TW200934756A - A method and an arrangement for making methanol - Google Patents

A method and an arrangement for making methanol Download PDF

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Publication number
TW200934756A
TW200934756A TW097104540A TW97104540A TW200934756A TW 200934756 A TW200934756 A TW 200934756A TW 097104540 A TW097104540 A TW 097104540A TW 97104540 A TW97104540 A TW 97104540A TW 200934756 A TW200934756 A TW 200934756A
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Taiwan
Prior art keywords
carbon dioxide
methanol
wall surface
fuel cell
rotating
Prior art date
Application number
TW097104540A
Other languages
Chinese (zh)
Inventor
Alf Larsson
Olof Dahlberg
Dan Borgstrom
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Morphic Technologies Ab
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Publication date
Application filed by Morphic Technologies Ab filed Critical Morphic Technologies Ab
Publication of TW200934756A publication Critical patent/TW200934756A/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F03MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
    • F03DWIND MOTORS
    • F03D9/00Adaptations of wind motors for special use; Combinations of wind motors with apparatus driven thereby; Wind motors specially adapted for installation in particular locations
    • F03D9/20Wind motors characterised by the driven apparatus
    • F03D9/25Wind motors characterised by the driven apparatus the apparatus being an electrical generator
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516Multisteps
    • C07C29/1518Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02Monohydroxylic acyclic alcohols
    • C07C31/04Methanol
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/73After-treatment of removed components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F03MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
    • F03DWIND MOTORS
    • F03D1/00Wind motors with rotation axis substantially parallel to the air flow entering the rotor 
    • F03D1/06Rotors
    • F03D1/065Rotors characterised by their construction elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F03MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
    • F03DWIND MOTORS
    • F03D9/00Adaptations of wind motors for special use; Combinations of wind motors with apparatus driven thereby; Wind motors specially adapted for installation in particular locations
    • F03D9/10Combinations of wind motors with apparatus storing energy
    • F03D9/19Combinations of wind motors with apparatus storing energy storing chemical energy, e.g. using electrolysis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/70Wind energy
    • Y02E10/72Wind turbines with rotation axis in wind direction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E70/00Other energy conversion or management systems reducing GHG emissions
    • Y02E70/30Systems combining energy storage with energy generation of non-fossil origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/151Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Development (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Sustainable Energy (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Power Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Fuel Cell (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention relates to a method of making methanol. The method comprises the steps of providing a wall 1 having a surface 2 on which a carbonic anhydrase 3 is immobilized, exposing the surface 2 of the wall 1 to a stream of gas and using the carbonic anhydrase 3 to remove carbon dioxide from the stream of gas. The carbon dioxide so obtained is then used to produce methanol. The invention also relates to an arrangement for making methanol.

