoO x ; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenchexacarbonitrile; a metal complex, and a crosslinkable compounds.
- aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:
- Each of Ar 1 to Ar 9 is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine
- Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
- a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, hetero
- Ar 1 to Ar 9 is independently selected from the group consisting of:
- k is an integer from 1 to 20;
- X 101 to X 108 is C (including CH) or N;
- Z 101 is NAr 1 , O, or S;
- Ar 1 has the same group defined above.
- metal complexes used in HIL or HTL include, but are not limited to the following general formula:
- Met is a metal, which can have an atomic weight greater than 40;
- (Y 101 -Y 102 ) is a bidentate ligand, Y 101 and Y 101 are independently selected from C, N, O, P, and S;
- L 101 is an ancillary ligand;
- k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and
- k′+k′′ is the maximum number of ligands that may be attached to the metal.
- (Y 101 -Y 102 ) is a 2-phenylpyridine derivative. In another aspect, (Y 101 -Y 102 ) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc + /Fc couple less than about 0.6 V.
- Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, US06517957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025,
- An electron blocking layer may be used to reduce the number of electrons and/or excitons that leave the emissive layer.
- the presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer.
- a blocking layer may be used to confine emission to a desired region of an OLED.
- the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface.
- the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface.
- the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.
- the light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material.
- the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.
- metal complexes used as host are preferred to have the following general formula:
- Met is a metal
- (Y 103 -Y 104 ) is a bidentate ligand, Y 103 and Y 104 are independently selected from C, N, O, P, and S
- L 101 is an another ligand
- k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal
- k′+k′′ is the maximum number of ligands that may be attached to the metal.
- the metal complexes are:
- (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.
- Met is selected from Ir and Pt.
- (Y 103 -Y 104 ) is a carbene ligand.
- organic compounds used as host are selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine
- Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
- a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, ary
- the host compound contains at least one of the following groups in the molecule:
- each of R 101 to R 107 is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar’s mentioned above.
- X 101 to X 108 is selected from C (including CH) or N.
- Z 101 and Z 102 is selected from NR 101 , O, or S.
- Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, US7154114, WO2001039234, WO2004093207, WO2005014551, WO2005089025,
- One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure.
- the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials.
- suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
- Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, US06699599, US06916554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US2006013446
- a hole blocking layer may be used to reduce the number of holes and/or excitons that leave the emissive layer.
- the presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer.
- a blocking layer may be used to confine emission to a desired region of an OLED.
- the HBL material has a lower HOMO (further from the vacuum level) and or higher triplet energy than the emitter closest to the HBL interface.
- the HBL material has a lower HOMO (further from the vacuum level) and or higher triplet energy than one or more of the hosts closest to the HBL interface.
- compound used in HBL contains the same molecule or the same functional groups used as host described above.
Abstract
A composition including a first compound capable of functioning as a phosphorescent emitter in an OLED is provided. The first compound has at least one aromatic ring and at least one substituent R directly bonded to one of the at least one aromatic rings. Each substituent R has the formula of
where (a) G1 is selected from NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; and G2 is a non-aromatic polycyclic group; (b) G1 is a direct bond; and G2 is a non-aromatic spiro polycyclic group; or (c) G1 is selected from direct bond, NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; G2 is a non-aromatic polycyclic group; and R is directly bonded to a phenyl, pyridine, or triazine. R1, R2, and R3 are are a variety of substituents. Formulations and devices, such as an OLEDs, that include the first compound are also described.
Description
- This application is a continuation of co-pending U.S. Pat. Application No. 16/438,819, filed on Jun. 12, 2019, which is a continuation of U.S. Pat. Application No. 15/240,044, filed on Aug. 18, 2016, which claims priority to U.S. Provisional applications No. 62/213,757, filed on Sep. 3, 2015; No. 62/232,194, filed on Sep. 24, 2015; No. 62/291,960, filed on Feb. 5, 2016; No. 62/322,510, filed on Apr. 14, 2016; and No. 62/330,412 filed on May 2, 2016, the entire contents of which are incorporated herein by reference.
- The claimed invention was made by, on behalf of, and/or in connection with one or more of the following parties to a joint university corporation research agreement: The Regents of the University of Michigan, Princeton University, University of Southern California, and the Universal Display Corporation. The agreement was in effect on and before the date the claimed invention was made, and the claimed invention was made as a result of activities undertaken within the scope of the agreement.
- The present invention relates to compounds for use as emitters, and devices, such as organic light emitting diodes, including the same.
- Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.
- OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.
- One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Alternatively the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs.The white OLED can be either a single EML device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.
- One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)3, which has the following structure:
- In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.
- As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.
- As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.
- As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.
- A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.
- As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.
- As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.
- More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.
- According to one embodiment, a composition comprising a first compound is provided. In the composition, the first compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature, and the first compound has at least one aromatic ring and at least one substituent R, where each of the at least one substituent R is directly bonded to one of the at least one aromatic rings. Each of the at least one substituent R has the formula of
- where :
- (a) G1 is selected from the group consisting of NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; and G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3;
- (b) G1 is a direct bond; and G2 is a non-aromatic spiro polycyclic group, which can be further substituted by one or more R3; or
- (c) G1 is selected from the group consisting of: direct bond, NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3; and R is directly bonded to an aromatic ring selected from the group consisting of phenyl, pyridine, and triazine, which can be further fused to other rings;
- R1, R2, and R3 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
- each G1 and G2 can be independently, partially or fully deuterated.
- According to another embodiment, an organic light emitting diode/device (OLED) is also provided. The OLED can include an anode, a cathode, and an organic layer, disposed between the anode and the cathode. The organic layer can include the first compound as described herein. According to yet another embodiment, the organic light emitting device is incorporated into one or more device selected from a consumer product, an electronic component module, and/or a lighting panel.
- According to yet another embodiment, a formulation containing the first compound as described herein is provided.
-
FIG. 1 shows an organic light emitting device. -
FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer. - Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
- The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
- More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.
-
FIG. 1 shows an organiclight emitting device 100. The figures are not necessarily drawn to scale.Device 100 may include asubstrate 110, ananode 115, ahole injection layer 120, ahole transport layer 125, anelectron blocking layer 130, anemissive layer 135, ahole blocking layer 140, anelectron transport layer 145, anelectron injection layer 150, aprotective layer 155, acathode 160, and abarrier layer 170.Cathode 160 is a compound cathode having a firstconductive layer 162 and a secondconductive layer 164.Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in US 7,279,704 at cols. 6-10, which are incorporated by reference. - More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Pat. Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Pat. Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Pat. Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Pat. Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Pat. Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.
-
FIG. 2 shows aninverted OLED 200. The device includes asubstrate 210, acathode 215, anemissive layer 220, ahole transport layer 225, and ananode 230.Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, anddevice 200 hascathode 215 disposed underanode 230,device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect todevice 100 may be used in the corresponding layers ofdevice 200.FIG. 2 provides one example of how some layers may be omitted from the structure ofdevice 100. - The simple layered structure illustrated in
FIGS. 1 and 2 is provided by way of nonlimiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, indevice 200,hole transport layer 225 transports holes and injects holes intoemissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect toFIGS. 1 and 2 . - Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in
FIGS. 1 and 2 . For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties. - Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
- Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
- Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, laser printers, telephones, cell phones, tablets, phablets, personal digital assistants (PDAs), wearable device, laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, vehicles, a large area wall, theater or stadium screen, or a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18° C. to 30° C., and more preferably at room temperature (20-25° C.), but could be used outside this temperature range, for example, from -40° C. to + 80° C.
- The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.
- In the field of organic chemistry, a polycyclic compound is an organic chemical featuring several closed rings of atoms, primarily carbon. These ring substructures comprises cycloalkanes, aromatics, and other ring types. They come in sizes of three atoms and upward, and in combinations of linkages that include tethering (such as in biaryls), fusing (edge-to-edge, such as in anthracene and steroids), links via a single atom (such as in spiro compounds), and bridged cyclics such as adamantane. Though “poly” literally means “many”, in this context polycyclic includes smaller rings such as bicyclic, tricyclic, and tetracyclic.
- The term “halo,” “halogen,” or “halide” as used herein includes fluorine, chlorine, bromine, and iodine.
- The term “alkyl” as used herein contemplates both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl,and the like. Additionally, the alkyl group may be optionally substituted.
- The term “cycloalkyl” as used herein contemplates cyclic alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 10 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, adamantyl, and the like. Additionally, the cycloalkyl group may be optionally substituted.
- The term “alkenyl” as used herein contemplates both straight and branched chain alkene radicals. Preferred alkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl group may be optionally substituted.
- The term “alkynyl” as used herein contemplates both straight and branched chain alkyne radicals. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted.
- The terms “aralkyl” or “arylalkyl” as used herein are used interchangeably and contemplate an alkyl group that has as a substituent an aromatic group. Additionally, the aralkyl group may be optionally substituted.
- The term “heterocyclic group” as used herein contemplates aromatic and non-aromatic cyclic radicals. Hetero-aromatic cyclic radicals also means heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperdino, pyrrolidino, and the like, and cyclic ethers, such as tetrahydrofuran, tetrahydropyran, and the like. Additionally, the heterocyclic group may be optionally substituted.
- The term “aryl” or “aromatic group” as used herein contemplates single-ring groups and polycyclic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is aromatic, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted.
- The term “heteroaryl” as used herein contemplates single-ring hetero-aromatic groups that may include from one to five heteroatoms. The term heteroaryl also includes polycyclic hetero-aromatic systems having two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group may be optionally substituted.
- The alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl may be unsubstituted or may be substituted with one or more substituents selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, cyclic amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
- As used herein, “substituted” indicates that a substituent other than H is bonded to the relevant position, such as carbon. Thus, for example, where R1 is mono-substituted, then one R1 must be other than H. Similarly, where R1 is di-substituted, then two of R1 must be other than H. Similarly, where R1 is unsubstituted, R1 is hydrogen for all available positions.
- The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C-H groups in the respective fragment can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.
- It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.
- According to one embodiment, a composition comprising a first compound is described. In the composition, the first compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature, and the first compound has at least one aromatic ring and at least one substituent R, where each of the at least one substituent R is directly bonded to one of the at least one aromatic rings. Each of the at least one substituent R has the formula of
- where :
- (a) G1 is selected from the group consisting of NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; and G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3;
- (b) G1 is a direct bond; and G2 is a non-aromatic spiro polycyclic group, which can be further substituted by one or more R3; or
- (c) G1 is selected from the group consisting of: direct bond, NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3; and R is directly bonded to an aromatic ring selected from the group consisting of phenyl, pyridine, and triazine, which can be further fused to other rings;
- wherein R1, R2, and R3 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
- each G1 and G2 can be independently, partially or fully deuterated.
- In some embodiments, G1 is SiR1R2. In some embodiments, G1 is NR1. In some embodiments, G1 is alkyl. In some such embodiments, G1 is selected from the gourp consisiting of divalent methyl, ethyl, propyl, and butyl. In some embodiments, G1 is fully or partially deuterated.
- In some embodiments, G2 is polycyclic alkyl. In some embodiments, G2 is carborane. In some embodiments, G2 contains at least one heteroatom. In some embodiments, G2 includes at least one heterocyclic group.
- In some embodiments, the first compound is capable of emitting light from a triplet excited state to a ground singlet state at room temperature.
- In some embodiments, the first compound is a metal coordination complex having a metal-carbon bond. In some such embodiments, the metal is selected from the group consisting of Ir, Rh, Re, Ru, Os, Pt, Au, and Cu. In some such embodiments, the metal is Ir, while the metal is Pt is other embodiments.
- In some embodiments, the first compound has the formula of M(L1)x(L2)y(L3)z, where:
- L1, L2 and L3 can be the same or different;
- x is 1, 2, or 3;
- y is 0, 1, or 2;
- z is 0, 1, or 2;
- x+y+z is the oxidation state of the metal M;
- L1, L2 and L3 are each independently selected from the group consisting of:
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
- , and
-
- each X1 to X17 are independently selected from the group consisting of carbon and nitrogen;
- X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO2, CR′R″, SiR′R″, and GeR′R″;
- each R′ and R″ is independently, optionally fused or joined to form a ring;
- each Ra, Rb, Rc, and Rd independently represents from mono substitution to the maximum possible number of substitutions, or no substitution;
- each R′, R″, Ra, Rb, Rc, and Rd is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
- any two adjacent substitutents of Ra, Rb, Rc, and Rd are optionally fused or joined to form a ring or form a multidentate ligand; and
- at least one of the Ra, Rb, Rc, and Rd includes the at least one substituent R.
- In some embodiments where the first compound has the structure M(L1)x(L2)y(L3)z, the first compound has the formula of Ir(L1)2(L2). In some such embodiments, L1 has the formula selected from the group consisting of:
- and
- and L2 has the formula
- In some such embodiments, L2 has the formula:
- where:
- Re, Rf, Rh, and Ri are independently selected from group consisting of alkyl, cycloalkyl, aryl, and heteroaryl;
- at least one of Re, Rf, Rh, and Ri has at least two carbon atoms; and
- Rg is selected from group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
- In some embodiments where the first compound has the formula of Ir(L1)2(L2), ligands L1 and L2 are different and each independently selected from the group consisting of:
- , and
- In some embodiments where the first compound has the formula of Ir(L1)2(L2), ligands L1 and L2 are each independently selected from the group consisting of:
- , and
- In some embodiments where the first compound has the structure M(L1)x(L2)y(L3)z, the first compound has the formula of Pt(L1)2 or Pt(L1)(L2). In some embodiments where the first compound has the formula of Pt(L1)2 or Pt(L1)(L2), one L1 is connected to the other L1 or L2 to form a tetradentate ligand.
- In some embodiments where the first compound has the structure M(L1)x(L2)y(L3)z, at least one of Ra, Rb, Rc, and Rd includes an alkyl or cycloalkyl group that is partially or fully deuterated.
- In some embodiments, G2 is selected from the group consisting of:
- In some embodiments, each of the at least one substituent R is independently selected from the group consisting of:
- , and
- In some embodiments where the first compound has the structure M(L1)x(L2)y(L3)z,, at least one of L1, L2, and L3 is selected from the group consisting of:
- , and
- In some embodiments where the first compound has the formula of Ir(L1)2(L2), ligands L1 and L2 are different and each independently selected from the group consisting of:
- and
- In some embodiments where the first compound has the formula of M(L1)x(L2)y(L3)z, ligand L1 is LA having the following structure:
- selected from the group consisting of LA1 to LA2480 as listed below:
-
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1 RG1 H H H H H LA1241 CD3 H RG58 H H H LA2 RG2 H H H H H LA1242 CD3 H RG59 H H H LA3 RG3 H H H H H LA1243 CD3 H RG60 H H H LA4 RG4 H H H H H LA1244 CD3 H RG61 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA5 RG5 H H H H H LA1245 CD3 H RG62 H H H LA6 RG6 H H H H H LA1246 CD3 H RG63 H H H LA7 RG7 H H H H H LA1247 CD3 H RG64 H H H LA8 RG8 H H H H H LA1248 CD3 H RG65 H H H LA9 RG9 H H H H H LA1249 CD3 H RG66 H H H LA10 RG10 H H H H H LA1250 CD3 H RG67 H H H LA11 RG11 H H H H H LA1251 CD3 H RG68 H H H LA12 RG12 H H H H H LA1252 CD3 H RG69 H H H LA13 RG13 H H H H H LA1253 CD3 H RG70 H H H LA14 RG14 H H H H H LA1254 CD3 H RG71 H H H LA15 RG15 H H H H H LA1255 CD3 H RG72 H H H LA16 RG16 H H H H H LA1256 CD3 H RG73 H H H LA17 RG17 H H H H H LA1257 CD3 H RG74 H H H LA18 RG18 H H H H H LA1258 CD3 H RG75 H H H LA19 RG19 H H H H H LA1259 CD3 H RG76 H H H LA20 RG20 H H H H H LA1260 CD3 H RG77 H H H LA21 RG21 H H H H H LA1261 CD3 H RG78 H H H LA22 RG22 H H H H H LA1262 CD3 H RG79 H H H LA23 RG23 H H H H H LA1263 CD3 H RG80 H H H LA24 RG24 H H H H H LA1264 CD3 H RG81 H H H LA25 RG25 H H H H H LA1265 CD3 H RG82 H H H LA26 RG26 H H H H H LA1266 CD3 H RG83 H H H LA27 RG27 H H H H H LA1267 CD3 H RG84 H H H LA28 RG28 H H H H H LA1268 CD3 H RG85 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA29 RG29 H H H H H LA1269 CD3 H RG86 H H H LA30 RG30 H H H H H LA1270 CD3 H RG87 H H H LA31 RG31 H H H H H LA1271 CD3 H RG88 H H H LA32 RG32 H H H H H LA1272 CD3 H RG89 H H H LA33 RG33 H H H H H LA1273 CD3 H RG90 H H H LA34 RG34 H H H H H LA1274 CD3 H RG91 H H H LA35 RG35 H H H H H LA1275 CD3 H RG92 H H H LA36 RG36 H H H H H LA1276 CD3 H RG93 H H H LA37 RG37 H H H H H LA1277 CD3 H RG94 H H H LA38 RG38 H H H H H LA1278 CD3 H RG95 H H H LA39 RG39 H H H H H LA1279 CD3 H RG96 H H H LA40 RG40 H H H H H LA1280 CD3 H RG97 H H H LA41 RG41 H H H H H LA1281 CD3 H RG98 H H H LA42 RG42 H H H H H LA1282 CD3 H RG99 H H H LA43 RG43 H H H H H LA1283 CD3 H RG100 H H H LA44 RG44 H H H H H LA1284 CD3 H RG101 H H H LA45 RG45 H H H H H LA1285 CD3 H RG102 H H H LA46 RG46 H H H H H LA1286 CD3 H RG103 H H H LA47 RG47 H H H H H LA1287 CD3 H RG104 H H H LA48 RG48 H H H H H LA1288 CD3 H RG105 H H H LA49 RG49 H H H H H LA1289 CD3 H RG106 H H H LA50 RG50 H H H H H LA1290 CD3 H RG107 H H H LA51 RG51 H H H H H LA1291 CD3 H RG108 H H H LA52 RG52 H H H H H LA1292 CD3 H RG109 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA53 RG53 H H H H H LA1293 CD3 H RG110 H H H LA54 RG54 H H H H H LA1294 CD3 H RG111 H H H LA55 RG55 H H H H H LA1295 CD3 H RG112 H H H LA56 RG56 H H H H H LA1296 CD3 H RG113 H H H LA57 RG57 H H H H H LA1297 CD3 H RG114 H H H LA58 RG58 H H H H H LA1298 CD3 H RG115 H H H LA59 RG59 H H H H H LA1299 CD3 H RG116 H H H LA60 RG60 H H H H H LA1300 CD3 H RG117 H H H LA61 RG61 H H H H H LA1301 CD3 H RG118 H H H LA62 RG62 H H H H H LA1302 CD3 H RG119 H H H LA63 RG63 H H H H H LA1303 CD3 H RG120 H H H LA64 RG64 H H H H H LA1304 CD3 H RG121 H H H LA65 RG65 H H H H H LA1305 CD3 H RG122 H H H LA66 RG66 H H H H H LA1306 CD3 H RG123 H H H LA67 RG67 H H H H H LA1307 CD3 H RG124 H H H LA68 RG68 H H H H H LA1308 CD3 H RG125 H H H LA69 RG69 H H H H H LA1309 CD3 H RG126 H H H LA70 RG70 H H H H H LA1310 CD3 H RG127 H H H LA71 RG71 H H H H H LA1311 CD3 H RG128 H H H LA72 RG72 H H H H H LA1312 CD3 H RG129 H H H LA73 RG73 H H H H H LA1313 CD3 H RG130 H H H LA74 RG74 H H H H H LA1314 CD3 H RG131 H H H LA75 RG75 H H H H H LA1315 CD3 H RG132 H H H LA76 RG76 H H H H H LA1316 CD3 H RG133 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA77 RG77 H H H H H LA1317 CD3 H RG134 H H H LA78 RG78 H H H H H LA1318 CD3 H RG135 H H H LA79 RG79 H H H H H LA1319 CD3 H RG136 H H H LA80 RG80 H H H H H LA1320 CD3 H RG137 H H H LA81 RG81 H H H H H LA1321 CD3 H RG138 H H H LA82 RG82 H H H H H LA1322 CD3 H RG139 H H H LA83 RG83 H H H H H LA1323 CD3 H RG140 H H H LA84 RG84 H H H H H LA1324 CD3 H RG141 H H H LA85 RG85 H H H H H LA13 25 CD3 H RG142 H H H LA86 RG86 H H H H H LA1326 CD3 H RG143 H H H LA87 RG87 H H H H H LA1327 CD3 H RG144 H H H LA88 RG88 H H H H H LA1328 CD3 H RG145 H H H LA89 RG89 H H H H H LA1329 CD3 H RG146 H H H LA90 RG90 H H H H H LA1330 CD3 H RG147 H H H LA91 RG91 H H H H H LA1331 CD3 H RG148 H H H LA92 RG92 H H H H H LA1332 CD3 H RG149 H H H LA93 RG93 H H H H H LA1333 CD3 H RG150 H H H LA94 RG94 H H H H H LA1334 CD3 H RG151 H H H LA95 RG95 H H H H H LA1335 CD3 H RG152 H H H LA96 RG96 H H H H H LA1336 CD3 H RG153 H H H LA97 RG97 H H H H H LA1337 CD3 H RG154 H H H LA98 RG98 H H H H H LA1338 CD3 H RG155 H H H LA99 RG99 H H H H H LA1339 CD3 H RG156 H H H LA100 RG100 H H H H H LA1340 CD3 H RG157 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA101 RG101 H H H H H LA1341 CD3 H RG158 H H H LA102 RG102 H H H H H LA1342 CD3 H RG159 H H H LA103 RG103 H H H H H LA1343 CD3 H RG160 H H H LA104 RG104 H H H H H LA1344 CD3 H RG161 H H H LA105 RG105 H H H H H LA1345 CD3 H RG162 H H H LA106 RG106 H H H H H LA1346 CD3 H RG163 H H H LA107 RG107 H H H H H LA1347 CD3 H RG164 H H H LA108 RG108 H H H H H LA1348 CD3 H RG165 H H H LA109 RG109 H H H H H LA1349 CD3 H RG166 H H H LA110 RG110 H H H H H LA1350 CD3 H RG167 H H H LA111 RG111 H H H H H LA1351 CD3 H RG168 H H H LA112 RG112 H H H H H LA1352 CD3 H RG169 H H H LA113 RG113 H H H H H LA1353 H CD3 RG1 H H H LA114 RG114 H H H H H LA1354 H CD3 RG2 H H H LA115 RG115 H H H H H LA1355 H CD3 RG3 H H H LA116 RG116 H H H H H LA1356 H CD3 RG4 H H H LA117 RG117 H H H H H LA1357 H CD3 RG5 H H H LA118 RG118 H H H H H LA1358 H CD3 RG6 H H H LA119 RG119 H H H H H LA1359 H CD3 RG7 H H H LA120 RG120 H