US20140086755A1 - Turbocharger and component therefor - Google Patents
Turbocharger and component therefor Download PDFInfo
- Publication number
- US20140086755A1 US20140086755A1 US14/119,242 US201214119242A US2014086755A1 US 20140086755 A1 US20140086755 A1 US 20140086755A1 US 201214119242 A US201214119242 A US 201214119242A US 2014086755 A1 US2014086755 A1 US 2014086755A1
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- turbocharger
- iron
- based alloy
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 76
- 239000000956 alloy Substances 0.000 claims abstract description 37
- 229910052742 iron Inorganic materials 0.000 claims abstract description 36
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 35
- 150000004767 nitrides Chemical group 0.000 claims abstract description 10
- 229910052758 niobium Inorganic materials 0.000 claims description 11
- 229910052721 tungsten Inorganic materials 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 description 28
- 239000007789 gas Substances 0.000 description 20
- 238000000034 method Methods 0.000 description 18
- 230000008569 process Effects 0.000 description 17
- 230000007797 corrosion Effects 0.000 description 11
- 238000005260 corrosion Methods 0.000 description 11
- 239000010955 niobium Substances 0.000 description 10
- 239000011651 chromium Substances 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 9
- 238000007254 oxidation reaction Methods 0.000 description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 7
- 238000001556 precipitation Methods 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 239000011572 manganese Substances 0.000 description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000272534 Struthio camelus Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012629 conventional elemental analysis Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000010349 pulsation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000010200 validation analysis Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
- F01D25/24—Casings; Casing parts, e.g. diaphragms, casing fastenings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B37/00—Engines characterised by provision of pumps driven at least for part of the time by exhaust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
- F02C6/04—Gas-turbine plants providing heated or pressurised working fluid for other apparatus, e.g. without mechanical power output
- F02C6/10—Gas-turbine plants providing heated or pressurised working fluid for other apparatus, e.g. without mechanical power output supplying working fluid to a user, e.g. a chemical process, which returns working fluid to a turbine of the plant
- F02C6/12—Turbochargers, i.e. plants for augmenting mechanical power output of internal-combustion piston engines by increase of charge pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/10—Metals, alloys or intermetallic compounds
- F05D2300/13—Refractory metals, i.e. Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W
Definitions
- the invention relates to a component for turbocharger applications, in particular in a diesel engine, as per the preamble of claim 1 , and also to an exhaust-gas turbocharger comprising a component as per the preamble of claim 7 .
- Exhaust-gas turbochargers are systems intended to increase the power of piston engines.
- an exhaust-gas turbocharger the energy of the exhaust gases is used to increase the power.
- the increase in power is a result of the increase in the throughput of mixture per working stroke.
- a turbocharger consists essentially of an exhaust-gas turbine with a shaft and a compressor, wherein the compressor arranged in the intake tract of the engine is connected to the shaft and the blade wheels located in the casing of the exhaust-gas turbine and the compressor rotate.
- adjusting blades are additionally mounted rotatably in a blade bearing ring and are moved by means of an adjusting ring arranged in the turbine casing of the turbocharger.
- the material of the components of a turbocharger and in particular of the kinematics components or of the wastegate components thereof, or, in the case of a VTG turbocharger, also of the VTG components thereof.
- the material of these components has to be heat-resistant, i.e. it still has to afford sufficient strength and therefore dimensional stability even at very high temperatures of up to about 900° C.
- the material has to have a high resistance to wear and also appropriate oxidation resistance, so that the corrosion or wear on the material is reduced even at the high operating temperatures of several hundred ° C., and therefore the resistance of the material remains ensured under the extreme operating conditions.
- turbocharger applications as per the preamble of claim 1 and also a turbocharger as per the preamble of claim 7 , which have an improved temperature and oxidation resistance and therefore also a very good dimensional stability and high-temperature strength, and also corrosion resistance, are distinguished by optimum tribological properties and additionally show a reduced susceptibility to wear.
- an improved temperature resistance of the material and in particular improved sliding wear properties and a reduced tendency toward oxidation are achieved by the embodiment according to the invention, in the form of a component for turbocharger applications or of an exhaust-gas turbocharger comprising such a component, consisting of an iron-based alloy having a ferritic base structure which comprises a carbide and nitride structure.
- a carbide structure or nitride structure is understood to mean in this case a microstructural carbide precipitation phase or nitride precipitation phase which is formed in the grain and at the grain boundaries of the iron-based alloy.
- the carbide structure is, in particular, a dendritic microstructure, as a result of which a very good resistance of the material and therefore of the component to deformation and wear is also obtained.
- the component according to the invention and therefore the exhaust-gas turbocharger according to the invention are also dimensionally stable in long-term operation.
- the iron-based alloy according to the invention i.e. the ferritic iron-based material having a carbide and nitride structure which forms the component, is distinguished by a maximum sliding wear rate of 0.08 mm in diameter given a contact pressure of 20 MPa, a sliding speed of 0.0025 m/s, a component temperature of about 850° C. and 2 000 000 cycles, i.e. an extraordinary resistance to friction wear.
- the high-temperature strength, the dimensional stability and also the high-temperature performance are also improved.
- the wear properties of the component i.e. specifically the resistance thereof to friction wear
- the elements W, Ti and Nb substantially form the carbide formations in the iron-based alloy, which, in addition to the very good wear performance, also increases the corrosion resistance of the material and therefore of the component according to the invention.
- the component according to the invention for turbocharger applications is distinguished by the fact that it comprises at least one of the elements selected from: C, W, Cr, Mn, Ti, V, Nb and Si.