Description

200934756 九、發明說明: 【發明所屬之技術領域】 關於—種用於製造甲醇的方法與配置。 【先刖技術】 已知可使用甲醇以作為能量來源。例如 燃料電池於產生電力的方法中。 〇用於 .^ , 再亦可使用甲醇以藉搬植 ^此!。因此’本發明之目的係提供 適* ❹ 的配置以製造甲醇。本發明進-步之目的係提供:種:: 源可㈣取得或能源需求低時將能源儲存,以便% : :或有大量能源需求時可將所儲存之能源加以二::200934756 IX. Description of the invention: [Technical field to which the invention pertains] A method and arrangement for producing methanol. [Prior Art] It is known that methanol can be used as a source of energy. For example, a fuel cell is used in a method of generating electricity. 〇Used for .^, you can also use methanol to borrow it. . Thus, the object of the present invention is to provide a suitable configuration for the manufacture of methanol. The objective of the present invention is to provide:: Source: (4) Energy storage when energy consumption is low or so that %: : or when there is a large amount of energy demand, the stored energy can be added to two:

【發明内容】 本發明係關於一種製造甲 含之步驟為提供壁面,其具有 酐的表面’將壁面曝露於特別 酸針以從氣流中移除二氧化碳 隨後用於製造甲醇。 醇的方法。本發明方法所包 其上放置,例如固定著碳酸 是空氣的氣流中,且使用碳 。如此所得到的二氧化碳可 二氧化碳較佳係心其中係❹電能以將水與二氧化 碳轉化成甲醇的化學反應中以製造甲醇。 該壁面例如係藉風力發電廢的旋轉翼片以形成。來自 風力發電廠的電能然後可用於將水與二氧化碳轉化成甲 醇。當然,即使壁面係藉風力發電廠的旋轉翼片以形成, 用於製造曱醇的電能亦可以來自風力發電廠以外的來源。 旋轉翼片可以分隔成數個在旋轉翼片徑向上彼此分離 200934756 的處理室。每一個處理室然後可以具有碳酸酐配置,例如 固定於其上的壁面,以使每一個處理室可以萃取二氧化 石炭。 所得到的甲醇可隨後用於例如燃料電池中以產生電 能。 本發明亦關於一種製造甲醇的配置。該配置係包含壁 面,其具有碳酸酐配置(如固定)於其上的表面,以使二氧 化碳可從特別是空氣的氣體中萃取出。該配置係進一步含 有連、σ至壁面的燃料電池以及聯結至燃料電池的電能來 源。 該壁面可例如藉風力發電廠的旋轉翼片以形成。 在某些具體實例中,旋轉翼片可以分隔成複數個在旋 轉翼片彳工向上彼此分離的處理室。至少某些處理室且可能 疋每一個處理室將具有碳酸酐係放置/固定於其上的壁面, 以使某些(或每一個)處理室可萃取二氧化碳。SUMMARY OF THE INVENTION The present invention is directed to a method of making a gel comprising providing a wall having an anhydride surface that exposes the wall to a particular acid needle to remove carbon dioxide from the gas stream for subsequent use in the manufacture of methanol. The method of alcohol. The method of the present invention is placed thereon, for example, in a gas stream in which carbonic acid is fixed, and carbon is used. The carbon dioxide which can be obtained in this way is preferably a core in which a ruthenium electric energy is used in a chemical reaction for converting water and carbon dioxide into methanol to produce methanol. The wall surface is formed, for example, by a rotating fin of wind power generation. Electrical energy from a wind farm can then be used to convert water and carbon dioxide to methanol. Of course, even if the wall is formed by a rotating fin of a wind power plant, the electrical energy used to make the sterol can come from sources other than the wind power plant. The rotating vanes can be divided into a number of processing chambers that are separated from each other in the radial direction of the rotating fins 200934756. Each of the processing chambers can then have a carbonic acid anhydride configuration, such as a wall surface secured thereto, so that each of the processing chambers can extract carbon dioxide. The resulting methanol can then be used, for example, in a fuel cell to produce electricity. The invention also relates to a configuration for the manufacture of methanol. The arrangement comprises a wall having a surface on which the carbonic anhydride configuration (e.g., fixed) is such that carbon dioxide can be extracted from a gas, particularly air. The configuration further includes a continuous, σ-to-wall fuel cell and an electrical energy source coupled to the fuel cell. The wall can be formed, for example, by a rotating fin of a wind power plant. In some embodiments, the rotating vanes can be divided into a plurality of processing chambers that are separated from one another in the upward direction of the rotating fins. At least some of the processing chambers and possibly each of the processing chambers will have walls on which the carbonic acid anhydride is placed/fixed so that some (or each) of the processing chambers can extract carbon dioxide.