H H H H LA1360 H CD3 RG8 H H H LA121 RG121 H H H H H LA1361 H CD3 RG9 H H H LA122 RG122 H H H H H LA1362 H CD3 RG10 H H H LA123 RG123 H H H H H LA1363 H CD3 RG11 H H H LA124 RG124 H H H H H LA1364 H CD3 RG12 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA125 RG125 H H H H H LA1365 H CD3 RG13 H H H LA126 RG126 H H H H H LA1366 H CD3 RG14 H H H LA127 RG127 H H H H H LA1367 H CD3 RG15 H H H LA128 RG128 H H H H H LA1368 H CD3 RG16 H H H LA129 RG129 H H H H H LA1369 H CD3 RG17 H H H LA130 RG130 H H H H H LA1370 H CD3 RG18 H H H LA131 RG131 H H H H H LA1371 H CD3 RG19 H H H LA132 RG132 H H H H H LA1372 H CD3 RG20 H H H LA133 RG133 H H H H H LA1373 H CD3 RG21 H H H LA134 RG134 H H H H H LA1374 H CD3 RG22 H H H LA135 RG135 H H H H H LA1375 H CD3 RG23 H H H LA136 RG136 H H H H H LA1376 H CD3 RG24 H H H LA137 RG137 H H H H H LA1377 H CD3 RG25 H H H LA138 RG138 H H H H H LA1378 H CD3 RG26 H H H LA139 RG139 H H H H H LA1379 H CD3 RG27 H H H LA140 RG140 H H H H H LA1380 H CD3 RG28 H H H LA141 RG141 H H H H H LA1381 H CD3 RG29 H H H LA142 RG142 H H H H H LA1382 H CD3 RG30 H H H LA143 RG143 H H H H H LA1383 H CD3 RG31 H H H LA144 RG144 H H H H H LA1384 H CD3 RG32 H H H LA145 RG145 H H H H H LA1385 H CD3 RG33 H H H LA146 RG146 H H H H H LA1386 H CD3 RG34 H H H LA147 RG147 H H H H H LA1387 H CD3 RG35 H H H LA148 RG148 H H H H H LA1388 H CD3 RG36 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA149 RG149 H H H H H LA1389 H CD3 RG37 H H H LA150 RG150 H H H H H LA1390 H CD3 RG38 H H H LA151 RG151 H H H H H LA1391 H CD3 RG39 H H H LA152 RG152 H H H H H LA1392 H CD3 RG40 H H H LA153 RG153 H H H H H LA1393 H CD3 RG41 H H H LA154 RG154 H H H H H LA1394 H CD3 RG42 H H H LA155 RG155 H H H H H LA1395 H CD3 RG43 H H H LA156 RG156 H H H H H LA1396 H CD3 RG44 H H H LA157 RG157 H H H H H LA1397 H CD3 RG45 H H H LA158 RG158 H H H H H LA1398 H CD3 RG46 H H H LA159 RG159 H H H H H LA1399 H CD3 RG47 H H H LA160 RG160 H H H H H LA1400 H CD3 RG48 H H H LA161 RG161 H H H H H LA1401 H CD3 RG49 H H H LA162 RG162 H H H H H LA1402 H CD3 RG50 H H H LA163 RG163 H H H H H LA1403 H CD3 RG51 H H H LA164 RG164 H H H H H LA1404 H CD3 RG52 H H H LA165 RG165 H H H H H LA1405 H CD3 RG53 H H H LA166 RG166 H H H H H LA1406 H CD3 RG54 H H H LA167 RG167 H H H H H LA1407 H CD3 RG55 H H H LA168 RG168 H H H H H LA1408 H CD3 RG56 H H H LA169 RG169 H H H H H LA1409 H CD3 RG57 H H H LA170 RG1 H CD3 H H H LA1410 H CD3 RG58 H H H LA171 RG2 H CD3 H H H LA1411 H CD3 RG59 H H H LA172 RG3 H CD3 H H H LA1412 H CD3 RG60 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA173 RG4 H CD3 H H H LA1413 H CD3 RG61 H H H LA174 RG5 H CD3 H H H LA1414 H CD3 RG62 H H H LA175 RG6 H CD3 H H H LA1415 H CD3 RG63 H H H LA176 RG7 H CD3 H H H LA1416 H CD3 RG64 H H H LA177 RG8 H CD3 H H H LA1417 H CD3 RG65 H H H LA178 RG9 H CD3 H H H LA1418 H CD3 RG66 H H H LA179 RG10 H CD3 H H H LA1419 H CD3 RG67 H H H LA180 RG11 H CD3 H H H LA1420 H CD3 RG68 H H H LA181 RG12 H CD3 H H H LA1421 H CD3 RG69 H H H LA182 RG13 H CD3 H H H LA1422 H CD3 RG70 H H H LA183 RG14 H CD3 H H H LA1423 H CD3 RG71 H H H LA184 RG15 H CD3 H H H LA1424 H CD3 RG72 H H H LA185 RG16 H CD3 H H H LA1425 H CD3 RG73 H H H LA186 RG17 H CD3 H H H LA1426 H CD3 RG74 H H H LA187 RG18 H CD3 H H H LA1427 H CD3 RG75 H H H LA188 RG19 H CD3 H H H LA1428 H CD3 RG76 H H H LA189 RG20 H CD3 H H H LA1429 H CD3 RG77 H H H LA190 RG21 H CD3 H H H LA1430 H CD3 RG78 H H H LA191 RG22 H CD3 H H H LA1431 H CD3 RG79 H H H LA192 RG23 H CD3 H H H LA1432 H CD3 RG80 H H H LA193 RG24 H CD3 H H H LA1433 H CD3 RG81 H H H LA194 RG25 H CD3 H H H LA1434 H CD3 RG82 H H H LA195 RG26 H CD3 H H H LA1435 H CD3 RG83 H H H LA196 RG27 H CD3 H H H LA1436 H CD3 RG84 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA197 RG28 H CD3 H H H LA1437 H CD3 RG85 H H H LA198 RG29 H CD3 H H H LA1438 H CD3 RG86 H H H LA199 RG30 H CD3 H H H LA1439 H CD3 RG87 H H H LA200 RG31 H CD3 H H H LA1440 H CD3 RG88 H H H LA201 RG32 H CD3 H H H LA1441 H CD3 RG89 H H H LA202 RG33 H CD3 H H H LA1442 H CD3 RG90 H H H LA203 RG34 H CD3 H H H LA1443 H CD3 RG91 H H H LA204 RG35 H CD3 H H H LA1444 H CD3 RG92 H H H LA205 RG36 H CD3 H H H LA1445 H CD3 RG93 H H H LA206 RG37 H CD3 H H H LA1446 H CD3 RG94 H H H LA207 RG38 H CD3 H H H LA1447 H CD3 RG95 H H H LA208 RG39 H CD3 H H H LA1448 H CD3 RG96 H H H LA209 RG40 H CD3 H H H LA1449 H CD3 RG97 H H H LA210 RG41 H CD3 H H H LA1450 H CD3 RG98 H H H LA211 RG42 H CD3 H H H LA1451 H CD3 RG99 H H H LA212 RG43 H CD3 H H H LA1452 H CD3 RG100 H H H LA213 RG44 H CD3 H H H LA1453 H CD3 RG101 H H H LA214 RG45 H CD3 H H H LA1454 H CD3 RG102 H H H LA215 RG46 H CD3 H H H LA1455 H CD3 RG103 H H H LA216 RG47 H CD3 H H H LA1456 H CD3 RG104 H H H LA217 RG48 H CD3 H H H LA1457 H CD3 RG105 H H H LA218 RG49 H CD3 H H H LA1458 H CD3 RG106 H H H LA219 RG50 H CD3 H H H LA1459 H CD3 RG107 H H H LA220 RG51 H CD3 H H H LA1460 H CD3 RG108 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA221 RG52 H CD3 H H H LA1461 H CD3 RG109 H H H LA222 RG53 H CD3 H H H LA1462 H CD3 RG110 H H H LA223 RG54 H CD3 H H H LA1463 H CD3 RG111 H H H LA224 RG55 H CD3 H H H LA1464 H CD3 RG112 H H H LA225 RG56 H CD3 H H H LA1465 H CD3 RG113 H H H LA226 RG57 H CD3 H H H LA1466 H CD3 RG114 H H H LA227 RG58 H CD3 H H H LA1467 H CD3 RG115 H H H LA228 RG59 H CD3 H H H LA1468 H CD3 RG116 H H H LA229 RG60 H CD3 H H H LA1469 H CD3 RG117 H H H LA230 RG61 H CD3 H H H LA1470 H CD3 RG118 H H H LA231 RG62 H CD3 H H H LA1471 H CD3 RG119 H H H LA232 RG63 H CD3 H H H LA1472 H CD3 RG120 H H H LA233 RG64 H CD3 H H H LA1473 H CD3 RG121 H H H LA234 RG65 H CD3 H H H LA1474 H CD3 RG122 H H H LA235 RG66 H CD3 H H H LA1475 H CD3 RG123 H H H LA236 RG67 H CD3 H H H LA1476 H CD3 RG124 H H H LA237 RG68 H CD3 H H H LA1477 H CD3 RG125 H H H LA238 RG69 H CD3 H H H LA1478 H CD3 RG126 H H H LA239 RG70 H CD3 H H H LA1479 H CD3 RG127 H H H LA240 RG71 H CD3 H H H LA1480 H CD3 RG128 H H H LA241 RG72 H CD3 H H H LA1481 H CD3 RG129 H H H LA242 RG73 H CD3 H H H LA1482 H CD3 RG130 H H H LA243 RG74 H CD3 H H H LA1483 H CD3 RG131 H H H LA244 RG75 H CD3 H H H LA1484 H CD3 RG132 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA245 RG76 H CD3 H H H LA1485 H CD3 RG133 H H H LA246 RG77 H CD3 H H H LA1486 H CD3 RG134 H H H LA247 RG78 H CD3 H H H LA1487 H CD3 RG135 H H H LA248 RG79 H CD3 H H H LA1488 H CD3 RG136 H H H LA249 RG80 H CD3 H H H LA1489 H CD3 RG137 H H H LA250 RG81 H CD3 H H H LA1490 H CD3 RG138 H H H LA251 RG82 H CD3 H H H LA1491 H CD3 RG139 H H H LA252 RG83 H CD3 H H H LA1492 H CD3 RG140 H H H LA253 RG84 H CD3 H H H LA1493 H CD3 RG141 H H H LA254 RG85 H CD3 H H H LA1494 H CD3 RG142 H H H LA255 RG86 H CD3 H H H LA1495 H CD3 RG143 H H H LA256 RG87 H CD3 H H H LA1496 H CD3 RG144 H H H LA257 RG88 H CD3 H H H LA1497 H CD3 RG145 H H H LA258 RG89 H CD3 H H H LA1498 H CD3 RG146 H H H LA259 RG90 H CD3 H H H LA1499 H CD3 RG147 H H H LA260 RG91 H CD3 H H H LA1500 H CD3 RG148 H H H LA261 RG92 H CD3 H H H LA1501 H CD3 RG149 H H H LA262 RG93 H CD3 H H H LA1502 H CD3 RG150 H H H LA263 RG94 H CD3 H H H LA1503 H CD3 RG151 H H H LA264 RG95 H CD3 H H H LA1504 H CD3 RG152 H H H LA265 RG96 H CD3 H H H LA1505 H CD3 RG153 H H H LA266 RG97 H CD3 H H H LA1506 H CD3 RG154 H H H LA267 RG98 H CD3 H H H LA1507 H CD3 RG155 H H H LA268 RG99 H CD3 H H H LA1508 H CD3 RG156 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA269 RG100 H CD3 H H H LA1509 H CD3 RG157 H H H LA270 RG101 H CD3 H H H LA1510 H CD3 RG158 H H H LA271 RG102 H CD3 H H H LA1511 H CD3 RG159 H H H LA272 RG103 H CD3 H H H LA1512 H CD3 RG160 H H H LA273 RG104 H CD3 H H H LA1513 H CD3 RG161 H H H LA274 RG105 H CD3 H H H LA1514 H CD3 RG162 H H H LA275 RG106 H CD3 H H H LA1515 H CD3 RG163 H H H LA276 RG107 H CD3 H H H LA1516 H CD3 RG164 H H H LA277 RG108 H CD3 H H H LA1517 H CD3 RG165 H H H LA278 RG109 H CD3 H H H LA1518 H CD3 RG166 H H H LA279 RG110 H CD3 H H H LA1519 H CD3 RG167 H H H LA280 RG111 H CD3 H H H LA1520 H CD3 RG168 H H H LA281 RG112 H CD3 H H H LA1521 H CD3 RG169 H H H LA282 RG113 H CD3 H H H LA1522 RG1 CD3 CD3 H H H LA283 RG114 H CD3 H H H LA1523 RG2 CD3 CD3 H H H LA284 RG115 H CD3 H H H LA1524 RG3 CD3 CD3 H H H LA285 RG116 H CD3 H H H LA1525 RG4 CD3 CD3 H H H LA286 RG117 H CD3 H H H LA1526 RG5 CD3 CD3 H H H LA287 RG118 H CD3 H H H LA1527 RG6 CD3 CD3 H H H LA288 RG119 H CD3 H H H LA1528 RG7 CD3 CD3 H H H LA289 RG120 H CD3 H H H LA1529 RG8 CD3 CD3 H H H LA290 RG121 H CD3 H H H LA1530 RG9 CD3 CD3 H H H LA291 RG122 H CD3 H H H LA1531 RG10 CD3 CD3 H H H LA292 RG123 H CD3 H H H LA1532 RG11 CD3 CD3 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA293 RG124 H CD3 H H H LA1533 RG12 CD3 CD3 H H H LA294 RG125 H CD3 H H H LA1534 RG13 CD3 CD3 H H H LA295 RG126 H CD3 H H H LA1535 RG14 CD3 CD3 H H H LA296 RG127 H CD3 H H H LA1536 RG15 CD3 CD3 H H H LA297 RG128 H CD3 H H H LA1537 RG16 CD3 CD3 H H H LA298 RG129 H CD3 H H H LA1538 RG17 CD3 CD3 H H H LA299 RG130 H CD3 H H H LA1539 RG18 CD3 CD3 H H H LA300 RG131 H CD3 H H H LA1540 RG19 CD3 CD3 H H H LA301 RG132 H CD3 H H H LA1541 CD3 RG1 H H H H LA302 RG133 H CD3 H H H LA1542 CD3 RG2 H H H H LA303 RG134 H CD3 H H H LA1543 CD3 RG3 H H H H LA304 RG135 H CD3 H H H LA1544 CD3 RG4 H H H H LA305 RG136 H CD3 H H H LA1545 CD3 RG5 H H H H LA306 RG137 H CD3 H H H LA1546 CD3 RG6 H H H H LA307 RG138 H CD3 H H H LA1547 CD3 RG7 H H H H LA308 RG139 H CD3 H H H LA1548 CD3 RG8 H H H H LA309 RG140 H CD3 H H H LA1549 CD3 RG9 H H H H LA310 RG141 H CD3 H H H LA1550 CD3 RG10 H H H H LA311 RG142 H CD3 H H H LA1551 CD3 RG11 H H H H LA312 RG143 H CD3 H H H LA1552 CD3 RG12 H H H H LA313 RG144 H CD3 H H H LA1553 CD3 RG13 H H H H LA314 RG145 H CD3 H H H LA1554 CD3 RG14 H H H H LA315 RG146 H CD3 H H H LA1555 CD3 RG15 H H H H LA316 RG147 H CD3 H H H LA1556 CD3 RG16 H H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA317 RG148 H CD3 H H H LA1557 CD3 RG17 H H H H LA318 RG149 H CD3 H H H LA1558 CD3 RG18 H H H H LA319 RG150 H CD3 H H H LA1559 CD3 RG19 H H H H LA320 RG151 H CD3 H H H LA1560 CD3 CD3 RG1 H H CD3 LA321 RG152 H CD3 H H H LA1561 CD3 CD3 RG2 H H CD3 LA322 RG153 H CD3 H H H LA1562 CD3 CD3 RG3 H H CD3 LA323 RG154 H CD3 H H H LA1563 CD3 CD3 RG4 H H CD3 LA324 RG155 H CD3 H H H LA1564 CD3 CD3 RG5 H H CD3 LA325 RG156 H CD3 H H H LA1565 CD3 CD3 RG6 H H CD3 LA326 RG157 H CD3 H H H LA1566 CD3 CD3 RG7 H H CD3 LA327 RG158 H CD3 H H H LA1567 CD3 CD3 RG8 H H CD3 LA328 RG159 H CD3 H H H LA1568 CD3 CD3 RG9 H H CD3 LA329 RG160 H CD3 H H H LA1569 CD3 CD3 RG10 H H CD3 LA330 RG161 H CD3 H H H LA1570 CD3 CD3 RG11 H H CD3 LA331 RG162 H CD3 H H H LA1571 CD3 CD3 RG12 H H CD3 LA332 RG163 H CD3 H H H LA1572 CD3 CD3 RG13 H H CD3 LA333 RG164 H CD3 H H H LA1573 CD3 CD3 RG14 H H CD3 LA334 RG165 H CD3 H H H LA1574 CD3 CD3 RG15 H H CD3 LA335 RG166 H CD3 H H H LA1575 CD3 CD3 RG16 H H CD3 LA336 RG167 H CD3 H H H LA1576 CD3 CD3 RG17 H H CD3 LA337 RG168 H CD3 H H H LA1577 CD3 CD3 RG18 H H CD3 LA338 RG169 H CD3 H H H LA1578 CD3 CD3 RG19 H H CD3 LA339 RG1 CD3 CD3 H H CD3 LA1579 CD3 H RG1 H H CD3 LA340 RG2 CD3 CD3 H H CD3 LA1580 CD3 H RG2 H H CD3 -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA341 RG3 CD3 CD3 H H CD3 LA1581 CD3 H RG3 H H CD3 LA342 RG4 CD3 CD3 H H CD3 LA1582 CD3 H RG4 H H CD3 LA343 RG5 CD3 CD3 H H CD3 LA1583 CD3 H RG5 H H CD3 LA344 RG6 CD3 CD3 H H CD3 LA1584 CD3 H RG6 H H CD3 LA345 RG7 CD3 CD3 H H CD3 LA1585 CD3 H RG7 H H CD3 LA346 RG8 CD3 CD3 H H CD3 LA1586 CD3 H RG8 H H CD3 LA347 RG9 CD3 CD3 H H CD3 LA1587 CD3 H RG9 H H CD3 LA348 RG10 CD3 CD3 H H CD3 LA1588 CD3 H RG10 H H CD3 LA349 RG11 CD3 CD3 H H CD3 LA1589 CD3 H RG11 H H CD3 LA350 RG12 CD3 CD3 H H CD3 LA1590 CD3 H RG12 H H CD3 LA351 RG13 CD3 CD3 H H CD3 LA1591 CD3 H RG13 H H CD3 LA352 RG14 CD3 CD3 H H CD3 LA1592 CD3 H RG14 H H CD3 LA353 RG15 CD3 CD3 H H CD3 LA1593 CD3 H RG15 H H CD3 LA354 RG16 CD3 CD3 H H CD3 LA1594 CD3 H RG16 H H CD3 LA355 RG17 CD3 CD3 H H CD3 LA1595 CD3 H RG17 H H CD3 LA356 RG18 CD3 CD3 H H CD3 LA1596 CD3 H RG18 H H CD3 LA357 RG19 CD3 CD3 H H CD3 LA1597 CD3 H RG19 H H CD3 LA358 RG20 CD3 CD3 H H CD3 LA1598 RG1 CD3 H H H H LA359 RG21 CD3 CD3 H H CD3 LA1599 RG2 CD3 H H H H LA360 RG22 CD3 CD3 H H CD3 LA1600 RG3 CD3 H H H H LA361 RG23 CD3 CD3 H H CD3 LA1601 RG4 CD3 H H H H LA362 RG24 CD3 CD3 H H CD3 LA1602 RG5 CD3 H H H H LA363 RG25 CD3 CD3 H H CD3 LA1603 RG6 CD3 H H H H LA364 RG26 CD3 CD3 H H CD3 LA1604 RG7 CD3 H H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA365 RG27 CD3 CD3 H H CD3 LA1605 RG8 CD3 H H H H LA366 RG28 CD3 CD3 H H CD3 LA1606 RG9 CD3 H H H H LA367 RG29 CD3 CD3 H H CD3 LA1607 RG10 CD3 H H H H LA368 RG30 CD3 CD3 H H CD3 LA1608 RG11 CD3 H H H H LA369 RG31 CD3 CD3 H H CD3 LA1609 RG12 CD3 H H H H LA370 RG32 CD3 CD3 H H CD3 LA1610 RG13 CD3 H H H H LA371 RG33 CD3 CD3 H H CD3 LA1611 RG14 CD3 H H H H LA372 RG34 CD3 CD3 H H CD3 LA1612 RG15 CD3 H H H H LA373 RG35 CD3 CD3 H H CD3 LA1613 RG16 CD3 H H H H LA374 RG36 CD3 CD3 H H CD3 LA1614 RG17 CD3 H H H H LA375 RG37 CD3 CD3 H H CD3 LA1615 RG18 CD3 H H H H LA376 RG38 CD3 CD3 H H CD3 LA1616 RG19 CD3 H H H H LA377 RG39 CD3 CD3 H H CD3 LA1617 H CD3 RG1 H H CD3 LA378 RG40 CD3 CD3 H H CD3 LA1618 H CD3 RG2 H H CD3 LA379 RG41 CD3 CD3 H H CD3 LA1619 H CD3 RG3 H H CD3 LA380 RG42 CD3 CD3 H H CD3 LA1620 H CD3 RG4 H H CD3 LA381 RG43 CD3 CD3 H H CD3 LA1621 H CD3 RG5 H H CD3 LA382 RG44 CD3 CD3 H H CD3 LA1622 H CD3 RG6 H H CD3 LA383 RG45 CD3 CD3 H H CD3 LA1623 H CD3 RG7 H H CD3 LA384 RG46 CD3 CD3 H H CD3 LA1624 H CD3 RG8 H H CD3 LA385 RG47 CD3 CD3 H H CD3 LA1625 H CD3 RG9 H H CD3 LA386 RG48 CD3 CD3 H H CD3 LA1626 H CD3 RG10 H H CD3 LA387 RG49 CD3 CD3 H H CD3 LA1627 H CD3 RG11 H H CD3 LA388 RG50 CD3 CD3 H H CD3 LA1628 H CD3 RG12 H H CD3 -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA389 RG51 CD3 CD3 H H CD3 LA1629 H CD3 RG13 H H CD3 LA390 RG52 CD3 CD3 H H CD3 LA1630 H CD3 RG14 H H CD3 LA391 RG53 CD3 CD3 H H CD3 LA1631 H CD3 RG15 H H CD3 LA392 RG54 CD3 CD3 H H CD3 LA1632 H CD3 RG16 H H CD3 LA393 RG55 CD3 CD3 H H CD3 LA1633 H CD3 RG17 H H CD3 LA394 RG56 CD3 CD3 H H CD3 LA1634 H CD3 RG18 H H CD3 LA395 RG57 CD3 CD3 H H CD3 LA1635 H CD3 RG19 H H CD3 LA396 RG58 CD3 CD3 H H CD3 LA1636 H RG1 H H H H LA397 RG59 CD3 CD3 H H CD3 LA1637 H RG2 H H H H LA398 RG60 CD3 CD3 H H CD3 LA1638 H RG3 H H H H LA399 RG61 CD3 CD3 H H CD3 LA1639 H RG4 H H H H LA400 RG62 CD3 CD3 H H CD3 LA1640 H RG5 H H H H LA401 RG63 CD3 CD3 H H CD3 LA1641 H RG6 H H H H LA402 RG64 CD3 CD3 H H CD3 LA1642 H RG7 H H H H LA403 RG65 CD3 CD3 H H CD3 LA1643 H RG8 H H H H LA404 RG66 CD3 CD3 H H CD3 LA1644 H RG9 H H H H LA405 RG67 CD3 CD3 H H CD3 LA1645 H RG10 H H H H LA406 RG68 CD3 CD3 H H CD3 LA1646 H RG11 H H H H LA407 RG69 CD3 CD3 H H CD3 LA1647 H RG12 H H H H LA408 RG70 CD3 CD3 H H CD3 LA1648 H RG13 H H H H LA409 RG71 CD3 CD3 H H CD3 LA1649 H RG14 H H H H LA410 RG72 CD3 CD3 H H CD3 LA1650 H RG15 H H H H LA411 RG73 CD3 CD3 H H CD3 LA1651 H RG16 H H H H LA412 RG74 CD3 CD3 H H CD3 LA1652 H RG17 H H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA413 RG75 CD3 CD3 H H CD3 LA1653 H RG18 H H H H LA414 RG76 CD3 CD3 H H CD3 LA1654 H RG19 H H H H LA415 RG77 CD3 CD3 H H CD3 LA1655 H RG20 H H H H LA416 RG78 CD3 CD3 H H CD3 LA1656 H RG21 H H H H LA417 RG79 CD3 CD3 H H CD3 LA1657 H RG22 H H H H LA418 RG80 CD3 CD3 H H CD3 LA1658 H RG23 H H H H LA419 RG81 CD3 CD3 H H CD3 LA1659 H RG24 H H H H LA420 RG82 CD3 CD3 H H CD3 LA1660 H RG25 H H H H LA421 RG83 CD3 CD3 H H CD3 LA1661 H RG26 H H H H LA422 RG84 CD3 CD3 H H CD3 LA1662 H RG27 H H H H LA423 RG85 CD3 CD3 H H CD3 LA1663 H RG28 H H H H LA424 RG86 CD3 CD3 H H CD3 LA1664 H RG29 H H H H LA425 RG87 CD3 CD3 H H CD3 LA1665 H RG30 H H H H LA426 RG88 CD3 CD3 H H CD3 LA1666 H RG31 H H H H LA427 RG89 CD3 CD3 H H CD3 LA1667 H RG32 H H H H LA428 RG90 CD3 CD3 H H CD3 LA1668 H RG33 H H H H LA429 RG91 CD3 CD3 H H CD3 LA1669 H RG34 H H H H LA430 RG92 CD3 CD3 H H CD3 LA1670 H RG35 H H H H LA431 RG93 CD3 CD3 H H CD3 LA1671 H RG36 H H H H LA432 RG94 CD3 CD3 H H CD3 LA1672 H RG37 H H H H LA433 RG95 CD3 CD3 H H CD3 LA1673 H RG38 H H H H LA434 RG96 CD3 CD3 H H CD3 LA1674 H RG39 H H H H LA435 RG97 CD3 CD3 H H CD3 LA1675 H RG40 H H H H LA436 RG98 CD3 CD3 H H CD3 LA1676 H RG41 H H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA437 RG99 CD3 CD3 H H CD3 LA1677 H RG42 H H H H LA438 RG100 CD3 CD3 H H CD3 LA1678 H RG43 H H H H LA439 RG101 CD3 CD3 H H CD3 LA1679 H RG44 H H H H LA440 RG102 CD3 CD3 H H CD3 LA1680 H RG45 H H H H LA441 RG103 CD3 CD3 H H CD3 LA1681 H RG46 H H H H LA442 RG104 CD3 CD3 H H CD3 LA1682 H RG47 H H H H LA443 RG105 CD3 CD3 H H CD3 LA1683 H RG48 H H H H LA444 RG106 CD3 CD3 H H CD3 LA1684 H RG49 H H H H LA445 RG107 CD3 CD3 H H CD3 LA1685 H RG50 H H H H LA446 RG108 CD3 CD3 H H CD3 LA1686 H RG51 H H H H LA447 RG109 CD3 CD3 H H CD3 LA1687 H RG52 H H H H LA448 RG110 CD3 CD3 H H CD3 LA1688 H RG53 H H H H LA449 RG111 CD3 CD3 H H CD3 LA1689 H RG54 H H H H LA450 RG112 CD3 CD3 H H CD3 LA1690 H RG55 H H H H LA451 RG113 CD3 CD3 H H CD3 LA1691 H RG56 H H H H LA452 RG114 CD3 CD3 H H CD3 LA1692 H RG57 H H H H LA453 RG115 CD3 CD3 H H CD3 LA1693 H RG58 H H H H LA454 RG116 CD3 CD3 H H CD3 LA1694 H RG59 H H H H LA455 RG117 CD3 CD3 H H CD3 LA1695 H RG60 H H H H LA456 RG118 CD3 CD3 H H CD3 LA1696 H RG61 H H H H LA457 RG119 CD3 CD3 H H CD3 LA1697 H RG62 H H H H LA458 RG120 CD3 CD3 H H CD3 LA1698 H RG63 H H H H LA459 RG121 CD3 CD3 H H CD3 LA1699 H RG64 H H H H LA460 RG122 CD3 CD3 H H CD3 LA1700 H RG65 H H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA461 RG123 CD3 CD3 H H CD3 LA1701 H RG66 H H H H LA462 RG124 CD3 CD3 H H CD3 LA1702 H RG67 H H H H LA463 RG125 CD3 CD3 H H CD3 LA1703 H RG68 H H H H LA464 RG126 CD3 CD3 H H CD3 LA1704 H RG69 H H H H LA465 RG127 CD3 CD3 H H CD3 LA1705 H RG70 H H H H LA466 RG128 CD3 CD3 H H CD3 LA1706 H RG71 H H H H LA467 RG129 CD3 CD3 H H CD3 LA1707 H RG72 H H H H LA468 RG130 CD3 CD3 H H CD3 LA1708 H RG73 H H H H LA469 RG131 CD3 CD3 H H CD3 LA1709 H RG74 H H H H LA470 RG132 CD3 CD3 H H CD3 LA1710 H RG75 H H H H LA471 RG133 CD3 CD3 H H CD3 LA1711 H RG76 H H H H LA472 RG134 CD3 CD3 H H CD3 LA1712 H RG77 H H H H LA473 RG135 CD3 CD3 H H CD3 LA1713 H RG78 H H H H LA474 RG136 CD3 CD3 H H CD3 LA1714 H RG79 H H H H LA475 RG137 CD3 CD3 H H CD3 LA1715 H RG80 H H H H LA476 RG138 CD3 CD3 H H CD3 LA1716 H RG81 H H H H LA477 RG139 CD3 CD3 H H CD3 LA1717 H RG82 H H H H LA478 RG140 CD3 CD3 H H CD3 LA1718 H RG83 H H H H LA479 RG141 CD3 CD3 H H CD3 LA1719 H RG84 H H H H LA480 RG142 CD3 CD3 H H CD3 LA1720 H RG85 H H H H LA481 RG143 CD3 CD3 H H CD3 LA1721 H RG86 H H H H LA482 RG144 CD3 CD3 H H CD3 LA1722 H RG87 H H H H LA483 RG145 CD3 CD3 H H CD3 LA1723 H RG88 H H H H LA484 RG146 CD3 CD3 H H CD3 LA1724 H RG89 H H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA485 RG147 CD3 CD3 H H CD3 LA1725 H RG90 H H H H LA486 RG148 CD3 CD3 H H CD3 LA1726 H RG91 H H H H LA487 RG149 CD3 CD3 H H CD3 LA1727 H RG92 H H H H LA488 RG150 CD3 CD3 H H CD3 LA1728 H RG93 H H H H LA489 RG151 CD3 CD3 H H CD3 LA1729 H RG94 H H H H LA490 RG152 CD3 CD3 H H CD3 LA1730 H RG95 H H H H LA491 RG153 CD3 CD3 H H CD3 LA1731 H RG96 H H H H LA492 RG154 CD3 CD3 H H CD3 LA1732 H RG97 H H H H LA493 RG155 CD3 CD3 H H CD3 LA1733 H RG98 H H H H LA494 RG156 CD3 CD3 H H CD3 LA1734 H RG99 H H H H LA495 RG157 CD3 CD3 H H CD3 LA1735 H RG100 H H H H LA496 RG158 CD3 CD3 H H CD3 LA1736 H RG101 H H H H LA497 RG159 CD3 CD3 H H CD3 LA1737 H RG102 H H H H LA498 RG160 CD3 CD3 H H CD3 LA1738 H RG103 H H H H LA499 RG161 CD3 CD3 H H CD3 LA1739 H RG104 H H H H LA500 RG162 CD3 CD3 H H CD3 LA1740 H RG105 H H H H LA501 RG163 CD3 CD3 H H CD3 LA1741 H RG106 H H H H LA502 RG164 CD3 CD3 H H CD3 LA1742 H RG107 H H H H LA503 RG165 CD3 CD3 H H CD3 LA1743 H RG108 H H H H LA504 RG166 CD3 CD3 H H CD3 LA1744 H RG109 H H H H LA505 RG167 CD3 CD3 H H CD3 LA1745 H RG110 H H H H LA506 RG168 CD3 CD3 H H CD3 LA1746 H RG111 H H H H LA507 RG169 CD3 CD3 H H CD3 LA1747 H RG112 H H H H LA508 H RG1 CD3 H H H LA1748 H RG113 H H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA509 H RG2 CD3 H H H LA1749 H RG114 H H H H LA510 H RG3 CD3 H H H LA1750 H RG115 H H H H LA511 H RG4 CD3 H H H LA1751 H RG116 H H H H LA512 H RG5 CD3 H H H LA1752 H RG117 H H H H LA513 H RG6 CD3 H H H LA1753 H RG118 H H H H LA514 H RG7 CD3 H H H LA1754 H RG119 H H H H LA515 H RG8 CD3 H H H LA1755 H RG120 H H H H LA516 H RG9 CD3 H H H LA1756 H RG121 H H H H LA517 H RG10 CD3 H H H LA1757 H RG122 H H H H LA518 H RG11 CD3 H H H LA1758 H RG123 H H H H LA519 H RG12 CD3 H H H LA1759 H RG124 H H H H LA520 H RG13 CD3 H H H LA1760 H RG125 H H H H LA521 H RG14 CD3 H H H LA1761 H RG126 H H H H LA522 H RG15 CD3 H H H LA1762 H RG127 H H H H LA523 H RG16 CD3 H H H LA1763 H RG128 H H H H LA524 H RG17 CD3 H H H LA1764 H RG129 H H H H LA525 H RG18 CD3 H H H LA1765 H RG130 H H H H LA526 H RG19 CD3 H H H LA1766 H RG131 H H H H LA527 H RG20 CD3 H H H LA1767 H RG132 H H H H LA528 H RG21 CD3 H H H LA1768 H RG133 H H H H LA529 H RG22 CD3 H H H LA1769 H RG134 H H H H LA530 H RG23 CD3 H H H LA1770 H RG135 H H H H LA531 H RG24 CD3 H H H LA1771 H RG136 H H H H LA532 H RG25 CD3 H H H LA1772 H RG137 H H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA533 H RG26 CD3 H H H LA1773 H RG138 H H H H LA534 H RG27 CD3 H H H LA1774 H RG139 H H H H LA535 H RG28 CD3 H H H LA1775 H RG140 H H H H LA536 H RG29 CD3 H H H LA1776 H RG141 H H H H LA537 H RG30 CD3 H H H LA1777 H RG142 H H H H LA538 H RG31 CD3 H H H LA1778 H RG143 H H H H LA539 H RG32 CD3 H H H LA1779 H RG144 H H H H LA540 H RG33 CD3 H H H LA1780 H RG145 H H H H LA541 H RG34 CD3 H H H LA1781 H RG146 H H H H LA542 H RG35 CD3 H H H LA1782 H RG147 H H H H LA543 H RG36 CD3 H H H LA1783 H RG148 H H H H LA544 H RG37 CD3 H H H LA1784 H RG149 H H H H LA545 H RG38 CD3 H H H LA1785 H RG150 H H H H LA546 H RG39 CD3 H H H LA1786 H RG151 H H H H LA547 H RG40 CD3 H H H LA1787 H RG152 H H H H LA548 H RG41 CD3 H H H LA1788 H RG153 H H H H LA549 H RG42 CD3 H H H LA1789 H RG154 H H H H LA550 H RG43 CD3 H H H LA1790 H RG155 H H H H LA551 H RG44 CD3 H H H LA1791 H RG156 H H H H LA552 H RG45 CD3 H H H LA1792 H RG157 H H H H LA553 H RG46 CD3 H H H LA1793 H RG158 H H H H LA554 H RG47 CD3 H H H LA1794 H RG159 H H H H LA555 H RG48 CD3 H H H LA1795 H RG160 H H H H LA556 H RG49 CD3 H H H LA1796 H RG161 H H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA557 H RG50 CD3 H H H LA1797 H RG162 H H H H LA558 H RG51 CD3 H H H LA1798 H RG163 H H H H LA559 H RG52 CD3 H H H LA1799 H RG164 H H H H LA560 H RG53 CD3 H H H LA1800 H RG165 H H H H LA561 H RG54 CD3 H H H LA1801 H RG166 H H H H LA562 H RG55 CD3 H H H LA1802 H RG167 H H H H LA563 H RG56 CD3 H H H LA1803 H RG168 H H H H LA564 H RG57 CD3 H H H LA1804 H RG169 H H H H LA565 H RG58 CD3 H H H LA1805 H H RG1 H H H LA566 H RG59 CD3 H H H LA1806 H H RG2 H H H LA567 H RG60 CD3 H H H LA1807 H H RG3 H H H LA568 H RG61 CD3 H H H LA1808 H H RG4 H H H LA569 H RG62 CD3 H H H LA1809 H H RG5 H H H LA570 H RG63 CD3 H H H LA1810 H H RG6 H H H LA571 H RG64 CD3 H H H LA1811 H H RG7 H H H LA572 H RG65 CD3 H H H LA1812 H H RG8 H H H LA573 H RG66 CD3 H H H LA1813 H H RG9 H H H LA574 H RG67 CD3 H H H LA1814 H H RG10 H H H LA575 H RG68 CD3 H H H LA1815 H H RG11 H H H LA576 H RG69 CD3 H H H LA1816 H H RG12 H H H LA577 H RG70 CD3 H H H LA1817 H H RG13 H H H LA578 H RG71 CD3 H H H LA1818 H H RG14 H H H LA579 H RG72 CD3 H H H LA1819 H H RG15 H H H LA580 H RG73 CD3 H H H LA1820 H H RG16 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA581 H RG74 CD3 H H H LA1821 H H RG17 H H H LA582 H RG75 CD3 H H H LA1822 H H RG18 H H H LA583 H RG76 CD3 H H H LA1823 H H RG19 H H H LA584 H RG77 CD3 H H H LA1824 H H RG20 H H H LA585 H RG78 CD3 H H H LA1825 H H RG21 H H H LA586 H RG79 CD3 H H H LA1826 H H RG22 H H H LA587 H RG80 CD3 H H H LA1827 H H RG23 H H H LA588 H RG81 CD3 H H H LA1828 H H RG24 H H H LA589 H RG82 CD3 H H H LA1829 H H RG25 H H H LA590 H RG83 CD3 H H H LA1830 H H RG26 H H H LA591 H RG84 CD3 H H H LA1831 H H RG27 H H H LA592 H RG85 CD3 H H H LA1832 H H RG28 H H H LA593 H RG86 CD3 H H H LA1833 H H RG29 H H H LA594 H RG87 CD3 H H H LA1834 H H RG30 H H H LA595 H RG88 CD3 H H H LA1835 H H RG31 H H H LA596 H RG89 CD3 H H H LA1836 H H RG32 H H H LA597 H RG90 CD3 H H H LA1837 H H RG33 H H H LA598 H RG91 CD3 H H H LA1838 H H RG34 H H H LA599 H RG92 CD3 H H H LA1839 H H RG35 H H H LA600 H RG93 CD3 H H H LA1840 H H RG36 H H H LA601 H RG94 CD3 H H H LA1841 H H RG37 H H H LA602 H RG95 CD3 H H H LA1842 H H RG38 H H H LA603 H RG96 CD3 H H H LA1843 H H RG39 H H H LA604 H RG97 CD3 H H H LA1844 H H RG40 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA605 H RG98 CD3 H H H LA1845 H H RG41 H H H LA606 H RG99 CD3 H H H LA1846 H H RG42 H H H LA607 H RG100 CD3 H H H LA1847 H H RG43 H H H LA608 H RG101 CD3 H H H LA1848 H H RG44 H H H LA609 H RG102 CD3 H H H LA1849 H H RG45 H H H LA610 H RG103 CD3 H H H LA1850 H H RG46 H H H LA611 H RG104 CD3 H H H LA1851 H H RG47 H H H LA612 H RG105 CD3 H H H LA1852 H H RG48 H H H LA613 H RG106 CD3 H H H LA1853 H H RG49 H H H LA614 H RG107 CD3 H H H LA1854 H H RG50 H H H LA615 H RG108 CD3 H H H LA1855 H H RG51 H H H LA616 H RG109 CD3 H H H LA1856 H H RG52 H H H LA617 H RG110 CD3 H H H LA1857 H H RG53 H H H LA618 H RG111 CD3 H H H LA1858 H H RG54 H H H LA619 H RG112 CD3 H H H LA1859 H H RG55 H H H LA620 H RG113 CD3 H H H LA1860 H H RG56 H H H LA621 H RG114 CD3 H H H LA1861 H H RG57 H H H LA622 H RG115 CD3 H H H LA1862 H H RG58 H H H LA623 H RG116 CD3 H H H LA1863 H H RG59 H H H LA624 H RG117 CD3 H H H LA1864 H H RG60 H H H LA625 H RG118 CD3 H H H LA1865 H H RG61 H H H LA626 H RG119 CD3 H H H LA1866 H H RG62 H H H LA627 H RG120 CD3 H H H LA1867 H H RG63 H H H LA628 H RG121 CD3 H H H LA1868 H H RG64 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA629 H RG122 CD3 H H H LA1869 H H RG65 H H H LA630 H RG123 CD3 H H H LA1870 H H RG66 H H H LA631 H RG124 CD3 H H H LA1871 H H RG67 H H H LA632 H RG125 CD3 H H H LA1872 H H RG68 H H H LA633 H RG126 CD3 H H H LA1873 H H RG69 H H H LA634 H RG127 CD3 H H H LA1874 H H RG70 H H H LA635 H RG128 CD3 H H H LA1875 H H RG71 H H H LA636 H RG129 CD3 H H H LA1876 H H RG72 H H H LA637 H RG130 CD3 H H H LA1877 H H RG73 H H H LA638 H RG131 CD3 H H H LA1878 H H RG74 H H H LA639 H RG132 CD3 H H H LA1879 H H RG75 H H H LA640 H RG133 CD3 H H H LA1880 H H RG76 H H H LA641 H RG134 CD3 H H H LA1881 H H RG77 H H H LA642 H RG135 CD3 H H H