TW583706B - Forming method of fluorescent surface - Google Patents

Forming method of fluorescent surface Download PDF

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Publication number
TW583706B
TW583706B TW091106995A TW91106995A TW583706B TW 583706 B TW583706 B TW 583706B TW 091106995 A TW091106995 A TW 091106995A TW 91106995 A TW91106995 A TW 91106995A TW 583706 B TW583706 B TW 583706B
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Taiwan
Prior art keywords
phosphor
layer
conductive
film
transfer
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TW091106995A
Other languages
Chinese (zh)
Inventor
Takeshi Sasaki
Koichi Furui
Original Assignee
Sony Corp
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Publication date
Priority claimed from JP2001111292A external-priority patent/JP2002313230A/en
Priority claimed from JP2001111293A external-priority patent/JP2002313231A/en
Application filed by Sony Corp filed Critical Sony Corp
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Publication of TW583706B publication Critical patent/TW583706B/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J31/00Cathode ray tubes; Electron beam tubes
    • H01J31/08Cathode ray tubes; Electron beam tubes having a screen on or from which an image or pattern is formed, picked up, converted, or stored
    • H01J31/10Image or pattern display tubes, i.e. having electrical input and optical output; Flying-spot tubes for scanning purposes
    • H01J31/12Image or pattern display tubes, i.e. having electrical input and optical output; Flying-spot tubes for scanning purposes with luminescent screen
    • H01J31/15Image or pattern display tubes, i.e. having electrical input and optical output; Flying-spot tubes for scanning purposes with luminescent screen with ray or beam selectively directed to luminescent anode segments

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  • Cathode-Ray Tubes And Fluorescent Screens For Display (AREA)

Abstract

The subject of the present invention is to enable formation of a fluorescent surface with superior productivity by a transfer printing method, and in particular, to realize a common part with the conventional forming process of the fluorescent surface, that has only one fluorescent substance part. The solution is: a first fluorescent substance part and a second fluorescent substance part are formed in separate processes by a transfer printing method, using two transfer films 1, 2. Thereby, the conventional transfer film, which has been used for the ordinary flat cathode-ray tube having no icon display region, can still be used as a first transfer film 1 as it is. Also, a part of the manufacturing line of the conventional flat cathode-ray tube having no icon display region can be made common with respect to the forming process of the fluorescent surface. As compared with the case of forming the fluorescent surface as one lot by one transfer film, correction of only one process can do, even if either one of the forming processes of the first and the second fluorescent substance parts produce failures, thus the yield of manufacture can be improved.

Description

583706 A7 B7 五、發明説明(1 ) 【本發明所屬之技術領域】 本發明係有關具有複數螢光體部之螢光面之形成方法 ,尤其是有關利用轉印法之螢光面之形成方法。 【習知之技術】 自以往,陰極線管(CRT ; Cathode RAY Tube)就廣泛 被使用在電視受像機和各種監視裝置等。陰極線管係由配 備在管內(陰極線管內部)的電子鎗向螢光面放射電子波束 ,對管面配合其電子波束的掃瞄形成掃瞄畫面者。陰極線 管的種類大致上有直線型和扁平型。直線型之陰極線管係 以電子波束的發射口相對於螢光面而面對面地配置電子鎗 ,相對於螢光面的中心成爲略垂直地照射電子波束的構造 。另一方面,扁平型陰極線管係將電子鎗和螢光面設置在 略同一平面上,相對於螢光面成爲由斜向開始照射電子波 束的構造。扁平型陰極線管與直線型之陰極線管相比,可 達薄型化之故,多半被利用於較小型的裝置例如對講機裝 置的母機之監視器部分及攜帶型的TV(電視機)監視器等 〇 陰極線管係爲在畫面全體進丫了彩色顯不者’但連卓純 只用黑白視訊(單色)進行映像顯示者也需要被開發。特別 是黑白視訊顯示方式的扁平型陰極線管多數被利用在對講 機裝置中。黑白視訊顯示方式的陰極線管係例如藉由白色 發光螢光體形成螢光面全體’以1個電子波束來掃瞄螢光 面,藉此顯示黑白視訊映像。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐1 " •批衣-- (請先閱讀背面之注意事項再^寫本百^) 訂 經濟部智慧財產局員工消費合作社印製 > -4- 583706 A7 B7 五、發明説明(2 ) 【本發明欲解決之課題】 請 先 閲 讀 背 ιέ 之 注 意 事 項 再 寫 本 可是連利用黑白視訊顯示方式的陰極線管之裝置也要 求部分以彩色進行映像顯示。例如對講機裝置與火災偵測 器及瓦斯測漏檢知器等各種感應裝置組合,就能具有以全 體做爲保安系統的功能。在此種系統構成的情形下,促使 使用者注意之意思,是希望在母機側利用與通常之黑白視 訊顯示不同的顏色(例如紅色)來表現發生異常現象以實行 警告顯示。 於是,本申請人於日本特願第2000-045 1 14號及特願 第2000- 1 17594等中,提案一連黑白視訊顯示方式的陰極 線管也能部分進行彩色顯示的技術。 以下參照第14圖(A),(B),針對本申請人先前的發 明做簡單的說明。第14圖(A),(B)係簡略化扁平型陰極 線管方面的映像顯示部分而示之。習知黑白視訊顯示方式 的扁平型陰極線管110乃如第14圖(A)所示,映像顯示區 域111的全體是藉由單色的螢光體層(例如白色發光螢光 體層)112所形成。 經濟部智慧財產局員工消費合作社印製 一方面,按本申請人之發明的扁平型陰極線管1 2 0乃 如第14圖(B)所示,除設有單色螢光體層122做爲通常之 黑白視訊映像顯不的第1螢光體部1 2 1外,還具備彩色顯 示用之第2螢光體部123。於第2螢光體部123設有利用 與設在第1螢光體部121的螢光體層122不同的顏色所發 光的其他螢光體層1 24。螢光體層1 24係先圖案形成模仿 欲顯示的映像之形狀。第2螢光體部1 23之螢光體層1 24 本紙張尺度適用中國國家標準(CNS ) Α4規格(210 X 297公釐) 5- 583706 A7 B7 五、發明説明(3 ) I--------#批衣II (請先閱讀背面之注意事項再4-寫本百~) 係配合欲顯示的映像利用單色(例如紅色)或複數色加以形 成。藉此利用電子波束掃瞄第2螢光體部1 23時,其螢光 體圖案部分會發光,成爲圖像狀的彩色映像顯示。此時藉 由在第2螢光體部123形成複數螢光體圖案(圖像圖案 )124A,124B,124C,就可同時或個別顯示複數圖像映像 〇583706 A7 B7 V. Description of the invention (1) [Technical field to which the present invention belongs] The present invention relates to a method for forming a fluorescent surface having a plurality of fluorescent bodies, and particularly to a method for forming a fluorescent surface using a transfer method . [Know-how] Cathode ray tubes (CRT; Cathode RAY Tube) have been widely used in television receivers and various monitoring devices. The cathode-ray tube is an electron gun provided in the tube (inside the cathode-ray tube), which emits an electron beam toward the fluorescent surface, and the scanning surface is formed by scanning the tube surface with its electron beam. The types of cathode tubes are roughly linear and flat. The linear cathode-ray tube system arranges the electron gun with the emission port of the electron beam facing the fluorescent surface, and has a structure that irradiates the electron beam slightly perpendicularly to the center of the fluorescent surface. On the other hand, the flat-type cathode-ray tube system has a structure in which the electron gun and the fluorescent surface are arranged on a substantially same plane, and the electron beam is irradiated from an oblique direction with respect to the fluorescent surface. Compared with the straight cathode tube, the flat cathode tube can be made thinner. It is mostly used in smaller devices such as the monitor part of the main unit of a walkie talkie device and a portable TV (television) monitor. The cathode ray tube system is a color display in the whole picture ', but even Zhuochun who only uses black and white video (monochrome) for image display needs to be developed. In particular, flat cathode-ray tubes of the black-and-white video display method are mostly used in two-way radios. The cathode-ray tube of the black-and-white video display method, for example, forms the entire fluorescent screen with a white light-emitting phosphor, and scans the fluorescent screen with one electron beam, thereby displaying a black-and-white video image. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297mm1 " • Approved clothing-(Please read the notes on the back before ^ copy this one hundred ^) Order printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs & gt -4- 583706 A7 B7 V. Explanation of the invention (2) [Questions to be solved by the present invention] Please read the precautions before you write this, but even the device using the cathode-ray tube using the black and white video display method also requires part to be performed in color Video display. For example, the combination of walkie-talkie devices with various sensor devices such as fire detectors and gas leak detectors can have the function of the entire system as a security system. In the case of such a system configuration, users are reminded to pay attention This means that the parent machine uses a different color (for example, red) from the usual black-and-white video display to indicate that an abnormality has occurred to implement a warning display. Therefore, the applicant in Japanese Patent Application No. 2000-045 1 14 and Japanese Patent Application In 2000-1117594, etc., a technology was proposed in which even a cathode ray tube of a black-and-white video display method can partially perform color display. A brief description of the applicant's previous invention will be given in accordance with Figs. 14 (A) and (B). Figs. 14 (A) and (B) are simplified illustrations of the image display part of the flat cathode wire tube. As shown in FIG. 14 (A), the flat cathode ray tube 110 of the conventional black-and-white video display method is formed by a monochromatic phosphor layer (eg, a white light-emitting phosphor layer) 112 as a whole. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. On the one hand, according to the applicant's invention, the flat cathode wire tube 1 2 0 is shown in FIG. In addition to the first phosphor section 1 2 1 where the black-and-white video image is displayed, a second phosphor section 123 for color display is provided. The second phosphor section 123 is provided with a first phosphor section and a first phosphor section 123. The other phosphor layers 1 24 which emit light of different colors from the phosphor layer 122 of the body 121. The phosphor layers 1 24 are first patterned to imitate the shape of the image to be displayed. The phosphor layers of the second phosphor portion 1 23 1 24 This paper size applies to China National Standard (CNS) Α4 size (210 X 297 mm) 5- 5 83706 A7 B7 V. Description of the invention (3) I -------- # 批 衣 II (Please read the precautions on the back first and then 4-copy one hundred ~) It is used in monochrome with the image to be displayed (such as red ) Or multiple colors. When the second phosphor portion 1 23 is scanned with an electron beam, the phosphor pattern portion will emit light and become an image-like color image display. At this time, the second phosphor portion is displayed on the second phosphor portion. The light body portion 123 forms a plurality of phosphor patterns (image patterns) 124A, 124B, 124C, and a plurality of image images can be displayed simultaneously or individually.