【實施方式】 用於製造甲醇 ,wW々成你巴言提供壁 y z、具有其上配置(如固定)著碳酸酐3的表面2。碳酸 酐係具有可從氣流(例如空氣流)中移除二氧化碳的能力的 酵素。—種從空氣中移除二氧化碳的方法係例如揭示於美 ^ 第6143 556號中,關於碳酸酐與藉碳酸酐以* 厌方法的進一步細知可參考該文件。在枢赭 本發明的方法中,辟^ 據 中篪面1的表面2係曝露於像是空氣 blL中。碳酸酐3孫拉化 二、氣 酐3係藉此配置使用以從氣流中移除二氧化碳。 6 200934756 此所得到的二氧化碳隨後係用於製造甲醇。 如圖I中所顯示,碳酸酐3所放置之表面上的壁面] 將構成具有用於二氧化碳萃取的萃取室19的處理室8的 外表面。萃取室19可分隔成前方隔室20與後方隔室21, 且前方隔室20的所在係作為萃取 著液體。萃取室心的液體可藉泵浦22 “循環 方隔室20與後方隔室21間維持液體循環。後方隔室内的 ❹液體壓力較佳係應高於前方隔室2〇内的壓力。為此目的, 後方/、則方隔至20、2 1間可形成一流動限制23。液體 必須通過流動限制23以進入前方隔室。萃取室19内的液 體是含水磷酸鹽緩衝系統,即其係基於水。該液體可以含 有抗凍劑。處理室8的後方壁面4係與主要排放導管Μ 接觸。 二氧化碳的萃取係說明如下。例如為空氣的氣體通過 壁面1的表面上。二氧化碳將被碳酸酐所吸收,且通過壁 D 面1進入位於處理室8前方隔室20中的液體内。壁面1 放置碳酸酐3的部份係藉滲透性或半滲透性薄膜,像是半 滲透性塑膠膜或脂類薄膜以形成。薄膜可以掺雜以離子載 體以提供離子傳導管道。液體係藉泵浦22以循環進入後 方隔室21。二氧化碳係從後方隔室21通過後方壁面4以 進入主要排放導管24。後方壁面4亦係藉滲透性或半滲透 性薄膜,像是脂類薄膜以形成。在此方法過程中,大氣壓 力P!係高於前方隔室20内的壓力P2,亦即Ρι>ρ2 ^後方 隔室21内的壓力I亦高於前方隔室2〇内的壓力也就 7 200934756 是P3> Pz。後方隔室21内的壓力P3亦高於主要排玫導管 24内的壓力P4。 1克的碳酸酐每秒鐘可處理10莫耳的二氧化碳,其等 於44〇克的二氧化碳。在正常的空氣中,每立方米係有約 34〇毫升的二氧化碳’其等於每立方米0.61克的二氧化唆。 結果’ 1克的碳酸酐每秒鐘可處理70立方米空氣内的_氧 化碳。 ❹ ❹ 前方隔室20内的酸鹼值較佳係超過7〇β用於前方隔 室20内的適當酸鹼值可以例如是74。當酸鹼值超過7時" 二氧化碳將更容易溶解於前方隔室2〇(萃取隔室)内的水相 中。破酸酐係用》此處以將=氧化碳轉換成可立即溶解在 液體内的碳酸氫鹽。 參考圖2,壁面1伤莸始&迎,』 係藉碇轉翼片5以形成且係旋轉翼 片5的一部份。如圖3Φ路国- u 發電廠6的旋轉翼片5二:,翼片5可以是風力 應瞭解的是壁面1可藉旋轉翼片 5以外的事物以形成。装 曰從轉異片 構的-部份。例如其被風所移動的固定結 氣的氣流下的任何物::二排氣煙-或能夠曝露於像是空 轉翼二3:圖所3;’:轉翼:5可以是風力發電廠6之旋 轉轴係可旋轉地安轉翼片係安裝在轉轴27上。 如圖4與圖5;戶t 29支撐的外罩3〇上。 數個處理室8相通以不主要排放導管24係引導至可與 再參考圖2,主排敌X用*於一氧化碳萃取的主排放導管25。 導管25係從翼片5的外侧部份沿著旋 8 200934756 轉翼片5延伸且向上通過旋轉翼片5的轉軸27。主排放導 管25可以連接至設置於風力發電廠6結構内的低麗/真空 來源26。低壓來源26例如可以是泵浦或風扇。如圖3中 所示,二氧化碳可以視需要從低壓來源26經由其他導管 28 ’且最後到達其中二氡化碳係用於製造曱醇方法之燃料 電池9中。燃料電池9因此係連接至壁面1,以使經由壁 面1從空氣中所萃取的二氧化碳可從壁面1輸送至燃料電 池9。在前文中所揭示的具體實例中,壁面1係經由導管 24、25與28連接至燃料電池9以及低壓來源26。不過, 應可瞭解的是從壁面丨至燃料電池9的連接或溝通管線應 以不同於前文中所揭示者的方式來設計。例如,當使用低 壓來源26時,低壓來源26不必然得設置於風力發電廠6 的結構内。 從空氣中所萃取出的二氧化碳可用於在其中使用電能 以將水與二氧化碳轉化成甲醇的化學反應中製造曱醇,亦 ❹即電流+ C〇2 + H2〇~>CH3〇H(該方法於此係以簡化形式表 丁實際上3亥方法可U包括例如4 #令間化合物的形 成)。當壁面1係藉風力發電廠6的旋轉翼片5以形成時, 從風力發電廠6所得到的電能可用於其中水與二氧化碳係 轉化成甲醇的方法中。此外,電能可來自風力發電廠6以 外的其他來源。例如,其可來自輸電幹線。 為了製造甲醇,可以使用燃料電池9。在一製造甲醇 的方法中,燃料電池9係以相對於其正常操作模式為逆向 9 200934756 一種製造曱醇的方法現將參考圖6以解釋。在圖6中 可見到,所示之燃料電池9係具有陽極15與陰極16。陽 極15與陰極16係藉薄膜17以分隔。電路係藉編號18以 表示。為了製造曱醇,二氧化碳與水係經由燃料電池9上 的開口 11投入燃料電池9内。電流係在電路18處加入。 在陰極侧上’水係經由開口 13以加入,而I則係經由開 口 14以離開(應瞭解的是圖6僅是概略表示)。在圖6中, 甲醇(CHgOH)係經由開口 12以離開燃料電池。 應瞭解的是該方法亦可以與圖7中所示者相反的方向 進行。在圖7中’其係顯示甲醇如何經由開口 12以供應 至燃料電池9中。在所產生的反應中,電流係在電路18 中產生。 旋轉翼片5係分隔成數個在旋轉翼片5徑向上彼此分 離的處理室8,每一個處理室8係具有碳酸酐配置/固定於 其上的壁面1,以使每一個處理室8可萃取二氧化碳。若 有需要,可採取步驟以降低處理室内的壓力。 應瞭解的是本發明亦可從一種用於製造甲酵的配置的 觀點來描述,其係包含一壁面1,其具有碳酸酐3固定於 其上的表面2,以使二氧化碳可例如從空氣(但亦可從其他 氣體或從混雜其他氣體的空氣)中萃取出。此配置係含有— 連結至壁面1的燃料電池9,以及一連結至燃料電池9的 電能來源。電能來源可以例如是風力發電廠6,但其他的 電能來源亦是可能的。 現將參考圖4以解釋本發明的一觀點。在圖4中,於 200934756 萃取室19内所顯示液體的循環係以逆時針方向進行。 鄰近大氣的前方萃取室中,液體然後將以箭頭c的方向在 動。旋轉翼片5的配置較佳係使旋轉翼片5穿過空氣= 動時,空氣係以箭頭A的方向相對於旋轉翼片移動以使 可在正確的方向上協助壓迫萃取冑19内的流體。例如在 一風力發電廠中,風相對於旋轉翼片的運動方向可預先决 定且處理t 8的定向係使風有助於每個處理室8内^ 循環。[Embodiment] For the production of methanol, the surface of the wall is provided with a wall y z having a carbonic acid anhydride 3 disposed thereon (e.g., fixed). Carbonic anhydride is an enzyme that has the ability to remove carbon dioxide from a gas stream, such as an air stream. A method for removing carbon dioxide from air is disclosed, for example, in U.S. Patent No. 6,143,556, the disclosure of which is incorporated herein by reference. In the method of the present invention, the surface 2 of the kneading surface 1 is exposed to air blL. Carbonic acid anhydride 3 is extended. Second, the gas anhydride 3 is used in this configuration to remove carbon dioxide from the gas stream. 