LA1882 H H RG78 H H H LA643 H RG136 CD3 H H H LA1883 H H RG79 H H H LA644 H RG137 CD3 H H H LA1884 H H RG80 H H H LA645 H RG133 CD3 H H H LA1885 H H RG81 H H H LA646 H RG139 CD3 H H H LA1886 H H RG82 H H H LA647 H RG140 CD3 H H H LA1887 H H RG83 H H H LA648 H RG141 CD3 H H H LA1888 H H RG84 H H H LA649 H RG142 CD3 H H H LA1889 H H RG85 H H H LA650 H RG143 CD3 H H H LA1890 H H RG86 H H H LA651 H RG144 CD3 H H H LA1891 H H RG87 H H H LA652 H RG145 CD3 H H H LA1892 H H RG88 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA653 H RG146 CD3 H H H LA1893 H H RG89 H H H LA654 H RG147 CD3 H H H LA1894 H H RG90 H H H LA655 H RG148 CD3 H H H LA1895 H H RG91 H H H LA656 H RG149 CD3 H H H LA1896 H H RG92 H H H LA657 H RG150 CD3 H H H LA1897 H H RG93 H H H LA658 H RG151 CD3 H H H LA1898 H H RG94 H H H LA659 H RG152 CD3 H H H LA1899 H H RG95 H H H LA660 H RG153 CD3 H H H LA1900 H H RG96 H H H LA661 H RG154 CD3 H H H LA1901 H H RG97 H H H LA662 H RG155 CD3 H H H LA1902 H H RG98 H H H LA663 H RG156 CD3 H H H LA1903 H H RG99 H H H LA664 H RG157 CD3 H H H LA1904 H H RG100 H H H LA665 H RG158 CD3 H H H LA1905 H H RG101 H H H LA666 H RG159 CD3 H H H LA1906 H H RG102 H H H LA667 H RG160 CD3 H H H LA1907 H H RG103 H H H LA668 H RG161 CD3 H H H LA1908 H H RG104 H H H LA669 H RG162 CD3 H H H LA1909 H H RG105 H H H LA670 H RG163 CD3 H H H LA1910 H H RG106 H H H LA671 H RG164 CD3 H H H LA1911 H H RG107 H H H LA672 H RG165 CD3 H H H LA1912 H H RG108 H H H LA673 H RG166 CD3 H H H LA1913 H H RG109 H H H LA674 H RG167 CD3 H H H LA1914 H H RG110 H H H LA675 H RG168 CD3 H H H LA1915 H H RG111 H H H LA676 H RG169 CD3 H H H LA1916 H H RG112 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA677 CD3 RG1 CD3 H H CD3 LA1917 H H RG113 H H H LA678 CD3 RG2 CD3 H H CD3 LA1918 H H RG114 H H H LA679 CD3 RG3 CD3 H H CD3 LA1919 H H RG115 H H H LA680 CD3 RG4 CD3 H H CD3 LA1920 H H RG116 H H H LA681 CD3 RG5 CD3 H H CD3 LA1921 H H RG117 H H H LA682 CD3 RG6 CD3 H H CD3 LA1922 H H RG118 H H H LA683 CD3 RG7 CD3 H H CD3 LA1923 H H RG119 H H H LA684 CD3 RG8 CD3 H H CD3 LA1924 H H RG120 H H H LA685 CD3 RG9 CD3 H H CD3 LA1925 H H RG121 H H H LA686 CD3 RG10 CD3 H H CD3 LA1926 H H RG122 H H H LA687 CD3 RG11 CD3 H H CD3 LA1927 H H RG123 H H H LA688 CD3 RG12 CD3 H H CD3 LA1928 H H RG124 H H H LA689 CD3 RG13 CD3 H H CD3 LA1929 H H RG125 H H H LA690 CD3 RG14 CD3 H H CD3 LA1930 H H RG126 H H H LA691 CD3 RG15 CD3 H H CD3 LA1931 H H RG127 H H H LA692 CD3 RG16 CD3 H H CD3 LA1932 H H RG128 H H H LA693 CD3 RG17 CD3 H H CD3 LA1933 H H RG129 H H H LA694 CD3 RG18 CD3 H H CD3 LA1934 H H RG130 H H H LA695 CD3 RG19 CD3 H H CD3 LA1935 H H RG131 H H H LA696 CD3 RG20 CD3 H H CD3 LA1936 H H RG132 H H H LA697 CD3 RG21 CD3 H H CD3 LA1937 H H RG133 H H H LA698 CD3 RG22 CD3 H H CD3 LA1938 H H RG134 H H H LA699 CD3 RG23 CD3 H H CD3 LA1939 H H RG135 H H H LA700 CD3 RG24 CD3 H H CD3 LA1940 H H RG136 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA701 CD3 RG25 CD3 H H CD3 LA1941 H H RG137 H H H LA702 CD3 RG26 CD3 H H CD3 LA1942 H H RG138 H H H LA703 CD3 RG27 CD3 H H CD3 LA1943 H H RG139 H H H LA704 CD3 RG28 CD3 H H CD3 LA1944 H H RG140 H H H LA705 CD3 RG29 CD3 H H CD3 LA1945 H H RG141 H H H LA706 CD3 RG30 CD3 H H CD3 LA1946 H H RG142 H H H LA707 CD3 RG31 CD3 H H CD3 LA1947 H H RG143 H H H LA708 CD3 RG32 CD3 H H CD3 LA1948 H H RG144 H H H LA709 CD3 RG33 CD3 H H CD3 LA1949 H H RG145 H H H LA710 CD3 RG34 CD3 H H CD3 LA1950 H H RG146 H H H LA711 CD3 RG35 CD3 H H CD3 LA1951 H H RG147 H H H LA712 CD3 RG36 CD3 H H CD3 LA1952 H H RG148 H H H LA713 CD3 RG37 CD3 H H CD3 LA1953 H H RG149 H H H LA714 CD3 RG38 CD3 H H CD3 LA1954 H H RG150 H H H LA715 CD3 RG39 CD3 H H CD3 LA1955 H H RG151 H H H LA716 CD3 RG40 CD3 H H CD3 LA1956 H H RG152 H H H LA717 CD3 RG41 CD3 H H CD3 LA1957 H H RG153 H H H LA718 CD3 RG42 CD3 H H CD3 LA1958 H H RG154 H H H LA719 CD3 RG43 CD3 H H CD3 LA1959 H H RG155 H H H LA720 CD3 RG44 CD3 H H CD3 LA1960 H H RG156 H H H LA721 CD3 RG45 CD3 H H CD3 LA1961 H H RG157 H H H LA722 CD3 RG46 CD3 H H CD3 LA1962 H H RG158 H H H LA723 CD3 RG47 CD3 H H CD3 LA1963 H H RG159 H H H LA724 CD3 RG48 CD3 H H CD3 LA1964 H H RG160 H H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA725 CD3 RG49 CD3 H H CD3 LA1965 H H RG161 H H H LA726 CD3 RG50 CD3 H H CD3 LA1966 H H RG162 H H H LA727 CD3 RG51 CD3 H H CD3 LA1967 H H RG163 H H H LA728 CD3 RG52 CD3 H H CD3 LA1968 H H RG164 H H H LA729 CD3 RG53 CD3 H H CD3 LA1969 H H RG165 H H H LA730 CD3 RG54 CD3 H H CD3 LA1970 H H RG166 H H H LA731 CD3 RG55 CD3 H H CD3 LA1971 H H RG167 H H H LA732 CD3 RG56 CD3 H H CD3 LA1972 H H RG168 H H H LA733 CD3 RG57 CD3 H H CD3 LA1973 H H RG169 H H H LA734 CD3 RGS8 CD3 H H CD3 LA1974 H H H RG1 H H LA735 CD3 RG59 CD3 H H CD3 LA1975 H H H RG2 H H LA736 CD3 RG60 CD3 H H CD3 LA1976 H H H RG3 H H LA737 CD3 RG61 CD3 H H CD3 LA1977 H H H RG4 H H LA738 CD3 RG62 CD3 H H CD3 LA1978 H H H RG5 H H LA739 CD3 RG63 CD3 H H CD3 LA1979 H H H RG6 H H LA740 CD3 RG64 CD3 H H CD3 LA1980 H H H RG7 H H LA741 CD3 RG65 CD3 H H CD3 LA1981 H H H RG8 H H LA742 CD3 RG66 CD3 H H CD3 LA1982 H H H RG9 H H LA743 CD3 RG67 CD3 H H CD3 LA1983 H H H RG10 H H LA744 CD3 RG68 CD3 H H CD3 LA1984 H H H RG11 H H LA745 CD3 RG69 CD3 H H CD3 LA1985 H H H RG12 H H LA746 CD3 RG70 CD3 H H CD3 LA1986 H H H RG13 H H LA747 CD3 RG71 CD3 H H CD3 LA1987 H H H RG14 H H LA748 CD3 RG72 CD3 H H CD3 LA1988 H H H RG15 H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA749 CD3 RG73 CD3 H H CD3 LA1989 H H H RG16 H H LA750 CD3 RG74 CD3 H H CD3 LA1990 H H H RG17 H H LA751 CD3 RG75 CD3 H H CD3 LA1991 H H H RG18 H H LA752 CD3 RG76 CD3 H H CD3 LA1992 H H H RG19 H H LA753 CD3 RG77 CD3 H H CD3 LA1993 H H H RG20 H H LA754 CD3 RG78 CD3 H H CD3 LA1994 H H H RG21 H H LA755 CD3 RG79 CD3 H H CD3 LA1995 H H H RG22 H H LA756 CD3 RG80 CD3 H H CD3 LA1996 H H H RG23 H H LA757 CD3 RG81 CD3 H H CD3 LA1997 H H H RG24 H H LA758 CD3 RG82 CD3 H H CD3 LA1998 H H H RG25 H H LA759 CD3 RG83 CD3 H H CD3 LA1999 H H H RG26 H H LA760 CD3 RG84 CD3 H H CD3 LA2000 H H H RG27 H H LA761 CD3 RG85 CD3 H H CD3 LA2001 H H H RG28 H H LA762 CD3 RG86 CD3 H H CD3 LA2002 H H H RG29 H H LA763 CD3 RG87 CD3 H H CD3 LA2003 H H H RG30 H H LA764 CD3 RG88 CD3 H H CD3 LA2004 H H H RG31 H H LA765 CD3 RG89 CD3 H H CD3 LA2005 H H H RG32 H H LA766 CD3 RG90 CD3 H H CD3 LA2006 H H H RG33 H H LA767 CD3 RG91 CD3 H H CD3 LA2007 H H H RG34 H H LA768 CD3 RG92 CD3 H H CD3 LA2008 H H H RG35 H H LA769 CD3 RG93 CD3 H H CD3 LA2009 H H H RG36 H H LA770 CD3 RG94 CD3 H H CD3 LA2010 H H H RG37 H H LA771 CD3 RG95 CD3 H H CD3 LA2011 H H H RG38 H H LA772 CD3 RG96 CD3 H H CD3 LA2012 H H H RG39 H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA773 CD3 RG97 CD3 H H CD3 LA2013 H H H RG40 H H LA774 CD3 RG98 CD3 H H CD3 LA2014 H H H RG41 H H LA775 CD3 RG99 CD3 H H CD3 LA2015 H H H RG42 H H LA776 CD3 RG100 CD3 H H CD3 LA2016 H H H RG43 H H LA777 CD3 RG101 CD3 H H CD3 LA2017 H H H RG44 H H LA778 CD3 RG102 CD3 H H CD3 LA2018 H H H RG45 H H LA779 CD3 RG103 CD3 H H CD3 LA2019 H H H RG46 H H LA780 CD3 RG104 CD3 H H CD3 LA2020 H H H RG47 H H LA781 CD3 RG105 CD3 H H CD3 LA2021 H H H RG48 H H LA782 CD3 RG106 CD3 H H CD3 LA2022 H H H RG49 H H LA783 CD3 RG107 CD3 H H CD3 LA2023 H H H RG50 H H LA784 CD3 RG108 CD3 H H CD3 LA2024 H H H RG51 H H LA785 CD3 RG109 CD3 H H CD3 LA2025 H H H RG52 H H LA786 CD3 RG110 CD3 H H CD3 LA2026 H H H RG53 H H LA787 CD3 RG111 CD3 H H CD3 LA2027 H H H RG54 H H LA788 CD3 RG112 CD3 H H CD3 LA2028 H H H RG55 H H LA789 CD3 RG113 CD3 H H CD3 LA2029 H H H RG56 H H LA790 CD3 RG114 CD3 H H CD3 LA2030 H H H RG57 H H LA791 CD3 RG115 CD3 H H CD3 LA2031 H H H RGS8 H H LA792 CD3 RG116 CD3 H H CD3 LA2032 H H H RG59 H H LA793 CD3 RG117 CD3 H H CD3 LA2033 H H H RG60 H H LA794 CD3 RG118 CD3 H H CD3 LA2034 H H H RG61 H H LA795 CD3 RG119 CD3 H H CD3 LA2035 H H H RG62 H H LA796 CD3 RG120 CD3 H H CD3 LA2036 H H H RG63 H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA797 CD3 RG121 CD3 H H CD3 LA2037 H H H RG64 H H LA798 CD3 RG122 CD3 H H CD3 LA2038 H H H RG65 H H LA799 CD3 RG123 CD3 H H CD3 LA2039 H H H RG66 H H LA800 CD3 RG124 CD3 H H CD3 LA2040 H H H RG67 H H LA801 CD3 RG125 CD3 H H CD3 LA2041 H H H RG68 H H LA802 CD3 RG126 CD3 H H CD3 LA2042 H H H RG69 H H LA803 CD3 RG127 CD3 H H CD3 LA2043 H H H RG70 H H LA804 CD3 RG128 CD3 H H CD3 LA2044 H H H RG71 H H LA805 CD3 RG129 CD3 H H CD3 LA2045 H H H RG72 H H LA806 CD3 RG130 CD3 H H CD3 LA2046 H H H RG73 H H LA807 CD3 RG131 CD3 H H CD3 LA2047 H H H RG74 H H LA808 CD3 RG132 CD3 H H CD3 LA2048 H H H RG75 H H LA809 CD3 RG133 CD3 H H CD3 LA2049 H H H RG76 H H LA810 CD3 RG134 CD3 H H CD3 LA2050 H H H RG77 H H LA811 CD3 RG135 CD3 H H CD3 LA2051 H H H RG78 H H LA812 CD3 RG136 CD3 H H CD3 LA2052 H H H RG79 H H LA813 CD3 RG137 CD3 H H CD3 LA2053 H H H RG80 H H LA814 CD3 RG138 CD3 H H CD3 LA2054 H H H RG81 H H LA815 CD3 RG139 CD3 H H CD3 LA2055 H H H RG82 H H LA816 CD3 RG140 CD3 H H CD3 LA2056 H H H RG83 H H LA817 CD3 RG141 CD3 H H CD3 LA2057 H H H RG84 H H LA818 CD3 RG142 CD3 H H CD3 LA2058 H H H RG85 H H LA819 CD3 RG143 CD3 H H CD3 LA2059 H H H RG86 H H LA820 CD3 RG144 CD3 H H CD3 LA2060 H H H RG87 H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA821 CD3 RG145 CD3 H H CD3 LA2061 H H H RG88 H H LA822 CD3 RG146 CD3 H H CD3 LA2062 H H H RG89 H H LA823 CD3 RG147 CD3 H H CD3 LA2063 H H H RG90 H H LA824 CD3 RG148 CD3 H H CD3 LA2064 H H H RG91 H H LA825 CD3 RG149 CD3 H H CD3 LA2065 H H H RG92 H H LA826 CD3 RG150 CD3 H H CD3 LA2066 H H H RG93 H H LA827 CD3 RG151 CD3 H H CD3 LA2067 H H H RG94 H H LA828 CD3 RG152 CD3 H H CD3 LA2068 H H H RG95 H H LA829 CD3 RG153 CD3 H H CD3 LA2069 H H H RG96 H H LA830 CD3 RG154 CD3 H H CD3 LA2070 H H H RG97 H H LA831 CD3 RG155 CD3 H H CD3 LA2071 H H H RG98 H H LA832 CD3 RG156 CD3 H H CD3 LA2072 H H H RG99 H H LA833 CD3 RG157 CD3 H H CD3 LA2073 H H H RG100 H H LA834 CD3 RG158 CD3 H H CD3 LA2074 H H H RG101 H H LA835 CD3 RG159 CD3 H H CD3 LA2075 H H H RG102 H H LA836 CD3 RG160 CD3 H H CD3 LA2076 H H H RG103 H H LA837 CD3 RG161 CD3 H H CD3 LA2077 H H H RG104 H H LA838 CD3 RG162 CD3 H H CD3 LA2078 H H H RG105 H H LA839 CD3 RG163 CD3 H H CD3 LA2079 H H H RG106 H H LA840 CD3 RG164 CD3 H H CD3 LA2080 H H H RG107 H H LA841 CD3 RG165 CD3 H H CD3 LA2081 H H H RG108 H H LA842 CD3 RG166 CD3 H H CD3 LA2082 H H H RG109 H H LA843 CD3 RG167 CD3 H H CD3 LA2083 H H H RG110 H H LA844 CD3 RG168 CD3 H H CD3 LA2084 H H H RG111 H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA845 CD3 RG169 CD3 H H CD3 LA2085 H H H RG112 H H LA846 CD3 RG1 CD3 H H H LA2086 H H H RG113 H H LA847 CD3 RG2 CD3 H H H LA2087 H H H RG114 H H LA848 CD3 RG3 CD3 H H H LA2088 H H H RG115 H H LA849 CD3 RG4 CD3 H H H LA2089 H H H RG116 H H LA850 CD3 RG5 CD3 H H H LA2090 H H H RG117 H H LA851 CD3 RG6 CD3 H H H LA2091 H H H RG118 H H LA852 CD3 RG7 CD3 H H H LA2092 H H H RG119 H H LA853 CD3 RG8 CD3 H H H LA2093 H H H RG120 H H LA854 CD3 RG9 CD3 H H H LA2094 H H H RG121 H H LA855 CD3 RG10 CD3 H H H LA2095 H H H RG122 H H LA856 CD3 RG11 CD3 H H H LA2096 H H H RG123 H H LA857 CD3 RG12 CD3 H H H LA2097 H H H RG124 H H LA858 CD3 RG13 CD3 H H H LA2098 H H H RG125 H H LA859 CD3 RG14 CD3 H H H LA2099 H H H RG126 H H LA860 CD3 RG15 CD3 H H H LA2100 H H H RG127 H H LA861 CD3 RG16 CD3 H H H LA2101 H H H RG128 H H LA862 CD3 RG17 CD3 H H H LA2102 H H H RG129 H H LA863 CD3 RG18 CD3 H H H LA2103 H H H RG130 H H LA864 CD3 RG19 CD3 H H H LA2104 H H H RG131 H H LA865 CD3 RG20 CD3 H H H LA2105 H H H RG132 H H LA866 CD3 RG21 CD3 H H H LA2106 H H H RG133 H H LA867 CD3 RG22 CD3 H H H LA2107 H H H RG134 H H LA868 CD3 RG23 CD3 H H H LA2108 H H H RG135 H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA869 CD3 RG24 CD3 H H H LA2109 H H H RG136 H H LA870 CD3 RG25 CD3 H H H LA2110 H H H RG137 H H LA871 CD3 RG26 CD3 H H H LA2111 H H H RG138 H H LA872 CD3 RG27 CD3 H H H LA2112 H H H RG139 H H LA873 CD3 RG28 CD3 H H H LA2113 H H H RG140 H H LA874 CD3 RG29 CD3 H H H LA2114 H H H RG141 H H LA875 CD3 RG30 CD3 H H H LA2115 H H H RG142 H H LA876 CD3 RG31 CD3 H H H LA2116 H H H RG143 H H LA877 CD3 RG32 CD3 H H H LA2117 H H H RG144 H H LA878 CD3 RG33 CD3 H H H LA2118 H H H RG145 H H LA879 CD3 RG34 CD3 H H H LA2119 H H H RG146 H H LA880 CD3 RG35 CD3 H H H LA2120 H H H RG147 H H LA881 CD3 RG36 CD3 H H H LA2121 H H H RG148 H H LA882 CD3 RG37 CD3 H H H LA2122 H H H RG149 H H LA883 CD3 RG38 CD3 H H H LA2123 H H H RG150 H H LA884 CD3 RG39 CD3 H H H LA2124 H H H RG151 H H LA885 CD3 RG40 CD3 H H H LA2125 H H H RG152 H H LA886 CD3 RG41 CD3 H H H LA2126 H H H RG153 H H LA887 CD3 RG42 CD3 H H H LA2127 H H H RG154 H H LA888 CD3 RG43 CD3 H H H LA2128 H H H RG155 H H LA889 CD3 RG44 CD3 H H H LA2129 H H H RG156 H H LA890 CD3 RG45 CD3 H H H LA2130 H H H RG157 H H LA891 CD3 RG46 CD3 H H H LA2131 H H H RG158 H H LA892 CD3 RG47 CD3 H H H LA2132 H H H RG159 H H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA893 CD3 RG48 CD3 H H H LA2133 H H H RG160 H H LA894 CD3 RG49 CD3 H H H LA2134 H H H RG161 H H LA895 CD3 RG50 CD3 H H H LA2135 H H H RG162 H H LA896 CD3 RG51 CD3 H H H LA2136 H H H RG163 H H LA897 CD3 RG52 CD3 H H H LA2137 H H H RG164 H H LA898 CD3 RG53 CD3 H H H LA2138 H H H RG165 H H LA899 CD3 RG54 CD3 H H H LA2139 H H H RG166 H H LA900 CD3 RG55 CD3 H H H LA2140 H H H RG167 H H LA901 CD3 RG56 CD3 H H H LA2141 H H H RG168 H H LA902 CD3 RG57 CD3 H H H LA2142 H H H RG169 H H LA903 CD3 RG58 CD3 H H H LA2143 H H H H RG1 H LA904 CD3 RG59 CD3 H H H LA2144 H H H H RG2 H LA905 CD3 RG60 CD3 H H H LA2145 H H H H RG3 H LA906 CD3 RG61 CD3 H H H LA2146 H H H H RG4 H LA907 CD3 RG62 CD3 H H H LA2147 H H H H RG5 H LA908 CD3 RG63 CD3 H H H LA2148 H H H H RG6 H LA909 CD3 RG64 CD3 H H H LA2149 H H H H RG7 H LA910 CD3 RG65 CD3 H H H LA2150 H H H H RG8 H LA911 CD3 RG66 CD3 H H H LA2151 H H H H RG9 H LA912 CD3 RG67 CD3 H H H LA2152 H H H H RG10 H LA913 CD3 RG68 CD3 H H H LA2153 H H H H RG11 H LA914 CD3 RG69 CD3 H H H LA2154 H H H H RG12 H LA915 CD3 RG70 CD3 H H H LA2155 H H H H RG13 H LA916 CD3 RG71 CD3 H H H LA2156 H H H H RG14 H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA917 CD3 RG72 CD3 H H H LA2157 H H H H RG15 H LA918 CD3 RG73 CD3 H H H LA2158 H H H H RG16 H LA919 CD3 RG74 CD3 H H H LA2159 H H H H RG17 H LA920 CD3 RG75 CD3 H H H LA2160 H H H H RG18 H LA921 CD3 RG76 CD3 H H H LA2161 H H H H RG19 H LA922 CD3 RG77 CD3 H H H LA2162 H H H H RG20 H LA923 CD3 RG78 CD3 H H H LA2163 H H H H RG21 H LA924 CD3 RG79 CD3 H H H LA2164 H H H H RG22 H LA925 CD3 RG80 CD3 H H H LA2165 H H H H RG23 H LA926 CD3 RG81 CD3 H H H LA2166 H H H H RG24 H LA927 CD3 RG82 CD3 H H H LA2167 H H H H RG25 H LA928 CD3 RG83 CD3 H H H LA2168 H H H H RG26 H LA929 CD3 RG84 CD3 H H H LA2169 H H H H RG27 H LA930 CD3 RG85 CD3 H H H LA2170 H H H H RG28 H LA931 CD3 RG86 CD3 H H H LA2171 H H H H RG29 H LA932 CD3 RG87 CD3 H H H LA2172 H H H H RG30 H LA933 CD3 RG88 CD3 H H H LA2173 H H H H RG31 H LA934 CD3 RG89 CD3 H H H LA2174 H H H H RG32 H LA935 CD3 RG90 CD3 H H H LA2175 H H H H RG33 H LA936 CD3 RG91 CD3 H H H LA2176 H H H H RG34 H LA937 CD3 RG92 CD3 H H H LA2177 H H H H RG35 H LA938 CD3 RG93 CD3 H H H LA2178 H H H H RG36 H LA939 CD3 RG94 CD3 H H H LA2179 H H H H RG37 H LA940 CD3 RG95 CD3 H H H LA2180 H H H H RG38 H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA941 CD3 RG96 CD3 H H H LA2181 H H H H RG39 H LA942 CD3 RG97 CD3 H H H LA2182 H H H H RG40 H LA943 CD3 RG98 CD3 H H H LA2183 H H H H RG41 H LA944 CD3 RG99 CD3 H H H LA2184 H H H H RG42 H LA945 CD3 RG100 CD3 H H H LA2185 H H H H RG43 H LA946 CD3 RG101 CD3 H H H LA2186 H H H H RG44 H LA947 CD3 RG102 CD3 H H H LA2187 H H H H RG45 H LA948 CD3 RG103 CD3 H H H LA2188 H H H H RG46 H LA949 CD3 RG104 CD3 H H H LA2189 H H H H RG47 H LA950 CD3 RG105 CD3 H H H LA2190 H H H H RG48 H LA951 CD3 RG106 CD3 H H H LA2191 H H H H RG49 H LA952 CD3 RG107 CD3 H H H LA2192 H H H H RG50 H LA953 CD3 RG108 CD3 H H H LA2193 H H H H RG51 H LA954 CD3 RG109 CD3 H H H LA2194 H H H H RG52 H LA955 CD3 RG110 CD3 H H H LA2195 H H H H RG53 H LA956 CD3 RG111 CD3 H H H LA2196 H H H H RG54 H LA957 CD3 RG112 CD3 H H H LA2197 H H H H RG55 H LA958 CD3 RG113 CD3 H H H LA2198 H H H H RG56 H LA959 CD3 RG114 CD3 H H H LA2199 H H H H RG57 H LA960 CD3 RG115 CD3 H H H LA2200 H H H H RG58 H LA961 CD3 RG116 CD3 H H H LA2201 H H H H RG59 H LA962 CD3 RG117 CD3 H H H LA2202 H H H H RG60 H LA963 CD3 RG118 CD3 H H H LA2203 H H H H RG61 H LA964 CD3 RG119 CD3 H H H LA2204 H H H H RG62 H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA965 CD3 RG120 CD3 H H H LA2205 H H H H RG63 H LA966 CD3 RG121 CD3 H H H LA2206 H H H H RG64 H LA967 CD3 RG122 CD3 H H H LA2207 H H H H RG65 H LA968 CD3 RG123 CD3 H H H LA2208 H H H H RG66 H LA969 CD3 RG124 CD3 H H H LA2209 H H H H RG67 H LA970 CD3 RG125 CD3 H H H LA2210 H H H H RG68 H LA971 CD3 RG126 CD3 H H H LA2211 H H H H RG69 H LA972 CD3 RG127 CD3 H H H LA2212 H H H H RG70 H LA973 CD3 RG128 CD3 H H H LA2213 H H H H RG71 H LA974 CD3 RG129 CD3 H H H LA2214 H H H H RG72 H LA975 CD3 RG130 CD3 H H H LA2215 H H H H RG73 H LA976 CD3 RG131 CD3 H H H LA2216 H H H H RG74 H LA977 CD3 RG132 CD3 H H H LA2217 H H H H RG75 H LA978 CD3 RG133 CD3 H H H LA2218 H H H H RG76 H LA979 CD3 RG134 CD3 H H H LA2219 H H H H RG77 H LA980 CD3 RG135 CD3 H H H LA2220 H H H H RG78 H LA981 CD3 RG136 CD3 H H H LA2221 H H H H RG79 H LA982 CD3 RG137 CD3 H H H LA2222 H H H H RG80 H LA983 CD3 RG138 CD3 H H H LA2223 H H H H RG81 H LA984 CD3 RG139 CD3 H H H LA2224 H H H H RG82 H LA985 CD3 RG140 CD3 H H H LA2225 H H H H RG83 H LA986 CD3 RG141 CD3 H H H LA2226 H H H H RG84 H LA987 CD3 RG142 CD3 H H H LA2227 H H H H RG85 H LA988 CD3 RG143 CD3 H H H LA2228 H H H H RG86 H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA989 CD3 RG144 CD3 H H H LA2229 H H H H RG87 H LA990 CD3 RG145 CD3 H H H LA2230 H H H H RG88 H LA991 CD3 RG146 CD3 H H H LA2231 H H H H RG89 H LA992 CD3 RG147 CD3 H H H LA2232 H H H H RG90 H LA993 CD3 RG148 CD3 H H H LA2233 H H H H RG91 H LA994 CD3 RG149 CD3 H H H LA2234 H H H H RG92 H LA995 CD3 RG150 CD3 H H H LA2235 H H H H RG93 H LA996 CD3 RG151 CD3 H H H LA2236 H H H H RG94 H LA997 CD3 RG152 CD3 H H H LA2237 H H H H RG95 H LA998 CD3 RG153 CD3 H H H LA2238 H H H H RG96 H LA999 CD3 RG154 CD3 H H H LA2239 H H H H RG97 H LA1000 CD3 RG155 CD3 H H H LA2240 H H H H RG98 H LA1001 CD3 RG156 CD3 H H H LA2241 H H H H RG99 H LA1002 CD3 RG157 CD3 H H H LA2242 H H H H RG100 H LA1003 CD3 RG158 CD3 H H H LA2243 H H H H RG101 H LA1004 CD3 RG159 CD3 H H H LA2244 H H H H RG102 H LA1005 CD3 RG160 CD3 H H H LA2245 H H H H RG103 H LA1006 CD3 RG161 CD3 H H H LA2246 H H H H RG104 H LA1007 CD3 RG162 CD3 H H H LA2247 H H H H RG105 H LA1008 CD3 RG163 CD3 H H H LA2248 H H H H RG106 H LA1009 CD3 RG164 CD3 H H H LA2249 H H H H RG107 H LA1010 CD3 RG165 CD3 H H H LA2250 H H H H RG108 H LA1011 CD3 RG166 CD3 H H H LA2251 H H H H RG109 H LA1012 CD3 RG167 CD3 H H H LA2252 H H H H RG110 H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1013 CD3 RG168 CD3 H H H LA2253 H H H H RG111 H LA1014 CD3 RG169 CD3 H H H LA2254 H H H H RG112 H LA1015 CD3 CD3 RG1 H H H LA2255 H H H H RG113 H LA1016 CD3 CD3 RG2 H H H LA2256 H H H H RG114 H LA1017 CD3 CD3 RG3 H H H LA2257 H H H H RG115 H LA1018 CD3 CD3 RG4 H H H LA2258 H H H H RG116 H LA1019 CD3 CD3 RG5 H H H LA2259 H H H H RG117 H LA1020 CD3 CD3 RG6 H H H LA2260 H H H H RG118 H LA1021 CD3 CD3 RG7 H H H LA2261 H H H H RG119 H LA1022 CD3 CD3 RG8 H H H LA2262 H H H H RG120 H LA1023 CD3 CD3 RG9 H H H LA2263 H H H H RG121 H LA1024 CD3 CD3 RG10 H H H LA2264 H H H H RG122 H LA1025 CD3 CD3 RG11 H H H LA2265 H H H H RG123 H LA1026 CD3 CD3 RG12 H H H LA2266 H H H H RG124 H LA1027 CD3 CD3 RG13 H H H LA2267 H H H H RG125 H LA1028 CD3 CD3 RG14 H H H LA2268 H H H H RG126 H LA1029 CD3 CD3 RG15 H H H LA2269 H H H H RG127 H LA1030 CD3 CD3 RG16 H H H LA2270 H H H H RG128 H LA1031 CD3 CD3 RG17 H H H LA2271 H H H H RG129 H LA1032 CD3 CD3 RG18 H H H LA2272 H H H H RG130 H LA1033 CD3 CD3 RG19 H H H LA2273 H H H H RG131 H LA1034 CD3 CD3 RG20 H H H LA2274 H H H H RG132 H LA1035 CD3 CD3 RG21 H H H LA2275 H H H H RG133 H LA1036 CD3 CD3 RG22 H H H LA2276 H H H H RG134 H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1037 CD3 CD3 RG23 H H H LA2277 H H H H RG135 H LA1038 CD3 CD3 RG24 H H H LA2278 H H H H RG136 H LA1039 CD3 CD3 RG25 H H H LA2279 H H H H RG137 H LA1040 CD3 CD3 RG26 H H H LA2280 H H H H RG138 H LA1041 CD3 CD3 RG27 H H H LA2281 H H H H RG139 H LA1042 CD3 CD3 RG28 H H H LA2282 H H H H RG140 H LA1043 CD3 CD3 RG29 H H H LA2283 H H H H RG141 H LA1044 CD3 CD3 RG30 H H H LA2284 H H H H RG142 H LA1045 CD3 CD3 RG31 H H H LA2285 H H H H RG143 H LA1046 CD3 CD3 RG32 H H H LA2286 H H H H RG144 H LA1047 CD3 CD3 RG33 H H H LA2287 H H H H RG145 H LA1048 CD3 CD3 RG34 H H H LA2288 H H H H RG146 H LA1049 CD3 CD3 RG35 H H H LA2289 H H H H RG147 H LA1050 CD3 CD3 RG36 H H H LA2290 H H H H RG148 H LA1051 CD3 CD3 RG37 H H H LA2291 H H H H RG149 H LA1052 CD3 CD3 RG38 H H H LA2292 H H H H RG150 H LA1053 CD3 CD3 RG39 H H H LA2293 H H H H RG151 H LA1054 CD3 CD3 RG40 H H H LA2294 H H H H RG152 H LA1055 CD3 CD3 RG41 H H H LA2295 H H H H RG153 H LA1056 CD3 CD3 RG42 H H H LA2296 H H H H RG154 H LA1057 CD3 CD3 RG43 H H H LA2297 H H H H RG155 H LA1058 CD3 CD3 RG44 H H H LA2298 H H H H RG156 H LA1059 CD3 CD3 RG45 H H H LA2299 H H H H RG157 H LA1060 CD3 CD3 RG46 H H H LA2300 H H H H RG158 H -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1061 CD3 CD3 RG47 H H H LA2301 H H H H RG159 H LA1062 CD3 CD3 RG48 H H H LA2302 H H H H RG160 H LA1063 CD3 CD3 RG49 H H H LA2303 H H H H RG161 H LA1064 CD3 CD3 RG50 H H H LA2304 H H H H RG162 H LA1065 CD3 CD3 RG51 H H H LA2305 H H H H RG163 H LA1066 CD3 CD3 RG52 H H H LA2306 H H H H RG164 H LA1067 CD3 CD3 RG53 H H H LA2307 H H H H RG165 H LA1068 CD3 CD3 RG54 H H H LA2308 H H H H RG166 H LA1069 CD3 CD3 RG55 H H H LA2309 H H H H RG167 H LA1070 CD3 CD3 RG56 H H H LA2310 H H H H RG168 H LA1071 CD3 CD3 RG57 H H H LA2311 H H H H RG169 H LA1072 CD3 CD3 RG58 H H H LA2312 H H H H H RG1 LA1073 CD3 CD3 RG59 H H H LA2313 H H H H H RG2 LA1074 CD3 CD3 RG60 H H H LA2314 H H H H H RG3 LA1075 CD3 CD3 RG61 H H H LA2315 H H H H H RG4 LA1076 CD3 CD3 RG62 H H H LA2316 H H H H H RG5 LA1077 CD3 CD3 RG63 H H H LA2317 H H H H H RG6 LA1078 CD3 CD3 RG64 H H H LA2318 H H H H H RG7 LA1079 CD3 CD3 RG65 H H H LA2319 H H H H H RG8 LA1080 CD3 CD3 RG66 H H H LA2320 H H H H H RG9 LA1081 CD3 CD3 RG67 H H H LA2321 H H H H H RG10 LA1082 CD3 CD3 RG68 H H H LA2322 H H H H H RG11 LA1083 CD3 CD3 RG69 H H H LA2323 H H H H H RG12 LA1084 CD3 CD3 RG70 H H H LA2324 H H H H H RG13 -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1085 CD3 CD3 RG71 H H H LA2325 H H H H H RG14 LA1086 CD3 CD3 RG72 H H H LA2326 H H H H H RG15 LA1087 CD3 CD3 RG73 H H H LA2327 H H H H H RG16 LA1088 CD3 CD3 RG74 H H H LA2328 H H H H H RG17 LA1089 CD3 CD3 RG75 H H H LA2329 H H H H H RG18 LA1090 CD3 CD3 RG76 H H H LA2330 H H H H H RG19 LA1091 CD3 CD3 RG77 H H H LA2331 H H H H H RG20 LA1092 CD3 CD3 RG78 H H H LA2332 H H H H H RG21 LA1093 CD3 CD3 RG79 H H H LA2333 H H H H H RG22 LA1094 CD3 CD3 RG80 H H H LA2334 H H H H H RG23 LA1095 CD3 CD3 RG81 H H H LA2335 H H H H H RG24 LA1096 CD3 CD3 RG82 H H H LA2336 H H H H H RG25 LA1097 CD3 CD3 RG83 H H H LA2337 H H H H H RG26 LA1098 CD3 CD3 RG84 H H H LA2338 H H H H H RG27 LA1099 CD3 CD3 RG85 H H H LA2339 H H H H H RG28 LA1100 CD3 CD3 RG86 H H H LA2340 H H H H H RG29 LA1101 CD3 CD3 RG87 H H H LA2341 H H H H H RG30 LA1102 CD3 CD3 RG88 H H H LA2342 H H H H H RG31 LA1103 CD3 CD3 RG89 H H H LA2343 H H H H H RG32 LA1104 CD3 CD3 RG90 H H H LA2344 H H H H H RG33 LA1105 CD3 CD3 RG91 H H H LA2345 H H H H H RG34 LA1106 CD3 CD3 RG92 H H H LA2346 H H H H H RG35 LA1107 CD3 CD3 RG93 H H H LA2347 H H H H H RG36 LA1108 CD3 CD3 RG94 H H H LA2348 H H H H H RG37 -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1109 CD3 CD3 RG95 H H H LA2349 H H H H H RG38 LA1110 CD3 CD3 RG96 H H H LA2350 H H H H H RG39 LA1111 CD3 CD3 RG97 H H H LA2351 H H H H H RG40 LA1112 CD3 CD3 RG98 H H H LA2352 H H H H H RG41 LA1113 CD3 CD3 RG99 H H H LA2353 H H H H H RG42 LA1114 CD3 CD3 RG100 H H H LA2354 H H H H H RG43 LA1115 CD3 CD3 RG101 H H H LA2355 H H H H H RG44 LA1116 CD3 CD3 RG102 H H H LA2356 H H H H H RG45 LA1117 CD3 CD3 RG103 H H H LA2357 H H H H H RG46 LA1118 CD3 CD3 RG104 H H H LA2358 H H H H H RG47 LA1119 CD3 CD3 RG105 H H H LA2359 H H H H H RG48 LA1120 CD3 CD3 RG106 H H H LA2360 H H H H H RG49 LA1121 CD3 CD3 RG107 H H H LA2361 H H H H H RG50 LA1122 CD3 CD3 RG108 H H H LA2362 H H H H H RG51 LA1123 CD3 CD3 RG109 H H H LA2363 H H H H H RG52 LA1124 CD3 CD3 RG110 H H H LA2364 H H H H H RG53 LA1125 CD3 CD3 RG111 H H H LA2365 H H H H H RG54 LA1126 CD3 CD3 RG112 H H H LA2366 H H H H H RG55 LA1127 CD3 CD3 RG113 H H H LA2367 H H H H H RG56 LA1128 CD3 CD3 RG114 H H H LA2368 H H H H H RG57 LA1129 CD3 CD3 RG115 H H H LA2369 H H H H H RG58 LA1130 CD3 CD3 RG116 H H H LA2370 H H H H H RG59 LA1131 CD3 CD3 RG117 H H H LA2371 H H H H H RG60 LA1132 CD3 CD3 RG118 H H H LA2372 H H H H H RG61 -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1133 CD3 CD3 RG119 H H H LA2373 H H H H H RG62 LA1134 CD3 CD3 RG120 H H H LA2374 H H H H H RG63 LA1135 CD3 CD3 RG121 H H H LA2375 H H H H H RG64 LA1136 CD3 CD3 RG122 H H H LA2376 H H H H H RG65 LA1137 CD3 CD3 RG123 H H H LA2377 H H H H H RG66 LA1138 CD3 CD3 RG124 H H H LA2378 H H H H H RG67 LA1139 CD3 CD3 RG125 H H H LA2379 H H H H H RG68 LA1140 CD3 CD3 RG126 H H H LA2380 H H H H H RG69 LA1141 CD3 CD3 RG127 H H H LA2381 H H H H H RG70 LA1142 CD3 CD3 RG128 H H H LA2382 H H H H H RG71 LA1143 CD3 CD3 RG129 H H H LA2383 H H H H H RG72 LA1144 CD3 CD3 RG130 H H H LA2384 H H H H H RG73 LA1145 CD3 CD3 RG131 H H H LA2385 H H H H H RG74 LA1146 CD3 CD3 RG132 H H H LA2386 H H H H H RG75 LA1147 CD3 CD3 RG133 H H H LA2387 H H H H H RG76 LA1148 CD3 CD3 RG134 H H H LA2388 H H H H H RG77 LA1149 CD3 CD3 RG135 H H H LA2389 H H H H H RG78 LA1150 CD3 CD3 RG136 H H H LA2390 H H H H H RG79 LA1151 CD3 CD3 RG137 H H H LA2391 H H H H H RG80 LA1152 CD3 CD3 RG138 H H H LA2392 H H H H H RG81 LA1153 CD3 CD3 RG139 H H H LA2393 H H H H H RG82 LA1154 CD3 CD3 RG140 H H H LA2394 H H H H H RG83 LA1155 CD3 CD3 RG141 H H H LA2395 H H H H H RG84 LA1156 CD3 CD3 RG142 H H H LA2396 H H H H H RG85 -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1157 CD3 CD3 RG143 H H H LA2397 H H H H H RG86 LA1158 CD3 CD3 RG144 H H H LA2398 H H H H H RG87 LA1159 CD3 CD3 RG145 H H H LA2399 H H H H H RG88 LA1160 CD3 CD3 RG146 H H H LA2400 H H H H H RG89 LA1161 CD3 CD3 RG147 H H H LA2401 H H H H H RG90 LA1162 CD3 CD3 RG148 H H H LA2402 H H H H H RG91 LA1163 CD3 CD3 RG149 H H H LA2403 H H H H H RG92 LA1164 CD3 CD3 RG150 H H H LA2404 H H H H H RG93 LA1165 CD3 CD3 RG151 H H H LA2405 H H H H H RG94 LA1166 CD3 CD3 RG152 H H H LA2406 H H H H H RG95 LA1167 CD3 CD3 RG153 H H H LA2407 H H H H H RG96 LA1168 CD3 CD3 RG154 H H H LA2408 H H H H H RG97 LA1169 CD3 CD3 RG155 H H H LA2409 H H H H H RG98 LA1170 CD3 CD3 RG156 H H H LA2410 H H H H H RG99 LA1171 CD3 CD3 RG157 H H H LA2411 H H H H H RG100 LA1172 CD3 CD3 RG158 H H H LA2412 H H H H H RG101 LA1173 CD3 CD3 RG159 H H H LA2413 H H H H H RG102 LA1174 CD3 CD3 RG160 H H H LA2414 H H H H H RG103 LA1175 CD3 CD3 RG161 H H H LA2415 H H H H H RG104 LA1176 CD3 CD3 RG162 H H H LA2416 H H H H H RG105 LA1177 CD3 CD3 RG163 H H H LA2417 H H H H H RG106 LA1178 CD3 CD3 RG164 H H H LA2418 H H H H H RG107 LA1179 CD3 CD3 RG165 H H H LA2419 H H H H H RG108 LA1180 CD3 CD3 RG166 H H H LA2420 H H H H H RG109 -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1181 CD3 CD3 RG167 H H H LA2421 H H H H H RG110 LA1182 CD3 CD3 RG168 H H H LA2422 H H H H H RG111 LA1183 CD3 CD3 RG169 H H H LA2423 H H H H H RG112 LA1184 CD3 H RG1 H H H LA2424 H H H H H RG113 LA1185 CD3 H RG2 H H H LA2425 H H H H H RG114 LA1186 CD3 H RG3 H H H LA2426 H H H H H RG115 LA1187 CD3 H RG4 H H H LA2427 H H H H H RG116 LA1188 CD3 H RG5 H H H LA2428 H H H H H RG117 LA1189 CD3 H RG6 H H H LA2429 H H H H H RG118 LA1190 CD3 H RG7 H H H LA2430 H H H H H RG119 LA1191 CD3 H RG8 H H H LA2431 H H H H H RG120 LA1192 CD3 H RG9 H H H LA2432 H H H H H RG121 LA1193 CD3 H RG10 H H H LA2433 H H H H H RG122 LA1194 CD3 H RG11 H H H LA2434 H H H H H RG123 LA1195 CD3 H RG12 H H H LA2435 H H H H H RG124 LA1196 CD3 H RG13 H H H LA2436 H H H H H RG125 LA1197 CD3 H RG14 H H H LA2437 H H H H H RG126 LA1198 CD3 H RG15 H H H LA2438 H H H H H RG127 LA1199 CD3 H RG16 H H H LA2439 H H H H H RG128 LA1200 CD3 H RG17 H H H LA2440 H H H H H RG129 LA1201 CD3 H RG18 H H H LA2441 H H H H H RG130 LA1202 CD3 H RG19 H H H LA2442 H H H H H RG131 LA1203 CD3 H RG20 H H H LA2443 H H H H H RG132 LA1204 CD3 H RG21 H H H LA2444 H H H H H RG133 -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1205 CD3 H RG22 H H H LA2445 H H H H H RG134 LA1206 CD3 H RG23 H H H LA2446 H H H H H RG135 LA1207 CD3 H RG24 H H H LA2447 H H H H H RG136 LA1208 CD3 H RG25 H H H LA2448 H H H H H RG137 LA1209 CD3 H RG26 H H H LA2449 H H H H H RG138 LA1210 CD3 H RG27 H H H LA2450 H H H H H RG139 LA1211 CD3 H RG28 H H H LA2451 H H H H H RG140 LA1212 CD3 H RG29 H H H LA2452 H H H H H RG141 LA1213 CD3 H RG30 H H H LA2453 H H H H H RG142 LA1214 CD3 H RG31 H H H LA2454 H H H H H RG143 LA1215 CD3 H RG32 H H H LA2455 H H H H H RG144 LA1216 CD3 H RG33 H H H LA2456 H H H H H RG145 LA1217 CD3 H RG34 H H H LA2457 H H H H H RG146 LA1218 CD3 H RG35 H H H LA2458 H H H H H RG147 LA1219 CD3 H RG36 H H H LA2459 H H H H H RG148 LA1220 CD3 H RG37 H H H LA2460 H H H H H RG149 LA1221 CD3 H RG38 H H H LA2461 H H H H H RG150 LA1222 CD3 H RG39 H H H LA2462 H H H H H RG151 LA1223 CD3 H RG40 H H H LA2463 H H H H H RG152 LA1224 CD3 H RG41 H H H LA2464 H H H H H RG153 LA1225 CD3 H RG42 H H H LA2465 H H H H H RG154 LA1226 CD3 H RG43 H H H LA2456 H H H H H RG155 LA1227 CD3 H RG44 H H H LA2467 H H H H H RG156 LA1228 CD3 H RG45 H H H LA2456 H H H H H RG157 -