- the presence of at least one of these elements is to be understood as meaning that such an element or a combination of these elements is used to produce the iron-based alloy, which is then processed to form the component according to the invention.
- the elements added to the iron-based alloy can be present here in their original form, i.e. in elemental form, for example in the form of inclusions or precipitation phases, or else in the form of derivatives thereof, i.e. in the form of a compound of the corresponding element, e.g.
- the component according to the invention as a metal carbide or metal nitride, which form either during the production of the iron-based alloy or else when forming the component according to the invention which is produced therefrom.
- the presence of the elements can be detected directly in this case in the component according to the invention by conventional analytical methods.
- the element carbon serves here primarily for forming the carbide structure according to the invention, i.e. the carbidic precipitation phases, and therefore improves the strength of the material and also the high-temperature strength thereof, and therefore of the component according to the invention for turbocharger applications.
- the element tungsten too, mostly as a result of the formation of carbidic structures, increases the high-temperature strength and wear resistance of the material and contributes to the toughness thereof.
- a combination of tungsten with chromium and/or molybdenum makes it possible to considerably improve the corrosion resistance of the material in acid media, and also the hot corrosion performance.
- the use of chromium here increases the high-temperature tensile strength and the scaling resistance of the material.
- Chromium is additionally a strong carbide former, and therefore the wear properties of the material, and therefore of the component according to the invention, are also optimized thereby.
- the use of the element chromium in the iron-based alloy from which the component according to the invention for turbocharger applications is formed has yet another advantage: under the action of high exhaust-gas temperatures on the component, the chromium forms a Cr 2 O 3 surface layer, i.e. an oxidic surface layer on the component, which efficiently promotes the resistance of the component to sliding friction and friction wear under thermal loading.
- the use of manganese has a deoxidizing effect. It expands the gamma region of the iron-based alloy and increases the yield strength and tensile strength of the material.
- manganese promotes the wear resistance of the component, in particular at high operating temperatures.
- Vanadium refines the primary grain of the iron-based alloy during the production thereof and therefore refines the cast structure thereof. This achieves a high degree of grain refinement, which promotes the homogeneity of the iron-based alloy and permits a higher dynamic contact pressure of the material.
- the element niobium acts as a carbide former and therefore promotes the carbide structure in the grain and at the grain boundaries of the iron-based alloy.
- Niobium also increases the high-temperature strength and the fatigue strength of the material, and therefore also of the component according to the invention for turbocharger applications.
- Niobium furthermore promotes the ferrite formation and reduces the gamma region of the iron-based alloy, and can therefore be used in a regulative capacity.
- Silicon promotes the casting properties of the iron-based alloy by reducing the viscosity of the melt during casting.
- silicon in the material according to the invention promotes deoxidation, and therefore the addition of this element to the alloy decisively improves the resistance to hot corrosion.
- the properties of the iron-based alloy can therefore be controlled in a targeted manner, such that the component according to the invention for turbocharger applications and therefore also the exhaust-gas turbocharger according to the invention have a particularly balanced profile of properties. Further elements, and also compounds, can be introduced into the iron-based alloy.
- the component according to the invention for turbocharger applications is distinguished by the fact that it comprises substantially the elements carbon (C) with 0.1 to 0.5% by weight, in particular with 0.25 to 0.4% by weight, chromium (Cr) with 15 to 22% by weight, in particular with 18 to 20% by weight, manganese (Mn) with at most 1.3% by weight, in particular with at most 1% by weight, silicon (Si) with 0.8 to 2.1% by weight, in particular with 1 to 1.8% by weight, niobium (Nb) with 0.4 to 1.3% by weight, in particular with 0.6 to 1.1% by weight, titanium (Ti) with 0.2 to 0.6% by weight, in particular with 0.3 to 0.5% by weight, tungsten (W) with 1.8 to 3.0% by weight, in particular with 2 to 2.7% by weight, vanadium (V) with 0.3 to 1.0% by weight, in particular with 0.5 to 0.8% by weight, nitrogen (N) with at most 3% by weight, in particular with at most 2% by weight, and
- the indications of quantity in each case relate here to the overall weight of the iron-based alloy from which the component according to the invention is formed.
- the presence of said elements is to be understood as meaning that they can be present both in elemental form and also in the form of one of the compounds thereof in the iron-based alloy, and therefore in the component according to the invention for turbocharger applications.
- substantially the aforementioned elements are present in the component according to the invention in the quantities indicated. This means that unavoidable impurities may be present, although these preferably make up less than 2% by weight and in particular less than 1% by weight, based on the overall weight of the iron-based alloy.
- the unavoidable residues or impurities in this case comprise, for example, aluminum (Al), nickel (Ni), zirconium (Zr), cerium (Ce), boron (B), phosphorus (P) and sulfur (S).
- Al aluminum
- Ni nickel
- Zr zirconium
- Ce cerium
- B boron
- P phosphorus
- S sulfur
- the quantities of the individual elements can in this case be detected directly in the component according to the invention by means of conventional elemental analysis methods.
- This composition according to the invention provides a component which has a particularly high high-temperature strength, a temperature resistance up to 900° C. and therefore dimensional stability at a high temperature, and which is distinguished by outstanding sliding properties and therefore particularly low sliding wear.
- the corrosion resistance and oxidation resistance are maximized, in particular at high operating temperatures, as act during operation of a turbocharger on the corresponding component.
- a material which is produced in this way and from which the component according to the invention is formed thus has the following properties:
- the component for turbocharger applications is substantially free of sigma phases.