6 200934756 The carbon dioxide obtained here is subsequently used to make methanol. As shown in Fig. 1, the wall surface on the surface on which the carbonic anhydride 3 is placed] will constitute the outer surface of the processing chamber 8 having the extraction chamber 19 for carbon dioxide extraction. The extraction chamber 19 can be partitioned into a front compartment 20 and a rear compartment 21, and the front compartment 20 is located as an extraction liquid. The liquid of the extraction chamber can be maintained by the pump 22 "the liquid circulation between the circulation compartment 20 and the rear compartment 21. The pressure of the helium liquid in the rear compartment should preferably be higher than the pressure in the front compartment 2". Purpose, the rear/, then between 20 and 21, a flow restriction 23 can be formed. The liquid must pass through the flow restriction 23 to enter the front compartment. The liquid in the extraction chamber 19 is an aqueous phosphate buffer system, that is, based on The liquid may contain an antifreeze. The rear wall 4 of the treatment chamber 8 is in contact with the main discharge conduit 。. The extraction of carbon dioxide is described below. For example, the gas of air passes through the surface of the wall 1. The carbon dioxide will be replaced by carbonic anhydride. Absorbs and enters the liquid in the compartment 20 in the front of the processing chamber 8 through the wall D. The portion of the wall 1 in which the carbonic anhydride 3 is placed is a permeable or semipermeable membrane such as a semi-permeable plastic film or grease. A film-like film is formed. The film may be doped with an ion carrier to provide an ion-conducting conduit. The liquid system is pumped into the rear compartment 21 by a pump 22. The carbon dioxide is passed from the rear compartment 21 through the rear wall 4 to enter The main discharge conduit 24. The rear wall surface 4 is also formed by a permeable or semi-permeable membrane, such as a lipid film. During this process, the atmospheric pressure P! is higher than the pressure P2 in the front compartment 20, That is, the pressure I in the rear compartment 21 is also higher than the pressure in the front compartment 2〇. 7 200934756 is P3> Pz. The pressure P3 in the rear compartment 21 is also higher than that in the main duct 24 Pressure P4. 1 gram of carbonic acid anhydride can process 10 moles of carbon dioxide per second, which is equal to 44 grams of carbon dioxide. In normal air, there are about 34 milliliters of carbon dioxide per cubic meter' which is equal to each cubic 0.61 g of cerium oxide. Results '1 gram of carbonic anhydride can process 70 cubic meters of _ carbon monoxide per second. ❹ 酸 The pH in the front compartment 20 is preferably more than 7 〇β. The appropriate pH value in the front compartment 20 can be, for example, 74. When the pH value exceeds 7, the carbon dioxide will be more soluble in the aqueous phase in the front compartment 2 (extraction compartment). Here, the conversion of = carbon oxide into carbon that can be dissolved immediately in the liquid Hydrogen salt. Referring to Fig. 2, the wall 1 is smashed and swayed to form a part of the rotating blade 5. As shown in Fig. 3, the rotating wing of the road country - u power plant 6 Sheet 5 2: The flap 5 may be windy. It should be understood that the wall 1 may be formed by something other than the rotating flap 5. The mounting is a part of the rotating disc, for example, a fixed knot that is moved by