如此一來,藉由本申請人發明的陰極線管,除了以通 常顯示的黑白視訊映像外,圖像狀的映像能以彩色顯示。 以下將具有該圖像顯示功能的陰極線管簡稱爲「圖像CRT J ° 可是第14圖(A)所示的習知扁平型陰極線管110中, 形成其螢光面之方法據知有利用例如日本特願平第11 -247353號等所揭示之轉印法者。使用該轉印法之方法係 爲使用積層螢光面的構成要素(螢光體層及導電層等)之轉 印用薄膜,在陰極線管的被轉印面轉印螢光體層等。只要 按此方法就可在1個轉印用薄膜,全部一倂轉印螢光面的 構成要素。 經濟部智慧財產局員工消費合作社印製 然而,藉由使用此種1個轉印用薄膜的習知轉印法, 形成第14圖(B)所示的圖像CRT120之螢光面時,會產生 以下的問題。首先,爲了只在1個轉印用薄膜形成圖像 CRT 120之螢光面,加上通常的映像顯示部之螢光面(第1 螢光體部1 2 1)’必須使用全部積層圖像顯示部的螢光面( 第2螢光體部123)之構成要素。亦即,圖像CRT用之轉 印用溥膜係爲與習知扁平型陰極線管11 〇所使用之轉印用 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公餐)—----- -6- 經濟部智慧財產局員工消費合作杜印製 583706 A7 ___B7_ 五、發明説明(4 ) 薄膜不同的構造。因此,於螢光面之形成工程中,則有無 法與沒有圖像部的通常之扁平型陰極線管110的製造生產 線共通化的問題。又,亦有浪費習知使用之轉印用薄膜的 問題。又,一倂形成螢光面之故,只在一部分產生(例如 僅圖像顯示用的螢光體部123)形成不良時,而有螢光面 全體變不良,生產性受損的問題。 本發明係有鑑於相關問題點之發明,其目的在於提供 可利用轉印法形成生產性優的螢光面,尤其是僅有單一螢 光體部的習知螢光面之形成工程時,還可達到一部分共通 化之螢光面之形成方法。 【用以解決課題之手段】 按本發明之螢光面之形成方法係包含:使用至少積層 第1螢光體層的第1轉印用薄膜,利用轉印法形成第1螢 光體部之第1工程,和使用至少積層第2螢光體層的第2 轉印用薄膜,在與設有第1螢光體層之區域不同的區域, 利用轉印法形成第2螢光體部之第2工程。 再者,於本發明中,第1螢光體層係由例如發出白色 光的白色發光螢光體所構成。白色發光螢光體是指單獨發 出白色光的螢光體外,也包含例如以適當的比率混合藍色 發光螢光體和黃色發光螢光體,使外觀上發出白色光的螢 光體。 按本發明之螢光面之形成方法,係藉由使用至少積層 第1螢光體層的第1轉印用薄膜之轉印法形成第1螢光體 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) ' " I 0^------、玎------0 (請先閱讀背面之注意事項再t寫本XW-) -7- 583706 A7 ____ B7 五、發明説明(5 ) 部。又’藉由使用至少積層第2螢光體層的第2轉印用薄 膜之轉印法形成第2螢光體部。如此一來,將各螢光體部 使用各個轉印用薄膜在另外工程加以形成,例如習知使用 的轉印用薄膜仍然可做爲第1轉印用薄膜而再利用之。 【發明之實施形態】 以下針對本發明之實施形態參考圖面做詳細說明。 【第1實施形態】 首先’主要參考第1圖及第2圖,針對使用有關本發 明之第1實施形態的螢光面之形成方法所製造的扁平型陰 極線管之構成做說明。再者,圖中,扁平型陰極線管爲其 中一例,表示反射型者。又,第1圖係相當於第2圖中之 I -1線部分之斷面。 經濟部智慧財產局員工消費合作社印製 如第1圖所示,扁平型陰極線管30係具備有篩網3 1 、前面板32及漏斗部33。篩網31、前面板32及漏斗部 33係藉由例如透明的玻璃構件所構成,藉由利用該些面 板的三體構造來構成扁平型的玻璃管體(扁平管)。 在漏斗部33的後端部配設用來放射電子波束EB之 電子鎗35。在漏斗部33的內壁面塗佈由例如碳膜所製成 之內部導電膜53。內部導電膜53係被導電連接在被設置 在漏斗部33之圖未示的陽極端子,做爲施加高電壓(陽極 電壓)HV。又,圖未示,但在漏斗部33的外周部分配置 有欲令由電子鎗35所放射的電子波束EB進行偏向控制 8- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 583706 A7 B7 五、發明説明(8 ) 成5虎、文子及各種圖樣等任葸者,圖像映像4 2則可顯 示任意形狀。 請 先 閲 讀 背 之 注 意 事 項 再 寫 本 頁/ 將如以上所構成的扁平型陰極線管3 0應用於例如具 保全功能的對講機裝置時,實行如以下之顯示動作。再者 ,對講機裝置係爲一般以通信電纜連接子機和母機的裝置 之總稱。於具有保全功能的對講機裝置,係於母機連接火 災偵測器等周邊機器。本扁平型陰極線管3 0係於此種對 講機裝置中應用於母機的監視器部。 首先,在主映像顯示區域32Α利用子機之攝影機所 拍攝的映像爲黑白視訊(黑白)顯示。此時,第1螢光體部 5 1的第1螢光體層1 3是利用電子波束ΕΒ被掃瞄。此時 利用螢光體層13所產生的發光光線R1則藉由反射層14 的功能被反射到前面板3 2側。藉由經由該反射層14被反 射的光線R 1所形成的光學式之映像則由前面板3 2側做爲 主映像41而予觀察。 經濟部智慧財產局員工消費合作社印製 一方面,在圖像顯示區域32Β完成與例如保安系統 連動的圖像映像顯示。亦即,完成配合來看具備例如火災 偵測功能的周邊機器之偵測信號的圖像映像顯示。此時, 第2螢光體部52的第2螢光體層23是利用電子波束ΕΒ 被掃瞄,但此時所掃瞄的只在設有配合欲顯示的圖像映像 42之螢光體圖案的區域。亦即,例如只在形成火災偵測 用之螢光體圖案(例如炎狀之螢光體圖案)的區域。此時, 經由利用電子波束ΕΒ被掃瞄而產生的發光光線R2則藉 由反射層24的功能被反射到前面板32側。藉由經由該反 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 34) -11 - 583706 A7 B7 五、發明説明(9 射層24被反射的光線R2所形成的彩色圖像映像42則由 前面板32側被觀察。 請 先 閲 讀 背 ij 5 ί 事 項 再 寫 本 其次針對扁平型陰極線管3 0的製造方法,特別是其 螢光面5 0之形成方法做說明。 本實施形態係藉由使用轉印用薄膜之轉印法形成螢光 面。 於是先準備第3圖(A),(B)及第4圖(A),(B)所示的 2個轉印用薄膜1,2。第1轉印用薄膜1係爲用來形成第 1螢光體部5 1,第2轉印用薄膜2係爲用來形成第2螢光 體部52。再者,第4圖(A),(B)分別表示第3圖(A),(B) 所示之轉印用薄膜1,2的IVA-IVA線、IVB-IVB線部分 之斷面。 經濟部智慧財產局員工消費合作社印製 第1轉印用薄膜1乃如第3圖(A)及第4圖(A)所示, 於轉印基板11的一面積層轉印層1 〇。轉印層1 〇係由轉 印基板11側依序積層而形成剝離層1 2、螢光體層1 3、反 射層14、導電層15及接著層16。該第1轉印用薄膜1依 然可使用沒有圖像顯示區域32B之通常製造扁平型陰極 線管110(第14圖(A))之螢光面所使用的習知之轉印用薄 膜。 該第1轉印用薄膜1係如以下所製作。首先,轉印基 板11是準備例如厚度25μιη〜ΙΟΟμιη左右,最好爲75μιη 左右的樹脂薄膜。樹脂薄膜可使用例如PET(聚對苯二甲 酸乙二醇酯)薄膜。其次在該轉印基板11上依序利用印刷 法(例如網版印刷和照相凹版印刷等)形成剝離層1 2、第1 表纸張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) -12- 583706 A7 _ B7 五、發明説明(10 ) 螢光體層13、反射層14、導電層15及接著層16。 更具體是先在轉印基板11上於所定溫度(例如200°C 左右)中加以剝離,同時在較該剝離之溫度還高的溫度(例 如300°C左右)中,利用印刷法形成具有氣化之功能的剝 離層1 2。 該剝離層1 2係使用例如丙烯系樹脂,其厚度形成 6μιη 〜ΙΟμιη 左右。 其次,在該剝離層1 2上利用印刷法形成具有配合有 效畫面(主映像顯示區域32 Α(第2圖))之面積的第1螢光 體層13。該第1螢光體層13係將例如Y2〇2S (氧化硫化釔) 或Y2〇2S : TB(氧化硫化釔:铽賦活)等之微粒子(例如平均 粒徑4.5μιη以下)以20μιη〜30μιη左右的厚度加以形成。 經濟部智慧財產局員工消費合作社印製 其次,在該第1螢光體層1 3上利用印刷法形成例如 由氧化鈦(Ti〇2)、氧化錫(Sn〇2)或氧化鋁(Ah〇3)等所製成 之反射層13。反射層14的厚度例如形成1〇μιη〜 15μιη左 右。反射層1 4做爲氧化鈦層時,使用由氧化鈦粒子與黏 合劑所形成之塗料(所謂的糊狀體)加以印刷形成在第1螢 光體層13上。 其次,覆蓋該反射層14及第1螢光體層1 3地利用印 刷法形成具有配合第1螢光體部5 1及第2螢光體部52之 形成區域的面積,亦即配合螢光面全體的面積之導電層 15。該導電層15之厚度係形成例如3 μιη〜20 μχη左右。該 導電層1 5的材料爲例如平均粒徑1 μιη以下的微粒子,並 使用透明且電阻値爲燒成後100ΜΩ以下者。具體是使用 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) ---- -13- 583706 A7 B7 五、發明説明(11 ) 例如IT〇(Indium-Tin Oxide)等透明導電膜。再者,根據陰 極線管的用途係爲於碳和氧化鉻等燒成後成爲黑灰色的材 料,也可使用電阻値爲燒成後100ΜΩ以下者做爲導電層 15 ° 最後於該導電層1 5上利用印刷法形成由具有以較剝 離層1 2加以氣化的溫度還高的溫度而氣化之功能的例如 丁縮醛系樹脂或聚醯胺樹脂所形成之接著層1 6。接著層 16的厚度係形成例如6μιη〜ΙΟμιη左右。再者,丁縮醛系 樹脂及聚醯胺樹脂則約於400°C〜485 □的溫度加以氣化。 如以上般,第1轉印用薄膜1的各層之形成係利用例 如網版印刷而實行。此時,進行網版印刷形成各層後,利 用自然乾燥或乾燥機等使之乾燥,令各層之膜厚安定化。 此乾燥處理希望對每一各層實行之。亦即,希望重複施行 所謂針對某一層施行網版印刷並加以乾燥後,進行下一層 的網版印刷之工程。按此製作第1轉印用薄膜1 。 經濟部智慧財產局員工消費合作社印製 一方面,第2轉印用薄膜2乃如第3圖(B)及第4圖 (B)所示,在轉印基板21之一面積層具有配合第2螢光體 部52之形成區域的面積之轉印層20。轉印層20係由轉 印基板2 1側依序積層形成剝離層22、第2螢光體層23、 反射層24及接著層26。 該第2轉印用薄膜2的製作基本上也與第1轉印用薄 膜1同樣地施行。亦即,第2轉印用薄膜2係在以例如 PET所形成的轉印基板2 1上,利用例如網版印刷依序形 成剝離層22、第2螢光體層23、反射層24及接著層26 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ~ " -14- 583706 A7 — B7 五、發明説明(12) ’藉此所製作。此時具有與第1轉印用薄膜1同一功能的 層’基本上是用同一材料、厚度所形成。 更具體是如以下所製作。先在轉印基板2 1上利用印 刷法形成與第1轉印用薄膜1之剝離層1 2同樣的材料、 厚度之剝離層22。 其次’在該剝離層22上利用印刷法形成具有配合欲 顯示的圖像映像42(第2圖)之形狀的形狀、面積之第2螢 光體層23(23A,23B,23C)。該第2螢光體層23係使用 配合欲顯示的圖像映像4 2之種類(色)的螢光體所形成。 例如將各圖像映像42A,42B,42C用藍色、紅色、綠色 加以顯示時,將各螢光體層23A,23B,23C分別用藍色 、紅色、綠色的螢光體加以形成。再者,藍色的螢光體可 使用例如ZnS : Ag等。又,綠色的螢光體可使用例如ZnS :〇u,A1等。紅色的螢光體可使用例如y2〇2s : Ειι等。 其次,在該第2螢光體層1 3上利用與第1轉印用薄 膜1之反射層14同樣的材料、厚度藉由印刷法形成具有 配合圖像顯示區域32B(第2圖)的面積之反射層24。 經濟部智慧財產局員工消費合作社印製 最後覆蓋該反射層24地利用與第1轉印用薄膜1之 接著層1 6同樣的材料、厚度藉由印刷法形成具有配合第 2螢光體部52之形成區域的面積之接著層26。 就連針對以上所說明之第2轉印用薄膜2的形成工程 ,也是在形成各層後,與第1轉印用薄膜1同樣地,利用 自然乾燥或乾燥機等使之乾燥,令各層膜厚安定化。按此 製作第2轉印用薄膜2。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 346 -15- 583706 A7 B7 五、發明説明(13 請 先 閱 讀 背 之 注 意 事 項 再 填, 寫 本 其次’使用按以上所製作的轉印用薄膜1,2來形成 螢光面50 ’加以製造扁平型陰極線管30。該製造工程的 全體式流程乃如第8圖所示。 亦即,如第8圖所示,先藉由使用第1轉印用薄膜1 的轉印法形成第1螢光體部51(步驟S1)。其次藉由使用 第2轉印用薄膜2的轉印法形成第2螢光體部52。此係 在利用第1轉印用薄膜1所轉印形成的導電層1 5上,全 體重疊第2轉印用薄膜2的轉印層20所加以轉印藉此施 行之(步驟S2)。 其次,利用玻璃料焊接工程(F/S工程)接合篩網31、 前面板3 2及漏斗部3 3 (步驟S 3)。 經濟部智慧財產局員工消費合作社印製 其次,利用導通用導電膜54加以導電連接篩網3 1的 導電層15,和漏斗部33的內部導電膜53 (步驟S4)。導 通用導電膜54的形成乃如第7圖所示,藉由在從例如導 電層15的漏斗部33側之中央端部至內部導電膜53的篩 網3 1側之中央端部的區域,塗佈例如碳膜施行。此導通 用導電膜54是用例如440± 20。(:左右的溫度被燒成。形成 導通用導電膜54藉此在導電層15透過內部導電膜53及 導通用導電膜54施加陽極電壓HV。如以上製造扁平型陰 極線管3 0。 第1螢光體部51的形成工程(第8圖之步驟S1),更 詳細乃如第5圖(A)〜(D)所示地加以施行。 亦即,首先如第5圖(A)所示,將第1轉印用薄膜1 利用接著層1 6黏貼在篩網3 1的內面之所定位置。該接著 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -16- 583706 A7 B7 五、發明説明(14 ) 請 閲 背 意 事 項 再 填、 寫 本 頁-* 係在第1螢光體層13被轉印在配合第1螢光體部5 1之形 成區域的位置,且導電層15被轉印在配合第1螢光體部 5 1及第2螢光體部5 2的形成區域之位置的位置施行。其 次,將飾網3 1加熱到令轉印基板11剝離的溫度(例如約 20(TC )。藉此如第5圖(B)所示,轉印基板11剝離第1轉 印用薄膜1,轉印層1 〇被轉印到篩網3 1的內面。再者’ 剝離轉印基板11之際,不加熱篩網3 1 ’將加熱至所定溫 度(例如200°C〜25 0°C )的熱轉印滾輪’由轉印基板11側 進行推壓亦可。 經濟部智慧財產局員工消費合作社印製 其次,將剝離轉印基板11的篩網3 1 ’加熱到較轉印 基板11之剝離溫度更高的溫度(例如約3〇〇°C )。藉此如第 5圖(C)所示,令剝離層1 2氣化並由篩網3 1被排氣除去。 除去剝離層1 2後,接著將篩網3 1加熱到較令剝離層1 2 氣化之溫度更高的溫度(例如約400°C〜485°C )。藉此如第 5圖(D)所示,令接著層16氣化並通過導電層15、反射層 14及第1螢光體層1 3而自篩網3 1被排氣除去。按此在 篩網32的內面形成由導電層15、反射層14及第1螢光 體層13所組成之第1螢光體部5 1。此時,不光是導電層 1 5就連第1螢光體部5 1也會形成到第2螢光體部52的 形成區域。 一方面,第2螢光體部52的形成工程(第8圖之步驟 S2),更詳細乃如第6圖所示地施行之。 亦即,首先如第6圖(A)所示,將第2轉印用薄膜2 利用接著層26黏貼在藉由第1轉印用薄膜1所轉印形成 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -17- 583706 A7 B7 五、發明説明(15 ) 的導電層1 5上。該接著係在導電層1 5上於被轉印到配合 第2螢光體部52之形成區域的位置之位置黏貼第2螢光 體層23及反射層24。其次,將篩網3 1加熱到剝離轉印 基板21的溫度(例如約200°C )。藉此如第6圖(B)所示, 轉印基板21剝離第2轉印用薄膜2,轉印層20則透過導 電層1 5被轉印到篩網3 1的內面。再者,剝離轉印基板 21之際,不加熱篩網31,從轉印基板21側推壓被加熱到 所定溫度(例如200°C〜25(TC )的熱轉印滾輪亦可。 其次,將剝離轉印基板2 1的篩網3 1加熱到較轉印基 板21之剝離溫度更高的溫度(例如約300°C )。藉此如第6 圖(C)所示,令剝離層22氣化並從篩網31被排氣除去。 除去剝離層22後,接著將篩網3 1加熱到令剝離層22氣 化之溫度更高的溫度(例如約400°C〜485 °C )。藉此如第6 圖(D)所示,令接著層26氣化並通過反射層24及第2螢 光體層23從篩網31被排氣除去。按此在篩網32的內面 形成由導電層15、反射層24及第2螢光體層23所製成 之第2螢光體部52。 經濟部智慧財產局員工消費合作社印製 如以上說明,只要按本實施形態就可將第1螢光體部 5 1和第2螢光體部52,藉由使用2個轉印用薄膜1,2的 轉印法,在別的工程加以形成之故,對製造沒有圖像顯示 區域32B的通常之扁平型陰極綿管110(第14圖(A))所使 用的習知轉印用薄膜,仍然可做爲第1轉印用薄膜1使用 。藉此,因關螢光面50之形成工程,即可達到與沒有圖 像顯示區域32B的習知扁平型陰極線管之製造生產線部 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -18- 583706 A7 B7 五、發明説明(16 分共通化。又,與只用1個轉印用薄膜一倂形成螢光面之 情形不同,即使在第1螢光體部5 1及第2螢光體部5 2之 任一方的形成工程產生不良,只要重新進行任一方的工程 就可達到提高可靠性。 如此只要按照本實施形態,就不會浪費習知使用的轉 印用薄膜,可藉由轉印法形成生產性優的螢光面50。 【第2實施形態】 其次,針對本發明之第2實施形態做說明。再者,以 下之說明中,對於與上述第1實施形態中之構成要素同一 的部分附上同一的符號,省略適當說明。又,針對實質上 與上述第1實施形態同一的製造工程,其說明做適當省略 〇 上述第1實施形態中,如第1圖所示,利用第1螢光 體部5 1及第2螢光體部52做爲共通之一連續的層而形成 螢光面50的導電層15。因此,只在第1轉印用薄膜1(第 3圖(A)、第4圖(A))積層導電層15,於第2轉印用薄膜 2(第3圖(B)、第4圖(B))使用未積層導電層15的構造。 另一方面,本實施形態乃於形成螢光面50之際,如 第9圖(B)及第10圖(B)所示,與第1轉印用薄膜1同樣 地,使用積層導電層25的構造之第2轉印用薄膜2A。亦 即,第2轉印用薄膜2 A是使用在轉印基板2 1之一面依 序積層剝離層22、第2螢光體層23、反射層24、導電層 25及接著層26。第1轉印用薄膜1乃如第9圖(A)及第10 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X 297公釐) 請 先 閱 讀 背 意 事 項 再 寫 本 經濟部智慧財產局員工消費合作社印製 19- 583706 A7 _____________ B7 五、發明説明(17 ) (請先閲讀背面之注意事項再4·寫本瓦) 圖(A)所示,使用與上述第1實施形態同樣者,藉由使用 此種構造的轉印用薄膜1,2A,於第2螢光體部52係更 在與第1螢光體部51共通的導電層15之上,全體積層導 電層25,形成2層構造的導電層。再者,第10圖(A),(B) 係各別表示第9圖(A),(B)所示之轉印用薄膜1,2A的 XA-XA線、XB-XB線部分之斷面。 再者,於本實施形態中,導電層1 5是配合本發明之 「第1導電層」的其中一具體例,導電層25是配合本發 明之「第2導電層」的其中一具體例。 第2轉印用薄膜2A基本上可與上述第1實施形態所 使用的第2轉印用薄膜2同樣地加以製作。亦即,該第2 轉印用薄膜2A係在由例如pet所製成的轉印基板2 1上 ’利用例如網版印刷依序形成剝離層22、第2螢光體層 23、反射層24、導電層25及接著層26,藉此被製作。此 時’具有與上述第1實施形態同一功能之層,基本上是用 同一的材料、厚度所形成。 更具體是先在轉印基板2 1上,與上述第1實施形態 經濟部智慧財產局員工消費合作社印製 同樣地利用印刷法形成剝離層22、第2螢光體層23及反 射層24。 其次,覆蓋反射層24地將導電層25利用印刷法加以 形成。導電層25的材料 '厚度可與第i轉印用薄膜1的 導電層15相同。然後覆蓋該導電層25地將接著層26利 用印刷法加以形成。 連以上所說明的第2轉印用薄膜2A之形成工程中, 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -20- 583706 A7 __ B7 五、發明説明(18 ) (請先閱讀背面之注意事項再皆寫本X.) 形成各層後係與第1轉印用薄膜1同樣地,利用自然乾燥 或乾燥機等使之乾燥,令各層的膜厚安定化。按此製作第 2轉印用薄膜2A。 本實施形態的扁平型陰極線管3 0之製造工程之全體 流程,乃與上述第1實施形態相同,如第8圖所示。但是 本實施形態中,乃於步驟S2的第2螢光體部52之形成工 程中,進行使用第9圖(B)及第10圖(B)所示的構造之第2 轉印用薄膜2A之處理。 亦即,本實施形態中,第2螢光體部52之形成工程 乃如第11圖所示地加以施行之。 經濟部智慧財產局員工消費合作社印製 首先如第11圖(A)所示,將第2轉印用薄膜2A利用 接著層26黏貼在藉由第1轉印用薄膜1所轉印形成的導 電層1 5上。該接著係在導電層1 5上,於被轉印到配合第 2螢光體部52的形成區域之位置的位置來黏貼第2螢光 體層23、反射層24及導電層25。其次,進行與上述第1 實施形態同樣的加熱處理,如第11圖(B)所示,自第2轉 印用薄膜2A剝離轉印基板21,將轉印層20A透過導電層 1 5轉印到篩網3 1的內面。 其次,進行與上述第1實施形態同樣的加熱處理,並 如第11圖(C)所示,令剝離層22氣化,從篩網31加以排 氣除去。除去剝離層22後,更與上述第1實施形態同樣 地進行加熱到較令剝離層22氣化之溫度更高的溫度(例如 約400°C〜48 5 °C )之處理。藉此如第11圖(D)所示,令接 著層26氣化並通過導電層25、反射層24及第2螢光體 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐1 " -21 - 583706 A7 B7 五、發明説明(19) 層23,從篩網31被排氣除去。按此於篩網32的內面,In this way, with the cathode-ray tube invented by the present applicant, in addition to the usual black and white video image, the image-like image can be displayed in color. The cathode-ray tube having this image display function is hereinafter simply referred to as "image CRT J °". However, in the conventional flat-type cathode-ray tube 110 shown in FIG. 14 (A), a method for forming a fluorescent surface thereof is known to use, for example, The transfer method disclosed in Japanese Patent Application No. 11-247353, etc. The method using this transfer method is a film for transfer using the constituent elements (such as a phosphor layer and a conductive layer) of a laminated fluorescent surface, The phosphor layer and the like are transferred to the transfer surface of the cathode-ray tube. As long as this method, the components of the fluorescent surface can be transferred on one transfer film. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs However, by the conventional transfer method using such a transfer film, when forming the fluorescent surface of the image CRT120 shown in FIG. 14 (B), the following problems occur. First, in order to One transfer film forms the fluorescent surface of the image CRT 120, plus the fluorescent surface of the normal image display portion (the first phosphor portion 1 2 1). 'The fluorescent light of all laminated image display portions must be used. Elements of the surface (the second phosphor portion 123). That is, the image CRT is used for conversion. The printing film is the same as the conventional flat cathode wire tube 11 〇 The paper used for the transfer is applicable to the Chinese National Standard (CNS) A4 specification (210X297 meals) ------- -6- Ministry of Economy Wisdom Consumption cooperation by employees of the Property Bureau Du printed 583706 A7 ___B7_ V. Description of the invention (4) The structure of the film is different. Therefore, in the process of forming the fluorescent surface, there is a problem that cannot be compared with the ordinary flat cathode wire tube 110 without an image section. There is a problem of commonization of manufacturing production lines. Also, there is a problem of wasting a transfer film that is conventionally used. Moreover, only a part of the fluorescent surface is formed at a time (for example, only fluorescent materials for image display) Section 123) When the formation is defective, the entire fluorescent surface becomes poor and the productivity is impaired. The present invention is an invention in view of the related problems, and the object thereof is to provide a fluorescent product that can be formed with a high productivity by a transfer method. Surface, especially the conventional fluorescent surface formation process with only a single fluorescent body part, can also achieve a part of the common fluorescent surface formation method. [Means for solving the problem] According to the fluorescent light of the present invention Face formation The method includes a first process of forming a first phosphor portion by using a first transfer film having at least a first phosphor layer laminated thereon, and a second transfer of at least a second phosphor layer by using a transfer method. The second process of forming the second phosphor portion by a transfer method in a region different from the region where the first phosphor layer is provided with a thin film. In the present invention, the first phosphor layer is composed of, for example, It is composed of white light-emitting phosphors that emit white light. White light-emitting phosphors are fluorescent bodies that emit white light alone, and also include, for example, a mixture of blue light-emitting phosphors and yellow light-emitting phosphors at an appropriate ratio. A phosphor emitting white light in appearance. According to the method for forming a fluorescent surface of the present invention, a first phosphor sample is formed by a transfer method using a first transfer film laminated on at least a first phosphor layer. Paper size applies Chinese National Standard (CNS) A4 specification (210X 297mm) '" I 0 ^ ------, 玎 ------ 0 (Please read the precautions on the back before writing XW -) -7- 583706 A7 ____ B7 V. The description of the invention (5). Furthermore, the second phosphor portion is formed by a transfer method using a second transfer film in which at least a second phosphor layer is laminated. In this way, each phosphor portion is formed in a separate process using each transfer film. For example, a conventionally used transfer film can be reused as the first transfer film. [Embodiment of the invention] The embodiment of the present invention will be described in detail below with reference to the drawings. [First Embodiment] First, the configuration of a flat cathode wire tube manufactured by using the method for forming a fluorescent surface according to the first embodiment of the present invention will be described mainly with reference to Figs. 1 and 2. In the figure, a flat-type cathode wire tube is one of the examples, and a reflective type is shown. The first figure is a cross section corresponding to the line I -1 in the second figure. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs As shown in FIG. 1, the flat cathode wire tube 30 is provided with a screen 3 1, a front panel 32, and a funnel portion 33. The screen 31, the front panel 32, and the funnel portion 33 are made of, for example, a transparent glass member, and a flat glass tube body (flat tube) is formed by using the three-body structure of these panels. An electron gun 35 for emitting an electron beam EB is disposed at a rear end portion of the funnel portion 33. The inner wall surface of the funnel portion 33 is coated with an internal conductive film 53 made of, for example, a carbon film. The internal conductive film 53 is electrically connected to an anode terminal (not shown) provided in the funnel portion 33, and a high voltage (anode voltage) HV is applied. Although not shown in the figure, the outer periphery of the funnel portion 33 is provided with a bias control for the electron beam EB emitted by the electron gun 35. 8- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 583706 A7 B7 V. Description of the invention (8) Anyone who can make 5 tigers, texts, and various patterns, etc. The image map 4 2 can display any shape. Please read the notes on the back first and then write this page / When the flat cathode wire tube 30 configured as above is applied to, for example, a walkie-talkie device with a security function, perform the following display operations. Furthermore, the two-way radio device is a general term for a device that generally connects a slave unit and a master unit with a communication cable. The intercom device with security function is connected to the peripheral device such as the fire detector and the main unit. The flat cathode wire tube 30 is a monitor unit applied to a mother machine in such an interphone device. First, the image captured by the slave camera in the main image display area 32A is displayed as a black and white video (black and white). At this time, the first phosphor layer 13 of the first phosphor portion 51 is scanned with the electron beam EB. At this time, the light emitting light R1 generated by the phosphor layer 13 is reflected to the front panel 32 side by the function of the reflection layer 14. The optical image formed by the light R 1 reflected through the reflection layer 14 is observed from the front panel 32 side as the main image 41. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs On the one hand, the image display area 32B is linked to, for example, a security system image display. That is, it is completed to look at the image map display of the detection signals of peripheral devices having, for example, a fire detection function. At this time, the second phosphor layer 23 of the second phosphor portion 52 is scanned using the electron beam EB, but at this time, only the phosphor pattern corresponding to the image image 42 to be displayed is scanned. Area. That is, for example, only in a region where a phosphor pattern for fire detection (for example, a flaming phosphor pattern) is formed. At this time, the light emitting light R2 generated by being scanned with the electronic beam EB is reflected to the front panel 32 side by the function of the reflection layer 24. By applying the Chinese paper standard (CNS) A4 specification (210X297 mm) through this anti-paper size 34) -11-583706 A7 B7 V. Description of the invention (9 The color image formed by the reflected light R2 of the reflective layer 24 The image 42 is observed from the front panel 32 side. Please read the back of ij 5 and write this article. Next, the manufacturing method of the flat cathode wire tube 30, especially the method of forming the fluorescent surface 50, will be described. This embodiment The fluorescent surface is formed by a transfer method using a transfer film. Therefore, two transfer films shown in FIGS. 3 (A), (B) and 4 (A), (B) are prepared first. 1, 2. The first transfer film 1 is used to form the first phosphor portion 51, and the second transfer film 2 is used to form the second phosphor portion 52. Furthermore, the fourth Figures (A) and (B) show the sections of the IVA-IVA line and IVB-IVB line of the transfer film 1, 2 shown in Figure 3 (A) and (B), respectively. Intellectual Property Bureau, Ministry of Economic Affairs The employee transfer cooperative printed the first transfer film 1 as shown in FIGS. 3 (A) and 4 (A), and a transfer layer 1 was formed on an area of the transfer substrate 11. The transfer layer 1 was The transfer substrate 11 is laminated in order to form a peeling layer 1, 2, a phosphor layer 1, 3, a reflective layer 14, a conductive layer 15, and an adhesive layer 16. The first transfer film 1 can be used without an image display area. The conventional transfer film used for the fluorescent surface of the flat cathode tube 110 (FIG. 14 (A)) of 32B is generally manufactured. The first transfer film 1 is produced as follows. First, a transfer substrate 11 is to prepare, for example, a resin film having a thickness of about 25 μm to 100 μm, and preferably about 75 μm. For the resin film, for example, a PET (polyethylene terephthalate) film can be used. Next, printing is sequentially used on the transfer substrate 11 (Such as screen printing, gravure printing, etc.) to form the peeling layer1 2. The paper size of Table 1 applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -12- 583706 A7 _ B7 V. Description of the invention ( 10) The phosphor layer 13, the reflective layer 14, the conductive layer 15, and the adhesive layer 16. More specifically, the phosphor layer 13 is peeled off at a predetermined temperature (for example, about 200 ° C) on the transfer substrate 11 and at a temperature higher than the peeling temperature. High temperature (e.g. 300 ° C left ), A release layer 12 having a vaporization function is formed by a printing method. The release layer 12 is made of, for example, an acrylic resin, and has a thickness of about 6 μm to 10 μm. Next, a printing method is used on the release layer 12. The first phosphor layer 13 is formed to have an area that matches the effective screen (the main image display area 32 A (Figure 2)). The first phosphor layer 13 is, for example, Y2O2S (Yttrium Oxide Sulfide) or Y2O2S. : TB (Yttrium Oxide Sulfide: Gadolinium-activated) and other fine particles (for example, an average particle diameter of 4.5 μm or less) are formed in a thickness of about 20 μm to 30 μm. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The first phosphor layer 13 is formed by a printing method using, for example, titanium oxide (Ti〇2), tin oxide (Sn〇2), or alumina (Ah〇3). ) 等 的 生产 层 13。 13 made of a reflective layer. The thickness of the reflective layer 14 is, for example, about 10 μm to 15 μm. When the reflective layer 14 is a titanium oxide layer, a coating (a so-called paste) formed of titanium oxide particles and a binder is used for printing and formed on the first phosphor layer 13. Next, an area having a formation area matching the first phosphor portion 51 and the second phosphor portion 52 is formed by a printing method so as to cover the reflective layer 14 and the first phosphor layer 13, that is, the phosphor surface is matched. The entire area of the conductive layer 15. The thickness of the conductive layer 15 is, for example, about 3 μm to 20 μxη. The material of the conductive layer 15 is, for example, fine particles having an average particle diameter of 1 μm or less, and a transparent one having a resistance of 100 MΩ or less after firing is used. Specifically, the paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) ---- -13- 583706 A7 B7 V. Description of the invention (11) Such as IT〇 (Indium-Tin Oxide) and other transparent conductive films . In addition, according to the application of the cathode wire tube, it is a material that becomes black and gray after firing carbon, chromium oxide and the like. It is also possible to use a resistance 値 as the conductive layer 15 ° below 100MΩ after firing and finally to the conductive layer 1 5 The adhesive layer 16 formed of, for example, a butyral resin or a polyamide resin having a function of vaporizing at a temperature higher than the temperature at which the release layer 12 is vaporized is formed by a printing method. The thickness of the subsequent layer 16 is, for example, about 6 μm to 10 μm. In addition, butyral resins and polyamide resins are vaporized at a temperature of about 400 ° C to 485 □. As described above, the formation of each layer of the first transfer film 1 is performed by, for example, screen printing. At this time, after screen printing is performed to form each layer, it is dried using a natural dryer or a dryer to stabilize the film thickness of each layer. This drying process is desirably performed for each layer. That is, it is desirable to repeat the process of performing screen printing on one layer and drying it, and then performing screen printing on the next layer. In this way, the first transfer film 1 was produced. Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs On the one hand, the second transfer film 2 is shown in FIG. 3 (B) and FIG. 4 (B). The transfer layer 20 has an area in which the phosphor portion 52 is formed. The transfer layer 20 is formed by sequentially laminating a release layer 22, a second phosphor layer 23, a reflective layer 24, and an adhesive layer 26 on the transfer substrate 21 side. The production of the second transfer film 2 is basically performed in the same manner as the first transfer film 1. That is, the second transfer film 2 is formed on a transfer substrate 21 formed of, for example, PET, and a release layer 22, a second phosphor layer 23, a reflective layer 24, and an adhesive layer are sequentially formed by, for example, screen printing. 26 This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) ~ -14- 583706 A7 — B7 V. Description of the invention (12) The layer 'having the same function as that of the first transfer film 1 at this time is formed of substantially the same material and thickness. More specifically, it is produced as follows. First, a release layer 22 having the same material and thickness as the release layer 12 of the first transfer film 1 is formed on the transfer substrate 21 by a printing method. Next, a second phosphor layer 23 (23A, 23B, 23C) having a shape and an area corresponding to the shape of the image image 42 (Fig. 2) to be displayed is formed on the release layer 22 by a printing method. The second phosphor layer 23 is formed using a phosphor (color) of a type (color) that matches the image image 42 to be displayed. For example, when the image images 42A, 42B, and 42C are displayed in blue, red, and green, the phosphor layers 23A, 23B, and 23C are formed in blue, red, and green phosphors, respectively. As the blue phosphor, for example, ZnS: Ag can be used. As the green phosphor, for example, ZnS: oo, A1, and the like can be used. As the red phosphor, for example, y2〇2s: eil and the like can be used. Next, the second phosphor layer 13 is formed on the second phosphor layer 13 with the same material and thickness as the reflective layer 14 of the first transfer film 1 by a printing method to have an area having an area corresponding to the image display area 32B (FIG. 2). Reflective layer 24. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, and finally covering the reflective layer 24. The same material and thickness as those of the adhesive layer 16 of the first transfer film 1 are used to form the second phosphor portion 52 by printing. The area of the formation area is followed by the layer 26. Even for the formation process of the second transfer film 2 described above, after forming each layer, similar to the first transfer film 1, it is dried with a natural dryer or a dryer to make the thickness of each layer Stabilization. In this way, the second transfer film 2 was produced. This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 346 -15- 583706 A7 B7 V. Description of the invention (13 Please read the precautions on the back before filling in, write this book, and then use the conversion made by the above The thin films 1, 2 are printed to form a fluorescent surface 50 'to manufacture a flat cathode wire tube 30. The overall flow of the manufacturing process is shown in Fig. 8. That is, as shown in Fig. 8, it is first used by The first phosphor film portion 51 is formed by the transfer method of the first transfer film 1 (step S1). Secondly, the second phosphor portion 52 is formed by the transfer method using the second transfer film 2. This system The conductive layer 15 transferred and formed by the first transfer film 1 is transferred with the transfer layer 20 of the second transfer film 2 as a whole to perform transfer (step S2). The frit welding process (F / S project) joins the screen 31, the front panel 3 2 and the funnel section 3 3 (step S 3). It is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, followed by conductive conductive film 54 Connect the conductive layer 15 of the screen 31 and the internal conductive film 53 of the funnel portion 33 (step S4). The conductive conductive film 54 is formed as shown in FIG. 7, for example, from the central end portion on the side of the funnel portion 33 of the conductive layer 15 to the central end portion on the screen 31 side of the internal conductive film 53. For example, a carbon film is used for coating. The conductive conductive film 54 is fired at a temperature of, for example, 440 ± 20. (: Is fired at a temperature of about. The conductive conductive film 54 is formed so that the conductive layer 15 penetrates the internal conductive film 53 and An anode voltage HV is applied to the conductive film 54. The flat cathode wire tube 30 is manufactured as described above. The formation process of the first phosphor portion 51 (step S1 in FIG. 8) is shown in more detail in FIG. 5 (A) ~ That is, as shown in FIG. 5 (A), first, the first transfer film 1 is adhered to a predetermined position on the inner surface of the screen 31 using the adhesive layer 16 as shown in FIG. 5 (A). Then this paper size applies the Chinese National Standard (CNS) A4 specification (210X297mm) -16- 583706 A7 B7 V. Description of the invention (14) Please fill in the notes and write this page-* It is the first fluorescent The body layer 13 is transferred to a position matching the formation area of the first phosphor body 51, and the conductive layer 15 is transferred to the first matching area. The light body portion 51 and the second phosphor portion 52 are formed at the positions of the formation regions. Next, the decorative net 31 is heated to a temperature at which the transfer substrate 11 is peeled off (for example, about 20 (TC).) As shown in FIG. 5 (B), the transfer substrate 11 peels off the first transfer film 1, and the transfer layer 10 is transferred to the inner surface of the screen 31. Furthermore, when the transfer substrate 11 is peeled off It is also possible to press the thermal transfer roller 31 which is heated to a predetermined temperature (for example, 200 ° C to 25 0 ° C) without heating the screen 3 1 from the transfer substrate 11 side. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Next, the screen 3 1 ′ for peeling the transfer substrate 11 is heated to a temperature higher than the peeling temperature of the transfer substrate 11 (for example, about 300 ° C.). Thereby, as shown in FIG. 5 (C), the peeling layer 12 is vaporized and removed by the screen 31 by the exhaust. After the release layer 12 is removed, the screen 31 is then heated to a temperature higher than the temperature at which the release layer 12 is vaporized (for example, about 400 ° C to 485 ° C). Thereby, as shown in FIG. 5 (D), the adhesive layer 16 is vaporized and passed through the conductive layer 15, the reflective layer 14, and the first phosphor layer 13 to be removed from the screen 31 by the exhaust gas. A first phosphor portion 51 composed of a conductive layer 15, a reflective layer 14, and a first phosphor layer 13 is formed on the inner surface of the screen 32 as described above. At this time, not only the conductive layer 15 but also the first phosphor portion 51 is formed to the formation region of the second phosphor portion 52. On the one hand, the formation process of the second phosphor portion 52 (step S2 in FIG. 8) is performed in more detail as shown in FIG. That is, first, as shown in FIG. 6 (A), the second transfer film 2 is adhered with the adhesive layer 26 to the first transfer film 1 to form the paper. ) A4 specification (210X297 mm) -17- 583706 A7 B7 V. Description of the invention (15) on the conductive layer 15. Then, the second phosphor layer 23 and the reflective layer 24 are pasted on the conductive layer 15 at a position transferred to a position matching the formation region of the second phosphor portion 52. Next, the screen 31 is heated to a temperature at which the transfer substrate 21 is peeled off (for example, about 200 ° C). Thereby, as shown in FIG. 6 (B), the transfer substrate 21 peels off the second transfer film 2, and the transfer layer 20 is transferred to the inner surface of the screen 31 through the conductive layer 15. When the transfer substrate 21 is peeled off, the screen 31 is not heated, and the thermal transfer roller heated to a predetermined temperature (for example, 200 ° C to 25 (TC)) is pushed from the transfer substrate 21 side. Second, The screen 3 1 of the peeling transfer substrate 21 1 is heated to a temperature higher than the peeling temperature of the transfer substrate 21 (for example, about 300 ° C.). As a result, as shown in FIG. 6 (C), the peeling layer 22 is made. It is gasified and removed by the exhaust gas from the screen 31. After removing the release layer 22, the screen 31 is then heated to a temperature (for example, about 400 ° C to 485 ° C) at which the temperature at which the release layer 22 is vaporized. Thereby, as shown in FIG. 6 (D), the adhesive layer 26 is vaporized and removed from the screen 31 through the reflective layer 24 and the second phosphor layer 23. The inner surface of the screen 32 is formed by this. The second phosphor portion 52 made of the conductive layer 15, the reflective layer 24, and the second phosphor layer 23. The printing is performed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs as described above. As long as this embodiment is used, the first The phosphor portion 51 and the second phosphor portion 52 are formed in another process by a transfer method using two transfer films 1 and 2 so that there is no image display for manufacturing. The conventional transfer film used in the normal flat cathode sponge tube 110 (Fig. 14 (A)) in the region 32B can still be used as the first transfer film 1. As a result, the fluorescent surface 50 is closed. The formation process can be achieved with the production line of the conventional flat cathode wire tube without the image display area 32B. The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -18- 583706 A7 B7 V. Invention Explanation (16 points are common. It is different from the case where only one transfer film is used to form the fluorescent surface at a time, even in the first phosphor portion 51 and the second phosphor portion 52. Defective formation process, as long as any one of the processes is repeated, the reliability can be improved. In this way, as long as this embodiment is used, the conventionally used transfer film will not be wasted, and the productivity can be formed by the transfer method. Fluorescent surface 50. [Second Embodiment] Next, the second embodiment of the present invention will be described. In addition, in the following description, the same components as those in the first embodiment are attached with the same components. Symbol, omit appropriate In addition, for manufacturing processes that are substantially the same as those of the first embodiment, the description is appropriately omitted. In the first embodiment, as shown in FIG. 1, the first phosphor portion 51 and the second phosphor portion are used. The fluorescent body portion 52 is formed as a common continuous layer to form the conductive layer 15 of the fluorescent surface 50. Therefore, only the first transfer film 1 (FIG. 3 (A), FIG. 4 (A)) The conductive layer 15 is laminated, and a structure in which the conductive layer 15 is not laminated is used for the second transfer film 2 (Figures 3 (B) and 4 (B)). On the other hand, this embodiment is for forming a fluorescent surface. At 50, as shown in FIGS. 9 (B) and 10 (B), the second transfer film 2A having a structure in which the conductive layer 25 is laminated is used in the same manner as the first transfer film 1. That is, the second transfer film 2A is used in which a release layer 22, a second phosphor layer 23, a reflective layer 24, a conductive layer 25, and an adhesive layer 26 are sequentially laminated on one surface of the transfer substrate 21. The first transfer film 1 is as shown in Figure 9 (A) and 10. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm). Please read the note before writing to the staff of the Intellectual Property Bureau of the Ministry of Economic Affairs. Printed by the Consumer Cooperative 19- 583706 A7 _____________ B7 V. Description of the invention (17) (Please read the precautions on the back and then write the tile) Figure (A) shows the same as the first embodiment above. Using the transfer film 1, 2A having such a structure, the second phosphor portion 52 is further formed on the conductive layer 15 common to the first phosphor portion 51, and the entire conductive layer 25 is laminated to form a two-layer structure. Conductive layer. Note that Figs. 10 (A) and (B) show the XA-XA and XB-XB lines of the transfer film 1, 2A shown in Figs. 9 (A) and (B), respectively. surface. Furthermore, in this embodiment, the conductive layer 15 is a specific example of the "first conductive layer" in accordance with the present invention, and the conductive layer 25 is a specific example of the "second conductive layer" in accordance with the present invention. The second transfer film 2A can be basically produced in the same manner as the second transfer film 2 used in the first embodiment. That is, the second transfer film 2A is formed on the transfer substrate 21 made of, for example, pet, and the release layer 22, the second phosphor layer 23, the reflection layer 24, and the like are sequentially formed by, for example, screen printing. The conductive layer 25 and the adhesive layer 26 are thereby manufactured. In this case, the layer having the same function as that of the first embodiment is basically formed of the same material and thickness. More specifically, the release layer 22, the second phosphor layer 23, and the reflective layer 24 are formed on the transfer substrate 21 by the printing method in the same manner as in the first embodiment of the Intellectual Property Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives. Next, the conductive layer 25 is formed by covering the reflective layer 24 by a printing method. The material of the conductive layer 25 may be the same thickness as the conductive layer 15 of the i-th transfer film 1. Then, the adhesive layer 26 is formed by covering the conductive layer 25 by a printing method. In connection with the formation of the second transfer film 2A described above, the paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) -20- 583706 A7 __ B7 V. Description of the invention (18) (Please Read the precautions on the back before writing all X.) After forming each layer, it is dried with a natural dryer or a dryer in the same manner as the first transfer film 1 to stabilize the film thickness of each layer. In this way, a second transfer film 2A was produced. The overall flow of the manufacturing process of the flat cathode wire tube 30 of this embodiment is the same as that of the first embodiment described above, as shown in FIG. However, in this embodiment, the second transfer film 2A using the structure shown in Figs. 9 (B) and 10 (B) is performed in the formation process of the second phosphor portion 52 in step S2. Its processing. That is, in this embodiment, the formation process of the second phosphor portion 52 is performed as shown in Fig. 11. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs First, as shown in FIG. 11 (A), the second transfer film 2A is adhered to the conductive layer formed by the first transfer film 1 using an adhesive layer 26. Layers 1 to 5. The second phosphor layer 23, the reflective layer 24, and the conductive layer 25 are adhered to the conductive layer 15 at a position transferred to a position matching the formation region of the second phosphor portion 52. Next, the same heat treatment as in the first embodiment is performed. As shown in FIG. 11 (B), the transfer substrate 21 is peeled from the second transfer film 2A, and the transfer layer 20A is transferred through the conductive layer 15 and transferred. To the inside of the screen 31. Next, the same heat treatment as in the first embodiment is performed, and as shown in Fig. 11 (C), the peeling layer 22 is vaporized and removed from the screen 31 to remove the air. After removing the release layer 22, the same process as in the first embodiment described above is carried out to a temperature higher than the temperature at which the release layer 22 is vaporized (for example, about 400 ° C to 48 5 ° C). In this way, as shown in FIG. 11 (D), the adhesive layer 26 is vaporized and passed through the conductive layer 25, the reflective layer 24 and the second phosphor. " -21-583706 A7 B7 5. Description of the invention (19) The layer 23 is removed from the screen 31 by exhaust. According to the inner surface of the screen 32,