- Sigma phases are brittle, intermetallic phases of high hardness. They arise when a body-centered cubic metal and a face-centered cubic metal, whose atomic radii match with only a slight discrepancy, strike one another. Sigma phases of this type are undesirable since they have an embrittling effect and also because of the property of the iron matrix to withdraw chromium.
- the iron-based alloy according to the invention and therefore also the component according to the invention are substantially free of sigma phases, such that the undesirable effects described here fail to appear.
- the reduction in or prevention of the formation of sigma phases is controlled, in particular, by a targeted selection of the elements of the iron-based alloy, and in particular is achieved in that the silicon content in the alloy material is at most 2.1% by weight and preferably at most 1.8% by weight, based in each case on the overall weight of the iron-based alloy.
- a component for turbocharger applications which is distinguished by an outstanding wear performance, i.e. a high sliding wear resistance even at high temperatures of up to 900° C., a high high-temperature strength and also dimensional stability and furthermore by an excellent oxidation resistance and corrosion resistance.
- the component according to the invention is suitable in particular for those components for turbocharger applications which are exposed to high temperatures of up to 900° C. and/or high levels of friction.
- Exemplary components comprise kinematics components, wastegate components and VTG components, and in particular VTG components and flap mount parts.
- the iron-based alloy can be produced and processed to form the component according to the invention for turbocharger applications by means of conventional processes. To ensure dimensional stability, age-annealing can be carried out at 900° C. for about 2 hours, with subsequent air cooling, in order to generate secondary precipitations.
- the material can be welded by means of TIG, plasma and EB welding processes.
- claim 7 defines an exhaust-gas turbocharger comprising at least one component, as already described, which consists of an iron-based alloy having a ferritic base structure and comprises a carbide and nitride structure.
- FIG. 1 shows a perspective view, shown partially in section, of an exhaust-gas turbocharger according to the invention.
- FIG. 1 shows a turbocharger 1 according to the invention, which has a turbine casing 2 and a compressor casing 3 which is connected to the latter via a bearing casing 28 .
- the casings 2 , 3 and 28 are arranged along an axis of rotation R.
- the turbine casing is shown partially in section in order to illustrate the arrangement of a blade bearing ring 6 and a radially outer guide grate 18 , which is formed by said ring and has a plurality of adjusting blades 7 which are distributed over the circumference and have rotary axles 8 .
- nozzle cross sections are formed which, depending on the position of the adjusting blades 7 , are larger or smaller and act to a greater or lesser extent upon the turbine rotor 4 , positioned in the center on the axis of rotation R, with the exhaust gas from an engine, said exhaust gas being supplied via a supply duct 9 and discharged via a central connection piece 10 , in order to drive a compressor rotor 17 seated on the same shaft using the turbine rotor 4 .
- an actuating device 11 is provided in order to control the movement or the position of the adjusting blades 7 .
- This may be designed in any desired way, but a preferred embodiment has a control casing 12 which controls the control movement of a tappet member 14 fastened to it, in order to convert the movement of said tappet member on an adjusting ring 5 , located behind the blade bearing ring 6 , into a slight rotational movement of the latter.
- a free space 13 for the adjusting blades 7 is formed between the blade bearing ring 6 and an annular part 15 of the turbine casing 2 . So that this free space 13 can be ensured, the blade bearing ring 6 has spacers 16 .
- the indications of quantity of the individual elements relate in each case to the overall weight of the iron-based alloy.
- An iron-based alloy from which a plurality of components according to the invention for turbocharger applications, specifically flap shaft, flap plate and bush, were formed was produced from the following elements by a common process.
- the chemical analysis yielded the following values for the elements: C: 0.25 to 0.4% by weight, Cr: 18 to 20% by weight, Mn: less than 1% by weight, Si: 1 to 1.8% by weight, Nb: 0.6 to 1.1% by weight, Ti: 0.3 to 0.5% by weight, W: 2 to 2.7% by weight, V: 0.5 to 0.8% by weight, N: ⁇ 3% by weight, and Fe as the remainder.
- unavoidable residues of Al, Ni, Zr, Ce, B, P and S were found in traces with a proportion of less than 1% by weight.
- Measured value Property Tensile strength R m at 20° C. 655 MPa (ASTM E 8M/EN 10002-1) Yield strength R p 0.2 at 20° C. 277 MPa (standard process) Elongation at break 13.5% (standard process) Hardness 248 HB (ASTM E 92/ISO 6507-1) Coefficient of linear expansion at 20° C. 12.6 K ⁇ 1 (standard process) High-temperature strength R m at 900° C. 123 MPa (EN 10002-5) High-temperature strength R m at 800° C. 188 MPa (EN 10002-5) High-temperature strength R m at 700° C. 257 MPa (EN 10002-5) High-temperature strength R m at 600° C.
- the material was subjected to a validation test series which comprised the following tests:
- the respective component was distinguished in all tests by an outstanding resistance to the acting forces.
- the material therefore had an extremely high wear resistance and outstanding oxidation resistance, such that corrosion and wear/friction wear to the material were reduced considerably under the indicated conditions, and therefore the resistance of the material and therefore also of the component formed therefrom also remained ensured over a long time.
- the respective component (shaft/bush) according to the invention was distinguished by a low high-temperature oxidation, i.e. an oxidation rate of at most 40 ⁇ m, in particular of at most 35 ⁇ m, at a component temperature of 900° C.:
- Parameter Result Bearing load 10-18 N/mm 2 Sliding speed 0.0025 m/s Component temperature 500-900° C.