the wind. Anything under the airflow of air:: two exhaust smoke - or can be exposed to an air-wing rotor 2: Figure 3; ': rotor: 5 can be a rotating shaft of a wind power plant 6 rotatably The fins are mounted on the rotating shaft 27. As shown in Fig. 4 and Fig. 5, the outer cover 3 supported by the household t 29 is connected. The plurality of processing chambers 8 communicate with each other so as not to be mainly guided by the discharge duct 24, and can be referred to FIG. The main discharge conduit 25 is extracted from the carbon monoxide. The duct 25 extends from the outer portion of the airfoil 5 along the rotary ring 5 200934756 and extends upwardly through the shaft 27 of the rotary vane 5. The main discharge conduit 25 can be connected to a low/vacuum source 26 disposed within the structure of the wind power plant 6. The low pressure source 26 can be, for example, a pump or a fan. As shown in Figure 3, carbon dioxide can be passed from low pressure source 26 via other conduits 28' and ultimately to fuel cell 9 in which the carbon dioxide process is used to make the sterol process, as desired. The fuel cell 9 is thus connected to the wall surface 1 so that carbon dioxide extracted from the air via the wall 1 can be transported from the wall 1 to the fuel cell 9. In the specific example disclosed above, the wall 1 is connected to the fuel cell 9 and the low pressure source 26 via conduits 24, 25 and 28. However, it should be understood that the connection or communication line from the wall to the fuel cell 9 should be designed in a manner different from that disclosed above. For example, when a low pressure source 26 is used, the low pressure source 26 is not necessarily disposed within the structure of the wind power plant 6. The carbon dioxide extracted from the air can be used to produce sterols in a chemical reaction in which electrical energy is used to convert water and carbon dioxide into methanol, that is, current + C〇2 + H2〇~>CH3〇H (this method Herein, in a simplified form, the actual method can include, for example, the formation of a 4# intermetallic compound. When the wall 1 is formed by the rotary vanes 5 of the wind power plant 6, the electric energy obtained from the wind power plant 6 can be used in a method in which water and carbon dioxide are converted into methanol. In addition, electrical energy can come from other sources than the wind farm 6 . For example, it can come from a mains. For the production of methanol, a fuel cell 9 can be used. In a method of producing methanol, the fuel cell 9 is reversed with respect to its normal mode of operation. 9 200934756 A method of producing decyl alcohol will now be explained with reference to FIG. As seen in Figure 6, the illustrated fuel cell 9 has an anode 15 and a cathode 16. The anode 15 and the cathode 16 are separated by a film 17. The circuit is represented by the number 18. In order to produce sterol, carbon dioxide and water are introduced into the fuel cell 9 via the opening 11 in the fuel cell 9. Current is added at circuit 18. On the cathode side, the water system is introduced via the opening 13 and I is exited via the opening 14 (it is understood that Figure 6 is only schematically shown). In Figure 6, methanol (CHgOH) is passed through opening 12 to exit the fuel cell. It should be understood that the method can also be performed in the opposite direction to that shown in FIG. In Fig. 7, it shows how methanol is supplied to the fuel cell 9 via the opening 12. In the resulting reaction, a current is generated in circuit 18. The rotary vane 5 is divided into a plurality of processing chambers 8 which are separated