Ligand RA1 RA2 RA3 RA4 RA5 RA6 Ligand RA1 RA2 RA3 RA4 RA5 RA6 LA1229 CD3 H RG46 H H H LA2469 H H H H H RG158 LA1230 CD3 H RG47 H H H LA2470 H H H H H RG159 LA1231 CD3 H RG48 H H H LA2471 H H H H H RG160 LA1232 CD3 H RG49 H H H LA2472 H H H H H RG161 LA1233 CD3 H RG50 H H H LA2473 H H H H H RG162 LA1234 CD3 H RG51 H H H LA2474 H H H H H RG163 LA1235 CD3 H RG52 H H H LA2475 H H H H H RG164 LA1236 CD3 H RG53 H H H LA2476 H H H H H RG165 LA1237 CD3 H RG54 H H H LA2477 H H H H H RG166 LA1238 CD3 H RG55 H H H LA2478 H H H H H RG167 LA1239 CD3 H RG56 H H H LA2479 H H H H H RG168 LA1240 CD3 H RG57 H H H LA2480 H H H H H RG169 - wherein RG1 to RG169 have the following structures:
- In some embodiments where L1 is LA, the compound is Compound x selected from the group consisting of Compound 1 through Compound 2120400, where:
- Compound x has the formula Ir(LAi)(LBj)2, where
- x = 2480j + i – 2480,
- i is an integer from 1 to 2480,
- j is an integer from 1 to 855; and
- LBj is listed in the following table based on the following structure:
-
-
LBj, where j is RB1 RB2 RB3 RB4 1. H H H H 2. CH3 H H H 3. H CH3 H H 4. H H CH3 H 5. H H H CH3 6. CH3 H CH3 H 7. CH3 H H CH3 8. H CH3 CH3 H 9. H CH3 H CH3 10. H H CH3 CH3 11. CH3 CH3 CH3 H 12. CH3 CH3 H CH3 13. CH3 H CH3 CH3 14. H CH3 CH3 CH3 15. CH3 CH3 CH3 CH3 16. CH2CH3 H H H 17. CH2CH3 CH3 H H 18. CH2CH3 H CH3 H 19. CH2CH3 H H CH3 20. CH2CH3 CH3 CH3 H 21. CH2CH3 CH3 H CH3 22. CH2CH3 H CH3 CH3 23. CH2CH3 CH3 CH3 CH3 24. H CH2CH3 H H 25. CH3 CH2CH3 H H 26. H CH2CH3 CH3 H 27. H CH2CH3 H CH3 28. CH3 CH2CH3 CH3 H 29. CH3 CH2CH3 H CH3 30. H CH2CH3 CH3 CH3 31. CH3 CH2CH3 CH3 CH3 32. H H CH2CH3 H 33. CH3 H CH2CH3 H 34. H CH3 CH2CH3 H 35. H H CH2CH3 CH3 36. CH3 CH3 CH2CH3 H 37. CH3 H CH2CH3 CH3 38. H CH3 CH2CH3 CH3 39. CH3 CH3 CH2CH3 CH3 40. CH(CH3)2 H H H 41. CH(CH3)2 CH3 H H 42. CH(CH3)2 H CH3 H 43. CH(CH3)2 H H CH3 44. CH(CH3)2 CH3 CH3 H 45. CH(CH3)2 CH3 H CH3 46. CH(CH3)2 H CH3 CH3 47. CH(CH3)2 CH3 CH3 CH3 48. H CH(CH3)2 H H 49. CH3 CH(CH3)2 H H 50. H CH(CH3)2 CH3 H 51. H CH(CH3)2 H CH3 52. CH3 CH(CH3)2 CH3 H 53. CH3 CH(CH3)2 H CH3 54. H CH(CH3)2 CH3 CH3 55. CH3 CH(CH3)2 CH3 CH3 56. H H CH(CH3)2 H 57. CH3 H CH(CH3)2 H 58. H CH3 CH(CH3)2 H 59. H H CH(CH3)2 CH3 60. CH3 CH3 CH(CH3)2 H 61. CH3 H CH(CH3)2 CH3 62. H CH3 CH(CH3)2 CH3 63. CH3 CH3 CH(CH3)2 CH3 64. CH2CH(CH3)2 H H H 65. CH2CH(CH3)2 CH3 H H 66. CH2CH(CH3)2 H CH3 H 67. CH2CH(CH3)2 H H CH3 68. CH2CH(CH3)2 CH3 CH3 H 69. CH2CH(CH3)2 CH3 H CH3 70. CH2CH(CH3)2 H CH3 CH3 71. CH2CH(CH3)2 CH3 CH3 CH3 72. H CH2CH(CH3)2 H H 73. CH3 CH2CH(CH3)2 H H 74. H CH2CH(CH3)2 CH3 H 75. H CH2CH(CH3)2 H CH3 76. CH3 CH2CH(CH3)2 CH3 H 77. CH3 CH2CH(CH3)2 H CH3 78. H CH2CH(CH3)2 CH3 CH3 79. CH3 CH2CH(CH3)2 CH3 CH3 80. H H CH2CH(CH3)2 H 81. CH3 H CH2CH(CH3)2 H 82. H CH3 CH2CH(CH3)2 H 83. H H CH2CH(CH3)2 CH3 84. CH3 CH3 CH2CH(CH3)2 H 85. CH3 H CH2CH(CH3)2 CH3 86. H CH3 CH2CH(CH3)2 CH3 87. CH3 CH3 CH2CH(CH3)2 CH3 88. C(CH3)3 H H H 89. C(CH3)3 CH3 H H 90. C(CH3)3 H CH3 H 91. C(CH3)3 H H CH3 92. C(CH3)3 CH3 CH3 H 93. C(CH3)3 CH3 H CH3 94. C(CH3)3 H CH3 CH3 95. C(CH3)3 CH3 CH3 CH3 96. H C(CH3)3 H H 97. CH3 C(CH3)3 H H 98. H C(CH3)3 CH3 H 99. H C(CH3)3 H CH3 100. CH3 C(CH3)3 CH3 H 101. CH3 C(CH3)3 H CH3 102. H C(CH3)3 CH3 CH3 103. CH3 C(CH3)3 CH3 CH3 104. H H C(CH3)3 H 105. CH3 H C(CH3)3 H 106. H CH3 C(CH3)3 H 107. H H C(CH3)3 CH3 108. CH3 CH3 C(CH3)3 H 109. CH3 H C(CH3)3 CH3 110. H CH3 C(CH3)3 CH3 111. CH3 CH3 C(CH3)3 CH3 112. CH2C(CH3)3 H H H 113. CH2C(CH3)3 CH3 H H 114. CH2C(CH3)3 H CH3 H 115. CH2C(CH3)3 H H CH3 116. CH2C(CH3)3 CH3 CH3 H 117. CH2C(CH3)3 CH3 H CH3 118. CH2C(CH3)3 H CH3 CH3 119. CH2C(CH3)3 CH3 CH3 CH3 120. H CH2C(CH3)3 H H 121. CH3 CH2C(CH3)3 H H 122. H CH2C(CH3)3 CH3 H 123. H CH2C(CH3)3 H CH3 124. CH3 CH2C(CH3)3 CH3 H 125. CH3 CH2C(CH3)3 H CH3 126. H CH2C(CH3)3 CH3 CH3 127. CH3 CH2C(CH3)3 CH3 CH3 128. H H CH2C(CH3)3 H 129. CH3 H CH2C(CH3)3 H 130. H CH3 CH2C(CH3)3 H 131. H H CH2C(CH3)3 CH3 132. CH3 CH3 CH2C(CH3)3 H 133. CH3 H CH2C(CH3)3 CH3 134. H CH3 CH2C(CH3)3 CH3 135. CH3 CH3 CH2C(CH3)3 CH3 136. CH2C(CH3)2CF3 H H H 137. CH2C(CH3)2CF3 CH3 H H 138. CH2C(CH3)2CF3 H CH3 H 139. CH2C(CH3)2CF3 H H CH3 140. CH2C(CH3)2CF3 CH3 CH3 H 141. CH2C(CH3)2CF3 CH3 H CH3 142. CH2C(CH3)2CF3 H CH3 CH3 143. CH2C(CH3)2CF3 CH3 CH3 CH3 144. H CH2C(CH3)2CF3 H H 145. CH3 CH2C(CH3)2CF3 H H 146. H CH2C(CH3)2CF3 CH3 H 147. H CH2C(CH3)2CF3 H CH3 148. CH3 CH2C(CH3)2CF3 CH3 H 149. CH3 CH2C(CH3)2CF3 H CH3 150. H CH2C(CH3)2CF3 CH3 CH3 151. CH3 CH2C(CH3)2CF3 CH3 CH3 152. H H CH2C(CH3)2CF3 H 153. CH3 H CH2C(CH3)2CF3 H 154. H CH3 CH2C(CH3)2CF3 H 155. H H CH2C(CH3)2CF3 CH3 156. CH3 CH3 CH2C(CH3)2CF3 H 157. CH3 H CH2C(CH3)2CF3 CH3 158. H CH3 CH2C(CH3)2CF3 CH3 159. CH3 CH3 CH2C(CH3)2CF3 CH3 160. CH2CH2CF3 H H H 161. CH2CH2CF3 CH3 H H 162. CH2CH2CF3 H CH3 H 163. CH2CH2CF3 H H CH3 164. CH2CH2CF3 CH3 CH3 H 165. CH2CH2CF3 CH3 H CH3 166. CH2CH2CF3 H CH3 CH3 167. CH2CH2CF3 CH3 CH3 CH3 168. H CH2CH2CF3 H H 169. CH3 CH2CH2CF3 H H 170. H CH2CH2CF3 CH3 H 171. H CH2CH2CF3 H CH3 172. CH3 CH2CH2CF3 CH3 H 173. CH3 CH2CH2CF3 H CH3 174. H CH2CH2CF3 CH3 CH3 175. CH3 CH2CH2CF3 CH3 CH3 176. H H CH2CH2CF3 H 177. CH3 H CH2CH2CF3 H 178. H CH3 CH2CH2CF3 H 179. H H CH2CH2CF3 CH3 180. CH3 CH3 CH2CH2CF3 H 181. CH3 H CH2CH2CF3 CH3 182. H CH3 CH2CH2CF3 CH3 183. CH3 CH3 CH2CH2CF3 CH3 184. H H H 185. CH3 H H 186. H CH3 H 187. H H CH3 188. CH3 CH3 H 189. CH3 H CH3 190. H CH3 CH3 191. CH3 CH3 CH3 192. H H H 193. CH3 H H 194. H CH3 H 195. H H CH3 196. CH3 CH3 H 197. CH3 H CH3 198. H CH3 CH3 199. CH3 CH3 CH3 200. H H H 201. CH3 H H 202. H CH3 H 203. H H CH3 204. CH3 CH3 H 205. CH3 H CH3 206. H CH3 CH3 207. CH3 CH3 CH3 208. H H H 209. CH3 H H 210. H CH3 H 211. H H CH3 212. CH3 CH3 H 213. CH3 H CH3 214. H CH3 CH3 215. CH3 CH3 CH3 216. H H H 217. CH3 H H 218. H CH3 H 219. H H CH 3 220. CH3 CH3 H 221. CH3 H CH3 222. H CH3 CH3 223. CH3 CH3 CH3 224. H H H 225. CH3 H H 226. H CH3 H 227. H H CH3 228. CH3 CH3 H 229. CH3 H CH 3230. H CH3 CH3 231. CH3 CH3 CH3 232. H H H 233. CH3 H H 234. H CH3 H 235. H H CH3 236. CH3 CH3 H 237. CH3 H CH3 238. H CH3 CH3 239. CH3 CH3 CH3 240. H H H 241. CH3 H H 242. H CH3 H 243. H H CH3 244. CH3 CH3 H 245. CH3 H CH3 246. H CH3 CH3 247. CH3 CH3 CH3 248. H H H 249. CH3 H H 250. H CH3 H 251. H H CH3 252. CH3 CH3 H 253. CH3 H CH3 254. H CH3 CH3 255. CH3 CH3 CH3 256. H H H 257. CH3 H H 258. H CH3 H 259. H H CH3 260. CH3 CH3 H 261. CH3 H CH3 262. H CH3 CH3 263. CH3 CH3 CH3 264. H H H 265. CH3 H H 266. H CH3 H 267. H H CH3 268. CH3 CH3 H 269. CH3 H CH3 270. H CH3 CH3 271. CH3 CH3 CH3 272. H H H 273. CH3 H H 274. H CH3 H 275. H H CH3 276. CH3 CH3 H 277. CH3 H CH3 278. H CH3 CH3 279. CH3 CH3 CH3 280. H H H 281. CH3 H H 282. H CH3 H 283. H H CH3 284. CH3 CH3 H 285. CH3 H CH3 286. H CH3 CH3 287. CH3 CH3 CH3 288. H H H 289. CH3 H H 290. H CH3 H 291. H H CH3 292. CH3 CH3 H 293. CH3 H CH3 294. H CH3 CH3 295. CH3 CH3 CH3 296. H H H 297. CH3 H H 298. H CH3 H 299. H H CH3 300. CH3 CH3 H 301. CH3 H CH3 302. H CH3 CH3 303. CH3 CH3 CH3 304. H H H 305. CH3 H H 306. H CH3 H 307. H H CH3 308. CH3 CH3 H 309. CH3 H CH3 310. H CH3 CH3 311. CH3 CH3 CH3 312. H H H 313. CH3 H H 314. H CH3 H 315. H H CH3 316. CH3 CH3 H 317. CH3 H CH3 318. H CH3 CH3 319. CH3 CH3 CH3 320. H H H 321. CH3 H H 322. H CH3 H 323. H H CH3 324. CH3 CH3 H 325. CH3 H CH3 326. H CH3 CH3 327. CH3 CH3 CH3 328. CH(CH3)2 H CH2CH3 H 329. CH(CH3)2 H CH(CH3)2 H 330. CH(CH3)2 H CH2CH(CH3)2 H 331. CH(CH3)2 H C(CH3)3 H 332. CH(CH3)2 H CH2C(CH3)3 H 333. CH(CH3)2 H CH2CH2CF3 H 334. CH(CH3)2 H CH2C(CH3)2CF3 H 335. CH(CH3)2 H H 336. CH(CH3)2 H H 337. CH(CH3)2 H H 338. CH(CH3)2 H H 339. CH(CH3)2 H H 340. CH(CH3)2 H H 341. C(CH3)3 H CH2CH3 H 342. C(CH3)3 H CH(CH3)2 H 343. C(CH3)3 H CH2CH(CH3)2 H 344. C(CH3)3 H C(CH3)3 H 345. C(CH3)3 H CH2C(CH3)3 H 346. C(CH3)3 H CH2CH2CF3 H 347. C(CH3)3 H CH2C(CH3)2CF3 H 348. C(CH3)3 H H 349. C(CH3)3 H H 350. C(CH3)3 H H 351. C(CH3)3 H H 352. C(CH3)3 H H 353. C(CH3)3 H H 354. CH2C(CH3)3 H CH2CH3 H 355. CH2C(CH3)3 H CH(CH3)2 H 356. CH2C(CH3)3 H CH2CH(CH3)2 H 357. CH2C(CH3)3 H C(CH3)3 H 358. CH2C(CH3)3 H CH2C(CH3)3 H 359. CH2C(CH3)3 H CH2CH2CF3 H 360. CH2C(CH3)3 H CH2C(CH3)2CF3 H 361. CH2C(CH3)3 H H 362. CH2C(CH3)3 H H 363. CH2C(CH3)3 H H 364. CH2C(CH3)3 H H 365. CH2C(CH3)3 H H 366. CH2C(CH3)3 H H 367. H CH2CH3 H 368. H CH(CH3)2 H 369. H CH2CH(CH3)2 H 370. H C(CH3)3 H 371. H CH2C(CH3)3 H 372. H CH2CH2CF3 H 373. H CH2C(CH3)2CF3 H 374. H H 375. H H 376. H H 377. H H 378. H H 379. H H 380. H CH2CH3 H 381. H CH(CH3)2 H 382. H CH2CH(CH3)2 H 383. H C(CH3)3 H 384. H CH2C(CH3)3 H 385. H CH2CH2CF3 H 386. H CH2C(CH3)2CF3 H 387. H H 388. H H 389. H H 390. H H 391. H H 392. H H 393. H CH2CH(CH3)2 H 394. H C(CH3)3 H 395. H CH2C(CH3)3 H 396. H CH2CH2CF3 H 397. H CH2C(CH3)2CF3 H 398. H H 399. H H 400. H H 401. H H 402. H H 403. H H 404. H CH2CH(CH3)2 H 405. H C(CH3)3 H 406. H CH2C(CH3)3 H 407. H CH2CH2CF3 H 408. H CH2C(CH3)2CF3 H 409. H H 410. H H 411. H H 412. H H 413. H H 414. H H 415. H CH2CH(CH3)2 H 416. H C(CH3)3 H 417. H CH2C(CH3)3 H 418. H CH2CH2CF3 H 419. H CH2C(CH3)2CF3 H 420. H H 421. H H 422. H H 423. H H 424. H H 425. H H 426. CD3 H H H 427. H CD3 H H 428. H H CD3 H 429. H H H CD3 430. CD3 H CD3 H 431. CD3 H H CD3 432. H CD3 CD3 H 433. H CD3 H CD3 434. H H CD3 CD3 435. CD3 CD3 CD3 H 436. CD3 CD3 H CD3 437. CD3 H CD3 CD3 438. H CD3 CD3 CD3 439. CD3 CD3 CD3 CD3 440. CD2CH3 H H H 441. CD2CH3 CD3 H H 442. CD2CH3 H CD3 H 443. CD2CH3 H H CD3 444. CD2CH3 CD3 CD3 H 445. CD2CH3 CD3 H CD3 446. CD2CH3 H CD3 CD3 447. CD2CH3 CD3 CD3 CD3 448. H CD2CH3 H H 449. CD3 CD2CH3 H H 450. H CD2CH3 CD3 H 451. H CD2CH3 H CD3 452. CD3 CD2CH3 CD3 H 453. CD3 CD2CH3 H CD3 454. H CD2CH3 CD3 CD3 455. CD3 CD2CH3 CD3 CD3 456. H H CD2CH3 H 457. CD3 H CD2CH3 H 458. H CD3 CD2CH3 H 459. H H CD2CH3 CD3 460. CD3 CD3 CD2CH3 H 461. CD3 H CD2CH3 CD3 462. H CD3 CD2CH3 CD3 463. CD3 CD3 CD2CH3 CD3 464. CD(CH3)2 H H H 465. CD(CH3)2 CD3 H H 466. CD(CH3)2 H CD3 H 467. CD(CH3)2 H H CD3 468. CD(CH3)2 CD3 CD3 H 469. CD(CH3)2 CD3 H CD3 470. CD(CH3)2 H CD3 CD3 471. CD(CH3)2 CD3 CD3 CD3 472. H CD(CH3)2 H H 473. CD3 CD(CH3)2 H H 474. H CD(CH3)2 CD3 H 475. H CD(CH3)2 H CD3 476. CD3 CD(CH3)2 CD3 H 477. CD3 CD(CH3)2 H CD3 478. H CD(CH3)2 CD3 CD3 479. CD3 CD(CH3)2 CD3 CD3 480. H H CD(CH3)2 H 481. CD3 H CD(CH3)2 H 482. H CD3 CD(CH3)2 H 483. H H CD(CH3)2 CD3 484. CD3 CD3 CD(CH3)2 H 485. CD3 H CD(CH3)2 CD3 486. H CD3 CD(CH3)2 CD3 487. CD3 CD3 CD(CH3)2 CD3 488. CD(CD3)2 H H H 489. CD(CD3)2 CD3 H H 490. CD(CD3)2 H CD3 H 491. CD(CD3)2 H H CD3 492. CD(CD3)2 CD3 CD3 H 493. CD(CD3)2 CD3 H CD3 494. CD(CD3)2 H CD3 CD3 495. CD(CD3)2 CD3 CD3 CD3 496. H CD(CD3)2 H H 497. CD3 CD(CD3)2 H H 498. H CD(CD3)2 CD3 H 499. H CD(CD3)2 H CD3 500. CD3 CD(CD3)2 CD3 H 501. CD3 CD(CD3)2 H CD3 502. H CD(CD3)2 CD3 CD3 503. CD3 CD(CD3)2 CD3 CD3 504. H H CD(CD3)2 H 505. CD3 H CD(CD3)2 H 506. H CD3 CD(CD3)2 H 507. H H CD(CD3)2 CD3 508. CD3 CD3 CD(CD3)2 H 509. CD3 H CD(CD3)2 CD3 510. H CD3 CD(CD3)2 CD3 511. CD3 CD3 CD(CD3)2 CD3 512. CD2CH(CH3)2 H H H 513. CD2CH(CH3)2 CD3 H H 514. CD2CH(CH3)2 H CD3 H 515. CD2CH(CH3)2 H H CD3 516. CD2CH(CH3)2 CD3 CD3 H 517. CD2CH(CH3)2 CD3 H CD3 518. CD2CH(CH3)2 H CD3 CD3 519. CD2CH(CH3)2 CD3 CD3 CD3 520. H CD2CH(CH3)2 H H 521. CD3 CD2CH(CH3)2 H H 522. H CD2CH(CH3)2 CD3 H 523. H CD2CH(CH3)2 H CD3 524. CD3 CD2CH(CH3)2 CD3 H 525. CD3 CD2CH(CH3)2 H CD3 526. H CD2CH(CH3)2 CD3 CD3 527. CD3 CD2CH(CH3)2 CD3 CD3 528. H H CD2CH(CH3)2 H 529. CD3 H CD2CH(CH3)2 H 530. H CD3 CD2CH(CH3)2 H 531. H H CD2CH(CH3)2 CD3 532. CD3 CD3 CD2CH(CH3)2 H 533. CD3 H CD2CH(CH3)2 CD3 534. H CD3 CD2CH(CH3)2 CD3 535. CD3 CD3 CD2CH(CH3)2 CD3 536. CD2C(CH3)3 H H H 537. CD2C(CH3)3 CD3 H H 538. CD2C(CH3)3 H CD3 H 539. CD2C(CH3)3 H H CD3 540. CD2C(CH3)3 CD3 CD3 H 541. CD2C(CH3)3 CD3 H CD3 542. CD2C(CH3)3 H CD3 CD3 543. CD2C(CH3)3 CH3 CD3 CD3 544. H CD2C(CH3)3 H H 545. CD3 CD2C(CH3)3 H H 546. H CD2C(CH3)3 CD3 H 547. H CD2C(CH3)3 H CD3 548. CD3 CD2C(CH3)3 CD3 H 549. CD3 CD2C(CH3)3 H CD3 550. H CD2C(CH3)3 CD3 CD3 551. CD3 CD2C(CH3)3 CD3 CD3 552. H H CD2C(CH3)3 H 553. CD3 H CD2C(CH3)3 H 554. H CD3 CD2C(CH3)3 H 555. H H CD2C(CH3)3 CD3 556. CD3 CD3 CD2C(CH3)3 H 557. CD3 H CD2C(CH3)3 CD3 558. H CD3 CD2C(CH3)3 CD3 559. CD3 CD3 CD2C(CH3)3 CD3 560. CD2C(CH3)2CF3 H H H 561. CD2C(CH3)2CF3 CD3 H H 562. CD2C(CH3)2CF3 H CD3 H 563. CD2C(CH3)2CF3 H H CD3 564. CD2C(CH3)2CF3 CD3 CD3 H 565. CD2C(CH3)2CF3 CD3 H CD3 566. CD2C(CH3)2CF3 H CD3 CD3 567. CD2C(CH3)2CF3 CD3 CD3 CD3 568. H CD2C(CH3)2CF3 H H 569. CD3 CD2C(CH3)2CF3 H H 570. H CD2C(CH3)2CF3 CD3 H 571. H CD2C(CH3)2CF3 H CD3 572. CD3 CD2C(CH3)2CF3 CD3 H 573. CD3 CD2C(CH3)2CF3 H CD3 574. H CD2C(CH3)2CF3 CD3 CD3 575. CD3 CD2C(CH3)2CF3 CD3 CD3 576. H H CD2C(CH3)2CF3 H 577. CD3 H CD2C(CH3)2CF3 H 578. H CD3 CD2C(CH3)2CF3 H 579. H H CD2C(CH3)2CF3 CD3 580. CD3 CD3 CD2C(CH3)2CF3 H 581. CD3 H CD2C(CH3)2CF3 CD3 582. H CD3 CD2C(CH3)2CF3 CD3 583. CD3 CD3 CD2C(CH3)2CF3 CD3 584. CD2CH2CF3 H H H 585. CD2CH2CF3 CD3 H H 586. CD2CH2CF3 H CD3 H 587. CD2CH2CF3 H H CD3 588. CD2CH2CF3 CD3 CD3 H 589. CD2CH2CF3 CD3 H CD3 590. CD2CH2CF3 H CD3 CD3 591. CD2CH2CF3 CD3 CD3 CD3 592. H CD2CH2CF3 H H 593. CD3 CD2CH2CF3 H H 594. H CD2CH2CF3 CD3 H 595. H CD2CH2CF3 H CD3 596. CD3 CD2CH2CF3 CD3 H 597. CD3 CD2CH2CF3 H CD3 598. H CD2CH2CF3 CD3 CD3 599. CD3 CD2CH2CF3 CD3 CD3 600. H H CD2CH2CF3 H 601. CD3 H CD2CH2CF3 H 602. H CD3 CD2CH2CF3 H 603. H H CD2CH2CF3 CD3 604. CD3 CD3 CD2CH2CF3 H 605. CD3 H CD2CH2CF3 CD3 606. H CD3 CD2CH2CF3 CD3 607. CD3 CD3 CD2CH2CF3 CD3 608. H H H 609. CD3 H H 610. H CD3 H 611. H H CD3 612. CD3 CD3 H 613. CD3 H CD3 614. H CD3 CD3 615. CD3 CD3 CD3 616. H H H 617. CD3 H H 618. H CD3 H 619. H H CD3 620. CD3 CD3 H 621. CD3 H CD3 622. H CD3 CD3 623. CD3 CD3 CD3 624. H H H 625. CD3 H H 626. H CD3 H 627. H H CD3 628. CD3 CD3 H 629. CD3 H CD3 630. H CD3 CD3 631. CD3 CD3 CD3 632. H H H 633. CD3 H H 634. H CD3 H 635. H H CD3 636. CD3 CD3 H 637. CD3 H CD3 638. H CD3 CD3 639. CD3 CD3 CD3 640. H H H 641. CD3 H H 642. H CD3 H 643. H H CD3 644. CD3 CD3 H 645. CD3 H CD3 646. H CD3 CD3 647. CH3 CD3 CD3 648. H H H 649. CD3 H H 650. H CD3 H 651. H H CD3 652. CD3 CD3 H 653. CD3 H CD3 654. H CD3 CD3 655. CD3 CD3 CD3 656. H H H 657. CD3 H H 658. H CD3 H 659. H H CD3 660. CD3 CD3 H 661. CD3 H CD3 662. H CD3 CD3 663. CD3 CD3 CD3 664. H H H 665. CD3 H H 666. H CD3 H 667. H H CD3 668. CD3 CD3 H 669. CD3 H CD3 670. H CD3 CD3 671. CD3 CD3 CD3 672. H H H 673. CD3 H H 674. H CD3 H 675. H H CD3 676. CD3 CD3 H 677. CD3 H CD3 678. H CD3 CD3 679. CD3 CD3 CD3 680. H H H 681. CD3 H H 682. H CD3 H 683. H H CD3 684. CD3 CD3 H 685. CD3 H CD3 686. H CD3 CD3 687. CD3 CD3 CD3 688. H H H 689. CD3 H H 690. H CD3 H 691. H H CD3 692. CD3 CD3 H 693. CD3 H CD3 694. H CD3 CD3 695. CD3 CD3 CD3 696. H H H 697. CD3 H H 698. H CD3 H 699. H H CD3 700. CD3 CD3 H 701. CD3 H CD3 702. H CD3 CD3 703. CD3 CD3 CD3 704. H H H 705. CD3 H H 706. H CD3 H 707. H H CD3 708. CD3 CD3 H 709. CD3 H CD3 710. H CD3 CD3 711. CD3 CD3 CD3 712. H H H 713. CD3 H H 714. H CD3 H 715. H H CD3 716. CD3 CD3 H 717. CD3 H CD3 718. H CD3 CD3 719. CD3 CD3 CD3 720. H H H 721. CD3 H H 722. H CD3 H 723. H H CD3 724. CD3 CD3 H 725. CD3 H CD3 726. H CD3 CD3 727. CD3 CD3 CD3 728. H H H 729. CD3 H H 730. H CD3 H 731. H H CD3 732. CH3 CH3 H 733. CD3 H CD3 734. H CD3 CD3 735. CD3 CD3 CD3 736. H H H 737. CD3 H H 738. H CD3 H 739. H H CD3 740. CD3 CD3 H 741. CD3 H CD3 742. H CD3 CD3 743. CD3 CD3 CD3 744. H H H 745. CD3 H H 746. H CD3 H 747. H H CD3 748. CD3 CD3 H 749. CD3 H CD3 750. H CD3 CD3 751. CD3 CD3 CD3 752. CD(CH3)2 H CD2CH3 H 753. CD(CH3)2 H CD(CH3)2 H 754. CD(CH3)2 H CD2CH(CH3)2 H 755. CD(CH3)2 H C(CH3)3 H 756. CD(CH3)2 H CD2C(CH3)3 H 757. CD(CH3)2 H CD2CH2CF3 H 758. CD(CH3)2 H CD2C(CH3)2CF3 H 759. CD(CH3)2 H H 760. CD(CH3)2 H H 761. CD(CH3)2 H H 762. CD(CH3)2 H H 763. CD(CH3)2 H H 764. CD(CH3)2 H H 765. C(CH3)3 H CD2CH3 H 766. C(CH3)3 H CD(CH3)2 H 767. C(CH3)3 H CD2CH(CH3)2 H 768. C(CH3)3 H C(CH3)3 H 769. C(CH3)3 H CD2C(CH3)3 H 770. C(CH3)3 H CD2CH2CF3 H 771. C(CH3)3 H CD2C(CH3)2CF3 H 772. C(CH3)3 H H 773. C(CH3)3 H H 774. C(CH3)3 H H 775. C(CH3)3 H H 776. C(CH3)3 H H 777. C(CH3)3 H H 778. CD2C(CH3)3 H CD2CH3 H 779. CD2C(CH3)3 H CD(CH3)2 H 780. CD2C(CH3)3 H CD2CH(CH3)2 H 781. CD2C(CH3)3 H C(CH3)3 H 782. CD2C(CH3)3 H CD2C(CH3)3 H 783. CD2C(CH3)3 H CD2CH2CF3 H 784. CD2C(CH3)3 H CD2C(CH3)2CF3 H 785. CD2C(CH3)3 H H 786. CD2C(CH3)3 H H 787. CD2C(CH3)3 H H 788. CD2C(CH3)3 H H 789. CD2C(CH3)3 H H 790. CD2C(CH3)3 H H 791. H CD2CH3 H 792. H CD(CH3)2 H 793. H CD2CH(CH3)2 H 794. H C(CH3)3 H 795. H CD2C(CH3)3 H 796. H CD2CH2CF3 H 797. H CD2C(CH3)2CF3 H 798. H H 799. H H 800. H H 801. H H 802. H H 803. H H 804. H CD2CH3 H 805. H CD(CH3)2 H 806. H CD2CH(CH3)2 H 807. H C(CH3)3 H 808. H CD2C(CH3)3 H 809. H CD2CH2CF3 H 810. H CD2C(CH3)2CF3 H 811. H H 812. H H 813. H H 814. H H 815. H H 816. H H 817. H CD2CH3 H 818. H CD(CH3)2 H 819. H CD2CH(CH3)2 H 820. H C(CH3)3 H 821. H CD2C(CH3)3 H 822. H CD2CH2CF3 H 823. H CD2C(CH3)2CF3 H 824. H H 825. H H 826. H H 827. H H 828. H H 829. H H 830. H CD2CH3 H 831. H CD(CH3)2 H 832. H CD2CH(CH3)2 H 833. H C(CH3)3 H 834. H CD2C(CH3)3 H 835. H CD2CH2CF3 H 836. H CD2C(CH3)2CF3 H 837. H H 838. H H 839. H H 840. H H 841. H H 842. H H 843. H CD2CH3 H 844. H CD(CH3)2 H 845. H CD2CH(CH3)2 H 846. H C(CH3)3 H 847. H CD2C(CH3)3 H 848. H CD2CH2CF3 H 849. H CD2C(CH3)2CF3 H 850. H H 851. H H 852. H H 853. H H 854. H H 855. H H - In some embodiments, the first compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
- In another aspect of the present disclosure, an organic light-emitting device (OLED) comprising an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a first compound is disclosed. The first compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature, and the first compound has at least one aromatic ring and at least one substituent R, where each of the at least one substituent R is directly bonded to one of the at least one aromatic rings. Each of the at least one substituent R has the formula of
- where :
- G1 is
- (a) selected from the group consisting of NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; and G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3;
- (b) a direct bond; and G2 is a non-aromatic spiro polycyclic group, which can be further substituted by one or more R3; or
- (c) selected from the group consisting of: direct bond, NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3; and R is directly bonded to an aromatic ring selected from the group consisting of phenyl, pyridine, and triazine, which can be further fused to other rings;
- R1, R2, and R3 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
- each G1 and G2 is independently, optionally, partially or fully deuterated.
- The OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.
- The organic layer can also include a host. In some embodiments, two or more hosts are preferred. In some embodiments, the hosts used maybe a) bipolar, b) electron transporting, c) hole transporting or d) wide band gap materials that play little role in charge transport. In some embodiments, the host can include a metal complex. The host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan. Any substituent in the host can be an unfused substituent independently selected from the group consisting of CnH2n+1, OCnH2n+1, OAr1, N(CnH2n+1)2, N(Ar1)(Ar2), CH═CH—CnH2n+1, C≡C—CnH2n+1, Ar1, Ar1—Ar2, and CnH2n—Ar1, or the host has no substitution. In the preceding substituents n can range from 1 to 10; and Ar1 and Ar2 can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof. The host can be an inorganic compound. For example a Zn containing inorganic material e.g. ZnS.
- The host can be a compound comprising at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene. The host can include a metal complex. The host can be, but is not limited to, a specific compound selected from the group consisting of:
- and combinations thereof. Additional information on possible hosts is provided below.
- In yet another aspect of the present disclosure, a formulation that comprises the first compound is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, and an electron transport layer material, disclosed herein.
- The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.
- A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.
- Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804 and US2012146012.
- , and
- A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoOx; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenchexacarbonitrile; a metal complex, and a crosslinkable compounds.
- Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:
- Each of Ar1 to Ar9 is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
- In one aspect, Ar1 to Ar9 is independently selected from the group consisting of:
- wherein k is an integer from 1 to 20; X101 to X108 is C (including CH) or N; Z101 is NAr1, O, or S; Ar1 has the same group defined above.
- Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:
- wherein Met is a metal, which can have an atomic weight greater than 40; (Y101-Y102) is a bidentate ligand, Y101 and Y101 are independently selected from C, N, O, P, and S; L101 is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.
- In one aspect, (Y101-Y102) is a 2-phenylpyridine derivative. In another aspect, (Y101-Y102) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc+/Fc couple less than about 0.6 V.
- Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, US06517957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, US5061569, US5639914, WO05075451, WO07125714, WO08023550, WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.
- An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.
- The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.
- Examples of metal complexes used as host are preferred to have the following general formula:
- wherein Met is a metal; (Y103-Y104) is a bidentate ligand, Y103 and Y104 are independently selected from C, N, O, P, and S; L101 is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.
- In one aspect, the metal complexes are:
- wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.
- In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y103-Y104) is a carbene ligand.
- Examples of other organic compounds used as host are selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
- In one aspect, the host compound contains at least one of the following groups in the molecule:
- wherein each of R101 to R107 is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar’s mentioned above. k is an integer from 0 to 20 or 1 to 20; k‴ is an integer from 0 to 20. X101 to X108 is selected from C (including CH) or N. Z101 and Z102 is selected from NR101, O, or S.
- Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, US7154114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472,
- One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
- Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, US06699599, US06916554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, US6303238, US6413656, US6653654, US6670645, US6687266, US6835469, US6921915, US7279704, US7332232, US7378162, US7534505, US7675228, US7728137, US7740957, US7759489, US7951947, US8067099, US8592586, US8871361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456, WO2014112450.
- A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and or higher triplet energy than one or more of the hosts closest to the HBL interface.
- In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.
- In another aspect, compound used in HBL contains at least one of the following groups in the molecule:
- wherein k is an integer from 1 to 20; L101 is an another ligand, k′ is an integer from 1 to 3.
- Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.
- In one aspect, compound used in ETL contains at least one of the following groups in the molecule:
- wherein R101 is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar’s mentioned above. Ar1 to Ar3 has the similar definition as Ar’s mentioned above. k is an integer from 1 to 20. X101 to X108 is selected from C (including CH) or N.
- In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:
- wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L101 is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.
- Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, US6656612, US8415031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,
- In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.
- In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.
-
- 8-(4-chloropyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (4.75 g, 16.12 mmol) and [1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride (PEPPSI-IPr) (1.094 g, 1.612 mmol) were charged into a reaction flask with 50 mL of tetrahydrofuran (THF). This mixture was degassed with nitrogen then was stirred at room temperature (~22° C.). Then, bicyclo[2.2.1]heptan-2-ylzinc(II) bromide (97 ml, 48.3 mmol) was added to the reaction mixture via syringe. Stirring was continued at room temperature for 18 hours. The reaction mixture was quenched with aqueous ammonium chloride solution, then extracted with ethyl acetate. The extracts were dried over magnesium sulfate then filtered and concentrated to a reduced volume under vacuum. A solid was filtered from the resulting concentrate. The filtrate was passed through a silica gel column eluting with 2.5-5% THF/dichloromethane (DCM). The cleanest fractions were combined and concentrated under vacuum yielding 8-(4-(bicyclo[2.2.1]heptan-2-yl)pyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (4 g, 11.28 mmol, 70.0% yield) as a viscous light yellow oil.
-
- 8-(4-(bicyclo[2.2.1]heptan-2-yl)pyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (4 g, 11.28 mmol) was dissolved in 40 mL of THF. Dimethyl sulfoxide-d6 (37.9 g, 451 mmol) was syringed into the reaction mixture, followed by the addition of sodium tert-butoxide (0.542 g, 5.64 mmol). The resulting mixture was stirred and heated for 20 hours in a bath set at 65° C. The reaction mixture was quenched with 80 mL of D2O. The mixture was extracted two times with 400 mL ethyl acetate. The extracts were combined, washed with an aqueous LiCl solution, then dried over magnesium sulfate. The extracts were then filtered and concentrated under vacuum. The residue was passed through 3 × 120 g silica gel columns using 2.5-3.5% THF/ DCM. The clean product fractions yielded 8-(4-(bicyclo[2.2.1]heptan-2-yl-2-d)pyridin-2-yl)-2-(methyl- d3)benzofuro[2,3-b]pyridine (2.7 g, 7.53 mmol, 66.7% yield).
-
- 8-(4-(bicyclo[2.2.1]heptan-2-yl-2-d)pyridin-2-yl)-2-(methyl-d3)benzofuro[2,3-b]pyridine (2.6 g, 7.25 mmol) and the iridium salt shown in the synthetic scheme above (3.28 g, 4.19 mmol) were charged into a reaction flask with ethanol (32 mL) and methanol (32 mL). The reaction mixture was degassed with nitrogen then was heated for 3 days in an oil bath set at 70° C. The oil bath temperature was then raised to 80° C. and the raction mixture was stirred for two additional days. After this time, the reaction flask was cooled to room temperatrue (~ 20° C.). A yellow solid was isolated via filtration and was dried under vacuum with no heat. This solid was dissolved in toluene and was pre-absorbed on silica gel. This material was purified using silica gel chromatography through 6 × 125 g silica gel cartridges eluting with 0.7-0.8% ethyl acetate/toluene to yield a yellow solid that was triturated twicewith hot toluene. Compound 1064460 was then isolated as a yellow solid via filtration (0.60 g, 0.646 mmol, 15.4% yield) LC/MS confirmed the mass of the desired product.
-
- 8-(5-bromopyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (7 g, 20.64 mmol) and PEPPSI-IPr (1.051 g, 1.548 mmol) were charged into the reaction flask with 150 mL of THF. Bicyclo[2.2.1]heptan-2-ylzinc(II) bromide (70.2 ml, 35.1 mmol) was then syringed into the reaction flask and the mixture was degassed with nitrogen. This mixture was stirred at room temperature (~ 22° C.) for 16 hours. Gas chromatography/mass spetroscopy analysis showed the reaction to be complete. The reaction mixture was quenched with aqueous ammonium chloride, then the majority of the THF was removed under reduced pressure. Ethyl acetate was added to the aqueous mixture and this mixture was heated for several hours in a 70° C. bath. The organic layer was then separated and the aqueous layer was again extracted with ethyl acetate. The extracts were combined, washed with aqueous LiCl, then dried over magnesium sulfate. The extracts were then filtered and concentrated under vacuum. The crude residue was passed through 2 × 330 g silica gel columns using 3-6% THF/ toluene. Clean product fractions were combined and concentrated under vacuum yielding 8-(5-(bicyclo[2.2.1]heptan-2-yl)pyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (6 g, 16.93 mmol, 82% yield) as a foamy solid.
-
- 8-(5-(bicyclo[2.2.1]heptan-2-yl)pyridin-2-yl)-2-methylbenzofuro[2,3-b]pyridine (7.34 g, 20.71 mmol) was charged into a reaction flask with 60 mL of THF and dimethyl sulfoxide-d6 (35 ml, 500 mmol). Sodium tert-butoxide (0.596 g, 6.21 mmol) was then added all at once to the reaction mixture. This mixture was stirred and heated for 16 hours in an oil bath set at 65° C. The reaction mixture was cooled to room temperature (~ 22° C.) then was quenched with 80 mL of D2O. The mixture was extracted two times with 400 mL ethyl acetate. The extracts were combined, washed with aqueous LiCl, then dried over magnesium sulfate. The extracts were then filtered and concentrated under vacuum. The residue was passed through 3 × 330 g silica gel columns using 2.5-3.5% THF/ toluene. Clean product fractions yielded 8-(5-(bicyclo[2.2.1]heptan-2-yl-2-d)pyridin-2-yl)-2-(methyl-d3)benzofuro[2,3-b]pyridine (3.3 g, 9.21 mmol, 44.5% yield).
- 8-(5-(bicyclo[2.2.1]heptan-2-yl-2-d)pyridin-2-yl)-2-(methyl-d3)benzofuro[2,3-b]pyridine (3.3 g, 9.21 mmol) and the iridium salt shown in the scheme above (4.2 g, 5.37 mmol) were charged into the reaction flask with 40 mL ethanol and 40 mL methanol. This mixture was degassed with nitrogen then heated for five days in an oil bath set at 75° C. The reaction mixture was cooled to room temperature (~ 22° C.). A yellow solid was filtered from solution, which was then dried under vacuum. The yellow solid was dissolved in 400 mL of DCM and then passed through an activated plug of basic alumina. The DCM filtrate was evaporated under reduced vacuum. The crude residue was passed through 7 × 120 g silica gel columns eluting the columns with 5% ethyl acetate/ toluene. The major product eluted 1st from the columns was isolated as a yellow solid. This material was triturated twice with toluene/ heptane then isolated via filtration. The desired iridium complex was isolated as a yellow solid (0.8 g, 0.86 mmoL, 16.06% yield). Liquid chromatography/mass spectroscopy (LC/MS) analysis confirmed the mass of the desired product.
- All example devices were fabricated by high vacuum (<10-7 Torr) thermal evaporation. The anode electrode was 750 Å of indium tin oxide (ITO). The cathode consisted of 10 Å of Liq (8-hydroxyquinoline lithium) followed by 1,000 Å of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H2O and O2) immediately after fabrication, and a moisture getter was incorporated inside the package. The stack of the device examples consisted of sequentially, from the ITO surface, 100 Å of HATCN as the hole injection layer (HIL); 450 Å of HTM as a hole transporting layer (HTL); 50 Å of EBM as electron blocking layer, 400 Å of EML containing two component host (H1:H2 3:2 ratio) and emitter 12% (GD1 as Inventive Example 1 vs GD2 as comparison example CE 1), and 350 Å of Liq (8-hydroxyquinoline lithium) doped with 40% of ETM as the ETL. The chemical structures of the device materials are shown below.
- Table 1 shows the device layer thicknesses and materials.
-
TABLE 1 Device structure for evaluation of green emitters Layer Material Thickness [Å] Anode ITO 750 HIL HATCN 100 HTL HTM 450 EBL EBM 50 G EML H1:H2 (3:2):Emitter 12% 350 ETL Liq: ETM 40% 350 EIL Liq 10 Cathode Al 1000 - Emitter Example 1 (GD1) and Comparative Example CE1 (GD2) were used to demonstrate the superiority efficiency of the device with inventive vs. comparative compounds. The device External quantum efficiency (EQE) and luminance efficacy (LE) measured 10mA/cm2 are shown in the Table 2.
-
TABLE 2 External quantum efficiency of devices with inventive and comparative examples Example Emitter LE at 10mA/cm2 [cd/A] EQE at 10mA/cm2 [%] CE1 GD2 93.3 24.4 Example 1 GD1 98.1 25.7 - The observed device LE and EQE of inventive emitter is significantly higher vs.comparative emitter.
- It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.
Claims (20)
1. A composition comprising a first compound;
wherein the first compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature;
wherein the first compound has at least one aromatic ring and at least one substituent R;
wherein each of the at least one substituent R is directly bonded to one of the at least one aromatic ring;
wherein
(a) G1 is selected from the group consisting of NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; and G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3;
(b) G1 is a direct bond; and G2 is a non-aromatic spiro polycyclic group, which can be further substituted by one or more R3; or
(c) G1 is selected from the group consisting of: direct bond, NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3; and R is directly bonded to an aromatic ring selected from the group consisting of phenyl, pyridine, and triazine, which can be further fused to other rings;
wherein R1, R2, and R3 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
wherein each G1 and G2 can be independently, partially or fully deuterated.
2. The composition of claim 1 , wherein G2 is polycyclic alkyl.
3. The composition of claim 1 , wherein G2 is carborane.
4. The composition of claim 1 , wherein G2 contains at least one heteroatom.
5. The composition of claim 1 , wherein the first compound is capable of emitting light from a triplet excited state to a ground singlet state at room temperature.
6. The composition of claim 1 , wherein the first compound has the formula of
wherein L1, L2, and L3 can be the same or different;
wherein x is 1, 2, or 3;
wherein y is 0, 1, or 2;
wherein z is 0, 1, or 2;
wherein x+y+z is the oxidation state of the metal M;
wherein each X1 to X17 are independently selected from the group consisting of carbon and nitrogen;
wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO2, CR′R″, SiR′R″, and GeR′R″;
wherein each R′ and R″ can be independently, fused or joined to form a ring;
wherein each Ra, Rb, Rc, and Rd independently represents from mono substitution to the maximum possible number of substitutions, or no substitution;
wherein each R′, R″, Ra, Rb, Rc, and Rd is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any two adjacent substitutents of Ra, Rb, Rc, and Rd can be fused or joined to form a ring or form a multidentate ligand; and
wherein at least one of the Ra, Rb, Rc, and Rd includes the at least one substituent R.
7. The composition of claim 6 , wherein the first compound has the formula of
.
13. The composition of claim 6 , wherein L1 is LA having the following structure:
Ligand RA1
RA2
RA3
RA4
RA5
RA6 Ligand RA1
RA2
RA3
RA4
RA5
RA6
LA1
RG1
H H H H H LA1241
CD3
H RG58
H H H
LA2
RG2
H H H H H LA1242
CD3
H RG59
H H H
LA3
RG3
H H H H H LA1243
CD3
H RG60
H H H
LA4
RG4
H H H H H LA1244
CD3
H RG61
H H H
LA5
RG5
H H H H H LA1245
CD3
H RG62
H H H
LA6
RG6
H H H H H LA1246
CD3
H RG63
H H H
LA7
RG7
H H H H H LA1247
CD3
H RG64
H H H
LAB RG8
H H H H H LA1248
CD3
H RG65
H H H
LA9
RG9
H H H H H LA1249
CD3
H RG66
H H H
LA10
RG10
H H H H H LA1250
CD3
H RG67
H H H
LA11
RG11
H H H H H LA1251
CD3
H RG68
H H H
LA12
RG12 H H H H H LA1252
CD3
H RG69
H H H
LA13 RG13
H H H H H LA1253
CD3
H RG70
H H H
LA14
RG14
H H H H H LA1254
CD3
H RG71
H H H
LA15 RG15
H H H H H LA1255
CD3
H RG72
H H H
LA16
RG16
H H H H H LA1256
CD3
H RG73
H H H
LA17
RG17
H H H H H LA1257
CD3
H RG74
H H H
LA18
RG18
H H H H H LA1258
CD3
H RG75 H H H
LA19
RG19
H H H H H LA1259
CD3
H RG76
H H H
LA20
RG20
H H H H H LA1260
CD3
H RG77
H H H
LA21
RG21
H H H H H LA1261
CD3
H RG78
H H H
LA22
RG22
H H H H H LA1262
CD3
H RG79
H H H
LA23
RG23
H H H H H LA1263
CD3
H RG80
H H H
LA24
RG24
H H H H H LA1264
CD3
H RG81
H H H
LA25
RG25
H H H H H LA1265
CD3
H RG82
H H H
LA26
RG26
H H H H H LA1266
CD3
H RG84
H H H
LA27
RG27
H H H H H LA1267
CD3
H RG84
H H H
LA28
RG28
H H H H H LA1268
CD3
H RG85
H H H
LA29
RG29
H H H H H LA1269
CD3
H RG86
H H H
LA30
RG30
H H H H H LA1270
CD3
H RGB7
H H H
LA31
RG31
H H H H H LA1271
CD3
H RG88
H H H
LA32
RG32
H H H H H LA1272
CD3
H RG89
H H H
LA33
RG33
H H H H H LA1273
CD3
H RG90
H H H
LA34
RG34
H H H H H LA1274
CD3
H RG91
H H H
LA35
RG35
H H H H H LA1275
CD3
H RG92
H H H
LA36
RG36
H H H H H LA1276
CD3
H RG93
H H H
LA37
RG37
H H H H H LA1277
CD3
H RG94
H H H
LA38
RG38
H H H H H LA1278
CD3
H RG95
H H H
LA39
RG39
H H H H H LA1279
CD3
H RG96
H H H
LA40
RG40
H H H H H LA1280
CD3
H RG97
H H H
LA41
RG41
H H H H H LA1281
CD3
H RG98
H H H
LA42
RG42
H H H H H LA1282
CD3
H RG99
H H H
LA43
RG43
H H H H H LA1283
CD3
H RG100
H H H
LA44
RG44
H H H H H LA1284
CD3
H RG101
H H H
LA45
RG45
H H H H H LA1285
CD3
H RG102
H H H
LA46
RG46
H H H H H LA1286
CD3
H RG103
H H H
LA47
RG47
H H H H H LA1287
CD3
H RG104
H H H
LA48
RG48
H H H H H LA1288
CD3
H RG105
H H H
LA49
RG49
H H H H H LA1289
CD3
H RG106
H H H
LA50
RG50
H H H H H LA1290
CD3
H RG107
H H H
LA51
RG51
H H H H H LA1291
CD3
H RG108
H H H
LA52
RG52
H H H H H LA1292
CD3
H RG109
H H H
LA53
RG53
H H H H H LA1293
CD3
H RG110
H H H
LA54
RG54
H H H H H LA1294
CD3
H RG11 1
H H H
LA55
RG55
H H H H H LA1295
CD3
H RG11 2
H H H
LA56
RG56
H H H H H LA1296
CD3
H RG11 3
H H H
LA57
RG57
H H H H H LA1297
CD3
H RG11 4
H H H
LA58
RG58
H H H H H LA1298
CD3
H RG11 5
H H H
LA59
RG59
H H H H H LA1299
CD3
H RG11 6
H H H
LA60
RG60
H H H H H LA1300
CD3
H RG11 7
H H H
LA61
RG61
H H H H H LA1301
CD3
H RG1 1 8
H H H
LA62
RG62
H H H H H LA1302
CD3
H RG11 9
H H H
LA63
RG63
H H H H H LA1303
CD3
H RG1 2 0
H H H
LA64
RG64
H H H H H LA1304
CD3
H RG1 2 1
H H H
LA65
RG65
H H H H H LA1305
CD3
H RG1 2 2
H H H
LA66
RG66
H H H H H LA1306
CD3
H RG1 2 3
H H H
LA67
RG67
H H H H H LA1307
CD3
H RG 1 2 4
H H H
LA68
RG68
H H H H H LA1308
CD3
H RG 1 2 5
H H H
LA69
RG69
H H H H H LA1309
CD3
H RG 1 2 6
H H H
LA70
RG70
H H H H H LA13 1 0
CD3
H RG 1 2 7
H H H
LA71
RG71
H H H H H LA13 1 1
CD3
H RG 1 2 8
H H H
LA72
RG72
H H H H H LA1312
CD3
H RG 1 2 9
H H H
LA73
RG73
H H H H H LA1313
CD3
H RG 1 30
H H H
LA74
RG74
H H H H H LA1314
CD3
H RG 1 3 1
H H H
LA75
RG75
H H H H H LA1315
CD3
H RG 132
H H H
LA76
RG76
H H H H H LA1316
CD3
H RG 13 3
H H H
LA77
RG77
H H H H H LA1317
CD3
H RG 13 4
H H H
LA78
RG78
H H H H H LA1318
CD3
H RG 135
H H H
LA79
RG79
H H H H H LA1319
CD3
H RG 13 6
H H H
LA80
RG80
H H H H H LA13 2 0
CD3
H RG 137
H H H
LA8 1
RG81
H H H H H LA1321
CD3
H RG 138
H H H
LA82
RG82
H H H H H LA1322
CD3
H RG 139
H H H
LA83
RG83
H H H H H LA13 2 3
CD3
H RG 140
H H H
LA84
RG84
H H H H H LA1324
CD3
H RG 141
H H H
LA58
RG85
H H H H H LA13 2 5
CD3
H RG 142
H H H
LA86
RG86
H H H H H LA13 2 6
CD3
H RG 1 4 3
H H H
LA87
RG87
H H H H H LA13 2 7
CD3
H RG 144
H H H
LA58
RG88
H H H H H LA13 2 8
CD3
H RG 145
H H H
LA89
RG89
H H H H H LA13 2 9
CD3
H RG 146
H H H
LA90
RG90
H H H H H LA1330
CD3
H RG 147
H H H
LA91
RG91
H H H H H LA1331
CD3
H RG148
H H H
LA92
RG92
H H H H H LA1332
CD3
H RG149
H H H
LA93
RG93
H H H H H LA1333
CD3
H RG150
H H H
LA94
RG94
H H H H H LA1334
CD3
H RG151
H H H
LA95
RG95
H H H H H LA1335
CD3
H RG152
H H H
LA96
RG96
H H H H H LA1336
CD3
H RG153
H H H
LA97
RG97
H H H H H LA1337
CD3
H RG154
H H H
LA98
RG98
H H H H H LA1338
CD3
H RG155
H H H
LA99
RG99
H H H H H LA1339
CD3
H RG156
H H H
LA100
RG100
H H H H H LA1340
CD3
H RG157
H H H
LA101
RG101
H H H H H LA1341
CD3
H RG158
H H H
LA102
RG102
H H H H H LA1342
CD3
H RG159
H H H
LA103
RG103
H H H H H LA1343
CD3
H RG160
H H H
LA104
RG104
H H H H H LA1344
CD3
H RG161
H H H
LA105
RG105
H H H H H LA1345
CD3
H RG162
H H H
LA106
RG106
H H H H H LA1346
CD3
H RG163
H H H
LA107
RG107
H H H H H LA1347
CD3
H RG164
H H H
LA108
RG108
H H H H H LA1348
CD3
H RG165
H H H
LA109
RG109
H H H H H LA1349
CD3
H RG166
H H H
LA110
RG110
H H H H H LA1350
CD3
H RG167
H H H
LA111
RG111
H H H H H LA1351
CD3
H RG168
H H H
LA112
RG112
H H H H H LA1352
CD3
H RG169
H H H
LA113
RG113
H H H H H LA1353
H CD3
RG1
H H H
LA114
RG114
H H H H H LA1354
H CD3
RG2
H H H
LA115
RG115
H H H H H LA1355
H CD3
RG3
H H H
LA116
RG116
H H H H H LA1356
H CD3
RG4
H H H
LA117
RG117
H H H H H LA1357
H CD3
RG5
H H H
LA118
RG118
H H H H H LA1358
H CD3
RG6
H H H
LA119
RG119
H H H H H LA1359
H CD3
RG7
H H H
LA120
RG120
H H H H H LA1360
H CD3
RG8
H H H
LA121
RG121
H H H H H LA1361
H CD3
RG9
H H H
LA122
RG122
H H H H H LA1362
H CD3
RG10
H H H
LA123
RG123
H H H H H LA1363
H CD3
RG11
H H H
LA124
RG124
H H H H H LA1364
H CD3
RG12
H H H
LA125
RG125
H H H H H LA1365
H CD3
RG13
H H H
LA126
RG126
H H H H H LA1366
H CD3
RG14
H H H
LA127
RG127
H H H H H LA1367
H CD3
RG15
H H H
LA128
RG128
H H H H H LA1368
H CD3
RG16
H H H
LA129
RG129
H H H H H LA1369
H CD3
RG17
H H H
LA130
RG130
H H H H H LA1370
H CD3
RG18
H H H
LA1311
RG131
H H H H H LA1371
H CD3
RG19
H H H
LA132
RG132
H H H H H LA1372
H CD3
RG20
H H H
LA133
RG133
H H H H H LA1373
H CD3
RG21
H H H
LA134
RG134
H H H H H LA1374
H CD3
RG22
H H H
LA135
RG135
H H H H H LA1375
H CD3
RG23
H H H
LA136
RG136
H H H H H LA1376
H CD3
RG24
H H H
LA137
RG137
H H H H H LA1377
H CD3
RG25
H H H
LA138
RG138
H H H H H LA1378
H CD3
RG26
H H H
LA139
RG139
H H H H H LA1379
H CD3
RG27
H H H
LA140
RG140
H H H H H LA1380
H CD3
RG28
H H H
LA141
RG141
H H H H H LA1381
H CD3
RG29
H H H
LA142
RG142
H H H H H LA1382
H CD3
RG30
H H H
LA143
RG143
H H H H H LA1383
H CD3
RG31
H H H
LA144
RG144
H H H H H LA1384
H CD3
RG32
H H H
LA145
RG145
H H H H H LA1385
H CD3
RG33
H H H
LA146
RG146
H H H H H LA1386
H CD3
RG34
H H H
LA147
RG147
H H H H H LA1387
H CD3
RG35
H H H
LA148
RG148
H H H H H LA1388
H CD3
RG36
H H H
LA149
RG149
H H H H H LA1389
H CD3
RG37
H H H
LA150
RG150
H H H H H LA1390
H CD3
RG38
H H H
LA151
RG151
H H H H H LA1391
H CD3
RG39
H H H
LA152
RG152
H H H H H LA1392
H CD3
RG40
H H H
LA153
RG153
H H H H H LA1393
H CD3
RG41
H H H
LA154
RG154
H H H H H LA1394
H CD3
RG42
H H H
LA155
RG155
H H H H H LA1395
H CD3
RG43
H H H
LA156
RG156
H H H H H LA1396
H CD3
RG44
H H H
LA157
RG157
H H H H H LA1397
H CD3
RG45
H H H
LA158
RG158
H H H H H LA1398
H CD3
RG46
H H H
LA159
RG159
H H H H H LA1399
H CD3
RG47
H H H
LA160
RG160
H H H H H LA1400
H CD3
RG48
H H H
LA161
RG161
H H H H H LA1401
H CD3
RG49
H H H
LA162
RG162
H H H H H LA1402
H CD3
RG50
H H H
LA163
RG163
H H H H H LA1403
H CD3
RG51
H H H
LA164
RG164
H H H H H LA1404
H CD3
RG52
H H H
LA165
RG165
H H H H H LA1405
H CD3
RG53
H H H
LA166
RG166
H H H H H LA1406
H CD3
RG54
H H H
LA167
RG167
H H H H H LA1407
H CD3
RG55
H H H
LA168
RG168
H H H H H LA1408
H CD3
RG56
H H H
LA169
RG169
H H H H H LA1409
H CD3
RG57
H H H
LA170
RG1
H CD3
H H H LA1410
H CD3
RG58
H H H
LA171
RG2
H CD3
H H H LA1411
H CD3
RG59
H H H
LA172
RG3
H CD3
H H H LA1412
H CD3
RG60
H H H
LA173
RG4
H CD3
H H H LA1413
H CD3
RG61
H H H
LA174
RG5
H CD3
H H H LA1414
H CD3
RG62
H H H
LA175
RG6
H CD3
H H H LA1415
H CD3
RG63
H H H
LA176
RG7
H CD3
H H H LA1416
H CD3
RG64
H H H
LA177
RG8
H CD3
H H H LA1417
H CD3
RG65
H H H
LA178
RG9
H CD3
H H H LA1418
H CD3
RG66
H H H
LA179
RG10
H CD3
H H H LA1419
H CD3
RG67
H H H
LA180
RG11
H CD3
H H H LA1420
H CD3
RG68
H H H
LA181
RG12
H CD3
H H H LA1421
H CD3
RG69
H H H
LA182
RG13
H CD3
H H H LA1422
H CD3
RG70
H H H
LA183
RG14
H CD3
H H H LA1423
H CD3
RG71
H H H
LA184
RG15
H CD3
H H H LA1424
H CD3
RG72
H H H
LA185
RG16
H CD3
H H H LA1425
H CD3
RG73
H H H
LA186
RG17
H CD3
H H H LA1426
H CD3
RG74
H H H
LA187
RG18
H CD3
H H H LA1427
H CD3
RG75
H H H
LA188
RG19
H CD3
H H H LA1428
H CD3
RG76
H H H
LA189
RG20
H CD3
H H H LA1429
H CD3
RG77
H H H
LA190
RG21
H CD3
H H H LA1430
H CD3
RG78
H H H
LA191
RG22
H CD3
H H H LA1431
H CD3
RG79
H H H
LA192
RG23
H CD3
H H H LA1432
H CD3
RG80
H H H
LA193
RG24
H CD3
H H H LA1433
H CD3
RG81
H H H
LA194
RG25
H CD3
H H H LA1434
H CD3
RG82
H H H
LA195
RG26
H CD3
H H H LA1435
H CD3
RG83
H H H
LA196
RG27
H CD3
H H H LA1436
H CD3
RG84
H H H
LA197
RG28
H CD3
H H H LA1437
H CD3
RG85
H H H
LA198
RG29
H CD3
H H H LA1438
H CD3
RG86
H H H
LA199
RG30
H CD3
H H H LA1439
H CD3
RG87
H H H
LA200
RG31
H CD3
H H H LA1440
H CD3
RG88
H H H
LA201
RG32
H CD3
H H H LA1441
H CD3
RG89
H H H
LA202
RG33
H CD3
H H H LA1442
H CD3
RG90
H H H
LA203
RG34
H CD3
H H H LA1443
H CD3
RG91
H H H
LA204
RG35
H CD3
H H H LA1444
H CD3
RG92
H H H
LA205
RG36
H CD3
H H H LA1445
H CD3
RG93
H H H
LA206
RG37
H CD3
H H H LA1446
H CD3
RG94
H H H
LA207
RG38
H CD3
H H H LA1447
H CD3
RG95
H H H
LA208
RG39
H CD3
H H H LA1448
H CD3
RG96
H H H
LA209
RG40
H CD3
H H H LA1449
H CD3
RG97
H H H
LA210
RG41
H CD3
H H H LA1450
H CD3
RG98
H H H
LA211
RG42
H CD3
H H H LA1451
H CD3
RG99
H H H
LA212
RG43
H CD3
H H H LA1452
H CD3
RG100
H H H
LA213
RG44
H CD3
H H H LA1453
H CD3
RG101
H H H
LA214
RG46
H CD3
H H H LA1454
H CD3
RG102
H H H
LA215
RG46
H CD3
H H H LA1455
H CD3
RG103
H H H
LA216
RG47
H CD3
H H H LA1456
H CD3
RG104
H H H
LA217
RG48
H CD3
H H H LA1457
H CD3
RG105
H H H
LA218
RG49
H CD3
H H H LA1458
H CD3
RG106
H H H
LA219
RG50
H CD3
H H H LA1459
H CD3
RG107
H H H
LA220
RG51
H CD3
H H H LA1460
H CD3
RG108
H H H
LA221
RG52
H CD3
H H H LA1461
H CD3
RG109
H H H
LA222
RG53
H CD3
H H H LA1462
H CD3
RG110
H H H
LA223
RG54
H CD3
H H H LA1463
H CD3
RG111
H H H
LA224
RG55
H CD3
H H H LA1464
H CD3
RG112
H H H
LA225
RG56
H CD3
H H H LA1465
H CD3
RG113
H H H
LA226
RG57
H CD3
H H H LA1466
H CD3
RG114
H H H
LA227
RG58
H CD3
H H H LA1467
H CD3
RG115
H H H
LA228
RG59
H CD3
H H H LA1468
H CD3
RG116
H H H
LA229
RG60
H CD3
H H H LA1469
H CD3
RG117
H H H
LA230
RG61
H CD3
H H H LA1470
H CD3
RG118
H H H
LA231
RG62
H CD3
H H H LA1471
H CD3
RG119
H H H
LA232
RG63
H CD3
H H H LA1472
H CD3
RG120
H H H
LA233
RG64
H CD3
H H H LA1473
H CD3
RG121
H H H
LA234
RG65
H CD3
H H H LA1474
H CD3
RG122
H H H
LA235
RG66
H CD3
H H H LA1475
H CD3
RG123
H H H
LA236
RG67
H CD3
H H H LA1476
H CD3
RG124
H H H
LA237
RG68
H CD3
H H H LA1477
H CD3
RG125
H H H
LA238
RG69
H CD3
H H H LA1478
H CD3
RG126
H H H
LA239
RG70
H CD3
H H H LA1479
H CD3
RG127
H H H
LA240
RG71
H CD3
H H H LA1480
H CD3
RG128
H H H
LA241
RG72
H CD3
H H H LA1481
H CD3
RG129
H H H
LA242
RG73
H CD3
H H H LA1482
H CD3
RG130
H H H
LA243
RG74
H CD3
H H H LA1483
H CD3
RG131
H H H
LA244
RG75
H CD3
H H H LA1484
H CD3
RG132
H H H
LA245
RG76
H CD3
H H H LA1485
H CD3
RG133
H H H
LA246
RG77
H CD3
H H H LA1486
H CD3
RG134
H H H
LA247
RG78
H CD3
H H H LA1487
H CD3
RG135
H H H
LA248
RG79
H CD3
H H H LA1488
H CD3
RG136
H H H
LA249
RG80
H CD3
H H H LA1489
H CD3