- Surface roughness Rz 6.3 Test medium Diesel exhaust gas Test duration 500 h Clock frequency 0.2 Hz Adjustment angle 45° Friction value ⁇ 0.18 Journal diameter 4.7 mm Pressure pulsation >200 bar Exhaust-gas pressure 1.5 bar Wear rate ⁇ 0.08 mm
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Abstract
A component for turbocharger applications, in particular in diesel engines, which has an iron-based alloy having a ferritic base structure which has a carbide and nitride structure.
Description
- The invention relates to a component for turbocharger applications, in particular in a diesel engine, as per the preamble of claim 1, and also to an exhaust-gas turbocharger comprising a component as per the preamble of
claim 7. - Exhaust-gas turbochargers are systems intended to increase the power of piston engines. In an exhaust-gas turbocharger, the energy of the exhaust gases is used to increase the power. The increase in power is a result of the increase in the throughput of mixture per working stroke.
- A turbocharger consists essentially of an exhaust-gas turbine with a shaft and a compressor, wherein the compressor arranged in the intake tract of the engine is connected to the shaft and the blade wheels located in the casing of the exhaust-gas turbine and the compressor rotate. In the case of a turbocharger having a variable turbine geometry, adjusting blades are additionally mounted rotatably in a blade bearing ring and are moved by means of an adjusting ring arranged in the turbine casing of the turbocharger.
- Extremely high demands are made on the material of the components of a turbocharger, and in particular of the kinematics components or of the wastegate components thereof, or, in the case of a VTG turbocharger, also of the VTG components thereof. The material of these components has to be heat-resistant, i.e. it still has to afford sufficient strength and therefore dimensional stability even at very high temperatures of up to about 900° C. Furthermore, the material has to have a high resistance to wear and also appropriate oxidation resistance, so that the corrosion or wear on the material is reduced even at the high operating temperatures of several hundred ° C., and therefore the resistance of the material remains ensured under the extreme operating conditions.
- DE 10 2004 062 564 A1 discloses a blade bearing ring for a turbocharger having good thermal stability and low sliding wear. In this type of blade bearing ring, use is made of an austenitic material, an iron-based alloy which has a high sulfur content for improving the lubricating action of the component. Owing to the specific composition, the creep resistance of the material is increased and therefore an increased dimensional stability of the blade bearing ring is achieved at temperatures of above 850° C.
- In view of this, it is an object of the present invention to provide a component for turbocharger applications as per the preamble of claim 1 and also a turbocharger as per the preamble of
claim 7, which have an improved temperature and oxidation resistance and therefore also a very good dimensional stability and high-temperature strength, and also corrosion resistance, are distinguished by optimum tribological properties and additionally show a reduced susceptibility to wear. - The object is achieved by the features of claim 1 and of
claim 7. - An improved temperature resistance of the material and in particular improved sliding wear properties and a reduced tendency toward oxidation are achieved by the embodiment according to the invention, in the form of a component for turbocharger applications or of an exhaust-gas turbocharger comprising such a component, consisting of an iron-based alloy having a ferritic base structure which comprises a carbide and nitride structure. Within the context of the invention, a carbide structure or nitride structure is understood to mean in this case a microstructural carbide precipitation phase or nitride precipitation phase which is formed in the grain and at the grain boundaries of the iron-based alloy. The carbide structure is, in particular, a dendritic microstructure, as a result of which a very good resistance of the material and therefore of the component to deformation and wear is also obtained. Provision is therefore made of a component for turbocharger applications, or an exhaust-gas turbocharger which comprises at least one component according to the invention, which has an optimum temperature resistance up to 900° C., also has a high high-temperature strength, has a high wear and corrosion resistance and is distinguished in addition by very good sliding properties with a reduced tendency toward oxidation, in particular at the high operating temperatures. Furthermore, the component according to the invention and therefore the exhaust-gas turbocharger according to the invention are also dimensionally stable in long-term operation.
- Without being bound to theory, it is assumed that the presence of carbide precipitations and also nitride precipitations in the ferritic iron-based alloy considerably increases the stability of the alloy material and therefore the stability of the component, in particular to friction wear, and also the high-temperature strength thereof on account of this unique structure.
- By way of example, the iron-based alloy according to the invention, i.e. the ferritic iron-based material having a carbide and nitride structure which forms the component, is distinguished by a maximum sliding wear rate of 0.08 mm in diameter given a contact pressure of 20 MPa, a sliding speed of 0.0025 m/s, a component temperature of about 850° C. and 2 000 000 cycles, i.e. an extraordinary resistance to friction wear. In addition, the high-temperature strength, the dimensional stability and also the high-temperature performance are also improved.
- The dependent claims relate to advantageous developments of the invention.
- Thus, in one embodiment, the wear properties of the component, i.e. specifically the resistance thereof to friction wear, can be improved considerably by the use of at least one of the elements tungsten (W), titanium (Ti) and niobium (Nb) in the ferritic iron-based alloy from which the component according to the invention is formed. The elements W, Ti and Nb substantially form the carbide formations in the iron-based alloy, which, in addition to the very good wear performance, also increases the corrosion resistance of the material and therefore of the component according to the invention.
- In a further embodiment, the component according to the invention for turbocharger applications is distinguished by the fact that it comprises at least one of the elements selected from: C, W, Cr, Mn, Ti, V, Nb and Si. The presence of at least one of these elements is to be understood as meaning that such an element or a combination of these elements is used to produce the iron-based alloy, which is then processed to form the component according to the invention. The elements added to the iron-based alloy can be present here in their original form, i.e. in elemental form, for example in the form of inclusions or precipitation phases, or else in the form of derivatives thereof, i.e. in the form of a compound of the corresponding element, e.g. as a metal carbide or metal nitride, which form either during the production of the iron-based alloy or else when forming the component according to the invention which is produced therefrom. The presence of the elements can be detected directly in this case in the component according to the invention by conventional analytical methods.