from each other in the radial direction of the rotary vane 5, each of which has a wall surface 1 on which carbonic acid anhydride is disposed/fixed so that each of the processing chambers 8 can be extracted carbon dioxide. Steps can be taken to reduce the pressure in the chamber if needed. It will be appreciated that the invention may also be described from the point of view of a configuration for the manufacture of formazan, which comprises a wall 1 having a surface 2 to which the carbonic acid anhydride 3 is fixed, such that carbon dioxide can be, for example, from air ( However, it can also be extracted from other gases or from air mixed with other gases. This configuration contains a fuel cell 9 coupled to wall 1 and a source of electrical energy coupled to fuel cell 9. The source of electrical energy may for example be a wind power plant 6, but other sources of electrical energy are also possible. Reference will now be made to Figure 4 to explain one aspect of the present invention. In Fig. 4, the circulation of the liquid shown in the extraction chamber 19 in 200934756 is performed in a counterclockwise direction. In the forward extraction chamber adjacent to the atmosphere, the liquid will then move in the direction of arrow c. The configuration of the rotary vane 5 is preferably such that when the rotary vane 5 passes through the air = moving, the air moves relative to the rotary vane in the direction of arrow A to assist in compressing the fluid in the extraction crucible 19 in the correct direction. . For example, in a wind power plant, the direction of motion of the wind relative to the rotating fins can be predetermined and the orientation of the treatment of t 8 is such that the wind assists in the circulation of each of the processing chambers 8.

/亏圖3,根據本發明的配置可包括燃料電池9以及 連接至燃料電池9的儲槽10,以便於燃料電池9中所製造 的曱醇可隨後儲存於儲槽丨〇中。 該配置的功能係說明如下。當空氣通過壁面1時,二 氧化碳將被吸收且用於製造"。一#定之實例現將參考 其奴酸酐3係放置在風力發電廠6的旋轉翼片5的具體實 例以解釋。當風吹送時’風力發電薇6的旋轉翼片5將曝 露於空氣流下。電能係藉風力發電廠以產生且二氧化碳係 同時沿著旋轉翼片5以萃取出。一或多個導管24、25、28 可從旋轉翼片5引導至二氧化碳可於其中被轉換成甲醇的 燃料電池9。風力發電廠6所產生電力的一部份將用於一 反應’其中萃取出的二氧化碳將用於製造隨後可加以儲存 的甲醇。 在本發明的某些具體實例中,其對電能的需求可加以 •no·、、]例如’可以監測一或多個指標以決定其他地方是否 需要電能。此一指標例如可以是電價。電價的提高可顯示 11 200934756 對電力的需求已增強。當已顯示對電力的高度需求時,可 將儲存的甲醇用於製造電力,以使電力可在對電力的需求 高時製造出來。 ❹ ❿ 參考圖2,其係顯示一具體實例,其中旋轉翼片5係 分隔成複數個在旋轉翼片5徑向上彼此分離的處理室8^ 每一個處理室8係具有碳酸酐3配置/固定於其上的壁面i, 以使每-個處理室8可萃取二氧化碳。由於處理室8含有 液體,#只有|一處理室沿著整個旋轉翼片延伸時,液壓 將變得非所欲地间’液柱將升高且離心、力將使問題更為嚴 重*使用數個處理室8時,每一個處理室内的液體可與 其他處理室内的液體分隔。如此,可維持在較低液壓。 本發明亦可能應用在位於其中二氧化碳含量非常高的 環境内的固定表面上,像是1的排氣導管内。當然,亦 可考慮將旋轉翼片放置在此環境内。 藉著使用碳酸酐以從空氣中萃取出二氧化碳,其可提 供-實際上取之不盡的用於甲醇生產的二氧化碳來源,此 係因為地球大氣内的二氧化碳總量係非常地高。當使用碳 酸酐的原則係與風力發電I结合時,此意謂由風力發電廠 斤產生的電此可用於其中二氧化碳被轉化成甲醇的方法 :。此意謂甲醇可在非常低的費用下製造。在此方法中所 製造的甲料料當風不在吹動時用於產生電能。此 到:能的更可靠供應,因為從風力發電廠所得到的能量可 Ik時間更均勻地分配。 【圖式簡單說明】 12 200934756 圖1係本發明之概略圖。 圖2係顯示本發明之一具體實例,其中本發明係應用 於旋轉翼片上。 圖3係圖示本發明如何應用在風力發電廠上。 圖4係與圖丨所示者類似的截面圖,但更清楚地顯示 二氧化碳的排放路徑。 圖5係圖4所示之處理室的側視圖。 圖6係圖示於燃料電池内的方法。 0 ® 7係相對於圖6的方法以反向方式運作之方法的概 略圖。 【主要元件符號說明】 壁面 3 4/ Loss Figure 3, the configuration according to the present invention may include a fuel cell 9 and a reservoir 10 connected to the fuel cell 9 so that the sterol produced in the fuel cell 9 can be subsequently stored in the sump. The function of this configuration is explained below. When air passes through wall 1, carbon dioxide will be absorbed and used to make ". An example of this will now be explained with reference to a specific example in which the slave anhydride 3 system is placed in the rotary vane 5 of the wind power plant 6. When the wind blows, the rotating vane 5 of the wind power generator 6 will be exposed to the air flow. The electrical energy is generated by the wind power plant and the carbon