(請先閱讀背面之注意事項再费寫本百 C 在導電層15之上,以全體重疊導電層25地加以形成第2 螢光體部51。亦即,如第11圖(D)所示,從篩網32側依 序形成由導電層15、導電層25、反射層24及第2螢光體 層23所製成之第2螢光體部52。 如以上說明,連本實施形態也藉由使用2個轉印用薄 膜1,2 A的轉印法在別的工程形成第1螢光體部5 1和第 2螢光體部5 2之故,得到與上述第1實施形態同樣的效 果,形成生產性優的螢光面50。 【第3實施形態】 其次,針對本發明之第3實施形態做說明。再者,以 下之說明中,與上述第1及第2實施形態之構成要素同一 的部分附上同一的符號,省略適當說明。又,針對實質上 與上述第1及第2實施形態同一的製造工程,其說明加以 適當省略。 經濟部智慧財產局員工消費合作社印製 上述第2實施形態中,在與第1螢光體部5 1共通的 導電層15之上更全體式地重疊導電層25,加以形成第2 螢光體部52。一方面,本實施形態中,將第1螢光體部 5 1與第2螢光體部52,分別以部分重疊導電層地加以形 成。 本實施形態中,於形成螢光面50之際,使用第1 2圖 (A),(B)所示的2個轉印用薄膜1A,2B。該些轉印用薄 膜ΙΑ,2B的構成要素及其主要部分的斷面構造係與第10 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ~ — -22- 583706 A7 B7 五、發明説明(21 ) 發明之「第2導電層」的其中一具體例。 (請先閲讀背面之注意事項再皆寫本百 〇 以下參考第1 3圖加以說明本實施形態的扁平型陰極 線管30之製造工程的全體流程。 首先,藉由使用第1轉印用薄膜1 A的轉印法形成第 1螢光體部51(步驟S11)。此形成工程只有導電層15A的 形成面積不同,基本上與上述第1、第2實施形態相同。 其次,藉由使用第2轉印用薄膜2 B的轉印法形成第 2螢光體部5 2 (步驟S 1 2)。此時,在使用第1轉印用薄膜 1A所轉印形成的導電層15A部分重疊第2轉印用薄膜2B 的轉印層,特別是導電層25A而進行轉印。藉此,導電 連接第1螢光體部5 1的導電層15A,和第2螢光體部52 的導電層25A。 其次,利用玻璃料焊接工程(F/S工程)接合篩網31、 前面板32及漏斗部33 (步驟S 13)。 經濟部智慧財產局員工消費合作社印製 其次’將細網31的弟2營光體部52之導電層25A, 和漏斗部33之內部導電膜53利用導通用導電膜54做導 電連接(步驟S14)。導通用導電膜54的形成係與第7圖所 示之情形相同地,例如在由導電層2 5 A的漏斗部3 3側之 中央端部至內部導電膜53的篩網3 1側之中央端部的區域 ,塗佈例如碳膜藉此完成。該導通用導電膜54例如以 440±20C左右的溫度燒成。形成導通用導電膜54,藉此 於第2螢光體部52的導電層25A透過內部導電膜53及導 通用導電膜54施加陽極電壓HV。又,第1螢光體部51 的導電層15 A,和第2螢光體部52的導電層25a被導電 本紙張尺度適用中國國家標準(CNS ) A4規格(210XM7公釐) -24- 583706 A7 B7 五、發明説明(22 ) 連接之故,也可對導電層15A施加陽極電壓HV。按以上 製造扁平型陰極線管30。 (請先閲讀背面之注意事項再资寫本頁) 如以上說明,連本實施形態也將第1螢光體部5 1和 第2螢光體部52,藉由使用2個轉印用薄膜1A,2B的轉 印法,在別的工程形成之故,與例如只用1個轉印用薄膜 一倂形成螢光面之情形不同,就算在第1螢光體部5 1及 第2螢光體部52之任一方的形成工程產生不良,只要重 新進行任一方的工程就可達到提高可靠性,形成生產性優 的螢光面50。 再者,本發明乃針對利用轉印法形成螢光面做描述, 但也利用蒸鍍法和電鍍沈積法之別的方法做爲参考例做描 述。 經濟部智慧財產局員工消費合作社印製 首先,在篩網131的內面,將例如由鋁(A1)蒸鍍膜所 製成之第1導電膜115及第2導電膜125,如第16圖所 示形成被覆(步驟S1)。此時,第1導電膜115係形成在第 1螢光體部1 5 1的全體形成區域。又,同時形成對該第1 導電膜11 5施加電壓的引線部11 6。另一方面,第2導電 膜125乃於第2螢光體部152的形成區域中,在第2螢光 體層123的形成位置,利用與其螢光體圖案(圖像圖案)同 形狀加以形成。又同時形成對該第2導電膜25施加電壓 的引線部1 26( 1 26A,126B,126C)。該導電膜115,125及引 線部116,126係用光罩覆蓋例如導電膜115,125及引線 部11 6,1 26之形成區域以外的區域,利用蒸鍍法同時一 倂的加以形成。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -25- 3S6 583706 A7 __B7 五、發明説明(25 ) (請先閱讀背面之注意事項再填寫本頁) 光體層(亦即發光色不同的複數螢光體圖案)所形成之時, 對每個顏色進行電鍍沈積處理。例如將構成第2螢光體層 123的各螢光體層123A,123B,123C,分別利用藍色、 紅色、綠色的螢光體所形成之時,在分散各色的螢光體粉 體之電鍍液62中配置篩網1 3 1,依序進行電鍍沈積處理 。此時,電極兼保持部1 63的電極部分係在各電鍍沈積處 理工程,選擇性地接觸到各螢光體層123A,123B,123C 的形成面之各導電膜125A,125B,125C、引線部125A, 125B,125C。藉此在各電鍍沈積處理工程只對各導電膜 125A,125B,125C之中,成爲電鍍沈積對象的導電膜選 擇性地施加來自電源1 65的電壓。再者,藍色的螢光體粉 體可使用例如ZnS : Ag等。又,綠色的螢光體粉體可使 .用例如ZnS ; Cu,A1等。紅色的螢光體粉體可使用例如 Y2〇2s : Eu 等。 經濟部智慧財產局員工消費合作社印製 如以上所述,形成各螢光體層後,接著如第5圖所示 ,將各導電膜115,125的各引線部116,126,藉由利用 例如碳膜所製成的導通用導電膜1 54加以互相導電連接而 形成共通連接部154A(步驟S3)。藉此各導電膜115,125 就會互相導電連接。 其次,利用玻璃料焊接工程(F/S工程)接合篩網131 、前面板132及漏斗部133 (步驟S4)。 其次,將漏斗部33的內部導電膜153,和步驟S3所 形成的共通連接部丨54 A,例如塗佈碳膜藉此加以導電連 接(步驟S5)。藉此,如第17圖所示’在由各導電膜115 —本紙張尺度適用中國國家標準(CNS ) A4規格(2l〇X297公釐) -28 - 經濟部智慧財產局員工消費合作社印製 583706 A7 ___ B7 五、發明説明(26 ) ,125的各引線部116,126至內部導電膜153的篩網Π1 側之端部的區域,形成導通用導電膜1 54。其結果,篩網 131的各導電膜115,125,和漏斗部U3的內部導電膜 1 53會被導電連接。再者,導通用導電膜1 54是用例如 440± 20°C左右的溫度燒成的。又藉此在第1導電膜15及 第2導電膜125透過內部導電膜153及導通用導電膜154 施加陽極電壓HV。按以上製造扁平型陰極線管30。 再者’本發明不限於上述各實施形態可做種種變形實 施。例如本發明不光是扁平型的陰極線管,就連相對於螢 光面之中心而垂直地照射來看電子鎗的電子波束之直線型 的陰極線管也適用之。 又,上述各實施形態中乃針對將圖像顯示區域32B( 第2螢光體部52)相對於主映像顯示區域32A(第1螢光體 部51)而設在下側的例子做說明,但將圖像顯示區域32B 設在其他區域亦可。亦即將圖像顯示區域32B相對於主 映像顯示區域32A而設在上側、左側或右側的區域亦可 。又,將圖像顯示區域3 2 B設在2個以上的區域亦可。 【發明之效果】 如以上說明,只要按申請專利範圍第1項至第4項之 任一項所述之螢光面之形成方法,就能將第丨螢光體部藉 由使用至少積層第1螢光體層的第1轉印用薄膜之轉印法 加以形成,將第2螢光體部藉由使用另外至少積層第2螢 光體層的第2轉印用薄膜之轉印法加以形成之故,例如可 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公楚) I 裝 ; 訂 (請先閲讀背面之注意事項再4-寫本^--) -29- 583706 A7 B7 五、發明説明(27 ) (請先閲讀背面之注意事項再填寫本頁) 將習知使用的轉印用薄膜,仍然做爲第1轉印用薄膜加以 利用。藉此不會浪費習知使用的轉印用薄膜,可藉由轉印 法形成生產性優的螢光面。亦即,僅有單一螢光體部的習 知螢光面之形成工程時,還可達到一部分共通化。 【圖面之簡單說明】 第1圖係表示使用有關本發明之第1實施形態的螢光 面之形成方法所製造的扁平型陰極線管之要部構成之斷面 圖。 第2圖係表示由正面(前面板側)觀看第2圖所示的扁 平型陰極線管之狀態的正面圖。 第3圖係表示於有關本發明之第1實施形態的螢光面 之形成方法中所使用的第1及第2轉印用薄膜之構成的正 面圖。 第4圖係表示第3圖所示之第1及第2轉印用薄膜的 斷面構造之斷面圖。 經濟部智慧財產局員工消費合作社印製 第5圖係說明使用第3圖及第4圖所示的第1轉印用 薄膜之轉印工程的斷面圖。 第6圖係說明使用第3圖及第4圖所示的第2轉印用 薄膜之轉印工程的斷面圖。 第7圖係表示使用有關本發明之第1實施形態的螢光 面之形成方法所製造的扁平型陰極線管之螢光面之構造的 正面圖。 第8圖係說明包含有關本發明之第1實施形態的螢光 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -30 583706 A7 B7 五、發明説明(28 ) 面之形成方法的扁平型陰極線管之製造工程之流程圖。 (請先閲讀背面之注意事項再资寫本¥-c 第9圖係表示針對有關本發明之第2實施形態的螢光 面之形成方法所使用的第1及第2轉印用薄膜之構成的正 面圖。 第10圖係表示第9圖所示之第1及第2轉印用薄膜 的斷面構造之斷面圖。 第11圖係說明使用第9圖及第10圖所示的第2轉印 用薄膜之轉印工程之斷面圖。. 第1 2圖係表示針對有關本發明之第3實施形態的螢 光面之形成方法所使用的第1及第2轉印用薄膜之構成的 正面圖。 第1 3圖係說明包含有關本發明之第3實施形態的螢 光面之形成方法的扁平型陰極線管之製造工程的流程圖。 第14圖係針對陰極線管之顯示方式所示之說明圖, (A)係表示只可黑白視訊顯示之習知扁平型陰極線管,(B) 係表示即使爲黑白視訊顯示方式也可部分性地進行圖像狀 之彩色顯示的扁平型陰極線管。 經濟部智慧財產局員工消費合作社印製 第1 5圖係針對有關本發明之參考例之螢光面之形成 方法所使用的電鍍沈積裝置之構成圖。 第1 6圖係表示使用有關本發明之參考例的螢光面之 形成方法所製造的螢光面之螢光體的電鍍沈積前之構造的 正面圖。 第17圖係表示使用有關本發明之參考例的螢光面之 形成方法所製造的扁平型陰極線管之螢光面構造之正面圖 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐) -31 - 583706 A7 B7 五、發明説明(29 )(Please read the precautions on the back before writing the 100C on the conductive layer 15 to form the second phosphor portion 51 with the entire conductive layer 25 superimposed. That is, as shown in FIG. 11 (D), A second phosphor portion 52 made of the conductive layer 15, the conductive layer 25, the reflective layer 24, and the second phosphor layer 23 is sequentially formed from the screen 32 side. As described above, even in this embodiment, The transfer method using two transfer films 1, 2 A is used to form the first phosphor portion 51 and the second phosphor portion 52 in other processes, and the same effect as that of the first embodiment is obtained. To form a fluorescent surface 50 with excellent productivity. [Third Embodiment] Next, a third embodiment of the present invention will be described. Furthermore, in the following description, the constituent elements are the same as those of the first and second embodiments. The same symbols are attached to the same parts, and appropriate explanations are omitted. In addition, the description of manufacturing processes that are substantially the same as those in the first and second embodiments is omitted as appropriate. In the second embodiment, the conductive layer 15 is common to the first phosphor portion 51. The conductive layer 25 is stacked integrally to form a second phosphor portion 52. On the one hand, in this embodiment, the first phosphor portion 51 and the second phosphor portion 52 are partially overlapped, respectively. A conductive layer is formed. In this embodiment, when the fluorescent surface 50 is formed, two transfer films 1A and 2B shown in FIGS. 12 (A) and (B) are used. The constituent elements of the film IA, 2B and the cross-section structure of the main part of the film and the 10th paper size are applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) ~ -22- 583706 A7 B7 V. Description of the invention (21 ) One of the specific examples of the "second conductive layer" of the invention. (Please read the precautions on the back before writing this one hundred. The following describes the entire manufacturing process of the flat cathode wire tube 30 of this embodiment with reference to Figure 13 First, a first phosphor portion 51 is formed by a transfer method using a first transfer film 1 A (step S11). This formation process differs only in the formation area of the conductive layer 15A, which is basically the same as the first area described above. The second embodiment is the same. Second, by using the second transfer film 2 B The transfer method forms the second phosphor portion 5 2 (step S 1 2). At this time, the conductive layer 15A formed by the transfer using the first transfer film 1A partially overlaps the transfer of the second transfer film 2B. The printed layer, especially the conductive layer 25A, is used for transfer. Thereby, the conductive layer 15A of the first phosphor portion 51 and the conductive layer 25A of the second phosphor portion 52 are conductively connected. Next, the glass frit is used for welding. Project (F / S project) joining screen 31, front panel 32, and funnel section 33 (step S 13). Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, secondly, will be the younger brother of the fine mesh 31, the second camp, the body 52. The conductive layer 25A is electrically connected to the inner conductive film 53 of the funnel portion 33 by using a conductive film 54 (step S14). The conductive conductive film 54 is formed in the same manner as in the case shown in FIG. 7, for example, from the central end portion of the conductive layer 2 5 A on the side of the funnel portion 33 to the center of the screen 31 of the internal conductive film 53. The end area is coated with, for example, a carbon film. The conductive conductive film 54 is fired at, for example, a temperature of about 440 ± 20C. The conductive conductive film 54 is formed so that the anode layer HA is applied to the conductive layer 25A of the second phosphor portion 52 through the internal conductive film 53 and the conductive conductive film 54. In addition, the conductive layer 15 A of the first phosphor portion 51 and the conductive layer 25 a of the second phosphor portion 52 are electrically conductive. The paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210XM7 mm) -24- 583706. A7 B7 5. Description of the invention (22) For connection, an anode voltage HV may be applied to the conductive layer 15A. The flat cathode wire tube 30 is manufactured as described above. (Please read the precautions on the back before writing this page.) As described above, even in this embodiment, the first phosphor portion 51 and the second phosphor portion 52 are used by using two transfer films. The transfer method of 1A and 2B is formed in another process, for example, it is different from the case where only one transfer film is used to form the fluorescent surface at a time, even if the first phosphor portion 51 and the second fluorescent portion are formed. The formation process of any one of the light body portions 52 is defective, and if any one of the processes is performed again, reliability can be improved and a fluorescent surface 50 having excellent productivity can be formed. Furthermore, the present invention is described with reference to forming a fluorescent surface by a transfer method, but also uses a method other than a vapor deposition method and a plating method as a reference example. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs First, on the inner surface of the screen 131, a first conductive film 115 and a second conductive film 125 made of, for example, an aluminum (A1) vapor-deposited film, as shown in FIG. 16 The formation of a coating is shown (step S1). At this time, the first conductive film 115 is formed in the entire formation region of the first phosphor portion 151. A lead portion 116 that applies a voltage to the first conductive film 115 is formed at the same time. On the other hand, the second conductive film 125 is formed in the formation region of the second phosphor portion 152 with the same shape as the phosphor pattern (image pattern) at the position where the second phosphor layer 123 is formed. At the same time, lead portions 126 (126A, 126B, 126C) for applying a voltage to the second conductive film 25 are formed at the same time. The conductive films 115, 125 and the lead portions 116, 126 cover areas other than the formation areas of the conductive films 115, 125 and the lead portions 116, 126 with a photomask, for example, and are simultaneously formed by vapor deposition. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -25- 3S6 583706 A7 __B7 V. Description of the invention (25) (Please read the precautions on the back before filling this page) Photobody layer (that is, luminescence When a plurality of phosphor patterns with different colors are formed, each color is subjected to an electroplating process. For example, when the phosphor layers 123A, 123B, and 123C constituting the second phosphor layer 123 are formed using blue, red, and green phosphors, respectively, a plating solution 62 for dispersing phosphor powders of the respective colors is used. A sieve 1 3 1 is arranged in the middle, and electroplating deposition processing is performed sequentially. At this time, the electrode portions of the electrode and holding portion 163 are in each plating deposition process, and selectively contact the conductive films 125A, 125B, 125C, and lead portions 125A on the formation surfaces of the phosphor layers 123A, 123B, and 123C. , 125B, 125C. Thereby, in each of the electroplating and deposition treatment processes, only the conductive film to be electroplated and deposited among the conductive films 125A, 125B, and 125C is selectively applied with a voltage from the power source 165. As the blue phosphor powder, for example, ZnS: Ag and the like can be used. In addition, green phosphor powder can be used, for example, ZnS; Cu, A1 and the like. As the red phosphor powder, for example, Y202s: Eu can be used. As described above, the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs has printed each phosphor layer as described above, and then as shown in FIG. 5, the lead portions 116 and 126 of the conductive films 115 and 125 are formed by using, for example, carbon The conductive conductive film 154 made of the film is electrically connected to each other to form a common connection portion 154A (step S3). As a result, the conductive films 115 and 125 are electrically connected to each other. Next, the screen 131, the front panel 132, and the funnel part 133 are joined by a frit welding process (F / S process) (step S4). Next, the inner conductive film 153 of the funnel portion 33 and the common connection portion 54A formed in step S3 are, for example, coated with a carbon film to be conductively connected (step S5). As a result, as shown in Figure 17, 'Each conductive film 115 — This paper size applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) -28-Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 583706 A7 ___ B7 V. Description of the invention (26): The area of each lead portion 116, 126 of 125 to the end of the screen Π1 side of the internal conductive film 153 forms a conductive conductive film 154. As a result, the conductive films 115 and 125 of the screen 131 and the internal conductive film 153 of the funnel portion U3 are electrically connected. The conductive film 154 is fired at, for example, a temperature of about 440 ± 20 ° C. In this way, an anode voltage HV is applied to the first conductive film 15 and the second conductive film 125 through the internal conductive film 153 and the conductive conductive film 154. The flat cathode wire tube 30 is manufactured as described above. Furthermore, the present invention is not limited to the above-mentioned embodiments, and various modifications can be made. For example, the present invention is applicable not only to flat cathode ray tubes, but also to straight cathode ray tubes that illuminate the electron beam of an electron gun perpendicularly to the center of the fluorescent surface. In each of the embodiments described above, an example has been described in which the image display area 32B (the second phosphor portion 52) is provided below the main image display area 32A (the first phosphor portion 51), but The image display area 32B may be provided in another area. That is, the image display area 32B may be provided on the upper, left, or right side of the main image display area 32A. The image display area 3 2 B may be provided in two or more areas. [Effects of the Invention] As described above, as long as the method for forming a fluorescent surface described in any one of the scope of claims 1 to 4 of the patent application is applied, the fluorescent body portion can be laminated at least by using The first phosphor film is formed by a transfer method of a first transfer film, and the second phosphor portion is formed by a transfer method using a second transfer film that is laminated on at least a second phosphor layer. Therefore, for example, the paper size can be applied to the Chinese National Standard (CNS) A4 specification (210X297). I order; please order (please read the precautions on the back before 4-writing this ^-) -29- 583706 A7 B7 V. Invention Note (27) (Please read the precautions on the back before filling out this page) The conventional transfer film is still used as the first transfer film. Thereby, conventionally used transfer films are not wasted, and a fluorescent surface having excellent productivity can be formed by a transfer method. That is, when forming a conventional fluorescent surface with a single fluorescent body portion, it is possible to achieve some commonality. [Brief description of the drawing] Fig. 1 is a cross-sectional view showing the structure of a main part of a flat-type cathode wire tube manufactured by using the method for forming a fluorescent screen according to the first embodiment of the present invention. Fig. 2 is a front view showing a state where the flat cathode wire tube shown in Fig. 2 is viewed from the front (front panel side). Fig. 3 is a front view showing the structure of the first and second transfer films used in the method for forming a fluorescent surface according to the first embodiment of the present invention. Fig. 4 is a cross-sectional view showing the cross-sectional structure of the first and second transfer films shown in Fig. 3; Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Figure 5 is a cross-sectional view illustrating the transfer process using the first transfer film shown in Figures 3 and 4. Fig. 6 is a cross-sectional view illustrating a transfer process using the second transfer film shown in Figs. 3 and 4; Fig. 7 is a front view showing a structure of a fluorescent surface of a flat-type cathode wire tube manufactured by using the method for forming a fluorescent surface according to the first embodiment of the present invention. FIG. 8 is a diagram illustrating the size of the fluorescent paper according to the first embodiment of the present invention, and the Chinese national standard (CNS) A4 specification (210X297 mm) is applied. -30 583706 A7 B7 V. Method for forming the (28) surface of the invention The flow chart of the manufacturing process of the flat cathode wire tube. (Please read the precautions on the back before writing the copy ¥ -c Figure 9 shows the composition of the first and second transfer films used in the method for forming the fluorescent surface of the second embodiment of the present invention Front view. Fig. 10 is a cross-sectional view showing the cross-sectional structure of the first and second transfer films shown in Fig. 9. Fig. 11 is a view illustrating the use of the second and third views shown in Figs. 9 and 10. A cross-sectional view of the transfer process of the transfer film. Figures 12 and 12 show the structures of the first and second transfer films used in the method for forming a fluorescent surface according to the third embodiment of the present invention. Fig. 13 is a flowchart illustrating a manufacturing process of a flat cathode wire tube including a method for forming a fluorescent surface according to a third embodiment of the present invention. Fig. 14 shows a display mode of the cathode wire tube. (A) shows a conventional flat-type cathode ray tube that can only display black and white video, and (B) shows a flat-type cathode ray tube that can partially perform image-like color display even in a black and white video display mode Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Fig. 5 is a configuration diagram of an electroplating deposition apparatus used for a method for forming a fluorescent surface according to a reference example of the present invention. Fig. 16 is a diagram showing a method using the method for forming a fluorescent surface according to a reference example of the present invention. A front view of the structure of the phosphor before the electroplating of the phosphor. Fig. 17 is a front view showing the structure of the phosphor surface of a flat cathode-ray tube manufactured using the method of forming a phosphor according to a reference example of the present invention. The paper size of the book is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -31-583706 A7 B7 V. Description of the invention (29)