- The element carbon serves here primarily for forming the carbide structure according to the invention, i.e. the carbidic precipitation phases, and therefore improves the strength of the material and also the high-temperature strength thereof, and therefore of the component according to the invention for turbocharger applications. The element tungsten, too, mostly as a result of the formation of carbidic structures, increases the high-temperature strength and wear resistance of the material and contributes to the toughness thereof. A combination of tungsten with chromium and/or molybdenum, in particular, makes it possible to considerably improve the corrosion resistance of the material in acid media, and also the hot corrosion performance. The use of chromium here increases the high-temperature tensile strength and the scaling resistance of the material. Chromium is additionally a strong carbide former, and therefore the wear properties of the material, and therefore of the component according to the invention, are also optimized thereby. The use of the element chromium in the iron-based alloy from which the component according to the invention for turbocharger applications is formed has yet another advantage: under the action of high exhaust-gas temperatures on the component, the chromium forms a Cr2O3 surface layer, i.e. an oxidic surface layer on the component, which efficiently promotes the resistance of the component to sliding friction and friction wear under thermal loading. The use of manganese has a deoxidizing effect. It expands the gamma region of the iron-based alloy and increases the yield strength and tensile strength of the material. In addition, manganese promotes the wear resistance of the component, in particular at high operating temperatures. Vanadium refines the primary grain of the iron-based alloy during the production thereof and therefore refines the cast structure thereof. This achieves a high degree of grain refinement, which promotes the homogeneity of the iron-based alloy and permits a higher dynamic contact pressure of the material. In the iron-based alloy which forms the component according to the invention, the element niobium acts as a carbide former and therefore promotes the carbide structure in the grain and at the grain boundaries of the iron-based alloy. Niobium also increases the high-temperature strength and the fatigue strength of the material, and therefore also of the component according to the invention for turbocharger applications. Niobium furthermore promotes the ferrite formation and reduces the gamma region of the iron-based alloy, and can therefore be used in a regulative capacity. Silicon promotes the casting properties of the iron-based alloy by reducing the viscosity of the melt during casting. In addition, silicon in the material according to the invention promotes deoxidation, and therefore the addition of this element to the alloy decisively improves the resistance to hot corrosion. By suitably selecting and combining the elements, the properties of the iron-based alloy can therefore be controlled in a targeted manner, such that the component according to the invention for turbocharger applications and therefore also the exhaust-gas turbocharger according to the invention have a particularly balanced profile of properties. Further elements, and also compounds, can be introduced into the iron-based alloy.
- According to a further embodiment, the component according to the invention for turbocharger applications is distinguished by the fact that it comprises substantially the elements carbon (C) with 0.1 to 0.5% by weight, in particular with 0.25 to 0.4% by weight, chromium (Cr) with 15 to 22% by weight, in particular with 18 to 20% by weight, manganese (Mn) with at most 1.3% by weight, in particular with at most 1% by weight, silicon (Si) with 0.8 to 2.1% by weight, in particular with 1 to 1.8% by weight, niobium (Nb) with 0.4 to 1.3% by weight, in particular with 0.6 to 1.1% by weight, titanium (Ti) with 0.2 to 0.6% by weight, in particular with 0.3 to 0.5% by weight, tungsten (W) with 1.8 to 3.0% by weight, in particular with 2 to 2.7% by weight, vanadium (V) with 0.3 to 1.0% by weight, in particular with 0.5 to 0.8% by weight, nitrogen (N) with at most 3% by weight, in particular with at most 2% by weight, and iron (Fe) as the remainder. The indications of quantity in each case relate here to the overall weight of the iron-based alloy from which the component according to the invention is formed. As already stated, the presence of said elements is to be understood as meaning that they can be present both in elemental form and also in the form of one of the compounds thereof in the iron-based alloy, and therefore in the component according to the invention for turbocharger applications. In this embodiment, substantially the aforementioned elements are present in the component according to the invention in the quantities indicated. This means that unavoidable impurities may be present, although these preferably make up less than 2% by weight and in particular less than 1% by weight, based on the overall weight of the iron-based alloy. The unavoidable residues or impurities in this case comprise, for example, aluminum (Al), nickel (Ni), zirconium (Zr), cerium (Ce), boron (B), phosphorus (P) and sulfur (S). The quantities of the individual elements can in this case be detected directly in the component according to the invention by means of conventional elemental analysis methods.
- It has surprisingly been found that precisely the described combination provides a material, i.e. an iron-based alloy, which, when it is processed to form a component for turbocharger applications, provides said component with a particularly balanced profile of properties. This composition according to the invention provides a component which has a particularly high high-temperature strength, a temperature resistance up to 900° C. and therefore dimensional stability at a high temperature, and which is distinguished by outstanding sliding properties and therefore particularly low sliding wear. In addition, the corrosion resistance and oxidation resistance are maximized, in particular at high operating temperatures, as act during operation of a turbocharger on the corresponding component.