dioxide is simultaneously extracted along the rotating fins 5. One or more conduits 24, 25, 28 can be directed from the rotating vanes 5 to a fuel cell 9 in which carbon dioxide can be converted to methanol. A portion of the electricity generated by the wind power plant 6 will be used for a reaction' wherein the extracted carbon dioxide will be used to make methanol that can be subsequently stored. In some embodiments of the invention, its demand for electrical energy can be • no,, for example, ' can monitor one or more indicators to determine if electrical energy is needed elsewhere. This indicator can be, for example, a price of electricity. The increase in electricity prices can show 11 200934756 The demand for electricity has increased. When a high demand for electricity has been shown, the stored methanol can be used to make electricity so that the electricity can be manufactured when the demand for electricity is high. Referring to Fig. 2, there is shown a specific example in which the rotary vane 5 is divided into a plurality of processing chambers 8 which are radially separated from each other in the rotary vane 5. Each of the processing chambers 8 has a carbonic acid anhydride 3 configuration/fixation. The wall i on it is such that each of the processing chambers 8 can extract carbon dioxide. Since the processing chamber 8 contains liquid, #only|a processing chamber extends along the entire rotating fin, the hydraulic pressure will become undesired. 'The liquid column will rise and the centrifugal force will make the problem worse. In the processing chamber 8, the liquid in each processing chamber can be separated from the liquid in the other processing chambers. In this way, it can be maintained at a lower hydraulic pressure. The invention may also be applied to a fixed surface located in an environment in which the carbon dioxide content is very high, such as an exhaust duct of one. Of course, it is also conceivable to place the rotating fins in this environment. By using carbonic anhydride to extract carbon dioxide from the air, it provides an inexhaustible source of carbon dioxide for methanol production because the total amount of carbon dioxide in the Earth's atmosphere is very high. When the principle of using carbonic acid anhydride is combined with wind power generation I, this means that the electricity generated by the wind power plant can be used for a method in which carbon dioxide is converted into methanol: This means that methanol can be produced at very low cost. The material A produced in this method is used to generate electrical energy when the wind is not blowing. This is: a more reliable supply of energy, because the energy obtained from the wind power plant can be more evenly distributed in Ik time. BRIEF DESCRIPTION OF THE DRAWINGS 12 200934756 FIG. 1 is a schematic view of the present invention. Fig. 2 shows an embodiment of the invention in which the invention is applied to a rotary vane. Figure 3 illustrates how the invention can be applied to a wind power plant. Fig. 4 is a cross-sectional view similar to that shown in Fig. 2, but showing the carbon dioxide emission path more clearly. Figure 5 is a side elevational view of the processing chamber shown in Figure 4. Figure 6 is a diagram illustrating a method within a fuel cell. 0 ® 7 is an overview of the method of operating in a reverse manner with respect to the method of Figure 6. [Main component symbol description] Wall 3 4