(請先閲讀背面之注意事項再资寫本百C 【符號之說明】 1 A…第1轉印用薄膜 2,2A,2B…第2轉印用薄膜 10, 20 … 轉 印 層 11 · 2L· … 轉 印 基 板 12, 22 … 剝 離 層 13·· •第 1 螢 光 體 層 14, 24· 反 射 層 15, 25' 導 電 層 16, 26' 接 著 層 23·· •第 2 螢 光 層 30·· •扁 平 型 陰 極 線 31 ·· •篩: 網 32·· > •刖 面 板 經濟部智慧財產局員工消費合作社印製 32A…主映像顯示區域 32B…圖像顯示區域 3 3…漏斗部 35…電子鎗 41…主映像 4 2…圖像映像 5 0…螢光面 51…第1螢光體部 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -32- 583706 A7 B7 五、發明説明(30 ) 52…第2螢光體部 53···內部導電膜 54…導通用導電膜 (請先閲讀背面之注意事項再填寫本I·) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) -33-(Please read the precautions on the back before writing this 100C [Explanation of Symbols] 1 A ... The first transfer film 2, 2A, 2B ... The second transfer film 10, 20 ... Transfer layer 11 · 2L · … Transfer substrates 12, 22… peeling layer 13 ·· • 1st phosphor layer 14, 24 · reflective layer 15, 25 'conductive layer 16, 26' followed by 23 ·· • 2nd fluorescent layer 30 ·· • Flat Cathode Wire 31 ·· • Screen: Net 32 · > • 刖 Panel Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 32A ... Main image display area 32B ... Image display area 3 3 ... Funnel section 35 ... Electron gun 41 ... Main image 4 2 ... Image image 5 0 ... Fluorescent surface 51 ... First phosphor body This paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) -32- 583706 A7 B7 V. Description of the invention ( 30) 52 ... 2nd phosphor part 53 ... Internal conductive film 54 ... General conductive film (Please read the precautions on the back before filling in this I.) The paper printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Applicable to China National Standard (CNS) A4 (210X 297 mm) -33-