- A material which is produced in this way and from which the component according to the invention is formed thus has the following properties:
-
Mechanical property Value Measurement process Tensile strength Rm >650 MPa ASTM E 8M/EN 10002- 1; at elevated temp.: EN 10002-5 Yield strength Rp 0.2 >270 MPa Standard process Elongation at break >12% Standard process Hardness 225-265 HB ASTM E 92/ISO 6507-1 Coefficient of linear 10.5-14 K−1 Standard process expansion (20 to 900° C.) - According to a further embodiment of the invention, the component for turbocharger applications is substantially free of sigma phases. This applies in particular to the operation of the component according to the invention up to 900° C. This effectively counteracts embrittlement of the material, as a result of which the durability of the component is increased. Sigma phases are brittle, intermetallic phases of high hardness. They arise when a body-centered cubic metal and a face-centered cubic metal, whose atomic radii match with only a slight discrepancy, strike one another. Sigma phases of this type are undesirable since they have an embrittling effect and also because of the property of the iron matrix to withdraw chromium. The iron-based alloy according to the invention and therefore also the component according to the invention are substantially free of sigma phases, such that the undesirable effects described here fail to appear. The reduction in or prevention of the formation of sigma phases is controlled, in particular, by a targeted selection of the elements of the iron-based alloy, and in particular is achieved in that the silicon content in the alloy material is at most 2.1% by weight and preferably at most 1.8% by weight, based in each case on the overall weight of the iron-based alloy.
- What is therefore described according to the invention is a component for turbocharger applications which is distinguished by an outstanding wear performance, i.e. a high sliding wear resistance even at high temperatures of up to 900° C., a high high-temperature strength and also dimensional stability and furthermore by an excellent oxidation resistance and corrosion resistance. By virtue of these outstanding properties, the component according to the invention is suitable in particular for those components for turbocharger applications which are exposed to high temperatures of up to 900° C. and/or high levels of friction. Exemplary components comprise kinematics components, wastegate components and VTG components, and in particular VTG components and flap mount parts.
- The iron-based alloy can be produced and processed to form the component according to the invention for turbocharger applications by means of conventional processes. To ensure dimensional stability, age-annealing can be carried out at 900° C. for about 2 hours, with subsequent air cooling, in order to generate secondary precipitations. The material can be welded by means of TIG, plasma and EB welding processes.
- As an object which can be dealt with independently,
claim 7 defines an exhaust-gas turbocharger comprising at least one component, as already described, which consists of an iron-based alloy having a ferritic base structure and comprises a carbide and nitride structure. - The advantageous embodiments of the component according to the invention are also applicable in the embodiments of the exhaust-gas turbocharger according to the invention.
-
FIG. 1 shows a perspective view, shown partially in section, of an exhaust-gas turbocharger according to the invention.FIG. 1 shows a turbocharger 1 according to the invention, which has a turbine casing 2 and a compressor casing 3 which is connected to the latter via a bearingcasing 28. Thecasings 2, 3 and 28 are arranged along an axis of rotation R. The turbine casing is shown partially in section in order to illustrate the arrangement of a blade bearing ring 6 and a radiallyouter guide grate 18, which is formed by said ring and has a plurality of adjustingblades 7 which are distributed over the circumference and haverotary axles 8. In this way, nozzle cross sections are formed which, depending on the position of theadjusting blades 7, are larger or smaller and act to a greater or lesser extent upon the turbine rotor 4, positioned in the center on the axis of rotation R, with the exhaust gas from an engine, said exhaust gas being supplied via asupply duct 9 and discharged via acentral connection piece 10, in order to drive acompressor rotor 17 seated on the same shaft using the turbine rotor 4. - In order to control the movement or the position of the
adjusting blades 7, an actuating device 11 is provided. This may be designed in any desired way, but a preferred embodiment has a control casing 12 which controls the control movement of a tappet member 14 fastened to it, in order to convert the movement of said tappet member on an adjusting ring 5, located behind the blade bearing ring 6, into a slight rotational movement of the latter. Afree space 13 for theadjusting blades 7 is formed between the blade bearing ring 6 and anannular part 15 of the turbine casing 2. So that thisfree space 13 can be ensured, the blade bearing ring 6 hasspacers 16. - Unless specified otherwise, the indications of quantity of the individual elements relate in each case to the overall weight of the iron-based alloy.
- An iron-based alloy from which a plurality of components according to the invention for turbocharger applications, specifically flap shaft, flap plate and bush, were formed was produced from the following elements by a common process. The chemical analysis yielded the following values for the elements: C: 0.25 to 0.4% by weight, Cr: 18 to 20% by weight, Mn: less than 1% by weight, Si: 1 to 1.8% by weight, Nb: 0.6 to 1.1% by weight, Ti: 0.3 to 0.5% by weight, W: 2 to 2.7% by weight, V: 0.5 to 0.8% by weight, N: ≦3% by weight, and Fe as the remainder. In addition, unavoidable residues of Al, Ni, Zr, Ce, B, P and S were found in traces with a proportion of less than 1% by weight.
- The components produced in accordance with this example were distinguished by the following properties:
-
Measured value Property (measurement process) Tensile strength Rm at 20° C. 655 MPa (ASTM E 8M/EN 10002-1) Yield strength Rp 0.2 at 20° C. 277 MPa (standard process) Elongation at break 13.5% (standard process) Hardness 248 HB (ASTM E 92/ISO 6507-1) Coefficient of linear expansion at 20° C. 12.6 K−1 (standard process) High-temperature strength Rm at 900° C. 123 MPa (EN 10002-5) High-temperature strength Rm at 800° C. 188 MPa (EN 10002-5) High-temperature strength Rm at 700° C. 257 MPa (EN 10002-5) High-temperature strength Rm at 600° C. 333 MPa (EN 10002-5) High-temperature strength Rm at 500° C. 395 MPa (EN 10002-5) High-temperature strength Rm at 400° C. 443 MPa (EN 10002-5) Yield strength Rp 0.2 at 900° C. 83 MPa (standard process) Yield strength Rp 0.2 at 800° C. 115 MPa (standard process) Yield strength Rp 0.2 at 700° C. 174 MPa (standard process) Yield strength Rp 0.2 at 600° C. 229 MPa (standard process) Yield strength Rp 0.2 at 500° C. 281 MPa (standard process) Yield strength Rp 0.2 at 400° C. 360 MPa (standard process) - The material was subjected to a validation test series which comprised the following tests:
- Open-air weathering test
- Climate change test
- Thermal shock test/cycle test—300 h
- Hot-gas corrosion test in a cracking furnace
- Strauss test according to DIN EN ISO 3651-2
- Vibration friction wear test on a tribometer: bush/shaft at operating temperature (900° C.)