RG137
H H H
LA250
RG81
H CD3
H H H LA1490
H CD3
RG138
H H H
LA251
RG82
H CD3
H H H LA1491
H CD3
RG139
H H H
LA252
RG83
H CD3
H H H LA1492
H CD3
RG140
H H H
LA253
RG84
H CD3
H H H LA1493
H CD3
RG141
H H H
LA254
RG85
H CD3
H H H LA1494
H CD3
RG142
H H H
LA255
RG86
H CD3
H H H LA1495
H CD3
RG143
H H H
LA256
RG87
H CD3
H H H LA1496
H CD3
RG144
H H H
LA257
RG88
H CD3
H H H LA1497
H CD3
RG145
H H H
LA258
RG89
H CD3
H H H LA1498
H CD3
RG146
H H H
LA259
RG90
H CD3
H H H LA1499
H CD3
RG147
H H H
LA260
RG91
H CD3
H H H LA1500
H CD3
RG148
H H H
LA261
RG92
H CD3
H H H LA1501
H CD3
RG149
H H H
LA262
RG93
H CD3
H H H LA1502
H CD3
RG150
H H H
LA263
RG94
H CD3
H H H LA1503
H CD3
RG151
H H H
LA264
RG95
H CD3
H H H LA1504
H CD3
RG152
H H H
LA265
RG96
H CD3
H H H LA1505
H CD3
RG153
H H H
LA266
RG97
H CD3
H H H LA1506
H CD3
RG154
H H H
LA267
RG98
H CD3
H H H LA1507
H CD3
RG155
H H H
LA268
RG99
H CD3
H H H LA1508
H CD3
RG156
H H H
LA269
RG100
H CD3
H H H LA1509
H CD3
RG157
H H H
LA270
RG101
H CD3
H H H LA1510
H CD3
RG158
H H H
LA271
RG102
H CD3
H H H LA1511
H CD3
RG159
H H H
LA272
RG103
H CD3
H H H LA1512
H CD3
RG160
H H H
LA273
RG104
H CD3
H H H LA1513
H CD3
RG161
H H H
LA274
RG105
H CD3
H H H LA1514
H CD3
RG162
H H H
LA275
RG106
H CD3
H H H LA1515
H CD3
RG163
H H H
LA276
RG107
H CD3
H H H LA1516
H CD3
RG164
H H H
LA277
RG108
H CD3
H H H LA1517
H CD3
RG165
H H H
LA278
RG109
H CD3
H H H LA1518
H CD3
RG166
H H H
LA279
RG110
H CD3
H H H LA1519
H CD3
RG167
H H H
LA280
RG111
H CD3
H H H LA1520
H CD3
RG168
H H H
LA281
RG112
H CD3
H H H LA1521
H CD3
RG169
H H H
LA282
RG11 3
H CD3
H H H LA1522
RG1
CD3
CD3
H H H
LA283
RG114
H CD3
H H H LA1523
RG2
CD3
CD3
H H H
LA284
RG115
H CD3
H H H LA1524
RG3
CD3
CD3
H H H
LA285
RG116
H CD3
H H H LA1525
RG4
CD3
CD3
H H H
LA286
RG117
H CD3
H H H LA1526
RG5
CD3
CD3
H H H
LA287
RG118
H CD3
H H H LA1527
RG6
CD3
CD3
H H H
LA288
RG119
H CD3
H H H LA1528
RG7
CD3
CD3
H H H
LA289
RG120
H CD3
H H H LA1529
RG8
CD3
CD3
H H H
LA290
RG121
H CD3
H H H LA1530
RG9
CD3
CD3
H H H
LA291
RG122
H CD3
H H H LA1531
RG10
CD3
CD3
H H H
LA292
RG123
H CD3
H H H LA1532
RG11
CD3
CD3
H H H
LA293
RG124
H CD3
H H H LA1533
RG12
CD3
CD3
H H H
LA294
RG125
H CD3
H H H LA1534
RG13
CD3
CD3
H H H
LA295
RG126
H CD3
H H H LA1535
RG14
CD3
CD3
H H H
LA296
RG127
H CD3
H H H LA1536
RG15
CD3
CD3
H H H
LA297
RG128
H CD3
H H H LA1537
RG16
CD3
CD3
H H H
LA298
RG129
H CD3
H H H LA1538
RG17
CD3
CD3
H H H
LA299
RG130
H CD3
H H H LA1539
RG18
CD3
CD3
H H H
LA300
RG131
H CD3
H H H LA1540
RG19
CD3
CD3
H H H
LA301
RG132
H CD3
H H H LA1541
CD3
RG1
H H H H
LA302
RG133
H CD3
H H H LA1542
CD3
RG2
H H H H
LA303
RG134
H CD3
H H H LA1543
CD3
RG3
H H H H
LA304
RG135
H CD3
H H H LA1544
CD3
RG4
H H H H
LA305
RG136
H CD3
H H H LA1545
CD3
RG5
H H H H
LA306
RG137
H CD3
H H H LA1546
CD3
RG6
H H H H
LA307
RG138
H CD3
H H H LA1547
CD3
RG7
H H H H
LA308
RG139
H CD3
H H H LA1548
CD3
RG8
H H H H
LA309
RG140
H CD3
H H H LA1549
CD3
RG9
H H H H
LA310
RG141
H CD3
H H H LA1550
CD3
RG10
H H H H
LA311
RG142
H CD3
H H H LA1551
CD3
RG11
H H H H
LA312
RG143
H CD3
H H H LA1552
CD3
RG12
H H H H
LA313
RG144
H CD3
H H H LA1553
CD3
RG13
H H H H
LA314
RG145
H CD3
H H H LA1554
CD3
RG14
H H H H
LA315
RG146
H CD3
H H H LA1555
CD3
RG15
H H H H
LA316
RG147
H CD3
H H H LA1556
CD3
RG16
H H H H
LA317
RG148
H CD3
H H H LA1557
CD3
RG17
H H H H
LA318
RG149
H CD3
H H H LA1558
CD3
RG18
H H H H
LA319
RG150
H CD3
H H H LA1559
CD3
RG19
H H H H
LA320
RG151
H CD3
H H H LA1560
CD3
CD3
RG1
H H CD3
LA321
RG152
H CD3
H H H LA1561
CD3
CD3
RG2
H H CD3
LA322
RG153
H CD3
H H H LA1562
CD3
CD3
RG3
H H CD3
LA323
RG154
H CD3
H H H LA1563
CD3
CD3
RG4
H H CD3
LA324
RG155
H CD3
H H H LA1564
CD3
CD3
RG5
H H CD3
LA325
RG156
H CD3
H H H LA1565
CD3
CD3
RG6
H H CD3
LA326
RG15 7
H CD3
H H H LA1566
CD3
CD3
RG7
H H CD3
LA327
RG158
H CD3
H H H LA1567
CD3
CD3
RG8
H H CD3
LA328
RG159
H CD3
H H H LA1568
CD3
CD3
RG9
H H CD3
LA329
RG160
H CD3
H H H LA1569
CD3
CD3
RG10
H H CD3
LA330
RG161
H CD3
H H H LA1570
CD3
CD3
RG11
H H CD3
LA331
RG162
H CD3
H H H LA1571
CD3
CD3
RG12
H H CD3
LA332
RG163
H CD3
H H H LA1572
CD3
CD3
RG13
H H CD3
LA333
RG164
H CD3
H H H LA1573
CD3
CD3
RG14
H H CD3
LA334
RG165
H CD3
H H H LA1574
CD3
CD3
RG15
H H CD3
LA335
RG166
H CD3
H H H LA1575
CD3
CD3
RG16
H H CD3
LA336
RG167
H CD3
H H H LA1576
CD3
CD3
RG17
H H CD3
LA337
RG168
H CD3
H H H LA1577
CD3
CD3
RG18
H H CD3
LA338
RG69
H CD3
H H H LA1578
CD3
CD3
RG19
H H CD3
LA339
RG1
CD3
CD3
H H CD3
LA1579
CD3
H RG1
H H CD3
LA340
RG2
CD3
CD3
H H CD3
LA1580
CD3
H RG2
H H CD3
LA341
RG3
CD3
CD3
H H CD3
LA1581
CD3
H RG3
H H CD3
LA342
RG4
CD3
CD3
H H CD3
LA1582
CD3
H RG4
H H CD3
LA343
RG5
CD3
CD3
H H CD3
LA1583
CD3
H RG5
H H CD3
LA344
RG6
CD3
CD3
H H CD3
LA1584
CD3
H RG6
H H CD3
LA345
RG7
CD3
CD3
H H CD3
LA1585
CD3
H RG7
H H CD3
LA346
RG8
CD3
CD3
H H CD3
LA1586
CD3
H RG8
H H CD3
LA347
RG9
CD3
CD3
H H CD3
LA1587
CD3
H RG9
H H CD3
LA348
RG10
CD3
CD3
H H CD3
LA1588
CD3
H RG10
H H CD3
LA349
RG11
CD3
CD3
H H CD3
LA1589
CD3
H RG11
H H CD3
LA350
RG12
CD3
CD3
H H CD3
LA1590
CD3
H RG12
H H CD3
LA351
RG13
CD3
CD3
H H CD3
LA1591
CD3
H RG13
H H CD3
LA352
RG14
CD3
CD3
H H CD3
LA1592
CD3
H RG14
H H CD3
LA353
RG15
CD3
CD3
H H CD3
LA1593
CD3
H RG15
H H CD3
LA354
RG16
CD3
CD3
H H CD3
LA1594
CD3
H RG16
H H CD3
LA355
RG17
CD3
CD3
H H CD3
LA1595
CD3
H RG17
H H CD3
LA356
RG18
CD3
CD3
H H CD3
LA1596
CD3
H RG18
H H CD3
LA357
RG19
CD3
CD3
H H CD3
LA1597
CD3
H RG19
H H CD3
LA358
RG20
CD3
CD3
H H CD3
LA1598
RG1
CD3
H H H H
LA359
RG21
CD3
CD3
H H CD3
LA1599
RG2
CD3
H H H H
LA360
RG22
CD3
CD3
H H CD3
LA1600
RG3
CD3
H H H H
LA361
RG23
CD3
CD3
H H CD3
LA1601
RG4
CD3
H H H H
LA362
RG24
CD3
CD3
H H CD3
LA1602
RG5
CD3
H H H H
LA363
RG25
CD3
CD3
H H CD3
LA1603
RG6
CD3
H H H H
LA364
RG26
CD3
CD3
H H CD3
LA1604
RG7
CD3
H H H H
LA365
RG27
CD3
CD3
H H CD3
LA1605
RG8
CD3
H H H H
LA366
RG28
CD3
CD3
H H CD3
LA1606
RG9
CD3
H H H H
LA367
RG29
CD3
CD3
H H CD3
LA1607
RG10
CD3
H H H H
LA368
RG30
CD3
CD3
H H CD3
LA1608
RG11
CD3
H H H H
LA369
RG31
CD3
CD3
H H CD3
LA1609
RG12
CD3
H H H H
LA370
RG32
CD3
CD3
H H CD3
LA1610
RG13
CD3
H H H H
LA371
RG33
CD3
CD3
H H CD3
LA1611
RG14
CD3
H H H H
LA372
RG34
CD3
CD3
H H CD3
LA1612
RG15
CD3
H H H H
LA373
RG35
CD3
CD3
H H CD3
LA1613
RG16
CD3
H H H H
LA374
RG36
CD3
CD3
H H CD3
LA1614
RG17
CD3
H H H H
LA375
RG37
CD3
CD3
H H CD3
LA1615
RG18
CD3
H H H H
LA376
RG38
CD3
CD3
H H CD3
LA1616
RG19
CD3
H H H H
LA377
RG39
CD3
CD3
H H CD3
LA1617
H CD3
RG1
H H CD3
LA378
RG40
CD3
CD3
H H CD3
LA1618
H CD3
RG2
H H CD3
LA379
RG41
CD3
CD3
H H CD3
LA1619
H CD3
RG3
H H CD3
LA380
RG42
CD3
CD3
H H CD3
LA1620
H CD3
RG4
H H CD3
LA381
RG43
CD3
CD3
H H CD3
LA1621
H CD3
RG5
H H CD3
LA382
RG44
CD3
CD3
H H CD3
LA1622
H CD3
RG6
H H CD3
LA383
RG45
CD3
CD3
H H CD3
LA1623
H CD3
RG7
H H CD3
LA384
RG46
CD3
CD3
H H CD3
LA1624
H CD3
RG8
H H CD3
LA385
RG47
CD3
CD3
H H CD3
LA1625
H CD3
RG9
H H CD3
LA386
RG48
CD3
CD3
H H CD3
LA1626
H CD3
RG10
H H CD3
LA387
RG49
CD3
CD3
H H CD3
LA1627
H CD3
RG11
H H CD3
LA388
RG50
CD3
CD3
H H CD3
LA1628
H CD3
RG12
H H CD3
LA389
RG51
CD3
CD3
H H CD3
LA1629
H CD3
RG13
H H CD3
LA390
RG52
CD3
CD3
H H CD3
LA1630
H CD3
RG14
H H CD3
LA391
RG53
CD3
CD3
H H CD3
LA1631
H CD3
RG15
H H CD3
LA392
RG54
CD3
CD3
H H CD3
LA1632
H CD3
RG16
H H CD3
LA393
RG55
CD3
CD3
H H CD3
LA1633
H CD3
RG17
H H CD3
LA394
RG56
CD3
CD3
H H CD3
LA1634
H CD3
RG18
H H CD3
LA395
RG57
CD3
CD3
H H CD3
LA1635
H CD3
RG19
H H CD3
LA396
RG58
CD3
CD3
H H CD3
LA1636
H RG1
H H H H
LA397
RG59
CD3
CD3
H H CD3
LA1637
H RG2
H H H H
LA398
RG60
CD3
CD3
H H CD3
LA1638
H RG3
H H H H
LA399
RG61
CD3
CD3
H H CD3
LA1639
H RG4
H H H H
LA400
RG62
CD3
CD3
H H CD3
LA1640
H RG5
H H H H
LA401
RG63
CD3
CD3
H H CD3
LA1641
H RG6
H H H H
LA402
RG64
CD3
CD3
H H CD3
LA1642
H RG7
H H H H
LA403
RG65
CD3
CD3
H H CD3
LA1643
H RG8
H H H H
LA404
RG66
CD3
CD3
H H CD3
LA1644
H RG9
H H H H
LA405
RG67
CD3
CD3
H H CD3
LA1645
H RG10
H H H H
LA406
RG68
CD3
CD3
H H CD3
LA1646
H RG11
H H H H
LA407
RG69
CD3
CD3
H H CD3
LA1647
H RG12
H H H H
LA408
RG70
CD3
CD3
H H CD3
LA1648
H RG13
H H H H
LA409
RG71
CD3
CD3
H H CD3
LA1649
H RG14
H H H H
LA410
RG72
CD3
CD3
H H CD3
LA1650
H RG15
H H H H
LA41
RG73
CD3
CD3
H H CD3
LA1651
H RG16
H H H H
LA412
RG74
CD3
CD3
H H CD3
LA1652
H RG17
H H H H
LA413
RG75
CD3
CD3
H H CD3
LA1653
H RG18
H H H H
LA414
RG76
CD3
CD3
H H CD3
LA1654
H RG19
H H H H
LA415
RG77
CD3
CD3
H H CD3
LA1655
H RG20
H H H H
LA416
RG78
CD3
CD3
H H CD3
LA1656
H RG21
H H H H
LA417
RG79
CD3
CD3
H H CD3
LA1657
H RG22
H H H H
LA418
RG80
CD3
CD3
H H CD3
LA1658
H RG23
H H H H
LA419
RG81
CD3
CD3
H H CD3
LA1659
H RG24
H H H H
LA420
RG82
CD3
CD3
H H CD3
LA1660
H RG25
H H H H
LA421
RG83
CD3
CD3
H H CD3
LA1661
H RG26
H H H H
LA422
RG84
CD3
CD3
H H CD3
LA1662
H RG27
H H H H
LA423
RG85
CD3
CD3
H H CD3
LA1663
H RG28
H H H H
LA424
RG86
CD3
CD3
H H CD3
LA1664
H RG29
H H H H
LA425
RGB7
CD3
CD3
H H CD3
LA1665
H RG30
H H H H
LA426
RG88
CD3
CD3
H H CD3
LA1666
H RG31
H H H H
LA427
RG89
CD3
CD3
H H CD3
LA1667
H RG32
H H H H
LA428
RG90
CD3
CD3
H H CD3
LA1668
H RG33
H H H H
LA429
RG91
CD3
CD3
H H CD3
LA1669
H RG34
H H H H
LA430
RG92
CD3
CD3
H H CD3
LA1670
H RG35
H H H H
LA431
RG93
CD3
CD3
H H CD3
LA1671
H RG36
H H H H
LA432
RG94
CD3
CD3
H H CD3
LA1672
H RG37
H H H H
LA433
RG95
CD3
CD3
H H CD3
LA1673
H RG38
H H H H
LA434
RG96
CD3
CD3
H H CD3
LA1674
H RG39
H H H H
LA435
RG97
CD3
CD3
H H CD3
LA1675
H RG40
H H H H
LA436
RG98
CD3
CD3
H H CD3
LA1676
H RG41
H H H H
LA437
RG99
CD3
CD3
H H CD3
LA1677
H RG42
H H H H
LA438
RG100
CD3
CD3
H H CD3
LA1678
H RG43
H H H H
LA439
RG101
CD3
CD3
H H CD3
LA1679
H RG44
H H H H
LA440
RG102
CD3
CD3
H H CD3
LA1680
H RG45
H H H H
LA441
RG103
CD3
CD3
H H CD3
LA1681
H RG46
H H H H
LA442
RG104
CD3
CD3
H H CD3
LA1682
H RG47
H H H H
LA443
RG105
CD3
CD3
H H CD3
LA1683
H RG48
H H H H
LA444
RG106
CD3
CD3
H H CD3
LA1684
H RG49
H H H H
LA445
RG107
CD3
CD3
H H CD3
LA1685
H RG50
H H H H
LA446
RG108
CD3
CD3
H H CD3
LA1686
H RG51
H H H H
LA447
RG109
CD3
CD3
H H CD3
LA1687
H RG52
H H H H
LA448
RG110
CD3
CD3
H H CD3
LA1688
H RG53
H H H H
LA449
RG111
CD3
CD3
H H CD3
LA1689
H RG54
H H H H
LA450
RG112
CD3
CD3
H H CD3
LA1690
H RG55
H H H H
LA451
RG113
CD3
CD3
H H CD3
LA1691
H RG56
H H H H
LA452
RG114
CD3
CD3
H H CD3
LA1692
H RG57
H H H H
LA453
RG115
CD3
CD3
H H CD3
LA1693
H RG58
H H H H
LA454
RG116
CD3
CD3
H H CD3
LA1694
H RG59
H H H H
LA455
RG117
CD3
CD3
H H CD3
LA1695
H RG60
H H H H
LA456
RG118
CD3
CD3
H H CD3
LA1696
H RG61
H H H H
LA457
RG119
CD3
CD3
H H CD3
LA1697
H RG62
H H H H
LA458
RG120
CD3
CD3
H H CD3
LA1698
H RG63
H H H H
LA459
RG121
CD3
CD3
H H CD3
LA1699
H RG64
H H H H
LA460
RG122
CD3
CD3
H H CD3
LA1700
H RG65
H H H H
LA461
RG123
CD3
CD3
H H CD3
LA1701
H RG66
H H H H
LA462
RG124
CD3
CD3
H H CD3
LA1702
H RG67
H H H H
LA463
RG125
CD3
CD3
H H CD3
LA1703
H RG68
H H H H
LA464
RG126
CD3
CD3
H H CD3
LA1704
H RG69
H H H H
LA465
RG127
CD3
CD3
H H CD3
LA1705
H RG70
H H H H
LA466
RG128
CD3
CD3
H H CD3
LA1706
H RG71
H H H H
LA467
RG129
CD3
CD3
H H CD3
LA1707
H RG72
H H H H
LA468
RG130
CD3
CD3
H H CD3
LA1708
H RG73
H H H H
LA469
RG131
CD3
CD3
H H CD3
LA1709
H RG74
H H H H
LA470
RG132
CD3
CD3
H H CD3
LA1710
H RG75
H H H H
LA471
RG133
CD3
CD3
H H CD3
LA1711
H RG76
H H H H
LA472
RG134
CD3
CD3
H H CD3
LA1712
H RG77
H H H H
LA473
RG135
CD3
CD3
H H CD3
LA1713
H RG78
H H H H
LA474
RG136
CD3
CD3
H H CD3
LA1714
H RG79
H H H H
LA475
RG137
CD3
CD3
H H CD3
LA1715
H RG80
H H H H
LA476
RG138
CD3
CD3
H H CD3
LA1716
H RG81
H H H H
LA477
RG139
CD3
CD3
H H CD3
LA1717
H RG82
H H H H
LA478
RG140
CD3
CD3
H H CD3
LA1718
H RG83
H H H H
LA479
RG141
CD3
CD3
H H CD3
LA1719
H RG84
H H H H
LA480
RG142
CD3
CD3
H H CD3
LA1720
H RG85
H H H H
LA481
RG143
CD3
CD3
H H CD3
LA1721
H Rcss
H H H H
LA482
RG144
CD3
CD3
H H CD3
LA1722
H RGB7
H H H H
LA483
RG145
CD3
CD3
H H CD3
LA1723
H RG88
H H H H
LA484
RG146
CD3
CD3
H H CD3
LA1724
H RG89
H H H H
LA485
RG147
CD3
CD3
H H CD3
LA1725
H RG90
H H H H
LA486
RG148
CD3
CD3
H H CD3
LA1726
H RG91
H H H H
LA487
RG149
CD3
CD3
H H CD3
LA1727
H RG92
H H H H
LA488
RG150
CD3
CD3
H H CD3
LA1728
H RG93
H H H H
LA489
RG151
CD3
CD3
H H CD3
LA1729
H RG94
H H H H
LA490
RG152
CD3
CD3
H H CD3
LA1730
H RG95
H H H H
LA491
RG153
CD3
CD3
H H CD3
LA1731
H RG96
H H H H
LA492
RG154
CD3
CD3
H H CD3
LA1732
H RG97
H H H H
LA493
RG155
CD3
CD3
H H CD3
LA1733
H RG98
H H H H
LA494
RG156
CD3
CD3
H H CD3
LA1734
H RG99
H H H H
LA495
RG157
CD3
CD3
H H CD3
LA1735
H RG100
H H H H
LA496
RG158
CD3
CD3
H H CD3
LA1736
H RG101
H H H H
LA497
RG159
CD3
CD3
H H CD3
LA1737
H RG102
H H H H
LA498
RG160
CD3
CD3
H H CD3
LA1738
H RG103
H H H H
Ligand RA1
RA2
RA3
RA4
RA5
RA6
Ligand RA1
RA2
RA3
RA4
RA5
RA6
LA499
RG161
CD3
CD3
H H CD3
LA1739
H RG104
H H H H
LA500
RG162
CD3
CD3
H H CD3
LA1740
H RG105
H H H H
LA501
RG163
CD3
CD3
H H CD3
LA1741
H RG106
H H H H
LA502
RG164
CD3
CD3
H H CD3
LA1742
H RG107
H H H H
LA503
RG165
CD3
CD3
H H CD3
LA1743
H RG108
H H H H
LA504
RG166
CD3
CD3
H H CD3
LA1744
H RG109
H H H H
LA505
RG167
CD3
CD3
H H CD3
LA1745
H RG110
H H H H
LA506
RG168
CD3
CD3
H H CD3
LA1746
H RG111
H H H H
LA507
RG169
CD3
CD3
H H CD3
LA1747
H RG112
H H H H
LA508
H RG1
CD3
H H H LA1748
H RG113
H H H H
LA509
H RG2
CD3
H H H LA1749
H RG114
H H H H
LA510
H RG3
CD3
H H H LA1750
H RG115
H H H H
LA511
H RG4
CD3
H H H LA1751
H RG116
H H H H
LA512
H RG5
CD3
H H H LA1752
H RG117
H H H H
LA513
H RG6
CD3
H H H LA1753
H RG118
H H H H
LA514
H RG7
CD3
H H H LA1754
H RG119
H H H H
LA515
H RG8
CD3
H H H LA1755
H RG120
H H H H
LA516
H RG9
CD3
H H H LA1756
H RG121
H H H H
LA517
H RG10
CD3
H H H LA1757
H RG122
H H H H
LA518
H RG11
CD3
H H H LA1758
H RG123
H H H H
LA519
H RG12
CD3
H H H LA1759
H RG124
H H H H
LA520
H RG13
CD3
H H H LA1760
H RG125
H H H H
LA521
H RG14
CD3
H H H LA1761
H RG126
H H H H
LA522
H RG15
CD3
H H H LA1762
H RG127
H H H H
LA523
H RG16
CD3
H H H LA1763
H RG128
H H H H
LA524
H RG17
CD3
H H H LA1764
H RG129
H H H H
LA525
H RG18
CD3
H H H LA1765
H RG130
H H H H
LA526
H RG19
CD3
H H H LA1766
H RG131
H H H H
LA527
H RG20
CD3
H H H LA1767
H RG132
H H H H
LA528
H RG21
CD3
H H H LA1768
H RG133
H H H H
LA529
H RG22
CD3
H H H LA1769
H RG134
H H H H
LA530
H RG23
CD3
H H H LA1770
H RG135
H H H H
LA531
H RG24
CD3
H H H LA1771
H RG136
H H H H
LA532
H RG25
CD3
H H H LA1772
H RG137
H H H H
LA533
H RG26
CD3
H H H LA1773
H RG138
H H H H
LA534
H RG27
CD3
H H H LA1774
H RG139
H H H H
LA535
H RG28
CD3
H H H LA1775
H RG140
H H H H
LA536
H RG29
CD3
H H H LA1776
H RG141
H H H H
LA537
H RG30
CD3
H H H LA1777
H RG142
H H H H
LA538
H RG31
CD3
H H H LA1778
H RG143
H H H H
LA539
H RG32
CD3
H H H LA1779
H RG144
H H H H
LA540
H RG33
CD3
H H H LA1780
H RG145
H H H H
LA541
H RG34
CD3
H H H LA1781
H RG146
H H H H
LA542
H RG35
CD3
H H H LA1782
H RG147
H H H H
LA543
H RG36
CD3
H H H LA1783
H RG148
H H H H
LA544
H RG37
CD3
H H H LA1784
H RG149
H H H H
LA545
H RG38
CD3
H H H LA1785
H RG150
H H H H
LA546
H RG39
CD3
H H H LA1786
H RG151
H H H H
LA547
H RG40
CD3
H H H LA1787
H RG152
H H H H
LA548
H RG41
CD3
H H H LA1788
H RG153
H H H H
LA549
H RG42
CD3
H H H LA1789
H RG154
H H H H
LASS0
H RG43
CD3
H H H LA1790
H RG155
H H H H
LA551
H RG44
CD3
H H H LA1791
H RG156
H H H H
LA552
H RG45
CD3
H H H LA1792
H RG157
H H H H
LA553
H RG46
CD3
H H H LA1793
H RG158
H H H H
LA554
H RG47
CD3
H H H LA1794
H RG159
H H H H
LA555
H RG48
CD3
H H H LA1795
H RG160
H H H H
LA556
H RG49
CD3
H H H LA1796
H RG161
H H H H
LA557
H RG50
CD3
H H H LA1797
H RG162
H H H H
LA558
H RG51
CD3
H H H LA1798
H RG163
H H H H
LA559
H RG52
CD3
H H H LA1799
H RG164
H H H H
LA560
H RG53
CD3
H H H LA1800
H RG165
H H H H
LA561
H RG54
CD3
H H H LA1801
H RG166
H H H H
LA562
H RG55
CD3
H H H LA1802
H RG167
H H H H
LA563
H RG56
CD3
H H H LA1803
H RG168
H H H H
LA564
H RG57
CD3
H H H LA1804
H RG169
H H H H
LA565
H RG58
CD3
H H H LA1805
H H RG1
H H H
LA566
H RG59
CD3
H H H LA1806
H H RG2
H H H
LA567
H RG60
CD3
H H H LA1807
H H RG3
H H H
LA568
H RG61
CD3
H H H LA1808
H H RG4
H H H
LA569
H RG62
CD3
H H H LA1809
H H RG5
H H H
LA570
H RG63
CD3
H H H LA1810
H H RG6
H H H
LA571
H RG64
CD3
H H H LA1811
H H RG7
H H H
LA572
H RG65
CD3
H H H LA1812
H H RG8
H H H
LA573
H RG66
CD3
H H H LA1813
H H RG9
H H H
LA574
H RG67
CD3
H H H LA1814
H H RG10
H H H
LA575
H RG68
CD3
H H H LA1815
H H RG11
H H H
LA576
H RG69
CD3
H H H LA1816
H H RG12
H H H
LA577
H RG70
CD3
H H H LA1817
H H RG13
H H H
LA578
H RG71
CD3
H H H LA1818
H H RG14
H H H
LA579
H RG72
CD3
H H H LA1819
H H RG15
H H H
LA580
H RG73
CD3
H H H LA1820
H H RG16
H H H
LA581
H RG74
CD3
H H H LA1821
H H RG17
H H H
LA582
H RG75
CD3
H H H LA1822
H H RG18
H H H
LA583
H RG76
CD3
H H H LA1823
H H RG19
H H H
LA584
H RG77
CD3
H H H LA1824
H H RG20
H H H
LA585
H RG78
CD3
H H H LA1825
H H RG21
H H H
LA586
H RG79
CD3
H H H LA1826
H H RG22
H H H
LA587
H RG80
CD3
H H H LA1827
H H RG23
H H H
LA588
H RG81
CD3
H H H LA1828
H H RG24
H H H
LA589
H RG82
CD3
H H H LA1829
H H RG25
H H H
LA590
H RG83
CD3
H H H LA1830
H H RG26
H H H
LA591
H RG84
CD3
H H H LA1831
H H RG27
H H H
LA592
H RG85
CD3
H H H LA1832
H H RG28
H H H
LA593
H RG86
CD3
H H H LA1833
H H RG29
H H H
LA594
H RG87
CD3
H H H LA1834
H H RG30
H H H
LA595
H RG88
CD3
H H H LA1835
H H RG31
H H H
LA596
H RG89
CD3
H H H LA1836
H H RG32
H H H
LA597
H RG90
CD3
H H H LA1837
H H RG33
H H H
LA598
H RG91
CD3
H H H LA1838
H H RG34
H H H
LA599
H RG92
CD3
H H H LA1839
H H RG35
H H H
LA600
H RG93
CD3
H H H LA1840
H H RG36
H H H
LA601
H RG94
CD3
H H H LA1841
H H RG37
H H H
LA602
H RG95
CD3
H H H LA1842
H H RG38
H H H
LA603
H RG96
CD3
H H H LA1843
H H RG39
H H H
LA604
H RG97
CD3
H H H LA1844
H H RG40
H H H
LA605
H RG98
CD3
H H H LA1845
H H RG41
H H H
LA606
H RG99
CD3
H H H LA1846
H H RG42
H H H
LA607
H RG100
CD3
H H H LA1847
H H RG43
H H H
LA608
H RG101
CD3
H H H LA1848
H H RG44
H H H
LA609
H RG102
CD3
H H H LA1849
H H RG45
H H H
LA610
H RG103
CD3
H H H LA1850
H H RG46
H H H
LA611
H RG104
CD3
H H H LA1851
H H RG47
H H H
LA612
H RG105
CD3
H H H LA1852
H H RG48
H H H
LA613
H RG106
CD3
H H H LA1853
H H RG49
H H H
LA614
H RG107
CD3
H H H LA1854
H H RG50
H H H
LA615
H RG108
CD3
H H H LA1855
H H RG51
H H H
LA616
H RG109
CD3
H H H LA1856
H H RG52
H H H
LA617
H RG110
CD3
H H H LA1857
H H RG53
H H H
LA618
H RG111
CD3
H H H LA1858
H H RG54
H H H
LA619
H RG112
CD3
H H H LA1859
H H RG55
H H H
LA620
H RG113
CD3
H H H LA1860
H H RG56
H H H
LA621
H RG114
CD3
H H H LA1861
H H RG57
H H H
LA622
H RG115
CD3
H H H LA1862
H H RG58
H H H
LA623
H RG116
CD3
H H H LA1863
H H RG59
H H H
LA624
H RG117
CD3
H H H LA1864
H H RG60
H H H
LA625
H RG118
CD3
H H H LA1865
H H RG61
H H H
LA626
H RG119
CD3
H H H LA1866
H H RG62
H H H
LA627
H RG120
CD3
H H H LA1867
H H RG63
H H H
LA628
H RG121
CD3
H H H LA1868
H H RG64
H H H
LA629
H RG122
CD3
H H H LA1869
H H RG65
H H H
LA630
H RG123
CD3
H H H LA1870
H H RG66
H H H
LA631
H RG124
CD3
H H H LA1871
H H RG67
H H H
LA632
H RG125
CD3
H H H LA1872
H H RG68
H H H
LA633
H RG126
CD3
H H H LA1873
H H RG69
H H H
LA634
H RG127
CD3
H H H LA1874
H H RG70
H H H
LA635
H RG128
CD3
H H H LA1875
H H RG71
H H H
LA636
H RG129
CD3
H H H LA1876
H H RG72
H H H
LA637
H RG130
CD3
H H H LA1877
H H RG73
H H H
LA638
H RG131
CD3
H H H LA1878
H H RG74
H H H
LA639
H RG132
CD3
H H H LA1879
H H RG75
H H H
LA640
H RG133
CD3
H H H LA1880
H H RG76
H H H
LA641
H RG134
CD3
H H H LA1881
H H RG77
H H H
LA642
H RG135
CD3
H H H LA1882
H H RG78
H H H
LA643
H RG136
CD3
H H H LA1883
H H RG79
H H H
LA644
H RG137
CD3
H H H LA1884
H H RG80
H H H
LA645
H RG138
CD3
H H H LA1885
H H RG81
H H H
LA646
H RG139
CD3
H H H LA1886
H H RG82
H H H
LA647
H RG140
CD3
H H H LA1887
H H RG83
H H H
LA648
H RG141
CD3
H H H LA1888
H H RG84
H H H
LA649
H RG142
CD3
H H H LA1889
H H RG85
H H H
LA650
H RG1 4 3
CD3
H H H LA1890
H H RG86
H H H
LA651
H RG1 4 4
CD3
H H H LA1891
H H RG87
H H H
LA652
H RG1 4 5
CD3
H H H LA1892
H H RG88
H H H
LA653
H RG1 4 6
CD3
H H H LA1893
H H RG89
H H H
LA654
H RG1 4 7
CD3
H H H LA1894
H H RG90
H H H
LA655
H RG1 4 8
CD3
H H H LA1895
H H RG91
H H H
LA656
H RG1 4 9
CD3
H H H LA1896
H H RG92
H H H
LA657
H RG1 5 0
CD3
H H H LA1897
H H RG93
H H H
LA658
H RG1 5 1
CD3
H H H LA1898
H H RG94
H H H
LA659
H RG1 5 2
CD3
H H H LA1899
H H RG95
H H H
LA660
H RG1 5 3
CD3
H H H LA1900
H H RG96
H H H
LA661
H RG1 5 4
CD3
H H H LA1901
H H RG97
H H H
LA662
H RG1 5 5
CD3
H H H LA1902
H H RG98
H H H
LA663
H RG1 5 6
CD3
H H H LA1903
H H RG99
H H H
LA664
H RG1 5 7
CD3
H H H LA1904
H H RG100
H H H
LA665
H RG158
CD3
H H H LA1905
H H RG101
H H H
LA666
H RG159
CD3
H H H LA1906
H H RG102 H H H
LA667
H RG160
CD3
H H H LA1907
H H RG103
H H H
LA668
H RG161
CD3
H H H LA1908
H H RG104
H H H
LA669
H RG162
CD3
H H H LA1909
H H RG105
H H H
LA670
H RG163
CD3
H H H LA1910
H H RG106
H H H
LA671
H RG164
CD3
H H H LA1911
H H RG107
H H H
LA672
H RG165
CD3
H H H LA1912
H H RG108
H H H
LA673
H RG166
CD3
H H H LA1913
H H RG109
H H H
LA674
H RG167
CD3
H H H LA1914
H H RG110
H H H
LA675
H RG168
CD3
H H H LA1915
H H RG111
H H H
LA676
H RG169
CD3
H H H LA1916
H H RG112
H H H
LA677
CD3 RG1
CD3
H H CD3
LA1917
H H RG113
H H H
LA678
CD3 RG2
CD3
H H CD3
LA1918
H H RG114
H H H
LA679
CD3 RG3
CD3
H H CD3
LA1919
H H RG1 1 5
H H H
LA680
CD3 RG4
CD3
H H CD3
LA1920
H H RG116
H H H
LA681
CD3 RG5
CD3
H H CD3
LA1921
H H RG117
H H H
LA682
CD3 RG6
CD3
H H CD3
LA1922
H H RG118
H H H
LA683
CD3 RG7
CD3
H H CD3
LA1923
H H RG119
H H H
LA684
CD3 RG8
CD3
H H CD3
LA1924
H H RG120
H H H
LA685
CD3 RG9
CD3
H H CD3
LA1925
H H RG121
H H H
LA686
CD3 RG10
CD3
H H CD3
LA1926
H H RG122
H H H
LA687
CD3 RG11
CD3
H H CD3
LA1927
H H RG123
H H H
LA688
CD3 RG12
CD3
H H CD3
LA1928
H H RG124
H H H
LA689
CD3 RG13
CD3
H H CD3
LA1929
H H RG125
H H H
LA690
CD3 RG14
CD3
H H CD3
LA1930
H H RG126
H H H
LA691
CD3 RG15
CD3
H H CD3
LA1931
H H RG127
H H H
LA692
CD3 RG16
CD3
H H CD3
LA1932
H H RG128
H H H
LA693
CD3 RG17
CD3
H H CD3
LA1933
H H RG12 9
H H H
LA694
CD3 RG18
CD3
H H CD3
LA1934
H H RG1 3 0
H H H
LA695
CD3 RG19
CD3
H H CD3
LA1935
H H RG1 3 1
H H H
LA696
CD3 RG20
CD3
H H CD3
LA1936
H H RG1 3 2
H H H
LA697
CD3 RG21
CD3
H H CD3
LA1937
H H RG1 3 3
H H H
LA698
CD3 RG22
CD3
H H CD3
LA1938
H H RG1 3 4
H H H
LA699
CD3 RG23
CD3
H H CD3
LA1939
H H RG1 3 5
H H H
LA700
CD3 RG24
CD3
H H CD3
LA1940
H H RG1 3 6
H H H
LA701
CD3 RG25
CD3
H H CD3
LA1941
H H RG1 3 7
H H H
LA702
CD3
RG26
CD3
H H CD3
LA1942
H H RG1 3 8
H H H
LA703
CD3
RG27
CD3
H H CD3
LA1943
H H RG1 3 9
H H H
LA704
CD3
RG28
CD3
H H CD3
LA1944
H H RG1 4 0
H H H
LA705
CD3
RG29
CD3
H H CD3
LA1945
H H RG1 4 1
H H H
LA706
CD3
RG30
CD3
H H CD3
LA1946
H H RG1 4 2
H H H
LA707
CD3
RG31
CD3
H H CD3
LA1947
H H RG1 4 3
H H H
LA708
CD3
RG32
CD3
H H CD3
LA1948
H H RG1 4 4
H H H
LA709
CD3
RG33
CD3
H H CD3
LA1949
H H RG1 4 5
H H H
LA710
CD3
RG34
CD3
H H CD3
LA1950
H H RG1 4 6
H H H
LA711
CD3
RG35
CD3
H H CD3
LA1951
H H RG1 4 7
H H H
LA712
CD3
RG36
CD3
H H CD3
LA1952
H H RG1 4 8
H H H
LA713
CD3
RG37
CD3
H H CD3
LA1953
H H RG1 4 9
H H H
LA714
CD3
RG38
CD3
H H CD3
LA1954
H H RG1 5 0
H H H
LA715
CD3
RG39
CD3
H H CD3
LA1955
H H RG151
H H H
LA716
CD3
RG40
CD3
H H CD3
LA1956
H H RG152
H H H
LA717
CD3
RG41
CD3
H H CD3
LA1957
H H RG151 3
H H H
LA718
CD3
RG42
CD3
H H CD3
LA1958
H H RG154
H H H
LA719
CD3
RG43
CD3
H H CD3
LA1959
H H RG155
H H H
LA720
CD3
RG44
CD3
H H CD3
LA1960
H H RG156
H H H
LA721
CD3
RG45
CD3
H H CD3
LA1961
H H RG157
H H H
LA722
CD3
RG46
CD3
H H CD3
LA1962
H H RG158
H H H
LA723
CD3
RG47
CD3
H H CD3
LA1963
H H RG159
H H H
LA724
CD3
RG48
CD3
H H CD3
LA1964
H H RG160
H H H
LA725
CD3
RG49
CD3
H H CD3
LA1965
H H RG161
H H H
LA726
CD3
RG50
CD3
H H CD3
LA1966
H H RG162
H H H
LA727
CD3
RG51
CD3
H H CD3
LA1967
H H RG163
H H H
LA728
CD3
RG52
CD3
H H CD3
LA1968
H H RG164
H H H
LA729
CD3
RG53
CD3
H H CD3
LA1969
H H RG165
H H H
LA730
CD3
RG54
CD3
H H CD3
LA1970
H H RG166
H H H
LA731
CD3
RG55
CD3
H H CD3
LA1971
H H RG167
H H H
LA732
CD3
RG56
CD3
H H CD3
LA1972
H H RG168
H H H
LA733
CD3
RG57
CD3
H H CD3
LA1973
H H RG169
H H H
LA734
CD3
RG58
CD3
H H CD3
LA1974
H H H RG1
H H
LA735
CD3
RG59
CD3
H H CD3
LA1975
H H H RG2
H H
LA736
CD3
RG60
CD3
H H CD3
LA1976
H H H RG3
H H
LA737
CD3
RG61
CD3
H H CD3
LA1977
H H H RG4
H H
LA738
CD3
RG62
CD3
H H CD3
LA1978
H H H RG5
H H
LA739
CD3
RG63
CD3
H H CD3
LA1979
H H H RG6
H H
LA740
CD3
RG64
CD3
H H CD3
LA1980
H H H RG7
H H
LA741
CD3
RG65
CD3
H H CD3
LA1981
H H H RG8
H H
LA742
CD3
RG66
CD3
H H CD3
LA1982
H H H RG9
H H
LA743
CD3
RG67
CD3
H H CD3
LA1983
H H H RG10
H H
LA744
CD3
RG68
CD3
H H CD3
LA1984
H H H RG11
H H
LA745
CD3
RG69
CD3
H H CD3
LA1985
H H H RG12