Claims (1)

經濟部智慧財產局員工消費合作社印製 583706 A8 B8 C8 _ _ D8 六、申請專利範圍q 1. 一種螢光面之形成方法,其特徵爲包含:至少使用 積層第1螢光體層之第1轉印用薄膜,利用轉印法形成第 1螢光體部之第1工程、 和至少使用積層第2螢光體層之第2轉印用薄膜,在 與設有前述第1螢光體層之範圍不同的範圍,利用轉印法 形成第2螢光體部之第2工程。 2. 如申請專範圍第1項所述之螢光面之形成方法,其 中,於前述第1轉印用薄膜更積層導電層, 於前述第1工程中,將前述導電層轉印到前述第1螢 光體部及前述第2螢光體部的形成區域之同時,將前述第 1螢光體層轉印到前述第1螢光體部的形成區域, 於前述第2工程中,將前述第2螢光體層,以全體重 疊在經由前述第1工程所轉印的導電層之上地,轉印到前 述第2螢光體部的形成區域。 3·如申請專範圍第1項所述之螢光面之形成方法, 其中,於前述第1轉印用薄膜更積層第1導電層的伺時, 也在前述第2轉印用薄膜更積層第2導電層, 於前述第1工程中,將前述第1導電層轉印到前述第 1螢光體部及前述第2螢光體部的形成區域之同時,將前 述第1螢光體層轉印到前述第1螢光體部的形成區域, 於前述第2工程中,將前述第2螢光體層及前述第2 導電層,以全體重疊在經由前述第1工程所轉印的第丨導 電層之上地,轉印到前述第2螢光體部的形成區域。 4 ·如申請專範圍第1項所述之螢光面之形成方法,:^ 本#氏張尺度適用中國國家橾準(〇奶)八4規格(210乂297公釐) :-- (請先閱讀背面之注意事項再填寫本頁) ,裝· 、11 -34- 583706 A8 B8 C8 D8 六、申請專利範圍 2 中,於前述第1轉印用薄膜更積層第1導電層的同時,也 在前述第2轉印用薄膜更積層第2導電層, 於前述第1工程中,將前述第1導電層轉印到前述第 1螢光體部及前述第2螢光體部的形成區域之同時,將前 述第1螢光體層轉印到前述第1螢光體部的形成區域, 於前述第2工程中,將前述第2螢光體層及前述第2 導電層,以全體重疊在經由前述第1工程所轉印的第1導 電層之上地,轉印到前述第2螢光體部的形成區域。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -35- 583706 第91106995號專利申請案中文說明書修正頁 民國92气^月3曰修正 -------- B7_ 五、發明説明(6) 之偏向軛等。 (請先閱讀背面之注意事項再填寫本頁) 則面板3 2係爲平板形狀。另一'方面’飾網3 1係成爲 於垂直方向(上下方向)彎曲的形狀。在篩網3 1的內壁面 側’亦即面對前面板3 2的面側形成螢光面5 0。螢光面5 0 係具有第1螢光體部5 1,和第2螢光體部52。 第1螢光體部51通常爲進行黑白視訊映像顯示,由 篩網3 1的內壁面側依序積層導電層1 5、反射層1 4及第1 螢光體層13所構成。另一方面,第2螢光體部51係爲進 行圖像狀之映像顯示,由篩網31的內壁面側依序積層導 電層15、反射層24及第2螢光體層23所構成。 導電層15是用第1螢光體部51及第2螢光體部52 成爲共通之一連續的層。導電層1 5係藉由以例如碳膜所 製成的導通用導電膜54而被導電連接在漏斗部33的內部 導電膜53。藉此,對導電層15透過內部導電膜53及導 通用導電膜54施加陽極電壓HV。各反射層14,24具有 將經由電子波束EB入射到各螢光體層1 3,23所產生的 各發光光線R 1,R2反射到前面板32側的功能。 經濟部智慧財產局員工消費合作社印製 第1螢光體層13及第2螢光體層23係爲同時配合電 子波束EB的入射而進行發光’但可由各種不同的螢光體 所構成。更詳細係第1營光體層1 3是藉由例如白色發光 螢光體所構成。該第1螢光體層13乃如第7圖所示’至 少配合包含通常用來顯示映像的主映像顯示區域3 2 A (相 當於通常的有效畫面區域)(第2圖)的區域全體而一樣地 設置。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公褒1 -9- 583706 A7 B7Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 583706 A8 B8 C8 _ _ D8 VI. Scope of patent application q 1. A method for forming a fluorescent surface, comprising: using at least the first turn of a laminated first phosphor layer The printing film has a first process of forming a first phosphor portion by a transfer method, and a second transfer film using at least a laminated second phosphor layer, and is different from the range in which the first phosphor layer is provided. The second process of forming the second phosphor portion by the transfer method. 2. The method for forming a fluorescent surface according to item 1 of the application scope, wherein a conductive layer is further laminated on the first transfer film, and in the first process, the conductive layer is transferred to the first At the same time as the formation area of the first phosphor portion and the second phosphor portion, the first phosphor layer is transferred to the formation area of the first phosphor portion. In the second process, the first phosphor layer is transferred. The 2 phosphor layers are superimposed on the entire conductive layer transferred through the first process and transferred to the formation region of the second phosphor portion. 3. The method for forming a fluorescent surface as described in the first item of the application scope, wherein when the first conductive film is further laminated with the first conductive layer, the second transfer film is further laminated with the second conductive film. The second conductive layer, in the first process, transfers the first conductive layer to the formation area of the first phosphor portion and the second phosphor portion, and transfers the first phosphor layer Printed on the formation area of the first phosphor part, and in the second process, the second phosphor layer and the second conductive layer are superimposed on the entire first conductive part transferred by the first process Layer-by-layer, it is transferred to the formation area of the said 2nd fluorescent body part. 4 · As for the method of forming the fluorescent surface described in item 1 of the application scope ,: ^ This Zhang scale is applicable to China National Standard (0 Milk) 8 4 specifications (210 to 297 mm):-(Please Read the precautions on the back before filling in this page), install ·, 11 -34- 583706 A8 B8 C8 D8 6. In the scope of patent application 2, while the first conductive film is laminated with the first conductive layer, In the second transfer film, a second conductive layer is further laminated, and in the first process, the first conductive layer is transferred to a region where the first phosphor portion and the second phosphor portion are formed. At the same time, the first phosphor layer is transferred to the formation area of the first phosphor portion. In the second process, the second phosphor layer and the second conductive layer are superimposed on each other via the entire portion. The first conductive layer transferred by the first process is transferred onto the formation region of the second phosphor portion. (Please read the notes on the back before filling this page) The paper size printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) -35- 583706 Patent Application No. 91106995 Revised page of the Chinese manual 92. Revised on the 3rd month of the Republic of China -------- B7_ V. Explanation of the invention (6) towards the yoke. (Please read the precautions on the back before filling out this page.) Panel 3 2 is flat. On the other side, the decorative net 31 is curved in a vertical direction (up and down direction). A fluorescent surface 50 is formed on the inner wall surface side 'of the screen 31, that is, the surface side facing the front panel 32. The phosphor surface 50 includes a first phosphor portion 51 and a second phosphor portion 52. The first phosphor portion 51 is usually a black-and-white video image display, and is composed of a conductive layer 15, a reflective layer 14, and a first phosphor layer 13 that are sequentially laminated on the inner wall surface side of the screen 31. On the other hand, the second phosphor portion 51 is an image-like image display, and is configured by sequentially stacking the conductive layer 15, the reflective layer 24, and the second phosphor layer 23 on the inner wall surface side of the screen 31. The conductive layer 15 is a continuous layer common to the first phosphor portion 51 and the second phosphor portion 52. The conductive layer 15 is conductively connected to a conductive film 53 inside the funnel portion 33 by a conductive conductive film 54 made of, for example, a carbon film. Thereby, an anode voltage HV is applied to the conductive layer 15 through the internal conductive film 53 and the conductive conductive film 54. Each of the reflection layers 14, 24 has a function of reflecting the respective light-emitting rays R1, R2 generated by being incident on the phosphor layers 1 3, 23 via the electron beam EB to the front panel 32 side. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The first phosphor layer 13 and the second phosphor layer 23 emit light while cooperating with the incidence of the electron beam EB ', but may be composed of various phosphors. In more detail, the first camping light layer 13 is made of, for example, a white light-emitting phosphor. The first phosphor layer 13 is the same as that shown in FIG. 7 at least in the entire area including the main image display area 3 2 A (equivalent to a normal effective screen area) (FIG. 2) that is usually used to display an image. Ground setting. This paper size is applicable to Chinese National Standard (CNS) A4 (210X 297 males 1 -9-583706 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(7) 另一方面’第2螢光體層23係藉由利用與第1螢光 體層1 3不同的顏色發光的其他螢光體所構成。該第2螢 光體層2 3係將與顯示在主映像顯示區域3 2 A之主映像4 1 不同的圖像狀之彩色映像(圖像映像)42(42A,42B,42C) ’顯示在圖像顯示區域32B(第2圖)地被設置。該第2螢 光體層23乃如第7圖所示,事先以圖案形成與欲顯示之 映像同等的形狀(模擬圖像映像42的形狀)。因而,第2 螢光體層23不必全部設置在配合圖像顯示區域32B的區 域’基本上只部份地設在欲顯示圖像映像42的區域。此 時’不顯示圖像映像42的部分(不設第2螢光體層23的 部分),例如積層黑色物質(石墨等)的黑底顯影管之構造 爲佳。 第2螢光體層23的各螢光體層23A,23B,23C(第7 圖)係配合欲顯示的圖像映像4 2,用單色(例如紅色)或複 數色所形成。藉此,用電子波束EB加以掃瞄時,所掃瞄 的螢光體圖案部分會發光,藉由其發光光線R2而於圖像 顯示區域32B顯示配合其螢光體圖案的圖像映像42。在 配合圖像顯示區域3 2 B的區域,如第7圖所示形成由複數 螢光體層23 A,23 B,23C所製成的螢光圖案,藉此同時 或個別顯示複數圖像映像42A,42B,42C。 再者,第2圖中,如第7圖所示,第2螢光體層23 是用星形、四角形及圓形的螢光體層23 A,23 B,23 C所 形成,藉此表示顯示星形、四角形及圓形的圖像映像42A ,42B,4 2C之案例。然而,第2螢光體層23的形狀可形 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) I ^^裝IT i (請先閲讀背面之注意事項再填寫本頁) - 10- 583706Printed by the Employees ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (7) On the other hand, the 'second phosphor layer 23 is composed of other phosphors that emit light in a different color from the first phosphor layer 13 . The second phosphor layer 2 3 is a color image (image image) 42 (42A, 42B, 42C) which is different from the main image 4 1 displayed in the main image display area 3 2 A. An image display area 32B (FIG. 2) is provided. The second phosphor layer 23 is formed in a pattern equivalent to the image to be displayed (the shape of the analog image image 42) in a pattern as shown in Fig. 7 in advance. Therefore, the second phosphor layer 23 does not need to be entirely provided in a region 'corresponding to the image display region 32B, and is basically only partially provided in a region where the image image 42 is to be displayed. In this case, the portion where the image image 42 is not displayed (the portion where the second phosphor layer 23 is not provided), such as a black matrix developing tube in which a black substance (graphite, etc.) is laminated, is preferable. Each of the phosphor layers 23A, 23B, and 23C (Fig. 7) of the second phosphor layer 23 is formed of a single color (for example, red) or a plurality of colors in accordance with the image image 42 to be displayed. Thereby, when scanning with the electron beam EB, the scanned phosphor pattern portion emits light, and an image image 42 corresponding to the phosphor pattern is displayed on the image display area 32B by the emitted light R2. In the area corresponding to the image display area 3 2 B, as shown in FIG. 7, a fluorescent pattern made of a plurality of phosphor layers 23 A, 23 B, and 23C is formed, thereby displaying the plurality of image images 42A simultaneously or individually. , 42B, 42C. In the second figure, as shown in FIG. 7, the second phosphor layer 23 is formed of star, quadrangular, and circular phosphor layers 23 A, 23 B, and 23 C, thereby representing a display star. Examples of image images 42A, 42B, 4 2C in the shape of a square, a quadrangle and a circle. However, the shape of the second phosphor layer 23 can be shaped. The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) I ^^ IT i (Please read the precautions on the back before filling out this page)-10 -583706 五、發明説明(2() 圖(A),(B)所示的轉印用薄膜i,2A相同。