- The respective component was distinguished in all tests by an outstanding resistance to the acting forces. The material therefore had an extremely high wear resistance and outstanding oxidation resistance, such that corrosion and wear/friction wear to the material were reduced considerably under the indicated conditions, and therefore the resistance of the material and therefore also of the component formed therefrom also remained ensured over a long time.
- The components (shaft/bush) according to the invention were subjected to a thermal cycle test, in which the thermal shocks were carried out as follows:
- 1. use of stationary rotors;
- 2. 2-EGT operation;
- 3. test duration: 350 h (approximately 2000 cycles);
- 4. throughout the test, the exhaust-gas flap of the EGTs remains open by 15′;
- 5. high temperature: rated power point T3=750° C., mass flow EGT on the turbine side: 0.5 kg/s;
- 6. low temperature: T3=100° C., mass flow EGT on the turbine side: 0.5 kg/s;
- 7. cycle duration: 2×5 min. (10 min.);
- 8. three intermediate crack tests are carried out.
- Given the following load collective, the respective component (shaft/bush) according to the invention was distinguished by a low high-temperature oxidation, i.e. an oxidation rate of at most 40 μm, in particular of at most 35 μm, at a component temperature of 900° C.:
-
Parameter Result Bearing load 10-18 N/mm2 Sliding speed 0.0025 m/s Component temperature 500-900° C. Surface roughness Rz 6.3 Test medium Diesel exhaust gas Test duration 500 h Clock frequency 0.2 Hz Adjustment angle 45° Friction value <0.18 Journal diameter 4.7 mm Pressure pulsation >200 bar Exhaust-gas pressure 1.5 bar Wear rate <0.08 mm - The results indicated here verify that the component according to the invention is ideally suited for turbocharger applications in a temperature range of up to 900° C.
-
- 1 Turbocharger
- 2 Turbine casing
- 3 Compressor casing
- 4 Turbine rotor
- 5 Adjusting ring
- 6 Blade bearing ring
- 7 Adjusting blades
- 8 Pivot axles
- 9 Supply duct
- 10 Axial connection piece
- 11 Actuating device
- 12 Control casing
- 13 Free space for
guide blades 7 - 14 Tappet member
- 15 Annular part of the turbine casing 2
- 16 Spacer/spacer cam
- 17 Compressor rotor
- 18 Guide grate
- 28 Bearing casing
- R Axis of rotation
Claims (12)
1. A component for turbocharger applications, in particular in diesel engines, comprising an iron-based alloy having a ferritic base structure comprising a carbide and nitride structure.
2. The component for turbocharger applications as claimed in claim 1 , comprising at least one of the elements selected from: W, Ti and Nb.
3. The component for turbocharger applications as claimed in claim 1 , comprising at least one of the elements selected from: C, W, Cr, Mn, Ti, V, Nb and Si.
4. The component for turbocharger applications as claimed in claim 1 , comprising substantially the following elements:
C: 0.1 to 0.5% by weight, in particular 0.25 to 0.4% by weight,
Cr: 15 to 22% by weight, in particular 18 to 20% by weight,
Mn: ≦1.3% by weight, in particular ≦1% by weight,
Si: 0.8 to 2.1% by weight, in particular 1 to 1.8% by weight,
Nb: 0.4 to 1.3% by weight, in particular 0.6 to 1.1% by weight,
Ti: 0.2 to 0.6% by weight, in particular 0.3 to 0.5% by weight,
W: 1.8 to 3.0% by weight, in particular 2 to 2.7% by weight,
V: 0.3 to 1.0% by weight, in particular 0.5 to 0.8% by weight,
N: ≦3% by weight, in particular ≦2% by weight, and
Fe: ad 100% by weight.
5. The component for turbocharger applications as claimed in claim 1 , wherein it is substantially free of sigma phases.
6. The component for turbocharger applications as claimed in claim 1 , wherein the component is at least one of a kinematics component, a wastegate component and a VTG component.
7. An exhaust-gas turbocharger in particular for diesel engines, comprising at least one component consisting of an iron-based alloy having a ferritic base structure comprising a carbide and nitride structure.
8. The exhaust-gas turbocharger as claimed in claim 7 , wherein the component comprises at least one of the elements selected from: W, Ti and Nb.
9. The exhaust-gas turbocharger as claimed in claim 7 , wherein the component comprises substantially the following elements:
C: 0.1 to 0.5% by weight, in particular 0.25 to 0.4% by weight,
Cr: 15 to 22% by weight, in particular 18 to 20% by weight,
Mn: ≦1.3% by weight, in particular ≦1% by weight,
Si: 0.8 to 2.1% by weight, in particular 1 to 1.8% by weight,
Nb: 0.4 to 1.3% by weight, in particular 0.6 to 1.1% by weight,
Ti: 0.2 to 0.6% by weight, in particular 0.3 to 0.5% by weight,
W: 1.8 to 3.0% by weight, in particular 2 to 2.7% by weight,
V: 0.3 to 1.0% by weight, in particular 0.5 to 0.8% by weight,
N: ≦3% by weight, in particular ≦2% by weight, and
Fe: ad 100% by weight.