H H
LA746
CD3
RG70
CD3
H H CD3
LA1986
H H H RG13
H H
LA747
CD3
RG71
CD3
H H CD3
LA1987
H H H RG14
H H
LA748
CD3
RG72
CD3
H H CD3
LA1988
H H H RG15
H H
LA749
CD3
RG73
CD3
H H CD3
LA1989
H H H RG16
H H
LA750
CD3
RG74
CD3
H H CD3
LA1990
H H H RG17
H H
LA751
CD3
RG75
CD3
H H CD3
LA1991
H H H RG18
H H
LA752
CD3
RG76
CD3
H H CD3
LA1992
H H H RG19
H H
LA753
CD3
RG77
CD3
H H CD3
LA1993
H H H RG20
H H
LA754
CD3
RG78
CD3
H H CD3
LA1994
H H H RG21
H H
LA755
CD3
RG79
CD3
H H CD3
LA1995
H H H RG22
H H
LA756
CD3
RG80
CD3
H H CD3
LA1996
H H H RG23
H H
LA757
CD3
RG81
CD3
H H CD3
LA1997
H H H RG24
H H
LA758
CD3
RG82
CD3
H H CD3
LA1998
H H H RG25
H H
LA759
CD3
RG83
CD3
H H CD3
LA1999
H H H RG26
H H
LA760
CD3
RG84
CD3
H H CD3
LA2000
H H H RG27
H H
LA761
CD3
RG85
CD3
H H CD3
LA2001
H H H RG28
H H
LA762
CD3
RG86
CD3
H H CD3
LA2002
H H H RG29
H H
LA763
CD3
RG87
CD3
H H CD3
LA2003
H H H RG30
H H
LA764
CD3
RG88
CD3
H H CD3
LA2004
H H H RG31
H H
LA765
CD3
RG89
CD3
H H CD3
LA2005
H H H RG32
H H
LA766
CD3
RG90
CD3
H H CD3
LA2006
H H H RG33
H H
LA767
CD3
RG91
CD3
H H CD3
LA2007
H H H RG34
H H
LA768
CD3
RG92
CD3
H H CD3
LA2008
H H H RG35
H H
LA769
CD3
RG93
CD3
H H CD3
LA2009
H H H RG36
H H
LA770
CD3
RG94
CD3
H H CD3
LA2010
H H H RG37
H H
LA771
CD3
RG95
CD3
H H CD3
LA2011
H H H RG38
H H
LA772
CD3
RG96
CD3
H H CD3
LA2012
H H H RG39
H H
LA773
CD3
RG97
CD3
H H CD3
LA2013
H H H RG40
H H
LA774
CD3
RG98
CD3
H H CD3
LA2014
H H H RG41
H H
LA775
CD3
RG99
CD3
H H CD3
LA2015
H H H RG42
H H
LA776
CD3
RG100
CD3
H H CD3
LA2016
H H H RG43
H H
LA777
CD3
RG101
CD3
H H CD3
LA2017
H H H RG44
H H
LA778
CD3
RG102
CD3
H H CD3
LA2018
H H H RG45
H H
LA779
CD3
RG103
CD3
H H CD3
LA2019
H H H RG46
H H
LA780
CD3
RG104
CD3
H H CD3
LA2020
H H H RG47
H H
LA781
CD3
RG105
CD3
H H CD3
LA2021
H H H RG48
H H
LA782
CD3
RG106
CD3
H H CD3
LA2022
H H H RG49
H H
LA783
CD3
RG107
CD3
H H CD3
LA2023
H H H RG50
H H
LA784
CD3
RG108
CD3
H H CD3
LA2024
H H H RG51
H H
LA785
CD3
RG109
CD3
H H CD3
LA2025
H H H RG52
H H
LA786
CD3
RG110
CD3
H H CD3
LA2026
H H H RG53
H H
LA787
CD3
RG111
CD3
H H CD3
LA2027
H H H RG54
H H
LA788
CD3
RG112
CD3
H H CD3
LA2028
H H H RG55
H H
LA789
CD3
RG113
CD3
H H CD3
LA2029
H H H RG56
H H
LA790
CD3
RG114
CD3
H H CD3
LA2030
H H H RG57
H H
LA791
CD3
RG115
CD3
H H CD3
LA2031
H H H RG58
H H
LA792
CD3
RG116
CD3
H H CD3
LA2032
H H H RG59
H H
LA793
CD3
RG117
CD3
H H CD3
LA2033
H H H RG60
H H
LA794
CD3
RG118
CD3
H H CD3
LA2034
H H H RG61
H H
LA795
CD3
RG119
CD3
H H CD3
LA2035
H H H RG62
H H
LA796
CD3
RG120
CD3
H H CD3
LA2036
H H H RG63
H H
LA797
CD3
RG121
CD3
H H CD3
LA2037
H H H RG64
H H
LA798
CD3
RG122
CD3
H H CD3
LA2038
H H H RG65
H H
LA799
CD3
RG123
CD3
H H CD3
LA2039
H H H RG66
H H
LA800
CD3
RG124
CD3
H H CD3
LA2040
H H H RG67
H H
LA801
CD3
RG125
CD3
H H CD3
LA2041
H H H RG68
H H
LA802
CD3
RG126
CD3
H H CD3
LA2042
H H H RG69
H H
LA803
CD3
RG127
CD3
H H CD3
LA2043
H H H RG70
H H
LA804
CD3
RG128
CD3
H H CD3
LA2044
H H H RG71
H H
LA805
CD3
RG129
CD3
H H CD3
LA2045
H H H RG72
H H
LA806
CD3
RG130
CD3
H H CD3
LA2046
H H H RG73
H H
LA807
CD3
RG131
CD3
H H CD3
LA2047
H H H RG74
H H
LA808
CD3
RG132
CD3
H H CD3
LA2048
H H H RG75
H H
LA809
CD3
RG133
CD3
H H CD3
LA2049
H H H RG76
H H
LA810
CD3
RG134
CD3
H H CD3
LA2050
H H H RG77
H H
LA811
CD3
RG135
CD3
H H CD3
LA2051
H H H RG78
H H
LA812
CD3
RG136
CD3
H H CD3
LA2052
H H H RG79
H H
LA813
CD3
RG137
CD3
H H CD3
LA2053
H H H RG80
H H
LA814
CD3
RG138
CD3
H H CD3
LA2054
H H H RG81
H H
LA815
CD3
RG139
CD3
H H CD3
LA2055
H H H RG82
H H
LA816
CD3
RG140
CD3
H H CD3
LA2056
H H H RG83
H H
LA817
CD3
RG141
CD3
H H CD3
LA2057
H H H RG84
H H
LA818
CD3
RG142
CD3
H H CD3
LA2058
H H H RG85
H H
LA819
CD3
RG143
CD3
H H CD3
LA2059
H H H RG86
H H
LA820
CD3
RG144
CD3
H H CD3
LA2060
H H H RG87
H H
LA821
CD3
RG145
CD3
H H CD3
LA2061
H H H RG88
H H
LA822
CD3
RG146
CD3
H H CD3
LA2062
H H H RG89
H H
LA823
CD3
RG147
CD3
H H CD3
LA2063
H H H RG90
H H
LA824
CD3
RG148
CD3
H H CD3
LA2064
H H H RG91
H H
LA825
CD3
RG149
CD3
H H CD3
LA2065
H H H RG92
H H
LA826
CD3
RG150
CD3
H H CD3
LA2066
H H H RG93
H H
LA827
CD3
RG151
CD3
H H CD3
LA2067
H H H RG94
H H
LA828
CD3
RG152
CD3
H H CD3
LA2068
H H H RG95
H H
LA829
CD3
RG153
CD3
H H CD3
LA2069
H H H RG96
H H
LA830
CD3
RG154
CD3
H H CD3
LA2070
H H H RG97
H H
LA831
CD3
RG155
CD3
H H CD3
LA2071
H H H RG98
H H
LA832
CD3
RG156
CD3
H H CD3
LA2072
H H H RG99
H H
LA833
CD3
RG157
CD3
H H CD3
LA2073
H H H RG100
H H
LA834
CD3
RG158
CD3
H H CD3
LA2074
H H H RG101
H H
LA835
CD3
RG159
CD3
H H CD3
LA2075
H H H RG102
H H
LA836
CD3
RG160
CD3
H H CD3
LA2076
H H H RG103
H H
LA837
CD3
RG161
CD3
H H CD3
LA2077
H H H RG104
H H
LA838
CD3
RG162
CD3
H H CD3
LA2078
H H H RG105
H H
LA839
CD3
RG163
CD3
H H CD3
LA2079
H H H RG106
H H
LA840
CD3
RG164
CD3
H H CD3
LA2080
H H H RG107
H H
LA841
CD3
RG165
CD3
H H CD3
LA2081
H H H RG108
H H
LA842
CD3
RG166
CD3
H H CD3
LA2082
H H H RG10 9
H H
LA843
CD3
RG167
CD3
H H CD3
LA2083
H H H RG110
H H
LA844
CD3
RG168
CD3
H H CD3
LA2084
H H H RG111
H H
LA845
CD3
RG169
CD3
H H CD3
LA2085
H H H RG112
H H
LA846
CD3
RG1
CD3
H H H LA2086
H H H RG113
H H
LA847
CD3
RG2
CD3
H H H LA2087
H H H RG114
H H
LA848
CD3
RG3
CD3
H H H LA2088
H H H RG11 5
H H
LA849
CD3
RG4
CD3
H H H LA2089
H H H RG116
H H
LA850
CD3
RG5
CD3
H H H LA2090
H H H RG117
H H
LA851
CD3
RG6
CD3
H H H LA2091
H H H RG118
H H
LA852
CD3
RG7
CD3
H H H LA2092
H H H RG119
H H
LA853
CD3
RG8
CD3
H H H LA2093
H H H RG120
H H
LA854
CD3
RG9
CD3
H H H LA2094
H H H RG12 1
H H
LA855
CD3
RG10
CD3
H H H LA2095
H H H RG122
H H
LA856
CD3
RG11
CD3
H H H LA2096
H H H RG123
H H
LA857
CD3
RG12
CD3
H H H LA2097
H H H RG124
H H
LA858
CD3
RG13
CD3
H H H LA2098
H H H RG125
H H
LA859
CD3
RG14
CD3
H H H LA2099
H H H RG126
H H
LA860
CD3
RG15
CD3
H H H LA2100
H H H RG127
H H
LA861
CD3
RG16
CD3
H H H LA2101
H H H RG12 8
H H
LA862
CD3
RG17
CD3
H H H LA2102
H H H RG129
H H
LA863
CD3
RG18
CD3
H H H LA2103
H H H RG130
H H
LA864
CD3
RG19
CD3
H H H LA2104
H H H RG131
H H
LA865
CD3
RG20
CD3
H H H LA2105
H H H RG132
H H
LA866
CD3
RG21
CD3
H H H LA2106
H H H RG133
H H
LA867
CD3
RG22
CD3
H H H LA2107
H H H RG134
H H
LA868
CD3
RG23
CD3
H H H LA2108
H H H RG135
H H
LA869
CD3
RG24
CD3
H H H LA2109
H H H RG136
H H
LA870
CD3
RG25
CD3
H H H LA2110
H H H RG137
H H
LA871
CD3
RG26
CD3
H H H LA2111
H H H RG138
H H
LA872
CD3
RG27
CD3
H H H LA2112
H H H RG139
H H
LA873
CD3
RG28
CD3
H H H LA2113
H H H RG1 4 0
H H
LA874
CD3
RG29
CD3
H H H LA2114
H H H RG1 4 1
H H
LA875
CD3
RG30
CD3
H H H LA2115
H H H RG1 4 2
H H
LA876
CD3
RG31
CD3
H H H LA2116
H H H RG1 4 3
H H
LA877
CD3
RG32
CD3
H H H LA2117
H H H RG1 4 4
H H
LA878
CD3
RG33
CD3
H H H LA2118
H H H RG1 4 5
H H
LA879
CD3
RG34
CD3
H H H LA2119
H H H RG1 4 6
H H
LA880
CD3
RG35
CD3
H H H LA2120
H H H RG1 4 7
H H
LA881
CD3
RG36
CD3
H H H LA2121
H H H RG1 4 8
H H
LA882
CD3
RG37
CD3
H H H LA2122
H H H RG1 4 9
H H
LA883
CD3
RG 38
CD3
H H H LA2123
H H H RG1 5 0
H H
LA884
CD3
RG39
CD3
H H H LA2124
H H H RG1 5 1
H H
LA885
CD3
RG40
CD3
H H H LA2125
H H H RG1 5 2
H H
LA886
CD3
RG41
CD3
H H H LA2126
H H H RG1 5 3
H H
LA887
CD3
RG42
CD3
H H H LA2127
H H H RG1 5 4
H H
LA888
CD3
RG43
CD3
H H H LA2128
H H H RG1 5 5
H H
LA889
CD3
RG44
CD3
H H H LA2129
H H H RG1 5 6
H H
LA890
CD3
RG45
CD3
H H H LA2130
H H H RG1 5 7
H H
LA891
CD3
RG46
CD3
H H H LA2131
H H H RG1 5 8
H H
LA892
CD3
RG47
CD3
H H H LA2132
H H H RG1 5 9
H H
LA893
CD3
RG48
CD3
H H H LA2133
H H H RG1 6 0
H H
LA894
CD3
RG49
CD3
H H H LA2134
H H H RG1 6 1
H H
LA895
CD3
RG50
CD3
H H H LA2135
H H H RG1 6 2
H H
LA896
CD3
RG51
CD3
H H H LA2136
H H H RG1 6 3
H H
LA897
CD3
RG52
CD3
H H H LA2137
H H H RG1 6 4
H H
LA898
CD3
RG53
CD3
H H H LA2138
H H H RG1 6 5
H H
LA899
CD3
RG54
CD3
H H H LA2139
H H H RG1 6 6
H H
LA900
CD3
RG55
CD3
H H H LA2140
H H H RG1 6 7
H H
LA901
CD3
RG56
CD3
H H H LA2141
H H H RG1 6 8
H H
LA902
CD3
RG57
CD3
H H H LA2142
H H H RG1 6 9
H H
LA903
CD3
RG58
CD3
H H H LA2143
H H H H RG1
H
LA904
CD3
RG 5 9
CD3
H H H LA2144
H H H H RG2
H
LA905
CD3
RG60
CD3
H H H LA2145
H H H H RG3
H
LA906
CD3
RG61
CD3
H H H LA2146
H H H H RG4
H
LA907
CD3
RG62
CD3
H H H LA2147
H H H H RG5
H
LA908
CD3
RG63
CD3
H H H LA2148
H H H H RG6
H
LA909
CD3
RG64
CD3
H H H LA2149
H H H H RG7
H
LA910
CD3
RG65
CD3
H H H LA2150
H H H H RG8
H
LA911
CD3
RG66
CD3
H H H LA2151
H H H H RG9
H
LA912
CD3
RG67
CD3
H H H LA2152
H H H H RG10
H
LA913
CD3
RG68
CD3
H H H LA2153
H H H H RG11
H
LA914
CD3
RG69
CD3
H H H LA2154
H H H H RG12
H
LA915
CD3
RG70
CD3
H H H LA2155
H H H H RG13
H
LA916
CD3
RG71
CD3
H H H LA2156
H H H H RG14
H
LA917
CD3
RG72
CD3
H H H LA2157
H H H H RG15
H
LA918
CD3
RG73
CD3
H H H LA2158
H H H H RG16
H
LA919
CD3
RG74
CD3
H H H LA2159
H H H H RG17
H
LA920
CD3
RG75
CD3
H H H LA2160
H H H H RG18
H
LA921
CD3
RG76
CD3
H H H LA2161
H H H H RG19
H
LA922
CD3
RG77
CD3
H H H LA2162
H H H H RG20
H
LA923
CD3
RG78
CD3
H H H LA2163
H H H H RG21
H
LA924
CD3
RG79
CD3
H H H LA2164
H H H H RG22
H
LA925
CD3
RG80
CD3
H H H LA2165
H H H H RG23
H
LA926
CD3
RG81
CD3
H H H LA2166
H H H H RG24
H
LA927
CD3
RG82
CD3
H H H LA2167
H H H H RG25
H
LA928
CD3
RG83
CD3
H H H LA2168
H H H H RG26
H
LA929
CD3
RG84
CD3
H H H LA2169
H H H H RG27
H
LA930
CD3
RG85
CD3
H H H LA2170
H H H H RG28
H
LA931
CD3
RG86
CD3
H H H LA2171
H H H H RG29
H
LA932
CD3
RG87
CD3
H H H LA2172
H H H H RG30
H
LA933
CD3
RG88
CD3
H H H LA2173
H H H H RG31
H
LA934
CD3
RG89
CD3
H H H LA2174
H H H H RG32
H
LA935
CD3
RG90
CD3
H H H LA2175
H H H H RG33
H
LA936
CD3
RG91
CD3
H H H LA2176
H H H H RG34
H
LA937
CD3
RG92
CD3
H H H LA2177
H H H H RG35
H
LA938
CD3
RG93
CD3
H H H LA2178
H H H H RG36
H
LA939
CD3
RG94
CD3
H H H LA2179
H H H H RG37
H
LA940
CD3
RG95
CD3
H H H LA2180
H H H H RG38
H
LA941
CD3
RG96
CD3
H H H LA2181
H H H H RG39
H
LA942
CD3
RG97
CD3
H H H LA2182
H H H H RG40
H
LA943
CD3
RG98
CD3
H H H LA2183
H H H H RG41
H
LA944
CD3
RG99
CD3
H H H LA2184
H H H H RG42
H
LA945
CD3
RG100
CD3
H H H LA2185
H H H H RG43
H
LA946
CD3
RG101
CD3
H H H LA2186
H H H H RG44
H
LA947
CD3
RG102
CD3
H H H LA2187
H H H H RG45
H
LA948
CD3
RG103
CD3
H H H LA2188
H H H H RG46
H
LA949
CD3
RG104
CD3
H H H LA2189
H H H H RG47
H
LA950
CD3
RG105
CD3
H H H LA2190
H H H H RG48
H
LA951
CD3
RG106
CD3
H H H LA2191
H H H H RG49
H
LA952
CD3
RG107
CD3
H H H LA2192
H H H H RG50
H
LA953
CD3
RG108
CD3
H H H LA2193
H H H H RG51
H
LA954
CD3
RG109
CD3
H H H LA2194
H H H H RG52
H
LA955
CD3
RG110
CD3
H H H LA2195
H H H H RG53
H
LA956
CD3
RG111
CD3
H H H LA2196
H H H H RG54
H
LA957
CD3
RG112
CD3
H H H LA2197
H H H H RG55
H
LA958
CD3
RG113
CD3
H H H LA2198
H H H H RG56
H
LA959
CD3
RG114
CD3
H H H LA2199
H H H H RG57
H
LA960
CD3
RG115
CD3
H H H LA2200
H H H H RG58
H
LA961
CD3
RG116
CD3
H H H LA2201
H H H H RG59
H
LA962
CD3
RG117
CD3
H H H LA2202
H H H H RG60
H
LA963
CD3
RG118
CD3
H H H LA2203
H H H H RG61
H
LA964
CD3
RG119
CD3
H H H LA2204
H H H H RG62
H
LA965
CD3
RG120
CD3
H H H LA2205
H H H H RG63
H
LA966
CD3
RG121
CD3
H H H LA2206
H H H H RG64
H
LA967
CD3
RG122
CD3
H H H LA2207
H H H H RG65
H
LA968
CD3
RG123
CD3
H H H LA2208
H H H H RG66
H
LA969
CD3
RG124
CD3
H H H LA2209
H H H H RG67
H
LA970
CD3
RG125
CD3
H H H LA2210
H H H H RG68
H
LA971
CD3
RG126
CD3
H H H LA2211
H H H H RG69
H
LA972
CD3
RG127
CD3
H H H LA2212
H H H H RG70
H
LA973
CD3
RG128
CD3
H H H LA2213
H H H H RG71
H
LA974
CD3
RG129
CD3
H H H LA2214
H H H H RG72
H
LA975
CD3
RG130
CD3
H H H LA2215
H H H H RG73
H
LA976
CD3
RG131
CD3
H H H LA2216
H H H H RG74
H
LA977
CD3
RG132
CD3
H H H LA2217
H H H H RG75
H
LA978
CD3
RG133
CD3
H H H LA2218
H H H H RG76
H
LA979
CD3
RG134
CD3
H H H LA2219
H H H H RG77
H
LA980
CD3
RG135
CD3
H H H LA2220
H H H H RG78
H
LA981
CD3
RG136
CD3
H H H LA2221
H H H H RG79
H
LA982
CD3
RG137
CD3
H H H LA2222
H H H H RG80
H
LA983
CD3
RG138
CD3
H H H LA2223
H H H H RG81
H
LA984
CD3
RG139
CD3
H H H LA2224
H H H H RG82
H
LA985
CD3
RG140
CD3
H H H LA2225
H H H H RG83
H
LA986
CD3
RG141
CD3
H H H LA2226
H H H H RG84
H
LA987
CD3
RG142
CD3
H H H LA2227
H H H H RG85
H
LA988
CD3
RG143
CD3
H H H LA2228
H H H H RG86
H
LA989
CD3
RG144
CD3
H H H LA2229
H H H H RG87
H
LA990
CD3
RG145
CD3
H H H LA2230
H H H H RG88
H
LA991
CD3
RG146
CD3
H H H LA2231
H H H H RG89
H
LA992
CD3
RG147
CD3
H H H LA2232
H H H H RG90
H
LA993
CD3
RG148
CD3
H H H LA2233
H H H H RG91
H
LA994
CD3
RG149
CD3
H H H LA2234
H H H H RG92
H
LA995
CD3
RG150
CD3
H H H LA2235
H H H H RG93
H
LA996
CD3
RG151
CD3
H H H LA2236
H H H H RG94
H
LA997
CD3
RG152
CD3
H H H LA2237
H H H H RG95
H
LA998
CD3
RG153
CD3
H H H LA2238
H H H H RG96
H
LA999
CD3
RG154
CD3
H H H LA2239
H H H H RG97
H
LA1000
CD3
RG155
CD3
H H H LA2240
H H H H RG98
H
LA1001
CD3
RG156
CD3
H H H LA2241
H H H H RG99
H
LA1002
CD3
RG157
CD3
H H H LA2242
H H H H RG100
H
LA1003
CD3
RG158
CD3
H H H LA2243
H H H H RG101
H
LA1004
CD3
RG159
CD3
H H H LA2244
H H H H RG102
H
LA1005
CD3
RG160
CD3
H H H LA2245
H H H H RG103
H
LA1006
CD3
RG161
CD3
H H H LA2246
H H H H RG104
H
LA1007
CD3
RG162
CD3
H H H LA2247
H H H H RG105
H
LA1008
CD3
RG163
CD3
H H H LA2248
H H H H RG106
H
LA1009
CD3
RG164
CD3
H H H LA2249
H H H H RG107
H
LA1010
CD3
RG165
CD3
H H H LA2250
H H H H RG108
H
LA1011
CD3
RG166
CD3
H H H LA2251
H H H H RG109
H
LA1012
CD3
RG167
CD3
H H H LA2252
H H H H RG110
H
LA1013
CD3
RG168
CD3
H H H LA2253
H H H H RG111
H
LA1014
CD3
RG169
CD3
H H H LA2254
H H H H RG112
H
LA1015
CD3
CD3
RG1
H H H LA2255
H H H H RG113
H
LA1016
CD3
CD3
RG2
H H H LA2256
H H H H RG114
H
LA1017
CD3
CD3
RG3
H H H LA2257
H H H H RG115
H
LA1018
CD3
CD3
RG4
H H H LA2258
H H H H RG116
H
LA1019
CD3
CD3
RG5
H H H LA2259
H H H H RG117
H
LA1020
CD3
CD3
RG6
H H H LA2260
H H H H RG118
H
LA1021
CD3
CD3
RG7
H H H LA2261
H H H H RG119
H
LA1022
CD3
CD3
RG8
H H H LA2262
H H H H RG120
H
LA1023
CD3
CD3
RG9
H H H LA2263
H H H H RG121
H
LA1024
CD3
CD3
RG10
H H H LA2264
H H H H RG122
H
LA1025
CD3
CD3
RG11
H H H LA2265
H H H H RG123
H
LA1026
CD3
CD3
RG12
H H H LA2266
H H H H RG124
H
LA1027
CD3
CD3
RG13
H H H LA2267
H H H H RG125
H
LA1028
CD3
CD3
RG14
H H H LA2268
H H H H RG126
H
LA1029
CD3
CD3
RG15
H H H LA2269
H H H H RG127
H
LA1030
CD3
CD3
RG16
H H H LA2270
H H H H RG128
H
LA1031
CD3
CD3
RG17
H H H LA2271
H H H H RG129
H
LA1032
CD3
CD3
RG18
H H H LA2272
H H H H RG130
H
LA1033
CD3
CD3
RG19
H H H LA2273
H H H H RG131
H
LA1034
CD3
CD3
RG20
H H H LA2274
H H H H RG132
H
LA1035
CD3
CD3
RG21
H H H LA2275
H H H H RG133
H
LA1036
CD3
CD3
RG22
H H H LA2276
H H H H RG134
H
LA1037
CD3
CD3
RG23
H H H LA2277
H H H H RG135
H
LA1038
CD3
CD3
RG24
H H H LA2278
H H H H RG136
H
LA1039
CD3
CD3
RG25
H H H LA2279
H H H H RG137
H
LA1040
CD3
CD3
RG26
H H H LA2280
H H H H RG138
H
LA1041
CD3
CD3
RG27
H H H LA2281
H H H H RG139
H
LA1042
CD3
CD3
RG28
H H H LA2282
H H H H RG140
H
LA1043
CD3
CD3
RG29
H H H LA2283
H H H H RG141
H
LA1044
CD3
CD3
RG30
H H H LA2284
H H H H RG142
H
LA1045
CD3
CD3
RG31
H H H LA2285
H H H H RG143
H
LA1046
CD3
CD3
RG32
H H H LA2286
H H H H RG144
H
LA1047
CD3
CD3
RG33
H H H LA2287
H H H H RG145
H
LA1048
CD3
CD3
RG34
H H H LA2288
H H H H RG146
H
LA1049
CD3
CD3
RG35
H H H LA2289
H H H H RG147
H
LA1050
CD3
CD3
RG36
H H H LA2290
H H H H RG148
H
LA1051
CD3
CD3
RG37
H H H LA2291
H H H H RG149
H
LA1052
CD3
CD3
RG38
H H H LA2292
H H H H RG150
H
LA1053
CD3
CD3
RG39
H H H LA2293
H H H H RG151
H
LA1054
CD3
CD3
RG40
H H H LA2294
H H H H RG152
H
LA1055
CD3
CD3
RG41
H H H LA2295
H H H H RG153
H
LA1056
CD3
CD3
RG42
H H H LA2296
H H H H RG154
H
LA1057
CD3
CD3
RG43
H H H LA2297
H H H H RG155
H
LA1058
CD3
CD3
RG44
H H H LA2298
H H H H RG156
H
LA1059
CD3
CD3
RG45
H H H LA2299
H H H H RG157
H
LA1060
CD3
CD3
RG46
H H H LA2300
H H H H RG158
H
LA1061
CD3
CD3
RG47
H H H LA2301
H H H H RG159
H
LA1062
CD3
CD3
RG48
H H H LA2302
H H H H RG160
H
LA1063
CD3
CD3
RG49
H H H LA2303
H H H H RG161
H
LA1064
CD3
CD3
RG50
H H H LA2304
H H H H RG162
H
LA1065
CD3
CD3
RG51
H H H LA2305
H H H H RG163
H
LA1066
CD3
CD3
RG52
H H H LA2306
H H H H RG164
H
LA1067
CD3
CD3
RG53
H H H LA2307
H H H H RG165
H
LA1068
CD3
CD3
RG54
H H H LA2308
H H H H RG166
H
LA1069
CD3
CD3
RG55
H H H LA2309
H H H H RG167
H
LA1070
CD3
CD3
RG56
H H H LA2310
H H H H RG168
H
LA1071
CD3
CD3
RG57
H H H LA2311
H H H H RG169
H
LA1072
CD3
CD3
RG58
H H H LA2312
H H H H H RG1
LA1073
CD3
CD3
RG59
H H H LA2313
H H H H H RG2
LA1074
CD3
CD3
RG60
H H H LA2314
H H H H H RG3
LA1075
CD3
CD3
RG61
H H H LA2315
H H H H H RG4
LA1076
CD3
CD3
RG62
H H H LA2316
H H H H H RG5
LA1077
CD3
CD3
RG63
H H H LA2317
H H H H H RG6
LA1078
CD3
CD3
RG64
H H H LA2318
H H H H H RG7
LA1079
CD3
CD3
RG65
H H H LA2319
H H H H H RG8
LA1080
CD3
CD3
RG66
H H H LA2320
H H H H H RG9
LA1081
CD3
CD3
RG67
H H H LA2321
H H H H H RG10
LA1082
CD3
CD3
RG68
H H H LA2322
H H H H H RG11
LA1083
CD3
CD3
RG69
H H H LA2323
H H H H H RG12
LA1084
CD3
CD3
RG70
H H H LA2324
H H H H H RG13
LA1085
CD3
CD3
RG71
H H H LA2325
H H H H H RG14
LA1086
CD3
CD3
RG72
H H H LA2326
H H H H H RG15
LA1087
CD3
CD3
RG73
H H H LA2327
H H H H H RG16
LA1088
CD3
CD3
RG74
H H H LA2328
H H H H H RG17
LA1089
CD3
CD3
RG75
H H H LA2329
H H H H H RG18
LA1090
CD3
CD3
RG76
H H H LA2330
H H H H H RG19
LA1091
CD3
CD3
RG77
H H H LA2331
H H H H H RG20
LA1092
CD3
CD3
RG78
H H H LA2332
H H H H H RG21
LA1093
CD3
CD3
RG79
H H H LA2333
H H H H H RG22
LA1094
CD3
CD3
RG80
H H H LA2334
H H H H H RG23
LA1095
CD3
CD3
RG81
H H H LA2335
H H H H H RG24
LA1096
CD3
CD3
RG82
H H H LA2336
H H H H H RG25
LA1097
CD3
CD3
RG83
H H H LA2337
H H H H H RG26
LA1098
CD3
CD3
RG84
H H H LA2338
H H H H H RG27
LA1099
CD3
CD3
RG85
H H H LA2339
H H H H H RG28
LA1100
CD3
CD3
RG86
H H H LA2340
H H H H H RG29
LA1101
CD3
CD3
RG87
H H H LA2341
H H H H H RG30
LA1102
CD3
CD3
RG88
H H H LA2342
H H H H H RG31
LA1103
CD3
CD3
RG89
H H H LA2343
H H H H H RG32
LA1104
CD3
CD3
RG90
H H H LA2344
H H H H H RG33
LA1105
CD3
CD3
RG91
H H H LA2345
H H H H H RG34
LA1106
CD3
CD3
RG92
H H H LA2346
H H H H H RG35
LA1107
CD3
CD3
RG93
H H H LA2347
H H H H H RG36
LA1108
CD3
CD3
RG94
H H H LA2348
H H H H H RG37
LA1109
CD3
CD3
RG95
H H H LA2349
H H H H H RG38
LA1110
CD3
CD3
RG96
H H H LA2350
H H H H H RG39
LA1111
CD3
CD3
RG97
H H H LA2351
H H H H H RG40
LA1112
CD3
CD3
RG98
H H H LA2352
H H H H H RG41
LA1113
CD3
CD3
RG99
H H H LA2353
H H H H H RG42
LA1114
CD3
CD3
RG100
H H H LA2354
H H H H H RG43
LA1115
CD3
CD3
RG101
H H H LA2355
H H H H H RG44
LA1116
CD3
CD3
RG102
H H H LA2356
H H H H H RG45
LA1117
CD3
CD3
RG103
H H H LA2357
H H H H H RG46
LA1118
CD3
CD3
RG104
H H H LA2358
H H H H H RG47
LA1119
CD3
CD3
RG105
H H H LA2359
H H H H H RG48
LA1120
CD3
CD3
RG106
H H H LA2360
H H H H H RG49
LA1121
CD3
CD3
RG107
H H H LA2361
H H H H H RG50
LA1122
CD3
CD3
RG108
H H H LA2362
H H H H H RG51
LA1123
CD3
CD3
RG109
H H H LA2363
H H H H H RG52
LA1124
CD3
CD3
RG110
H H H LA2364
H H H H H RG53
LA1125
CD3
CD3
RG111
H H H LA2365
H H H H H RG54
LA1126
CD3
CD3
RG112
H H H LA2366
H H H H H RG55
LA1127
CD3
CD3
RG113
H H H LA2367
H H H H H RG56
LA1128
CD3
CD3
RG114
H H H LA2368
H H H H H RG57
LA1129
CD3
CD3
RG115
H H H LA2369
H H H H H RG58
LA1130
CD3
CD3
RG116
H H H LA2370
H H H H H RG59
LA1131
CD3
CD3
RG117
H H H LA2371
H H H H H RG60
LA1132
CD3
CD3
RG118
H H H LA2372
H H H H H RG61
LA1133
CD3
CD3
RG119
H H H LA2373
H H H H H RG62
LA1134
CD3
CD3
RG120
H H H LA2374
H H H H H RG63
LA1135
CD3
CD3
RG121
H H H LA2375
H H H H H RG64
LA1136
CD3
CD3
RG122
H H H LA2376
H H H H H RG65
LA1137
CD3
CD3
RG123
H H H LA2377
H H H H H RG66
LA1138
CD3
CD3
RG124
H H H LA2378
H H H H H RG67
LA1139
CD3
CD3
RG125
H H H LA2379
H H H H H RG68
LA1140
CD3
CD3
RG126
H H H LA2380
H H H H H RG69
LA1141
CD3
CD3
RG127
H H H LA2381
H H H H H RG70
LA1142
CD3
CD3
RG128
H H H LA2382
H H H H H RG71
LA1143
CD3
CD3
RG129
H H H LA2383
H H H H H RG72
LA1144
CD3
CD3
RG130
H H H LA2384
H H H H H RG73
LA1145
CD3
CD3
RG131
H H H LA2385
H H H H H RG74
LA1146
CD3
CD3
RG132
H H H LA2386
H H H H H RG75
LA1147
CD3
CD3
RG133
H H H LA2387
H H H H H RG76
LA1148
CD3
CD3
RG134
H H H LA2388
H H H H H RG77
LA1149
CD3
CD3
RG135
H H H LA2389
H H H H H RG78
LA1150
CD3
CD3
RG136
H H H LA2390
H H H H H RG79
LA1151
CD3
CD3
RG137
H H H LA2391
H H H H H RG80
LA1152
CD3
CD3
RG138
H H H LA2392
H H H H H RG81
LA1153
CD3
CD3
RG139
H H H LA2393
H H H H H RG82
LA1154
CD3
CD3
RG140
H H H LA2394
H H H H H RG83
LA1155
CD3
CD3
RG141
H H H LA2395
H H H H H RG84
LA1156
CD3
CD3
RG142
H H H LA2396
H H H H H RG85
LA1157
CD3
CD3
RG143
H H H LA2397
H H H H H RG86
LA1158
CD3
CD3
RG144
H H H LA2398
H H H H H RG87
LA1159
CD3
CD3
RG145
H H H LA2399
H H H H H RG88
LA1160
CD3
CD3
RG146
H H H LA2400
H H H H H RG89
LA1161
CD3
CD3
RG147
H H H LA2401
H H H H H RG90
LA1162
CD3
CD3
RG148
H H H LA2402
H H H H H RG91
LA1163
CD3
CD3
RG149
H H H LA2403
H H H H H RG92
LA1164
CD3
CD3
RG150
H H H LA2404
H H H H H RG93
LA1165
CD3
CD3
RG151
H H H LA2405
H H H H H RG94
LA1166
CD3
CD3
RG152
H H H LA2406
H H H H H RG95
LA1167
CD3
CD3
RG153
H H H LA2407
H H H H H RG96
LA1168
CD3
CD3
RG154
H H H LA2408
H H H H H RG97
LA1169
CD3
CD3
RG155
H H H LA2409
H H H H H RG98
LA1170
CD3
CD3
RG156
H H H LA2410
H H H H H RG99
LA1171
CD3
CD3
RG157
H H H LA2411
H H H H H RG100
LA1172
CD3
CD3
RG158
H H H LA2412
H H H H H RG101
LA1173
CD3
CD3
RG159
H H H LA2413
H H H H H RG102
LA1174
CD3
CD3
RG160
H H H LA2414
H H H H H RG103
LA1175
CD3
CD3
RG161
H H H LA2415
H H H H H RG104
LA1176
CD3
CD3
RG162
H H H LA2416
H H H H H RG105
LA1177
CD3
CD3
RG163
H H H LA2417
H H H H H RG106
LA1178
CD3
CD3
RG164
H H H LA2418
H H H H H RG107
LA1179
CD3
CD3
RG165
H H H LA2419
H H H H H RG108
LA1180
CD3
CD3
RG166
H H H LA2420
H H H H H RG109
LA1181
CD3
CD3
RG167
H H H LA2421
H H H H H RG110
LA1182
CD3
CD3
RG168
H H H LA2422
H H H H H RG111
LA1183
CD3
CD3
RG169
H H H LA2423
H H H H H RG112
LA1184
CD3
H RG1
H H H LA2424
H H H H H RG113
LA1185
CD3
H RG2
H H H LA2425
H H H H H RG114
LA1186
CD3
H RG3
H H H LA2426
H H H H H RG115
LA1187
CD3
H RG4
H H H LA2427
H H H H H RG116
LA1188
CD3
H RG5
H H H LA2428
H H H H H RG117
LA1189
CD3
H RG6
H H H LA2429
H H H H H RG118
LA1190
CD3
H RG7
H H H LA2430
H H H H H RG119
LA1191
CD3
H RG8
H H H LA2431
H H H H H RG120
LA1192
CD3
H RG9
H H H LA2432
H H H H H RG121
LA1193
CD3
H RG10
H H H LA2433
H H H H H RG122
LA1194
CD3
H RG11
H H H LA2434
H H H H H RG123
LA1195
CD3
H RG12
H H H LA2435
H H H H H RG124
LA1196
CD3
H RG13
H H H LA2436
H H H H H RG125
LA1197
CD3
H RG14
H H H LA2437
H H H H H RG126
LA1198
CD3
H RG15
H H H LA2438
H H H H H RG127
LA1199
CD3
H RG16
H H H LA2439
H H H H H RG128
LA1200
CD3
H RG17
H H H LA2440
H H H H H RG129
LA1201
CD3
H RG18
H H H LA2441
H H H H H RG130
LA1202
CD3
H RG19
H H H LA2442
H H H H H RG131
LA1203
CD3
H RG20
H H H LA2443
H H H H H RG132
LA1204
CD3
H RG21
H H H LA2444
H H H H H RG133
LA1205
CD3
H RG22
H H H LA2445
H H H H H RG134
LA1206
CD3
H RG23
H H H LA2446
H H H H H RG135
LA1207
CD3
H RG24
H H H LA2447
H H H H H RG136
LA1208
CD3
H RG25
H H H LA2448
H H H H H RG137
LA1209
CD3
H RG26
H H H LA2449
H H H H H RG138
LA1210
CD3
H RG27
H H H LA2450
H H H H H RG139
LA1211
CD3
H RG28
H H H LA2451
H H H H H RG140
LA1212
CD3
H RG29
H H H LA2452
H H H H H RG141
LA1213
CD3
H RG30
H H H LA2453
H H H H H RG142
LA1214
CD3
H RG31
H H H LA2454
H H H H H RG143
LA1215
CD3
H RG32
H H H LA2455
H H H H H RG144
LA1216
CD3
H RG33
H H H LA2456
H H H H H RG145
LA1217
CD3
H RG34
H H H LA2457
H H H H H RG146
LA1218
CD3
H RG35
H H H LA2458
H H H H H RG147
LA1219
CD3
H RG36
H H H LA2459
H H H H H RG148
LA1220
CD3
H RG37
H H H LA2460
H H H H H RG149
LA1221
CD3
H RG38
H H H LA2461
H H H H H RG150
LA1222
CD3
H RG39
H H H LA2462
H H H H H RG151
LA1223
CD3
H RG40
H H H LA2463
H H H H H RG152
LA1224
CD3
H RG41
H H H LA2464
H H H H H RG153
LA1225
CD3
H RG42
H H H LA2465
H H H H H RG154
LA1226
CD3
H RG43
H H H LA2466
H H H H H RG155
LA1227
CD3
H RG44
H H H LA2467
H H H H H RG156
LA1228
CD3
H RG45
H H H LA2468
H H H H H RG157
LA1229
CD3
H RG46
H H H LA2469
H H H H H RG158
LA1230
CD3
H RG47
H H H LA2470
H H H H H RG159
LA1231
CD3
H RG48
H H H LA2471
H H H H H RG160
LA1232
CD3
H RG49
H H H LA2472
H H H H H RG161
LA1233
CD3
H RG50
H H H LA2473
H H H H H RG162
LA1234
CD3
H RG51
H H H LA2474
H H H H H RG163
LA1235
CD3
H RG52
H H H LA2475
H H H H H RG164
LA1236
CD3
H RG53
H H H LA2476
H H H H H RG165
LA1237
CD3
H RG54
H H H LA2477
H H H H H RG166
LA1238
CD3
H RG55
H H H LA2478
H H H H H RG167
LA1239
CD3
H RG56
H H H LA2479
H H H H H RG168
LA1240
CD3
H RG57
H H H LA2480
H H H H H RG169
selected from the group consisting of L
A1 to LA2480 as listed below:
wherein R
G1 to RG169 have the following structures:
and
.