又,其製作方 法基本上也與轉印用薄膜1,2A相同。亦即,本竇施形 態中’第丨轉印用薄膜1 A是使用在轉印基板1 1的一面 依序利用印刷法積層形成剝離層1 2 A、第1螢光體層1 3、 反射層14 '導電層15A及接著層16A。又,第2轉印用 薄膜2 B是使用在轉印基板2 1的一面依序利用印刷法積層 形成剝離層22A、第2螢光體層23、反射層24、導電餍 25A及接著層26A。 但是本實施形態的轉印用薄膜1 A,2 B中,特別是各 個導電層15A,25A的形成面積是與第1〇圖(a),(B)所示 的轉印用薄膜1,2A不同的。 亦即,比較第9圖(A)和第12圖(A)即知,第1轉印 用薄膜1 A的導電層1 5 A係第2螢光體部5 2之形成側(圖 中爲上側)的面積縮得比第9圖(A)的第1轉印用薄膜1還 小的被形成。又,以配合該導電層1 5 A之面積的形狀, 連剝離層1 2 A及接著層1 6 A,其形成面積也被縮小。一方 面,第2轉印用薄膜2B的導電層25A之形成面積係比較 第9圖(B)和第1 2圖(B)即知,於轉印時,與第1轉印用 薄膜1 A之導電層1 5 A部分重疊的程度,與第9圖(B)的第 2轉印用薄膜2 A相比,第1螢光體部5 1的形成側(圖中 爲上側)被擴大。第1 2圖(A),( B)中,以符號d所示的部 分,於轉印時,爲互相重合的部分。 再者,本實施形態中,導電層1 5 A是配合本發明之 「第1導電層」的其中一具體例,導電層25A是配合本 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 訂 I# 經濟部智慧財產局員工消費合作社印製 •23- 583706 A7 B7 f 五、發明説明(2$ 其次,在第1導電膜1 15上及第2導電膜125上,分 別將第1螢光體層1 1 3及第2螢光體層1 23利用電鍍沈積 法加以選擇性地被覆形成(步驟S2)。 該螢光體層1 1 3,1 23的電鍍沈積處理係例如使用第 1 5圖所示的電鑛沈積裝置進行。該電鑛沈積裝置係主要 由收容電鍍液1 62之電鍍槽1 6 1,和具有保持做爲電鎪沈 積對象的篩網1 3 1,同時對螢光體層1 1 3,1 2 3的形成面 之導電膜1 1 5,1 2 5施加電壓的功能之電極兼保持部1 6 3 ,和面對面配置在螢光體層1 1 3,1 23的形成面之對向電 極1 6 4,和對電極兼保持部1 6 3及對向電極1 6 4供應電壓 之電源165所構成。 電鍍液1 62例如使用將螢光體、氧化銦、硝酸鋁及硝 酸鑭的混合物與純水、異丙醇、甘油加以混合,進行超音 波分散所製成者。此時,分散在電鍍液1 62的螢光體係使 用配合欲形成的螢光體層之種類(色)。例如形成第1螢光 體層113之情形,乃將白色發光螢光體、例如Y2〇2s (氧化 硫化釔)或Y 2 0 2 S : T B (氧化硫化釔:铽賦活)等之螢光粉體 分散到電鍍液1 62。又,形成第2螢光體層1 23之情形, 乃將配合其欲顯示的圖像映像42之種類的發光色之螢光 粉體分散到電鍍液362。 使用該電鍍沈積裝置的電鍍沈積處理係對每個螢光體 層,更詳細是對每個顏色進行。例如先利用電鍍沈積法形 成第1螢光體層Π 3後,利用電鍍沈積法形成第2螢光體 層1 23。此時,先在分散第1螢光體層1 1 3的構成成份之 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 -26- 583706 Α7 Β7 五、發明説明(24 白色發光螢光體的電鍍液1 62中,利用電極兼保持部1 63 加以保持配置篩網1 3 1。此時,電極兼保持部1 63的電極 部分會接觸到第1螢光體層1 1 3的形成面之第1導電膜 115之引線部116。藉此,透過電極兼保持部163只對第 1導電膜1 1 5選擇性地施加來自電源1 65的電壓。又,將 對向電極1 64以面對第1螢光體層1 1 3之形成面的第1導 電膜1 15加以配置。然後,如第15圖所示,於對向電極 1 64例如施加正電位,於第1導電膜1 1 5透過電極兼保持 部1 63及引線部1 1 6例如施加負電位,進行螢光體的電鍍 沈積處理。藉此針對篩網1 3 1的內面,於第1導電膜1 1 5 上選擇性地電鍍沈積形成第1螢光體層1 1 3.。 其次,在分散第2螢光體層1 23的構成成份之螢光體 粉體之電鍍液1 62中,利用電極兼保持部1 63加以保持配 置篩網1 3 1。此時,電極兼保持部1 63的電極部分會接觸 到第2螢光體層123的形成面之第2導電膜125之引線部 126。藉此透過電極兼保持部163只對第2導電膜125選 擇性地施加來自電源1 65的電壓。又,將對向電極1 64以 面對第2螢光體層1 23之形成面的第2導電膜1 25加以配 置。然後,如第1 1圖所示,在對向電極164例如施加正 電位’對第1導電膜1 1 5透過電極兼保持部1 63及引線部 1 1 6例如施加負電位,進行螢光體的電鍍沈積處理。藉此 針對篩網1 3 1的內面,於第2導電膜1 25上選擇性地電鍍 沈積形成所希望的顏色之第2螢光體層1 23。 再者,將第2螢光體層1 23利用發光色不同的複數螢 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) #¾衣-- (請先閲讀背面之注意事項再填寫本頁) 訂 -ΙΦ 經濟部智慧財產局員工消費合作社印製 -27 -5. Description of the invention (2 () Figures (A), (B) The transfer film i, 2A is the same. Also, the manufacturing method is basically the same as the transfer film 1, 2A. That is, the present In the form of Dou Shi, the "first transfer film 1 A" is used to form a peeling layer 1 2 A, a first phosphor layer 1 3, and a reflective layer 14 'conducting layer laminated on the transfer substrate 1 1 by printing in order. 15A and the adhesive layer 16A. The second transfer film 2 B is formed by laminating the transfer substrate 21 1 by printing in order to form a release layer 22A, a second phosphor layer 23, a reflective layer 24, and a conductive film. 25A and the adhesive layer 26A. However, in the transfer films 1 A and 2 B of this embodiment, in particular, the formation area of each of the conductive layers 15A and 25A is the same as that shown in FIGS. 10 (a) and (B). The printing film 1 and 2A are different. That is, comparing FIG. 9 (A) and FIG. 12 (A), it is understood that the conductive layer 15 A of the first transfer film 1 A is the second phosphor portion. The area on the formation side (upper side in the figure) of 5 2 is smaller than that of the first transfer film 1 in FIG. 9 (A). It is formed to fit the shape of the area of the conductive layer 15 A , Stripped The formation area of the layer 1 2 A and the adhesion layer 16 A is also reduced. On the one hand, the formation area of the conductive layer 25A of the second transfer film 2B is compared with FIG. 9 (B) and FIG. 12 (B ) That is, the degree of partial overlap with the conductive layer 15 A of the first transfer film 1 A at the time of transfer is compared with the second transfer film 2 A of FIG. 9 (B). The formation side (upper side in the figure) of the phosphor portion 51 is enlarged. In Figs. 12 (A) and (B), portions indicated by the symbol d are overlapped portions during transfer. Furthermore, in this embodiment, the conductive layer 15 A is a specific example of the "first conductive layer" that is compatible with the present invention. The conductive layer 25A is compatible with the Chinese paper standard (CNS) A4 specification (210X 297) in accordance with the paper size. (Mm) (Please read the precautions on the back before filling out this page) Order I # Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs • 23-583706 A7 B7 f 5. Description of the invention (2 $ Second, in the first conductive film The first phosphor layer 1 1 3 and the second phosphor layer 1 23 are selectively deposited on the first conductive layer 125 and the second conductive film 125 by a plating method. Overlay formation (step S2). The electroplating deposition treatment of the phosphor layers 1 1 3, 1 23 is performed using, for example, the electro-mineral deposition device shown in FIG. 15. The electro-mineral deposition device is mainly composed of a plating solution 1 62 The electroplating bath 1 6 1 and the screen 1 3 1 having a target for electrodeposition are applied, and at the same time, a voltage is applied to the conductive film 1 1 3, 1 2 3 on the formation surface of the phosphor layer 1 1 5 1 2 5 The function of the electrode-cum-holding portion 1 6 3, and the counter-electrode 1 6 4, and the counter-electrode-holding portion 1 6 3 and the counter-electrode 1 6 which are arranged face to face on the formation surface of the phosphor layer 1 1 3, 1 23 4 is constituted by a power source 165 for supplying a voltage. The plating solution 162 is produced by mixing a mixture of phosphor, indium oxide, aluminum nitrate, and lanthanum nitrate with pure water, isopropyl alcohol, and glycerin, and performing ultrasonic dispersion. At this time, the type (color) of the phosphor layer to be formed is used for the fluorescent system dispersed in the plating solution 162. For example, in the case where the first phosphor layer 113 is formed, a white light-emitting phosphor, such as Y2O2s (Yttrium Oxide Sulfide) or Y 2 0 2 S: TB (Yttrium Oxide Sulfide: Yttrium Activated), is used as a fluorescent powder. Dispersed into the plating solution 162. In the case of forming the second phosphor layer 123, the phosphor powder of the luminescent color that matches the type of the image image 42 to be displayed is dispersed in the plating solution 362. The plating deposition process using this plating deposition apparatus is performed for each phosphor layer, more specifically for each color. For example, after the first phosphor layer Π 3 is formed by the electroplating deposition method, the second phosphor layer 123 is formed by the electroplating deposition method. At this time, the paper size of the components of the 1st phosphor layer 1 1 3 is dispersed to the Chinese national standard (CNS) A4 specification (210X297 mm) (please read the precautions on the back before filling this page). Printed by the Consumers ’Cooperative of the Ministry of Intellectual Property Bureau -26- 583706 Α7 Β7 V. Description of the Invention (24 In the electroplating solution 1 62 of white light-emitting phosphor, the electrode and holding portion 1 63 are used to hold and arrange the screen 1 3 1. This At this time, the electrode portion of the electrode / holding portion 163 is in contact with the lead portion 116 of the first conductive film 115 on the formation surface of the first phosphor layer 1 13. As a result, only the first conductive is conducted through the electrode and holding portion 163 The film 1 1 5 selectively applies a voltage from the power source 1 65. Further, the counter electrode 1 64 is provided with the first conductive film 1 15 facing the formation surface of the first phosphor layer 1 1 3. Then, as in As shown in FIG. 15, for example, a positive potential is applied to the counter electrode 164, and a negative potential is applied to the first conductive film 1 1 5 through the electrode and holding portion 1 63 and the lead portion 1 1 6 to perform electroplating deposition of a phosphor, for example. This process is aimed at the inner surface of the screen 1 3 1 on the first conductive film 1 The first phosphor layer 1 1 is selectively electroplated on 15 to form an electroplating solution 1 62 for phosphor powder in which the constituents of the second phosphor layer 1 23 are dispersed. The portion 1 63 holds and arranges the screen 1 31. At this time, the electrode portion of the electrode-and-holding portion 1 63 contacts the lead portion 126 of the second conductive film 125 on the formation surface of the second phosphor layer 123. This allows transmission The electrode and holding portion 163 selectively applies a voltage from the power source 1 65 to the second conductive film 125 only. The second conductive film 1 faces the counter electrode 1 64 so as to face the formation surface of the second phosphor layer 1 23. 25. Then, as shown in FIG. 11, a positive potential is applied to the counter electrode 164, for example, 'a negative potential is applied to the first conductive film 1 1 5 through the electrode and holding portion 1 63 and the lead portion 1 1 6 A phosphor deposition process is performed, whereby the second phosphor layer 1 23 of a desired color is selectively electroplated and deposited on the second conductive film 1 25 against the inner surface of the screen 1 3 1. Furthermore, , The second phosphor layer 1 23 uses a plurality of fluorescent papers with different emission colors. CNS) A4 size (210X 297mm) # ¾ 衣-(Please read the notes on the back before filling out this page) Order -ΙΦ Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -27-
TW091106995A 2001-04-10 2002-04-08 Forming method of fluorescent surface TW583706B (en)

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JP2001111292A JP2002313230A (en) 2001-04-10 2001-04-10 Forming method for fluorescent surface
JP2001111293A JP2002313231A (en) 2001-04-10 2001-04-10 Forming method of fluorescent surface

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CN1383174A (en) 2002-12-04

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