10. The exhaust-gas turbocharger as claimed in claim 7 , wherein the component is substantially free of sigma phases.
11. The component for turbocharger applications as claimed in claim 1 , wherein the component is a VTG component and/or a flap mount part.
12. The exhaust-gas turbocharger as claimed in claim 7 , wherein the component comprises at least one of the elements selected from: C, W, Cr, Mn, Ti, V, Nb and Si.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE102011103535.8 | 2011-06-07 | ||
DE102011103535 | 2011-06-07 | ||
PCT/US2012/039278 WO2012170210A2 (en) | 2011-06-07 | 2012-05-24 | Turbocharger and component therefor |
Publications (1)
Publication Number | Publication Date |
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US20140086755A1 true US20140086755A1 (en) | 2014-03-27 |
Family
ID=47296681
Family Applications (1)
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US14/119,242 Abandoned US20140086755A1 (en) | 2011-06-07 | 2012-05-24 | Turbocharger and component therefor |
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US (1) | US20140086755A1 (en) |
JP (1) | JP2014523501A (en) |
KR (2) | KR20180108881A (en) |
CN (1) | CN103534458A (en) |
DE (1) | DE112012001811T5 (en) |
WO (1) | WO2012170210A2 (en) |
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WO2018022950A1 (en) * | 2016-07-28 | 2018-02-01 | Borgwarner Inc. | Ferritic steel for turbochargers |
US20190048441A1 (en) * | 2017-08-09 | 2019-02-14 | Honeywell International Inc. | Stainless steel alloys and turbocharger kinematic components formed from stainless steel alloys |
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DE102013216473A1 (en) | 2013-08-20 | 2015-02-26 | Bosch Mahle Turbo Systems Gmbh & Co. Kg | Bushing element for supporting a control shaft of a wastegate device or a variable turbine geometry |
US20150226110A1 (en) * | 2014-02-07 | 2015-08-13 | GM Global Technology Operations LLC | Turbocharger waste-gate valve assembly wear reduction |
US9499889B2 (en) * | 2014-02-24 | 2016-11-22 | Honeywell International Inc. | Stainless steel alloys, turbocharger turbine housings formed from the stainless steel alloys, and methods for manufacturing the same |
US11492690B2 (en) | 2020-07-01 | 2022-11-08 | Garrett Transportation I Inc | Ferritic stainless steel alloys and turbocharger kinematic components formed from stainless steel alloys |
CN113088829A (en) * | 2021-04-07 | 2021-07-09 | 天津达祥精密工业有限公司 | Ferrite system heat-resistant steel for automobile turbine shell and exhaust pipe and preparation method thereof |
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- 2012-05-24 KR KR1020187027399A patent/KR20180108881A/en not_active Application Discontinuation
- 2012-05-24 KR KR1020137034179A patent/KR20140038472A/en active IP Right Grant
- 2012-05-24 DE DE112012001811.7T patent/DE112012001811T5/en not_active Withdrawn
- 2012-05-24 US US14/119,242 patent/US20140086755A1/en not_active Abandoned
- 2012-05-24 JP JP2014514484A patent/JP2014523501A/en active Pending
- 2012-05-24 CN CN201280022878.4A patent/CN103534458A/en active Pending
- 2012-05-24 WO PCT/US2012/039278 patent/WO2012170210A2/en active Application Filing
Patent Citations (4)
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US2793113A (en) * | 1952-08-22 | 1957-05-21 | Hadfields Ltd | Creep resistant steel |
US2848323A (en) * | 1955-02-28 | 1958-08-19 | Birmingham Small Arms Co Ltd | Ferritic steel for high temperature use |
US2905577A (en) * | 1956-01-05 | 1959-09-22 | Birmingham Small Arms Co Ltd | Creep resistant chromium steel |
US20070215252A1 (en) * | 2006-02-23 | 2007-09-20 | Daido Tokushuko Kabushiki Kaisha | Ferritic stainless steel cast iron, cast part using the ferritic stainless steel cast iron, and process for producing the cast part |
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Title |
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Machine-English translation of JP06-256908, Takahashi Norio et al., 9/13/1994 * |
Table 1.1 Essential and Incidental Eleements in Steel and Cast Irons, p.3, Introduction to Steels and Cast Irons, 1997 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018022950A1 (en) * | 2016-07-28 | 2018-02-01 | Borgwarner Inc. | Ferritic steel for turbochargers |
US11821049B2 (en) | 2016-07-28 | 2023-11-21 | Borgwarner Inc. | Ferritic steel for turbochargers |
US20190048441A1 (en) * | 2017-08-09 | 2019-02-14 | Honeywell International Inc. | Stainless steel alloys and turbocharger kinematic components formed from stainless steel alloys |
US10844465B2 (en) * | 2017-08-09 | 2020-11-24 | Garrett Transportation I Inc. | Stainless steel alloys and turbocharger kinematic components formed from stainless steel alloys |
Also Published As
Publication number | Publication date |
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WO2012170210A3 (en) | 2013-01-31 |
KR20140038472A (en) | 2014-03-28 |
CN103534458A (en) | 2014-01-22 |
DE112012001811T5 (en) | 2014-02-06 |
WO2012170210A2 (en) | 2012-12-13 |
JP2014523501A (en) | 2014-09-11 |
KR20180108881A (en) | 2018-10-04 |
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