14. The composition of claim 13 , wherein the compound is Compound x selected from the group consisting of Compound x, wherein x is an integer from 1 to 2120400;
wherein Compound x has the formula Ir(LAi)(LBj)2;
wherein x = 2480j + i - 2480, i is an integer from 1 to 2480, and j is an integer from 1 to 855;
wherein each LBj has a structure based on the following structure:
j RB1
RB2
RB3
RB4
1. H H H H
2. CH3
H H H
3. H CH3
H H
4. H H CH3
H
5. H H H CH3
6. CH3
H CH3
H
7. CH3
H H CH3
8. H CH3
CH3
H
9. H CH3
H CH3
10. H H CH3
CH3
11. CH3
CH3
CH3
H
12. CH3
CH3
H CH3
13. CH3
H CH3
CH3
14. H CH3
CH3
CH3
15. CH3
CH3
CH3
CH3
16. CH2CH3
H H H
17. CH2CH3
CH3
H H
18. CH2CH3
H CH3
H
19. CH2CH3
H H CH3
20. CH2CH3
CH3
CH3
H
21. CH2CH3
CH3
H CH3
22. CH2CH3
H CH3
CH3
23. CH2CH3
CH3
CH3
CH3
24. H CH2CH3
H H
25. CH3
CH2CH3
H H
26. H CH2CH3
CH3
H
27. H CH2CH3
H CH3
28. CH3
CH2CH3
CH3
H
29. CH3
CH2CH3
H CH3
30. H CH2CH3
CH3
CH3
31. CH3
CH2CH3
CH3
CH3
32. H H CH2CH3
H
33. CH3
H CH2CH3
H
34. H CH3
CH2CH3
H
35. H H CH2CH3
CH3
36. CH3
CH3
CH2CH3
H
37. CH3
H CH2CH3
CH3
38. H CH3
CH2CH3
CH3
39. CH3
CH3
CH2CH3
CH3
40. CH(CH3)2
H H H
41. CH(CH3)2
CH3
H H
42. CH(CH3)2
H CH3
H
43. CH(CH3)2
H H CH3
44. CH(CH3)2
CH3
CH3
H
45. CH(CH3)2
CH3
H CH3
46. CH(CH3)2
H CH3
CH3
47. CH(CH3)2
CH3
CH3
CH3
48. H CH(CH3)2
H H
49. CH3
CH(CH3)2
H H
50. H CH(CH3)2
CH3
H
51. H CH(CH3)2
H CH3
52. CH3
CH(CH3)2
CH3
H
53. CH3
CH(CH3)2
H CH3
54. H CH(CH3)2
CH3
CH3
55. CH3
CH(CH3)2
CH3
CH3
56. H H CH(CH3)2
H
57. CH3
H CH(CH3)2
H
58. H CH3
CH(CH3)2
H
59. H H CH(CH3)2
CH3
60. CH3
CH3
CH(CH3)2
H
61. CH3
H CH(CH3)2
CH3
62. H CH3
CH(CH3)2
CH3
63. CH3
CH3
CH(CH3)2
CH3
64. CH2CH(CH3)2
H H H
65. CH2CH(CH3)2
CH3
H H
66. CH2CH(CH3)2
H CH3
H
67. CH2CH(CH3)2
H H CH3
68. CH2CH(CH3)2
CH3
CH3
H
69. CH2CH(CH3)2
CH3
H CH3
70. CH2CH(CH3)2
H CH3
CH3
71. CH2CH(CH3)2
CH3
CH3
CH3
72. H CH2CH(CH3)2
H H
73. CH3
CH2CH(CH3)2
H H
74. H CH2CH(CH3)2
CH3
H
75. H CH2CH(CH3)2
H CH3
76. CH3
CH2CH(CH3)2
CH3
H
77. CH3
CH2CH(CH3)2
H CH3
78. H CH2CH(CH3)2
CH3
CH3
79. CH3
CH2CH(CH3)2
CH3
CH3
80. H H CH2CH(CH3)2
H
81. CH3
H CH2CH(CH3)2
H
82. H CH3
CH2CH(CH3)2
H
83. H H CH2CH(CH3)2
CH3
84. CH3
CH3
CH2CH(CH3)2
H
85. CH3
H CH2CH(CH3)2
CH3
86. H CH3
CH2CH(CH3)2
CH3
87. CH3
CH3
CH2CH(CH3)2
CH3
88. C(CH3)3
H H H
89. C(CH3)3
CH3
H H
90. C(CH3)3
H CH3
H
91. C(CH3)3
H H CH3
92. C(CH3)3
CH3
CH3
H
93. C(CH3)3
CH3
H CH3
94. C(CH3)3
H CH3
CH3
95. C(CH3)3
CH3
CH3
CH3
96. H C(CH3)3
H H
97. CH3
C(CH3)3
H H
98. H C(CH3)3
CH3
H
99. H C(CH3)3
H CH3
100. CH3
C(CH3)3
CH3
H
101. CH3
C(CH3)3
H CH3
102. H C(CH3)3
CH3
CH3
103. CH3
C(CH3)3
CH3
CH3
104. H H C(CH3)3
H
105. CH3
H C(CH3)3
H
106. H CH3
C(CH3)3
H
107. H H C(CH3)3
CH3
108. CH3
CH3
C(CH3)3
H
109. CH3
H C(CH3)3
CH3
110. H CH3
C(CH3)3
CH3
111. CH3
CH3
C(CH3)3
CH3
112. CH2C(CH3)3
H H H
113. CH2C(CH3)3
CH3
H H
114. CH2C(CH3)3
H CH3
H
115. CH2C(CH3)3
H H CH3
116. CH2C(CH3)3
CH3
CH3
H
117. CH2C(CH3)3
CH3
H CH3
118. CH2C(CH3)3
H CH3
CH3
119. CH2C(CH3)3
CH3
CH3
CH3
120. H CH2C(CH3)3
H H
121. CH3
CH2C(CH3)3
H H
122. H CH2C(CH3)3
CH3
H
123. H CH2C(CH3)3
H CH3
124. CH3
CH2C(CH3)3
CH3
H
125. CH3
CH2C(CH3)3
H CH3
126. H CH2C(CH3)3
CH3
CH3
127. CH3
CH2C(CH3)3
CH3
CH3
128. H H CH2C(CH3)3
H
129. CH3
H CH2C(CH3)3
H
130. H CH3
CH2C(CH3)3
H
131. H H CH2C(CH3)3
CH3
132. CH3
CH3
CH2C(CH3)3
H
133. CH3
H CH2C(CH3)3
CH3
134. H CH3
CH2C(CH3)3
CH3
135. CH3
CH3
CH2C(CH3)3
CH3
136. CH2C(CH3)2CF3
H H H
137. CH2C(CH3)2CF3
CH3
H H
138. CH2C(CH3)2CF3
H CH3
H
139. CH2C(CH3)2CF3
H H CH3
140. CH2C(CH3)2CF3
CH3
CH3
H
141. CH2C(CH3)2CF3
CH3
H CH3
142. CH2C(CH3)2CF3
H CH3
CH3
143. CH2C(CH3)2CF3
CH3
CH3
CH3
144. H CH2C(CH3)2CF3
H H
145. CH3
CH2C(CH3)2CF3
H H
146. H CH2C(CH3)2CF3
CH3
H
147. H CH2C(CH3)2CF3
H CH3
148. CH3
CH2C(CH3)2CF3
CH3
H
149. CH3
CH2C(CH3)2CF3
H CH3
150. H CH2C(CH3)2CF3
CH3
CH3
151. CH3
CH2C(CH3)2CF3
CH3
CH3
152. H H CH2C(CH3)2CF3
H
153. CH3
H CH2C(CH3)2CF3
H
154. H CH3
CH2C(CH3)2CF3
H
155. H H CH2C(CH3)2CF3
CH3
156. CH3
CH3
CH2C(CH3)2CF3
H
157. CH3
H CH2C(CH3)2CF3
CH3
158. H CH3
CH2C(CH3)2CF3
CH3
159. CH3
CH3
CH2C(CH3)2CF3
CH3
160. CH2CH2CF3
H H H
161. CH2CH2CF3
CH3
H H
162. CH2CH2CF3
H CH3
H
163. CH2CH2CF3
H H CH3
164. CH2CH2CF3
CH3
CH3
H
165. CH2CH2CF3
CH3
H CH3
166. CH2CH2CF3
H CH3
CH3
167. CH2CH2CF3
CH3
CH3
CH3
168. H CH2CH2CF3
H H
169. CH3
CH2CH2CF3
H H
170. H CH2CH2CF3
CH3
H
171. H CH2CH2CF3
H CH3
172. CH3
CH2CH2CF3
CH3
H
173. CH3
CH2CH2CF3
H CH3
174. H CH2CH2CF3
CH3
CH3
175. CH3
CH2CH2CF3
CH3
CH3
176. H H CH2CH2CF3
H
177. CH3
H CH2CH2CF3
H
178. H CH3
CH2CH2CF3
H
179. H H CH2CH2CF3
CH3
180. CH3
CH3
CH2CH2CF3
H
181. CH3
H CH2CH2CF3
CH3
182. H CH3
CH2CH2CF3
CH3
183. CH3
CH3
CH2CH2CF3
CH3
184. H H H
185. CH3
H H
186. H CH3
H
187. H H CH3
188. CH3
CH3
H
189. CH3
H CH3
190. H CH3
CH3
191. CH3
CH3
CH3
192. H H H
193. CH3
H H
194. H CH3
H
195. H H CH3
196. CH3
CH3
H
197. CH3
H CH3
198. H CH3
CH3
199. CH3
CH3
CH3
200. H H H
201. CH3
H H
202. H CH3
H
203. H H CH3
204. CH3
CH3
H
205. CH3
H CH3
206. H CH3
CH3
207. CH3
CH3
CH3
208. H H H
209. CH3
H H
210. H CH3
H
211. H H CH3
212. CH3
CH3
H
213. CH3
H CH3
214. H CH3
CH3
215. CH3
CH3
CH3
216. H H H
217. CH3
H H
218. H CH3
H
219. H H CH3
220. CH3
CH3
H
221. CH3
H CH3
222. H CH3
CH3
223. CH3
CH3
CH3
224. H H H
225. CH3
H H
226. H CH3
H
227. H H CH3
228. CH3
CH3
H
229. CH3
H CH3
230. H CH3
CH3
231. CH3
CH3
CH3
232. H H H
233. CH3
H H
234. H CH3
H
235. H H CH3
236. CH3
CH3
H
237. CH3
H CH3
238. H CH3
CH3
239. CH3
CH3
CH3
240. H H H
241. CH3
H H
242. H CH3
H
243. H H CH3
244. CH3
CH3
H
245. CH3
H CH3
246. H CH3
CH3
247. CH3
CH3
CH3
248. H H H
249. CH3
H H
250. H CH3
H
251. H H CH3
252. CH3
CH3
H
253. CH3
H CH3
254. H CH3
CH3
255. CH3
CH3
CH3
256. H H H
257. CH3
H H
258. H CH3
H
259. H H CH3
260. CH3
CH3
H
261. CH3
H CH3
262. H CH3
CH3
263. CH3
CH3
CH3
264. H H H
265. CH3
H H
266. H CH3
H
267. H H CH3
268. CH3
CH3
H
269. CH3
H CH3
270. H CH3
CH3
271. CH3
CH3
CH3
272. H H H
273. CH3
H H
274. H CH3
H
275. H H CH3
276. CH3
CH3
H
277. CH3
H CH3
278. H CH3
CH3
279. CH3
CH3
CH3
280. H H H
281. H H
282. H CH3
H
283. H H CH3
284. CH3
CH3
H
285. CH3
H CH3
286. H CH3
CH3
287. CH3
CH3
CH3
288. H H H
289. CH3
H H
290. H CH3
H
291. H H CH3
292. CH3
CH3
H
293. CH3
H CH3
294. H CH3
CH3
295. CH3
CH3
CH3
296. H H H
297. CH3
H H
298. H CH3
H
299. H H CH3
300. CH3
CH3
H
301. CH3
H CH3
302. H CH3
CH3
303. CH3
CH3
CH3
304. H H H
305. CH3
H H
306. H CH3
H
307. H H CH3
308. CH3
CH3
H
309. CH3
H CH3
310. H CH3
CH3
311. CH3
CH3
CH3
312. H H H
313. CH3
H H
314. H CH3
H
315. H H CH3
316. CH3
CH3
H
317. CH3
H CH3
318. H CH3
CH3
319. CH3
CH3
CH3
320. H H H
321. CH3
H H
322. H CH3
H
323. H H CH3
324. CH3
CH3
H
325. CH3
H CH3
326. H CH3
CH3
327. CH3
CH3
CH3
328. CH(CH3)2
H CH2CH3
H
329. CH(CH3)2
H CH(CH3)2
H
330. CH(CH3)2
H CH2CH(CH3)2
H
331. CH(CH3)2
H C(CH3)3
H
332. CH(CH3)2
H CH2C(CH3)3
H
333. CH(CH3)2
H CH2CH2CF3
H
334. CH(CH3)2
H CH2C(CH3)2CF3
H
335. CH(CH3)2
H H
336. CH(CH3)2
H H
337. CH(CH3)2
H H
338. CH(CH3)2
H H
339. CH(CH3)2
H H
340. CH(CH3)2
H H
341. C(CH3)3
H CH2CH3
H
342. C(CH3)3
H CH(CH3)2
H
343. C(CH3)3
H CH2CH(CH3)2
H
344. C(CH3)3
H C(CH3)3
H
345. C(CH3)3
H CH2C(CH3)3
H
346. C(CH3)3
H CH2CH2CF3
H
347. C(CH3)3
H CH2C(CH3)2CF3
H
348. C(CH3)3
H H
349. C(CH3)3
H H
350. C(CH3)3
H H
351. C(CH3)3
H H
352. C(CH3)3
H H
353. C(CH3)3
H H
354. CH2C(CH3)3
H CH2CH3
H
355. CH2C(CH3)3
H CH(CH3)2
H
356. CH2C(CH3)3
H CH2CH(CH3)2
H
357. CH2C(CH3)3
H C(CH3)3
H
358. CH2C(CH3)3
H CH2C(CH3)3
H
359. CH2C(CH3)3
H CH2CH2CF3
H
360. CH2C(CH3)3
H CH2C(CH3)2CF3
H
361. CH2C(CH3)3
H H
362. CH2C(CH3)3
H H
363. CH2C(CH3)3
H H
364. CH2C(CH3)3
H H
365. CH2C(CH3)3
H H
366. CH2C(CH3)3
H H
367. H CH2CH3
H
368. H CH(CH3)2
H
369. H CH2CH(CH3)2
H
370. H C(CH3)3
H
371. H CH2C(CH3)3
H
372. H CH2CH2CF3
H
373. H CH2C(CH3)2CF3
H
374. H H
375. H H
376. H H
377. H H
378. H H
379. H H
380. H CH2CH3
H
381. H CH(CH3)2
H
382. H CH2CH(CH3)2
H
383. H C(CH3)3
H
384. H CH2C(CH3)3
H
385. H CH2CH2CF3
H
386. H CH2C(CH3)2CF3
H
387. H H
388. H H
389. H H
390. H H
391. H H
392. H H
393. H CH2CH(CH3)2
H
394. H C(CH3)3
H
395. H CH2C(CH3)3
H
396. H CH2CH2CF3
H
397. H CH2C(CH3)2CF3
H
398. H H
399. H H
400. H H
401. H H
402. H H
403. H H
404. H CH2CH(CH3)2
H
405. H C(CH3)3
H
406. H CH2C(CH3)3
H
407. H CH2CH2CF3
H
408. H CH2C(CH3)2CF3
H
409. H H
410. H H
411. H H
412. H H
413. H H
414. H H
415. H CH2CH(CH3)2
H
416. H C(CH3)3
H
417. H CH2C(CH3)3
H
418. H CH2CH2CF3
H
419. H CH2C(CH3)2CF3
H
420. H H
421. H H
422. H H
423. H H
424. H H
425. H H
426. CD3
H H H
427. H CD3
H H
428. H H CD3
H
429. H H H CD3
430. CD3
H CD3
H
431. CD3
H H CD3
432. H CD3
CD3
H
433. H CD3
H CD3
434. H H CD3
CD3
435. CD3
CD3
CD3
H
436. CD3
CD3
H CD3
437. CD3
H CD3
CD3
438. H CD3
CD3
CD3
439. CD3
CD3
CD3
CD3
440. CD2CH3
H H H
441. CD2CH3
CD3
H H
442. CD2CH3
H CD3
H
443. CD2CH3
H H CD3
444. CD2CH3
CD3
CD3
H
445. CD2CH3
CD3
H CD3
446. CD2CH3
H CD3
CD3
447. CD2CH3
CD3
CD3
CD3
448. H CD2CH3
H H
449. CD3
CD2CH3
H H
450. H CD2CH3
CD3
H
451. H CD2CH3
H CD3
452. CD3
CD2CH3
CD3
H
453. CD3
CD2CH3
H CD3
454. H CD2CH3
CD3
CD3
455. CD3
CD2CH3
CD3
CD3
456. H H CD2CH3
H
457. CD3
H CD2CH3
H
458. H CD3
CD2CH3
H
459. H H CD2CH3
CD3
460. CD3
CD3
CD2CH3
H
461. CD3
H CD2CH3
CD3
462. H CD3
CD2CH3
CD3
463. CD3
CD3
CD2CH3
CD3
464. CD(CH3)2
H H H
465. CD(CH3)2
CD3
H H
466. CD(CH3)2
H CD3
H
467. CD(CH3)2
H H CD3
468. CD(CH3)2
CD3
CD3
H
469. CD(CH3)2
CD3
H CD3
470. CD(CH3)2
H CD3
CD3
471. CD(CH3)2
CD3
CD3
CD3
472. H CD(CH3)2
H H
473. CD3
CD(CH3)2
H H
474. H CD(CH3)2
CD3
H
475. H CD(CH3)2
H CD3
476. CD3
CD(CH3)2
CD3
H
477. CD3
CD(CH3)2
H CD3
478. H CD(CH3)2
CD3
CD3
479. CD3
CD(CH3)2
CD3
CD3
480. H H CD(CH3)2
H
481. CD3
H CD(CH3)2
H
482. H CD3
CD(CH3)2
H
483. H H CD(CH3)2
CD3
484. CD3
CD3
CD(CH3)2
H
485. CD3
H CD(CH3)2
CD3
486. H CD3
CD(CH3)2
CD3
487. CD3
CD3
CD(CH3)2
CD3
488. CD(CD3)2
H H H
489. CD(CD3)2
CD3
H H
490. CD(CD3)2
H CD3
H
491. CD(CD3)2
H H CD3
492. CD(CD3)2
CD3
CD3
H
493. CD(CD3)2
CD3
H CD3
494. CD(CD3)2
H CD3
CD3
495. CD(CD3)2
CD3
CD3
CD3
496. H CD(CD3)2
H H
497. CD3
CD(CD3)2
H H
498. H CD(CD3)2
CD3
H
499. H CD(CD3)2
H CD3
500. CD3
CD(CD3)2
CD3
H
501. CD3
CD(CD3)2
H CD3
502. H CD(CD3)2
CD3
CD3
503. CD3
CD(CD3)2
CD3
CD3
504. H H CD(CD3)2
H
505. CD3
H CD(CD3)2
H
506. H CD3
CD(CD3)2
H
507. H H CD(CD3)2
CD3
508. CD3
CD3
CD(CD3)2
H
509. CD3
H CD(CD3)2
CD3
510. H CD3
CD(CD3)2
CD3
511. CD3
CD3
CD(CD3)2
CD3
512. CD2CH(CH3)2
H H H
513. CD2CH(CH3)2
CD3
H H
514. CD2CH(CH3)2
H CD3
H
515. CD2CH(CH3)2
H H CD3
516. CD2CH(CH3)2
CD3
CD3
H
517. CD2CH(CH3)2
CD3
H CD3
518. CD2CH(CH3)2
H CD3
CD3
519. CD2CH(CH3)2
CD3
CD3
CD3
520. H CD2CH(CH3)2
H H
521. CD3
CD2CH(CH3)2
H H
522. H CD2CH(CH3)2
CD3
H
523. H CD2CH(CH3)2
H CD3
524. CD3
CD2CH(CH3)2
CD3
H
525. CD3
CD2CH(CH3)2
H CD3
526. H CD2CH(CH3)2
CD3
CD3
527. CD3
CD2CH(CH3)2
CD3
CD3
528. H H CD2CH(CH3)2
H
529. CD3
H CD2CH(CH3)2
H
530. H CD3
CD2CH(CH3)2
H
531. H H CD2CH(CH3)2
CD3
532. CD3
CD3
CD2CH(CH3)2
H
533. CD3
H CD2CH(CH3)2
CD3
534. H CD3
CD2CH(CH3)2
CD3
535. CD3
CD3
CD2CH(CH3)2
CD3
536. CD2C(CH3)3
H H H
537. CD2C(CH3)3
CD3
H H
538. CD2C(CH3)3
H CD3
H
539. CD2C(CH3)3
H H CD3
540. CD2C(CH3)3
CD3
CD3
H
541. CD2C(CH3)3
CD3
H CD3
542. CD2C(CH3)3
H CD3
CD3
543. CD2C(CH3)3
CH3
CD3
CD3
544. H CD2C(CH3)3
H H
545. CD3
CD2C(CH3)3
H H
546. H CD2C(CH3)3
CD3
H
547. H CD2C(CH3)3
H CD3
548. CD3
CD2C(CH3)3
CD3
H
549. CD3
CD2C(CH3)3
H CD3
550. H CD2C(CH3)3
CD3
CD3
551. CD3
CD2C(CH3)3
CD3
CD3
552. H H CD2C(CH3)3
H
553. CD3
H CD2C(CH3)3
H
554. H CD3
CD2C(CH3)3
H
555. H H CD2C(CH3)3
CD3
556. CD3
CD3
CD2C(CH3)3
H
557. CD3
H CD2C(CH3)3
CD3
558. H CD3
CD2C(CH3)3
CD3
559. CD3
CD3
CD2C(CH3)3
CD3
560. CD2C(CH3)2CF3
H H H
561. CD2C(CH3)2CF3
CD3
H H
562. CD2C(CH3)2CF3
H CD3
H
563. CD2C(CH3)2CF3
H H CD3
564. CD2C(CH3)2CF3
CD3
CD3
H
565. CD2C(CH3)2CF3
CD3
H CD3
566. CD2C(CH3)2CF3
H CD3
CD3
567. CD2C(CH3)2CF3
CD3
CD3
CD3
568. H CD2C(CH3)2CF3
H H
569. CD3
CD2C(CH3)2CF3
H H
570. H CD2C(CH3)2CF3
CD3
H
571. H CD2C(CH3)2CF3
H CD3
572. CD3
CD2C(CH3)2CF3
CD3
H
573. CD3
CD2C(CH3)2CF3
H CD3
574. H CD2C(CH3)2CF3
CD3
CD3
575. CD3
CD2C(CH3)2CF3
CD3
CD3
576. H H CD2C(CH3)2CF3
H
577. CD3
H CD2C(CH3)2CF3
H
578. H CD3
CD2C(CH3)2CF3
H
579. H H CD2C(CH3)2CF3
CD3
580. CD3
CD3
CD2C(CH3)2CF3
H
581. CD3
H CD2C(CH3)2CF3
CD3
582. H CD3
CD2C(CH3)2CF3
CD3
583. CD3
CD3
CD2C(CH3)2CF3
CD3
584. CD2CH2CF3
H H H
585. CD2CH2CF3
CD3
H H
586. CD2CH2CF3
H CD3
H
587. CD2CH2CF3
H H CD3
588. CD2CH2CF3
CD3
CD3
H
589. CD2CH2CF3
CD3
H CD3
590. CD2CH2CF3
H CD3
CD3
591. CD2CH2CF3
CD3
CD3
CD3
592. H CD2CH2CF3
H H
593. CD3
CD2CH2CF3
H H
594. H CD2CH2CF3
CD3
H
595. H CD2CH2CF3
H CD3
596. CD3
CD2CH2CF3
CD3
H
597. CD3
CD2CH2CF3
H CD3
598. H CD2CH2CF3
CD3
CD3
599. CD3
CD2CH2CF3
CD3
CD3
600. H H CD2CH2CF3
H
601. CD3
H CD2CH2CF3
H
602. H CD3
CD2CH2CF3
H
603. H H CD2CH2CF3
CD3
604. CD3
CD3
CD2CH2CF3
H
605. CD3
H CD2CH2CF3
CD3
606. H CD3
CD2CH2CF3
CD3
607. CD3
CD3
CD2CH2CF3
CD3
608. H H H
609. CD3
H H
610. H CD3
H
611. H H CD3
612. CD3
CD3
H
613. CD3
H CD3
614. H CD3
CD3
615. CD3
CD3
CD3
616. H H H
617. CD3
H H
618. H CD3
H
619. H H CD3
620. CD3
CD3
H
621. CD3
H CD3
622. H CD3
CD3
623. CD3
CD3
CD3
624. H H H
625. CD3
H H
626. H CD3
H
627. H H CD3
628. CD3
CD3
H
629. CD3
H CD3
630. H CD3
CD3
631. CD3
CD3
CD3
632. H H H
633. CD3
H H
634. H CD3
H
635. H H CD3
636. CD3
CD3
H
637. CD3
H CD3
638. H CD3
CD3
639. CD3
CD3
CD3
640. H H H
641. CD3
H H
642. H CD3
H
643. H H CD3
644. CD3
CD3
H
645. CD3
H CD3
646. H CD3
CD3
647. CH3
CD3
CD3
648. H H H
649. CD3
H H
650. H CD3
H
651. H H CD3
652. CD3
CD3
H
653. CD3
H CD3
654. H CD3
CD3
655. CD3
CD3
CD3
656. H H H
657. CD3
H H
658. H CD3
H
659. H H CD3
660. CD3
CD3
H
661. CD3
H CD3
662. H CD3
CD3
663. CD3
CD3
CD3
664. H H H
665. CD3
H H
666. H CD3
H
667. H H CD3
668. CD3
CD3
H
669. CD3
H CD3
670. H CD3
CD3
671. CD3
CD3
CD3
672. H H H
673. CD3
H H
674. H CD3
H
675. H H CD3
676. CD3
CD3
H
677. CD3
H CD3
678. H CD3
CD3
679. CD3
CD3
CD3
680. H H H
681. CD3
H H
682. H CD3
H
683. H H CD3
684. CD3
CD3
H
685. CD3
H CD3
686. H CD3
CD3
687. CD3
CD3
CD3
688. H H H
689. CD3
H H
690. H CD3
H
691. H H CD3
692. CD3
CD3
H
693. CD3
H CD3
694. H CD3
CD3
695. CD3
CD3
CD3
696. H H H
697. CD3
H H
698. H CD3
H
699. H H CD3
700. CD3
CD3
H
701. CD3
H CD3
702. H CD3
CD3
703. CD3
CD3
CD3
704. H H H
705. CD3
H H
706. H CD3
H
707. H H CD3
708. CD3
CD3
H
709. CD3
H CD3
710. H CD3
CD3
711. CD3
CD3
CD3
712. H H H
713. CD3
H H
714. H CD3
H
715. H H CD3
716. CD3
CD3
H
717. CD3
H CD3
718. H CD3
CD3
719. CD3
CD3
CD3
720. H H H
721. CD3
H H
722. H CD3
H
723. H H CD3
724. CD3
CD3
H
725. CD3
H CD3
726. H CD3
CD3
727. CD3
CD3
CD3
728. H H H
729. CD3
H H
730. H CD3
H
731. H H CD3
732. CH3
CH3
H
733. CD3
H CD3
734. H CD3
CD3
735. CD3
CD3
CD3
736. H H H
737. CD3
H H
738. H CD3
H
739. H H CD3
740. CD3
CD3
H
741. CD3
H CD3
742. H CD3
CD3
743. CD3
CD3
CD3
744. H H H
745. CD3
H H
746. H CD3
H
747. H H CD3
748. CD3
CD3
H
749. CD3
H CD3
750. H CD3
CD3
751. CD3
CD3
CD3
752. CD(CH3)2
H CD2CH3
H
753. CD(CH3)2
H CD(CH3)2
H
754. CD(CH3)2
H CD2CH(CH3)2
H
755. CD(CH3)2
H C(CH3)3
H
756. CD(CH3)2
H CD2C(CH3)3
H
757. CD(CH3)2
H CD2CH2CF3
H
758. CD(CH3)2
H CD2C(CH3)2CF3
H
759. CD(CH3)2
H H
760. CD(CH3)2
H H
761. CD(CH3)2
H H
762. CD(CH3)2
H H
763. CD(CH3)2
H H
764. CD(CH3)2
H H
765. C(CH3)3
H CD2CH3
H
766. C(CH3)3
H CD(CH3)2
H
767. C(CH3)3
H CD2CH(CH3)2
H
768. C(CH3)3
H C(CH3)3
H
769. C(CH3)3
H CD2C(CH3)3
H
770. C(CH3)3
H CD2CH2CF3
H
771. C(CH3)3
H CD2C(CH3)2CF3
H
772. C(CH3)3
H H
773. C(CH3)3
H H
774. C(CH3)3
H H
775. C(CH3)3
H H
776. C(CH3)3
H H
777. C(CH3)3
H H
778. CD2C(CH3)3
H CD2CH3
H
779. CD2C(CH3)3
H CD(CH3)2
H
780. CD2C(CH3)3
H CD2CH(CH3)2
H
781. CD2C(CH3)3
H C(CH3)3
H
782. CD2C(CH3)3
H CD2C(CH3)3
H
783. CD2C(CH3)3
H CD2CH2CF3
H
784. CD2C(CH3)3
H CD2C(CH3)2CF3
H
785. CD2C(CH3)3
H H
786. CD2C(CH3)3
H H
787. CD2C(CH3)3
H H
788. CD2C(CH3)3
H H
789. CD2C(CH3)3
H H
790. CD2C(CH3)3
H H
791. H CD2CH3
H
792. H CD(CH3)2
H
793. H CD2CH(CH3)2
H
794. H C(CH3)3
H
795. H CD2C(CH3)3
H
796. H CD2CH2CF3
H
797. H CD2C(CH3)2CF3
H
798. H H
799. H H
800. H H
801. H H
802. H H
803. H H
804. H CD2CH3
H
805. H CD(CH3)2
H
806. H CD2CH(CH3)2
H
807. H C(CH3)3
H
808. H CD2C(CH3)3
H
809. H CD2CH2CF3
H
810. H CD2C(CH3)2CF3
H
811. H H
812. H H
813. H H
814. H H
815. H H
816. H H
817. H CD2CH3
H
818. H CD(CH3)2
H
819. H CD2CH(CH3)2
H
820. H C(CH3)3
H
821. H CD2C(CH3)3
H
822. H CD2CH2CF3
H
823. H CD2C(CH3)2CF3
H
824. H H
825. H H
826. H H
827. H H
828. H H
829. H H
830. H CD2CH3
H
831. H CD(CH3)2
H
832. H CD2CH(CH3)2
H
833. H C(CH3)3
H
834. H CD2C(CH3)3
H
835. H CD2CH2CF3
H
836. H CD2C(CH3)2CF3
H
837. H H
838. H H
839. H H
840. H H
841. H H
842. H H
843. H CD2CH3
H
844. H CD(CH3)2
H
845. H CD2CH(CH3)2
H
846. H C(CH3)3
H
847. H CD2C(CH3)3
H
848. H CD2CH2CF3
H
849. H CD2C(CH3)2CF3
H
850. H H
851. H H
852. H H
853. H H
854. H H
855. H H
and R
B1, RB2, RB3, RB4 for each j is defined as follows:
.
15. An organic light-emitting device (OLED) comprising:
an anode;
a cathode; and
an organic layer, disposed between the anode and the cathode, comprising a first compound;
wherein the first compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature;
wherein the first compound has at least one aromatic ring and at least one substituent R;
wherein each of the at least one substituent R is directly bonded to one of the at least one aromatic ring;
wherein
(a) G1 is selected from the group consisting of NR1, SiR1R2, Ge R1R2, alkyl, cycloalkyl, and combinations thereof; and G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3;
(b) G1 is a direct bond; and G2 is a non-aromatic spiro polycyclic group, which can be further substituted by one or more R3; or
(c) G1 is selected from the group consisting of: direct bond, NR1, SiR1R2, Ge R1R2, alkyl, cycloalkyl, and combinations thereof; G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3; and R is directly bonded to an aromatic ring selected from the group consisting of phenyl, pyridine, and triazine, which can be further fused to other rings;
wherein R1, R2, and R3 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
wherein each G1 and G2 can be independently, partially or fully deuterated.
16. The OLED of claim 15 , wherein the OLED is incorporated into a device selected from the group consisting of a consumer product, an electronic component module, and a lighting panel.
17. The OLED of claim 15 , wherein the organic layer is an emissive layer and the compound is an emissive dopant or a non-emissive dopant.
18. The OLED of claim 15 , wherein the organic layer further comprises a host, wherein host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene, aza-triphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
20. A formulation comprising a composition including a first compound;
wherein the first compound is capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature;
wherein the first compound has at least one aromatic ring and at least one substituent R;
wherein each of the at least one substituent R is directly bonded to one of the at least one aromatic ring;
wherein
(a) G1 is selected from the group consisting of NR1, SiR1R2, Ge R1R2, alkyl, cycloalkyl, and combinations thereof; and G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3;
(b) G1 is a direct bond; and G2 is a non-aromatic spiro polycyclic group, which can be further substituted by one or more R3; or
(c) G1 is selected from the group consisting of: direct bond, NR1, SiR1R2, Ge R1R2, alkyl, cycloalkyl, and combinations thereof; G2 is a non-aromatic polycyclic group, which can be further substituted by one or more R3; and R is directly bonded to an aromatic ring selected from the group consisting of phenyl, pyridine, and triazine, which can be further fused to other rings;
wherein R1, R2, and R3 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
wherein each G1 and G2 can be independently, partially or fully deuterated.
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KR102384222B1 (en) * | 2014-09-26 | 2022-04-07 | 삼성전자주식회사 | Organometallic compound and organic light emitting device including the same |
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US10361381B2 (en) | 2019-07-23 |
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