8 9 10 表面 碳酸酐 後方壁面 旋轉翼片 風力發電廠 處理室 燃料電池 儲槽 11 開口 12 開口 13 開口 14 開口 13 200934756 15 陽極 16 陰極 17 薄膜 18 電路 19 萃取室 20 前方隔室 21 後方隔室 22 泵浦 ® 23流動限制 24 主要排放導管 25 主排放導管 26 低壓/真空來源 27 轉軸 28 其他導管 29 機柱 30 外罩 ❹ 148 9 10 Surface Carbonic Acid Rear Wall Rotating Airfoil Wind Power Plant Processing Room Fuel Cell Storage Tank 11 Opening 12 Opening 13 Opening 14 Opening 13 200934756 15 Anode 16 Cathode 17 Membrane 18 Circuit 19 Extraction Chamber 20 Front Compartment 21 Rear Compartment 22 Pump® 23 Flow Limit 24 Main Emission Catheter 25 Main Emission Conduit 26 Low Pressure/Vacuum Source 27 Shaft 28 Other Catheters 29 Post 30 Cover ❹ 14

Claims (1)

200934756 十、申請專利範圍: 1'種製造甲醇的方法,其所包含之步驟為提供藉風 力發電廠(6)的旋轉翼片(5)所形成的壁面,壁面(1)具有 其上配置著碳酸酐(3)的表面(2),將壁面〇)的表面(2)曝露 於氣流中,且使用碳酸酐(3)以從氣流中移除二氧化碳,且 將所知到的二氧化碳用在其中電能係用於將水與二氧化碳 轉化成曱醇的化學反應中以製造曱醇。 2·如咕求項1之方法,其中來自風力發電廠(6)的電能 係用於將水與二氧化碳轉化成甲醇。 3. 如請求項1之方法,其中該氣體係空氣。 4. 如明求項1-3項中任一項之方法,其中來自風力發 電廠的電能係用於將水與二氧化碳轉化成甲醇。 5:如請求項i之方法’其中旋轉翼片⑴係分隔成複數 個在旋轉翼片(5)徑向上彼此分離的處理室(8),每一個處理 室(8)係具有碳酸酐(3)配置於其上的壁面(1),以使每一個 _ 處理室(8)可萃取二氧化碳。 6.如响求項13項中任一項之方法,其中所得到的甲 醇隨後用於燃料電池中以產生電能 ^ 種用於製造甲醇的配置,其包含藉風力發電廠(6) 7旋轉翼片(5)所形成的壁面⑴,壁面⑴具有其上配置著 厌夂肝[3)的表*⑺,以使二氧化碳可從像是空氣中萃取 出 氧化碳可於其中轉化成甲醇的燃料電地(9),該燃料 電池(9)係連結至辟丨 IV ^ 至&面(1)、以使卒取出的二氧化碳可輸送至 燃料電池(9)、以及聯結至燃料電池(9)的電能來源。 15 200934756 8.如請求項7之配置,其中旋轉翼片(5)係分隔成複數 個在旋轉翼片(5)徑向上彼此分離的處理室(8),每一個處理 室(8)係具有碳酸酐(3)配置於其上的壁面(1),以使每一個 處理室(8)可萃取二氧化碳。 十一、圖式: 如次頁 ❹200934756 X. Patent application scope: 1' method for producing methanol, comprising the steps of providing a wall surface formed by a rotating fin (5) of a wind power plant (6) having a wall surface (1) disposed thereon The surface (2) of the carbonic anhydride (3) exposes the surface (2) of the wall surface) to the gas stream, and the carbonic anhydride (3) is used to remove carbon dioxide from the gas stream, and the known carbon dioxide is used therein. Electrical energy is used in the chemical reaction of converting water and carbon dioxide into sterols to produce sterols. 2. The method of claim 1, wherein the electrical energy from the wind power plant (6) is used to convert water and carbon dioxide to methanol. 3. The method of claim 1, wherein the gas system is air. 4. The method of any of clauses 1 to 3, wherein the electrical energy from the wind power plant is used to convert water and carbon dioxide to methanol. 5: The method of claim i wherein the rotating fin (1) is divided into a plurality of processing chambers (8) separated from each other in the radial direction of the rotating fins (5), each of the processing chambers (8) having carbonic anhydride (3) The wall surface (1) disposed thereon so that each of the processing chambers (8) can extract carbon dioxide. 6. The method of any one of clause 13, wherein the obtained methanol is subsequently used in a fuel cell to produce electrical energy, a configuration for producing methanol, comprising a wind turbine (6) 7 rotating wing The wall surface (1) formed by the sheet (5), the wall surface (1) having a table*(7) on which the anaesthetic liver [3] is disposed, so that carbon dioxide can be extracted from air like carbon, which can be converted into methanol fuel. Ground (9), the fuel cell (9) is connected to the 丨 丨 IV ^ to & face (1), so that the carbon dioxide that is taken out of the stroke can be transported to the fuel cell (9), and coupled to the fuel cell (9) Source of electrical energy. 15 200934756 8. The configuration of claim 7, wherein the rotating vane (5) is divided into a plurality of processing chambers (8) separated from each other in the radial direction of the rotating fins (5), each processing chamber (8) having The carbonic acid anhydride (3) is disposed on the wall surface (1) thereon so that each of the processing chambers (8) can extract carbon dioxide. XI. Schema: as the next page ❹ 1616
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